CHEMICAL KINETICS ition ean be defined as the change in concentration of a |, are the concentrations of R and P respectively at 1 [P}, are the concentrations of Rand P respectively st Average rate ofa reaction is defined asthe change in concentration of a canbe determined by dividing the change in phase occurs i sreased by 5X 10? mole Lin 10 second, Calcutate (D the rate of appearance of B ar ‘the rate of disappearance of 7. What are elementary and complex reactions? ‘The reactions taking place in one step are called elementary reactions ‘whereas when a sequence of elementary reactions , called mechanism, gives us the product , itis called ‘complex reaction.‘© Goneeniration of eactants (pressure in case of gases) s_ eapeermate, © {rkasenue of Capt o Catalyst © Naktis of tackent © Sud foce For a general reaction @N+AR—reC+ dD Where, a, 6, ¢, d= Stoichiometric coefficients of reactants and products Rate of reaction generally increases when reactant ay not be equal to 4 and b «> ales anes ig The sumof powers of expression is ealled the order of t Rode vom CK) ws debinad on He Aske. of deachion Uh oth dunclank ve une ch respect to a reactant. How will the entration of this reactant is ions of both A and B action becomes twenty seven ‘times when the concentration of A is increased three times, What is the order of the reaction? ‘Zero order react Rate of reaction is independent of the concentration of the reactants ‘on ot platinum surface at high k “5, What do you understand by preudo firstorder reactions? Give two =? examples of such reactions. Reactions which appears tobe higher order but actualy follows rst order kinetics a ‘Reactions tha are not fis-order reactions but which become first-order uo fis-order reactions. pseudo first-order reaction. sal this case is so large tht it can be 1 Tate equation becomes Rate = # ICH,COOCH.1, and the reaction. act like a first-order reaction. 12, Consider the equation 2 NO (q) + 212 (g) -9N2 (g) +2120 (2)‘The rate aw for this equation is first order with respect to H2 and 21H, +, second order with respect to NO. write the rate law for this reaction. Unit of Rate Constant Moleculasty ~ 2 (Bimolecular) + Fora general reaction aA +b cC+ dD Zero order reaction | 0 Integrated rate equations Zero order reactions First order reaction | od Molecularity~ 1 (Unimolecular) uut 9 a vdeo yeukd wth ef © = (mbit) a