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Fundamentals of Metals and Alloys Theory
Fundamentals of Metals and Alloys Theory
Fig. 1.2. Lattice distortion at solid solutions formation: a - atomic radius of dissolving
metal is greater than atomic radius of a solvent in SSS; b - atomic radius of dissolving
metal is less than atomic radius of a solvent in SSS; c - formation of ISS.
Principles of crystallization
Crystallization is a metal and alloy conversion from liquid to solid state. This
transformation is accompanied by formation of certain crystal lattice. The beginning of
crystallization is accompanied by occurring of nucleus center in a melt. The further
increase of crystals quantity and their sizes begins from these centers.
The crystallization process is quantitatively characterized by nuclei generation rate
Vcc (measured in mm-3s-1) and solidification rate Vcg (measured in mm/s) - the fig. 1.3.
Fig. 1.4. Relationship between nuclei generation rate Vcc , solidification rate Vcg and
degree of alloy supercooling
I
1
o
t C
A
L
m
L+A
t2
10
20
30
3
0
t1
B + (A + B )
A + (A + B )
A
L+B
t oC
40
50
60
70
80
B
90 100
Fig. 1.5. The equilibrium diagram of the first kind (a) with relevant cooling curve (b)
The line ACB is called as a liquidus line. It is a geometrical place of points where
alloys crystallization begins. The crystals of component A crystallize from a liquid melt L
on a line AC. Crystallization of component A finishes on a line ADC. The crystals of
component B crystallize from a liquid melt L on a line BC. Crystallization of component
B finishes on a line DCE. The line DCE is called as a solidus line. The eutectic mixture
of crystals (A+B) is formed on a line DCE in any point at constant temperature. A point
C corresponds to alloy of eutectic composition. In this point the eutectic mixture (A+B)
crystallizes only. Alloys with components concentration more to the left of a point C are
called as hypoeutectic. Alloys with components concentration relevant to point C are
called as eutectic. Alloys with components concentration more to the right of a point C
are called as hypereutectic.
The amount and composition of phases in alloy is determined by a rule of cuts.
This rule can be used only in two-phase area of the diagram. Conode (horizontal line) is
carried out up to intersection with liquidus and solidus lines at temperature t 1 for alloy of
I-concentration in area BCE of diagram. The cut nt1 is taking as 100 %. According to the
rule of cuts for definition of the fluid phase amount qlp in percentage it is necessary: to
relate a cut mt1, opposite to a liquidus line, to all length of a cut and multiplicate it on
100%, i.e.
qp
mt 1
100% .
nt 1
Similarly the solid phase amount qsp can be determined in percentage by the ratio
of cuts mn and nt1:
qsp
mn
100% .
nt 1
The second part of cuts rule consists in following: the projections of conode
intersection points with liquidus and solidus lines on concentration axis give necessary
values of liquid phases and solid phases densities.
The equilibrium diagram of the second kind
This diagram describes crystallization of alloys with components, dissolved
unlimitedly in each other both in solid and in liquid state. Examples of such alloys: iron nickel, iron - chrome, copper - nickel. The equilibrium diagram of the second kind is
t,o C
C
3
t
2
D
E
0
10
20
30
40
50
B ,%
60
70
80
90
100
Fig. 1.6. The equilibrium diagram of the second kind. Line ACB - a liquidus, line ABD - a
solidus.
The equilibrium diagram of the third kind
This diagram describes crystallization of alloys with components, dissolved
unlimitedly in each other in liquid state. In a solid state they are dissolved limitedly and
form a eutectic at crystallization. Figure 1.7 illustrates the equilibrium diagram of the
second kind.
In this diagram the pure components A and B cant crystallize. Solid solution of
component A is called . Solid solution of component B is called . Line DCE shows the
moment when mechanical mixture of solid solutions crystals is formed during
crystallization of fluid phase with point C density. As solubility B in A can vary, line DK
reflects temperature dependence of abundant crystals extraction. II - phase enriched with
a component B.
t, oC
I
L+
L+
11
K
0
3
10
20
30
40
50
B ,%
60
F
70
80
90
100
Fig. 1.7. The equilibrium diagram of the third kind. Line ACB - a liquidus, line ADCEBa solidus. DCE- a line of eutectic transformation. DK- a line of a limited solubility of
component B in component A. EF- a line of a marginal solubility of component A in a
component B.
The equilibrium diagram of the fourth kind
The equilibrium diagram of the fourth kind characterizes alloys, which components
A and B can resolve unlimitedly in each other in liquid state. Those components are
insoluble in a solid state and form steady chemical combinations. The equilibrium
diagram of the fourth kind is shown in a fig. 1.8.
The line CE in a fig. 1.8 refers to chemical compound AnBm. A point C corresponds
to melting point of chemical compound AnBm. The diagram has 2 eutectic points D and
D. The constant melting point and fixed components ratio are typical to chemical
compound AnBm.
t ,o C
C
A
A n Bm
D
100% A
100% B