Sol Aits 2013 FT II Jeea Paper 2

AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13
JEE(Advanced)-2013
FIITJEE
ANSWERS, HINTS & SOLUTIONS

FULL TEST II
(Paper 2)
ALL INDIA TEST SERIES
From Long Term Classroom Programs and Medium / Short Classroom Program 4 in Top 10, 10 in Top 20, 43 in Top
100, 75 in Top 200, 159 in Top 500 Ranks & 3542 t o t a l s e l e c t i o n s i n I I T - J E E 2 0 1 2
ANSWERS KEY
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
ANSWER
ANSWER
ANSWER
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
(A) (r)
(B) (p)
(C) (q), (s)
(D) (q), (s)
(A) (s)
(B) (q)
(C) (r)
(D) (q)
(A) (p, q, t)
(B) (p, r, s)
(C) (p, q, t)
(D) (q, t)
(A) (q, r)
(B) (q, r)
(C) (r, s)
(D) (p, t)
(A) (s)
(B) (t)
(C) (p)
(D) (q)
(A) (r)
(B) (r)
(C) (p)
(D) (r)
1.
2.
3.
4.
5.
1.
2.
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Physics
PART I
SECTION A
3.
t
t
q = 2CV 1 e 2CR ; Wb = 2CV 2 1 e 2CR
4.
LC = 4/200 = 0.02
5.
Gravitational potential inside a shell = constant
6.
In nuclear, nuclear force play major role. They are charge independent forces.
SECTION C
1.
Current is 2 = 0.1 A
current in circuit = 0.2 A
equivalent resistance about AB = 5
e = I R = 1 volts
and also
e=B A V
e
1
V=
=
= 5m / s .
BA 2 0.1
2.
Force on the rod

F Fm = ma
BA
F
(BAV E) = ma
r
BAE B2 A2 V mdV
F+
=
r
r
dt
solving
B2 A 2
BAE
F = mV0 sin(t) +
V0 cos t
r
r
Power expended by force is
B2 A 2 2
BAE
FV = mV02 sin(t)cos(t) +
V0 cos2 t
V0 cos t
r
r
Its average over the cycle is
B2 A 2 V02
.
2r
3.
Let A1 and A2 be the crosssectional area of the pipe at points P and Q respectively.
Let v1 and v2 be the velocities of oil at the points P and Q respectively.
By conservation of mass,
Q = A1v1 = A2v2
A
v 2 = 1 (v1 ) = 4v1
A2
Applying Bernoulliss equation between points P and Q, we have
1 2
1
v1 = P2 + v 22
2
2
1
2
P2 = P1 + (v1 v 22 )
2
1
= P1 + 0.9[16 256] 103
2
= 280 103 + ( 108) 103
P2 = 172 103 Nm2
P2 = 172 (KN m2).
P1 +
4.
P0 v 0
4
P0 v 0
Pv
= P0 v 0
= ( 4 ) 0 0 ; Put = 3.14
4
4
0.86
=
P0 v 0 = ( 0.22 ) (P0 v 0 )
4
Wnet = ( 2P0 v 0 ) (P0 v 0 )

Wnet
Wnet
Now,
Pv
T1 = 0 0
R
4P0 v 0
T2 =
Thus,
R
2P v
T3 = 0 0
R
U12 = 1
3R
[T2 T1 ]
2
U23 = 1
3R
[T3 T2 ]
2
U31 = 1
3R
[T1 T3 ]
2
Q12 = ( 4.5 )(P0 v 0 ) + (1.22)(P0 v 0 ) = ( 5.72)(P0 v 0 )

Q23 = 3P0 v 0 + 0 = 3 (P0 v 0 )
Q31 = 1.5 (P0 v 0 ) (P0 v 0 ) = 2.5 (P0 v 0 )
Thus efficiency =
=
0.22 (P0 v 0 )
( 5.72 ) (P0 v 0 )
Wnet
+ veheat
= 0.04
Thus efficiency is 4%
5.
The total momentum of the system in the horizontal

direction is conserved. We draw the F.B.D., assuming the
displacement of the block to be x1 and x2 in opposite
directions, and the total extension x is given by,
x = x1 + x2
and m1x1 = m2x2
d2 x
m1 21 = k(x1 + x 2 )
dt
m1
kx
x1
kx
m2
x2
d2 x 2
= k(x1 + x 2 )
dt 2
after suitably manipulating the equations,
we get,
and
m2
d2 x 2
dt
k(m1 + m2 )
.x
m1m2
i.e. the frequency =
1 k(m1 + m2 )
2
m1m2
1 300(2 + 3)
2
23
2.5Hz .
number of complete oscillations in 1 minute =
60
= 24 .
2.5
Chemistry
PART II
SECTION A
1.
2.
Gem-dihalides on substitution by OH produces carbonyl compound, which will reacts with

2,4-DNP but 1,2-dichloroethane will give vic-diol.
MnO 4
+ Fe+2
0.1 M
0.01M
E0 MnO
2
4
R.P.
+8H
Mn+2
+ Fe +3
0.09 M
Mn+2
>E
0
+
R.P. H
H2
So permanganate electrode behave as cathode.

Ecell = 1.51 0 = 1.51.
Using Nernsts equation :- (n = 5)
EMnO
Mn+2
MnO 4 H+
0.059
log
= 1.51 +
5
Mn+2
= 1.51 + 0.11 = 1.4 V

3.
Amine inversion will change the configuration of N only and not that of carbon.
5.
Compound (A) will first undergo Cannizzaro reaction and the product B then will undergo esterification.
6.
NH + HCl
NH4 Cl ( s ) at room temperature.
3
5000.3
760RT
6000.2
760RT
0 Moles
150
120
760RT 760RT
30
120
0
760RT
760RT
Now total moles =
30
100 1
+
760RT 760RT
Total P = 130 RT
760RT 1.5
P in torr =
(Total volume = 1. 5 Litre)
130
= 86.66 torr
1.5
SECTION C
5.
(S)-2,3-dimethylpentane, (R)-2,3-dimethylpentane, (S)-3-methylhexane and (R)-3-methylhexane.
Mathematics
PART III
SECTION A
1.
1
1
1 1
f(x) = x + x +
2
4
2 2
3/4
I=
g(x) dx let x = t +
1/ 4
1
I=
2
1/ 4
1/ 4
g t + dt
2
3

1
1
1
1 1
1
1
1
f t + = t3 + t + f f t + = t3 + t + t3 + t +
4
4
4 2
2
4
2
2
1
1
g t + = p(t) + where p(t) + p(t) = 0
2
2
1/ 4
I=
1/ 4
2.
1
1
dt =
2
4
Required area is
2 ex ln x + 1 1 (x 1)2 dx
0
1
1
n
r 1 r
1 n ( r
n
t
=
Cr 4 3r )
C
C
3
lim
r
t
n
n
n
n
5
5
r =1
r =1
t =o
n
n
1
1
n
n
Cr 4r
Cr 3r = lim n ( 5n 4n ) = 1 .
= lim n
n 5
n 5
r =1
r =1
3.
lim
4.
5.
In triangle OA1A2
2
1
2R 4
cos =
=
2
4
2R
2
2
R = 4+2 2
Also
2
2
( r + 1) ( r 1) = 4 + 2 2
4r = 4 + 2 2
1
r = 1 +
A8
A3
R /4 R
A1
A2
Vertex of octagen
O1
r
(r1)
1O
1 A2
R
3
f
= 2
2
3
f ' g' ( 2 ) = 1
2
f ' ( x ) = 25(2) ( 2x 3 )
24
4
sin x
3
3
3 7
f ' = g' ( 2 ) =
2 3
7
6.
Let the age of friends be a, ar, ar2, r > 1 and money distributed is x, xr, xr2 respectively.
(1 + r + r2)x = (a(1 + r + r2) + a)t
Also after 3 years ar2 + 3 = 2(a + 3)
a(r2 2) = 3
x + 105 = (a + 3)t and xr + 15 = (ar + 3)t (given)
(1 + r)x + 120 = (a(1 + r) + 6)t 2(a + 3)t = r2x 120 = 2x + 210
(r2 2)x = 330
Using (r2 2)x = 330, a(r2 2) = 3 x = 110a
110a + 105 = (a + 3)t 5(22a + 21) = (a + 3)t
and 110ar + 15 = (ar + 3)t 5(22ar + 3) = (ar + 3)t
22a + 21 a + 3
5ar = 7a + 6
=
22ar + 3 ar + 3
Where 5ar = 7a + 2(a(r2 2)) {Using a(r2 2) = 3}
3
2r2 5r + 3 = 0 r = . Hence a = 12 years
2
7.
Given cn = a1 + a2 + a3 + .. + an
where a1, a2, .., an are in A.P. with d = 2
and dn = b1 + b2 + b3 + + bn
where b1, b2, b3, .., bn are in A.P. with d = 2
Also (an, cn) lies on y = px2 + qx + r
Now cn = pan2 + qan + r
pan21
.. (1)
+ qan1 + r
cn 1 =
From (1) and (2), we get
cn cn 1 = p ( an2 an21 ) + q ( an an1 )
.. (2)
an = ( an an1 ) p ( an + an1 ) + q
.. (3)
an = p ( an + an1 )( an an1 ) + q ( an an1 )
( an an1 = d)
10.
y
at A, t = 1
x
1 9t 2
4
Slope of tangent at A, m =
= .
6t
3
Equation of tangent at A 3y + 4x + 2 = 0
Since tangent passes through the point B(t1) hence
3(t1 3t13) + 4(1 3t12) + 2 = 0
2
(t1 + 1)2(3t1 2) = 0 t1 =
3
2
1
B , .
9
3
y = t(1 3t2) t =
11.
Slope of tangents at x = 0 and m1 =
1
3
and m2 =
1
3
tan = .
3
SECTION B
2.
(A) We have f(x) =
1
lncos1 x
For domain of f(x), ln ( cos 1 x ) > 0 cos1 x > 1 and cos1 x

cos x cos 1 1 x < cos 1
Hence number of integers in the domain of f(x) are 2 i.e., 1 and 0
G
G
(B) Vector normal to the plane is n = i 3j + 2k and vector along the line is V = 2i + j 3k
G G
xv
236
7
Now sin = G G =
=
x v
14
14 14
Hence cosec = 2
4
(C) We have J =
(3 x
) tan ( 3 x 2 ) dx . Put (x + 5) = t, we get
5
1
2
2
J = ( 3 ( t 5 ) ) tan ( 3 ( t 5 ) ) dt
Now K =
( 6 6x + x
( 22 + 10t t
) tan ( 22 + 10t t 2 ) dt
) tan ( 6x x 2 6 ) dx . Put (x + 2) = z, we get
2
1
K=
( 6 6 ( z 2) + ( z 2) ) tan ( 6 ( z 2) ( z 2)
2
6 ) dz
( 22 10z + z
) tan ( 22 + 10z z2 ) dz
Hence (J + K) = 0
SECTION C
1.
7
1
A , 4, 0 , B 0, , 1 and C , 0, 8 .
2
3
56
Hence V =
18
10
2.
1+
(3
r 10
Cr + r 10 Cr
r =1
) =4
10
+ 10 29
= 1 and = 5
k>4
3.
n6
x=
C6 ( 31/ 3 )
y=
Cn 6 ( 31/ 3 )
( 41/ 3 )6
( 41/ 3 )x 6
and
x
1
n 12 / 3
1
= (12 ) n = 9
(12 )
=
y 12
9
4.
z2 + z 3 = 0
5.
Let y =
r =0
2n+1
2n+1
Cr =
2n+1
Cr
r =n +1
2y = 22n+1 y = 22n
n=3

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AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13

ANSWERS, HINTS & SOLUTIONS

ALL INDIA TEST SERIES

q = 2CV 1 e 2CR ; Wb = 2CV 2 1 e 2CR

Gravitational potential inside a shell = constant

Force on the rod

Wnet = ( 2P0 v 0 ) (P0 v 0 )

Q12 = ( 4.5 )(P0 v 0 ) + (1.22)(P0 v 0 ) = ( 5.72)(P0 v 0 )

The total momentum of the system in the horizontal

i.e. the frequency =

number of complete oscillations in 1 minute =

Gem-dihalides on substitution by OH produces carbonyl compound, which will reacts with

So permanganate electrode behave as cathode.

= 1.51 + 0.11 = 1.4 V

Now total moles =

(Total volume = 1. 5 Litre)

(S)-2,3-dimethylpentane, (R)-2,3-dimethylpentane, (S)-3-methylhexane and (R)-3-methylhexane.

g t + = p(t) + where p(t) + p(t) = 0

an = p ( an + an1 )( an an1 ) + q ( an an1 )

Slope of tangents at x = 0 and m1 =

(A) We have f(x) =

For domain of f(x), ln ( cos 1 x ) > 0 cos1 x > 1 and cos1 x

) tan ( 3 x 2 ) dx . Put (x + 5) = t, we get

) tan ( 6x x 2 6 ) dx . Put (x + 2) = z, we get

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