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B.
()(Cellulose fibers)
:
(cotton fiber)(Linen)(
(rayon) )(Tencel)(Modal)(Acetate
)
()-OH(
):
()(Protein fibers)
()
()
TPAEGBHT
(2)(Polyamide fibers)
(3)(Polyacrylonitrile fibers)
(-SO3H)(-CONH2)
()
(Site)
1.
(energy)
(1)
/(kcal/mol)
(Van der walls)
(2)
/(kcal/mol)
2.
(1)
()
WD
()
(Chrome)
(Chrome lake)
(2)
(A)
1845
1856
1858
1860
1865
1873
1876
1880
1884
1887
1890
1901
1912
1915
1921
1928
1929
1930
1938
1956
1971
Perkin
Aniline Black
alizarin
Witt
Orange
Bayer
Para Red
Congo Red
Primuline Red
Indanthrene
Naphthol AS
Indigosol
phthalocyanine
Rapidogen
Pigment Resin Color
benzidine--naphthylamine
B
(1)Dyeing as a mass transfer process
DYEBATH
FIBER
DYE
DYE
INTERFACE
(2)
DF
S[D]F
[D]S
(1)
SO3NaCOOH
2Acid dyes
pH=4.2~4.8pH
pH
WH2NWCOOH
FiberNH2 HSO3Dye
Fiber with
basic amino
group
Dye with
acidic sulfonic
acid group
FiberNH3SO3Dye
(3)
(Acid Mordant dyes and Metal complex Acid dyes)
(
)
11
1211
12
11
12Acid Violet 78
(
-----)
(A)
()
(1)(2)
(A)
(a)
2H
R-S-S-R
2R-S-H
2R-SNa
(b)
2 R S Na
()
O
H2O
R S S R + 2 NaOH
()
SDTX
D
S
T
X
6~7
5
(1)
(dichlorotriazine)
(1)
(E)(HS)
()(SE)
(A)
()
-OH-NH2-NHR-NO2
F
(
)
(B)
(Van
der Waals)
()
(8) (Pigments)
Pigments + Binder
() ()
Printing
()
OH
ester
ether
A
1OH
2DMDHEU2D
3BTCA
OH
(B)
(1):
-OH-NH2-COOH
(2) :
(C)
(1):
(2):
(D)
(1)-
(alkylamine)(dicyano
diamide)
15010
Bancroft
(2)-
(TiCl4)(SbCl3)
(3)THPC
(Proban)(trimethylol
melamine)
140
4~5