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Computation of Material Density: Gold Exemplar

George Singer
September 25, 2014
=
mass
volume
=
#Atoms in the unit cell Mass of an atom
Volume of the cell
=
nM
V
c
#Atoms in the unit cell, n = 4 (FCC)
Mass of an atom: M =
Atomic Weight (g/mol)
Avogadro number (atoms/mol)
=
A
N
A
A = Atomic weight (gold) = 196.97 g/mol
Avogadro number, N
A
= 6.022 10
23
atoms/mol
As shown earlier, for FCC, cell width, a = 2

2R
The Volume of the cell, V
c
= a
3
= (2

2R)
3
(since Gold is FCC)
The Atomic Radius (

Angstr om = 10
8
cm), R for Gold= 1.44

A =
1.44 10
8
cm
=
nM
V
c
=
n
A
N
A
a
3
=
nA
(2

2R)
3
N
A
=
4196.97
(
2

21.4410
8
)
3
6.02210
23
= 19.4 g/cm
3
(3 S.F.)
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