1. Boyles law: PV = constant (at constant T and n) 2. Charie's ha V/T = constant (at constant P and n) 4. Gay Lussac-Chartes’s law: P/T — constant (at constant V and n) 4. Avogndro’s hypothesis: Vex No. of molecules (at constant pressure and temperature) 5. Gas equation: PV=nrT o pv (where d is density of gas) 6, Graham's (at constant P and 7) MP MP2 7. Dalton’s law of partial pressure: Py= Py +P p+ Pct and P’, = Pp x mole fraction of A 4. Absolute density: (at constant T) d= <255- exqrossed usually ing hse" 9. Vapour density: Molecular weight = Wapour density x 2 (For gases only) 10. Different speed terms for molecular motion: BY yy = VW, where way is average speed nM KT ins = Wigs Wht tans i8 Foot mean square speed RT where upp i amp = most probable speed nar # May Stigus ? 5s L128 5 1224Kinetic equation: PV=(L/3)ri.t.tns (re is mass of one molecule and m is umber of molecule) 12. Kinetic energy: KE Jmol = 587 Average K.E, or K.E/molecul 13, ‘Van der Waals’ Equation: (kis Boltzman constant) [rego RT (for 1 mole) Pate yond) nr (form mole) ra «is van der Waals’ constant for attraction ; is van der Waals’ constant for volume. Als b= 4:Ner 14, Boyle's temperature (1): 15, Critical constants fa « ig hoe Ty, Peand Ve are critical temperature, critical pressure and ential volume respectively. 16. Inversion temperature (T)): ma ‘Rb 1. Law of corre: iding state: Tr 4 Jon P,, Vand 7; are reduced pressure, reduced volume and reduced temperature respectively. 18. Mean free path (3): Vou 3b T= (c is molecular diameter)