BINARY VAPOR LIQUID EQUILIBRIUM

Date
By

CheCalc.com

Chemical Engineering Calculations

10/08/14
CheCalc

User Input

Enter Binary Pair

Components
Antoine Equation Parameters
A
B
C
Molar Volume, V
Aij, Wilson Binary parameter
T x-y Diagram
Pressure

1
1-Propanol + Water
1
2
17.54
18.30
3166.38 3816.44
-80.15
-46.13
cm3/gmol
cal/gmol

PSIA

219
906.53

56
1396.64
P x-y Diagram
Temperature

20.0

Bubble

Bubble

Temperature (Deg F)

Dew

50.0
45.0
40.0
35.0
30.0
25.0
Pressure, PSIA
20.0
15.0
10.0
5.0
0.0
0.00

0.20

Change the vertical axis manually if graph does not appear properly
T x-y Chart Data
X

Y
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90

Temperature
F
0.00
228.0
0.37
206.3
0.41
204.6
0.43
203.9
0.45
203.5
0.47
203.5
0.50
203.9
0.55
205.1
0.62
207.5
0.75
212.4

P x-y Chart Data

X

Y
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90

0.00
0.36
0.40
0.42
0.45
0.48
0.51
0.57
0.64
0.77

0.40

Dew

0.60

0.8

1.00

1.00

222.2

Basis
- Vapor pressure is calculated using Antoine Equation :
Ln ( Pressure ( mmHg ) ) = A - B / ( Temperature ( K ) + C )
- Flash calculations are based on Modified Raoult's Law

1.00

1.00

250.0

Bubble

Dew

0.20

0.40

0.60

Pressure
PSIA
29.8
44.5
46.3
47.0
47.4
47.5
47.0
46.0
43.8
40.0

0.80

1.00

33.7

BINARY VAPOR LIQUID EQUILIBRIUM

Date
By

CheCalc.com

Chemical Engineering Calculations

10/08/14
CheCalc

User Input

Enter Binary Pair

Components
Antoine Equation Parameters
A
B
C
Molar Volume, V
Aij, Wilson Binary parameter
T x-y Diagram
Pressure

1
1-Propanol + Water
1
2
17.54
18.30
3166.38 3816.44
-80.15
-46.13
cm3/gmol
cal/gmol

Bar Abs

219
906.53

56
1396.64
P x-y Diagram
Temperature

1.4

Bubble

Dew

0.25
0.20
Pressure, Bara
0.15
0.10
0.05
Bubble

Dew

0.00
0.00

Temperature (Deg C)

0.20

Change the vertical axis manually if graph does not appear properly
T x-y Chart Data
X

Y
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90

Temperature
C
0.00
108.9
0.37
96.8
0.41
95.9
0.43
95.5
0.45
95.3
0.47
95.3
0.50
95.5
0.55
96.1
0.62
97.5
0.75
100.2

P x-y Chart Data

X

Y
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90

0.00
0.38
0.41
0.42
0.43
0.45
0.47
0.51
0.57
0.68

0.40

0.60

0.8

1.00

1.00

105.6

Basis
- Vapor pressure is calculated using Antoine Equation :
Ln ( Pressure ( mmHg ) ) = A - B / ( Temperature ( K ) + C )
- Flash calculations are based on Modified Raoult's Law

1.00

1.00

121.1

Bubble

Dew

00

0.20

0.40

0.60

Pressure
Bar A
0.1
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2

0.80

1.00

0.1