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MCAT Full Length1
MCAT Full Length1
06/26/2003
05:29 PM
Page 1
Physical Sciences
Time: 100 Minutes
Questions 177
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PHYSICAL SCIENCES
DIRECTIONS: Most of the questions in the Physical
Sciences test are organized into groups, with a
descriptive passage preceding each group of questions. Study the passage, then select the single best
answer to each question in the group. Some of the
questions are not based on a descriptive passage; you
must also select the best answer to these questions. If
you are unsure of the best answer, eliminate the
choices that you know are incorrect, then select an
answer from the choices that remain. Indicate your
selection by blackening the corresponding circle on
your answer sheet. A periodic table is provided below
for your use with the questions.
PERIODIC TABLE OF THE ELEMENTS
1
H
1.0
2
He
4.0
3
Li
6.9
4
Be
9.0
5
B
10.8
6
C
12.0
7
N
14.0
8
O
16.0
9
F
19.0
10
Ne
20.2
11
Na
23.0
12
Mg
24.3
13
Al
27.0
14
Si
28.1
15
P
31.0
16
S
32.1
17
Cl
35.5
18
Ar
39.9
19
K
39.1
20
Ca
40.1
21
Sc
45.0
22
Ti
47.9
23
V
50.9
24
Cr
52.0
25
Mn
54.9
26
Fe
55.8
27
Co
58.9
28
Ni
58.7
29
Cu
63.5
30
Zn
65.4
31
Ga
69.7
32
Ge
72.6
33
As
74.9
34
Se
79.0
35
Br
79.9
36
Kr
83.8
37
Rb
85.5
38
Sr
87.6
39
Y
88.9
40
Zr
91.2
41
Nb
92.9
42
Mo
95.9
43
Tc
(98)
44
Ru
101.1
45
Rh
102.9
46
Pd
106.4
47
Ag
107.9
48
Cd
112.4
49
In
114.8
50
Sn
118.7
51
Sb
121.8
52
Te
127.6
53
I
126.9
54
Xe
131.3
55
Cs
132.9
56
Ba
137.3
57
La *
138.9
72
Hf
178.5
73
Ta
180.9
74
W
183.9
75
Re
186.2
76
Os
190.2
77
Ir
192.2
78
Pt
195.1
79
Au
197.0
80
Hg
200.6
81
Tl
204.4
82
Pb
207.2
83
Bi
209.0
84
Po
(209)
85
At
(210)
86
Rn
(222)
87
Fr
(223)
88
Ra
226.0
89
Ac
227.0
104
Rf
(261)
105
Ha
(262)
106
Unh
(263)
107
Uns
(262)
108
Uno
(265)
109
Une
(267)
58
Ce
140.1
59
Pr
140.9
60
Nd
144.2
61
Pm
(145)
62
Sm
150.4
63
Eu
152.0
64
Gd
157.3
65
Tb
158.9
66
Dy
162.5
67
Ho
164.9
68
Er
167.3
69
Tm
168.9
70
Yb
173.0
71
Lu
175.0
90
Th
232.0
91
Pa
(231)
92
U
238.0
93
Np
(237)
94
Pu
(244)
95
Am
(243)
96
Cm
(247)
97
Bk
(247)
98
Cf
(251)
99
Es
(252)
100
Fm
(257)
101
Md
(258)
102
No
(259)
103
Lr
(260)
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The average distance a particle travels between collisions is known as the mean free path l. Intuitively, the
mean free path (mfp) could be expected to be larger for
gases at low pressure, since there is a lot of space between
particles. Similarly, the mfp should be larger when the gas
particles are small. The following expression for the mfp
shows this to be correct.
kT
l=
2s2P
Equation 4
fraction of molecules
neff
A(P P1)
=
2T
MR
t
Equation 5
Equation 1
where m is the mass of one particle and u is the root mean
square speed (rms speed) of the gas particles: (i.e., u =
[(v12 + v22 + ... + vn2)/N]1/2, where N is the number of gas
particles; this is different from the average speed). For an
ideal gas, the kinetic energy of all the particles is:
Etotal = (3/2)nRT
Equation 2
1. Which of the following gives values for both standard temperature and pressure?
A.
B.
C.
D.
u = (3RT/M)1/2
Equation 3
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H2
O2
N2
CO2
rms speed.
temperature.
Boltzmann constant.
universal gas constant.
A.
B.
C.
D.
Cl2(g)
O2(g)
CO2(g)
N2(g)
B.
PA
MB
PB
MA
C.
D.
PB
MB
PA
MA
MB
MA
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A.
B.
C.
D.
0.08 C
1.6 103 C
6.25 108 C
1.25 109 C
0.16 A
4A
6.25 A
8A
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C.
D.
Contact with the ground will decrease the resistance across the patients body.
The doctor administering the treatment will be
in greater danger of receiving an electric shock
if the patient is in electrical contact with the
ground.
Contact with the ground will cause a smaller
current to pass through the patients heart.
The patient receiving the treatment will be in
greater danger of receiving burns due to the high
current density if he is in electrical contact with
the ground.
the energy
increase.
the energy
decrease.
the electric
increase.
the electric
decrease.
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Due to the buffering effect of the soils cationexchange capacity, just measuring the soil solutions pH
will not indicate how much base is needed to change the
soil pH. In another experiment, measured amounts of acid
and base were added to 10-gram samples of well-mixed
soil that had been collected from various locations in a
field. The volumes of the samples were equalized by
adding water. The results were recorded in Figure 2.
pH
6
4
0.8
0.4
meq acid
0.4
0.8
meq base
O2CA2+OH
Figure 2
Figure 1
A pH-dependent charge develops when hydrogen dissociates from hydroxyl moieties on the outer surfaces of
the clay micelles. This leaves negatively-charged oxygen
atoms to which basic cations may adsorb. Likewise, a large
pH-dependent charge develops when hydrogen dissociates
from carboxylic acids and phenols in organic matter.
12. Which column(s) in Table 1 represent(s) the permanent charge of the soil micelles?
A.
B.
C.
D.
Al3+
H+
Al3+ and Basic Cations
Al3+ and H+
4%
6%
29%
40%
Table 1
(meq/100 g)
Sample I
Sample II
Sample III
pH
Al3+
Basic
Cations
H+
Total
Cation
Exchange
Capacity
4.5
5.3
6.0
11.7
1.6
0.5
1.9
16.3
9.8
34.0
19.5
7.8
47.6
37.4
18.1
14. Which soil from Table 1 most likely has the highest
percentage of organic matter?
A.
B.
C.
D.
I
II
III
Cannot be determined
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be
be
be
A.
B.
C.
D.
be
900 kg
1800 kg
9 105 kg
1.8 106 kg
17. Which of the following would probably NOT displace Al3+ in soil micelles?
A.
B.
C.
D.
20
30
40
50
B.
Na+
Mg2+
Si4+
Cr2+
C.
D.
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0.05 m
0.10 m
0.25 m
0.50 m
A.
B.
C.
D.
1/6
1/6
6
36
upwards.
downwards.
to the left.
to the right.
40 g
48 g
56 g
64 g
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A.
B.
C.
D.
144 kJ
432 kJ
576 kJ
900 kJ
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300 nm
600 nm
900 nm
1242 nm
A.
B.
C.
D.
9.936 eV
6.948 eV
4.968 eV
2.968 eV
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A.
B.
C.
D.
+++
++++
+++
32. Among conjugated polyenes (molecules with alternating carbon-carbon double and single bonds) why
are those that are longer able to absorb longer wavelengths of light?
A.
B.
C.
D.
H2
O2
N2
F2
Absorption of a photon can raise an electron to a higherenergy molecular orbital. The excited electron does not
immediately change its spin, which is opposite to that of the
electron with which it was previously paired. This singlet
state is relatively unstable: the molecule may interact with
another molecule, or fluoresce and return to its ground state.
Alternatively, there may be a change in spin direction somewhere in the system; the molecule then enters the so-called
triplet state, which generally has lower energy. The
molecule now cannot return quickly to its ground state,
since the excited electron no longer has a partner of opposite
spin with which to pair. It also cannot return to the singlet
state, because the singlet has greater energy. Consequently,
the triplet state, which has two unpaired electrons in separate orbitals, is long-lived by atomic standards, with a lifetime that may be ten seconds or more. During this period,
the molecule is highly reactive.
GO ON TO THE NEXT PAGE.
12
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A.
B.
C.
D.
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A.
B.
C.
D.
increase
decrease
remain the same
The answer depends on the incline angle of the
jump ramp.
38. Another ski jumper sets off from a point farther down
the jump track, and leaves the ramp at a speed of 16
m/s. If the time in flight is 4 s, what is the total horizontal distance traveled by the ski jumper after leaving the ramp?
A.
B.
C.
D.
4m
83 m
323 m
48 m
Figure 1
The distance traveled by the skier between leaving the
ski jump ramp and making contact with the slope is called
the jump distance. In some cases, in order to increase the
jump distance a skier will jump slightly upon leaving the
ramp, thereby increasing the vertical velocity.
Unless otherwise stated, assume that friction between
the skis and the slope is negligible, and ignore the effects
of air resistance.
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B.
C.
D.
6.9 m/s2
9.8 m/s2
13.9 m/s2
80 m/s2
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A.
43. Suppose an -particle starting from rest is accelerated through a 5 megavolt potential difference. What
is the final kinetic energy of the -particle? (Note:
Assume that e = 1.6 1019 C.)
A.
B.
C.
D.
1.6 1012 J
8.0 1013 J
6.4 1026 J
3.2 1026 J
B.
44. Based on the table below, what is the cell voltage for
the following reaction?
Fe2O3 + 2 Al 2 Fe + Al2O3
Half-Reaction
Fe2+ + 2e Fe
0.44
Fe3+ + 3e Fe
2H2O +
2e
H2 +
Al3+ + 3e Al
A.
B.
C.
D.
C.
0.037
2OH
0.83
1.66
D.
1.33 V
1.99 V
1.33 V
1.62 V
m2r2/42
22mr2
42mr2
mr2/2
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A.
B.
C.
D.
A
B
C
D
Page 18
0.1
2M
; [B
]=
[A
]=
time
Reaction 1
In this case, the first step in the reaction pathway is the
rate-determining step. Therefore, the overall rate of the reaction must equal the rate of the first step, k1[A] where k1 is the
rate constant for the first step. (Rate constants of the different
steps are denoted by kx, where x is the step number.)
Rate = k'[A]x
Rate = k'[B]y
Rate = k'[A]x[B]y
Rate = k[A]x[[B]y[R]z
0.02%
0.05%
0.1%
0.2%
A.
B.
C.
D.
E = E (RT/nF)ln([C]c[D]d/[A]a[B]b)
Equation 1
when
2M
; [B
]=
AB+C
(slow)
B + D E + F (fast)
E+CG
(fast)
0.2
0.2
rate
A+DF+G
Step 1
Step 2
Step 3
[A
]=
05:30 PM
1M
; [B
]=
06/26/2003
[A
]=
01 MCAT FL Test1
Rate = k1k2[D]/k1[C]
Rate = k1k2[D]/k1k2[C]
Rate = k1k2[A][D]/k1[C]
Rate = k1k2[A][D]/k1k2[C]
aA+bBcC+dD
Reaction 2
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54. Catalysts are effective in increasing the rate of a reaction because they:
I. k1/k1 = 1
II. E = E
III. ln([C]c[D]d/[A]a[B]b) = nFE/RT
A. I only
B. III only
C. I and II only
D. I, II, and III
A.
B.
C.
D.
1.07 V
1.10 V
1.13 V
1.20 V
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X-rays are produced by a device which beams electrons with an energy between 103 and 106 eV at a metal
plate. The electrons interact with the metal plate and are
stopped by it. Much of the energy of the incoming electrons is released in the form of X-rays, which are highenergy photons of electromagnetic radiation.
A.
B.
C.
D.
An example of such a device is shown below. Electrons are accelerated from the cathode towards the anode
by an electric field.
100 eV
1,000 eV
10,000 eV
1J
56. What is the direction of the electric field that accelerates the electrons?
A.
B.
C.
D.
It is shorter.
It is the same.
It is longer.
It depends on the energy of the incoming electron.
The second mechanism occurs when an incoming electron knocks an inner electron out of one of the metal atoms
of the anode. This electron is replaced by an electron from
a higher energy level of the atom, and a photon making up
the energy difference is emitted.
X-rays are absorbed by a material when they pass
through it. The amount of X-rays absorbed increases
with the density of the material. In addition, lower
energy X-rays are more likely to be absorbed than higher
energy X-rays. (Note: 1 eV = 1.6 1019 J; Plancks constant h = 4.1 1015 eVs; speed of light c = 3 108 m/s.)
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15,000 V
20,000 V
20,500 V
21,500 V
A.
C.
B.
D.
3 1018 Hz
6 1018 Hz
12 1018 Hz
24 1018 Hz
60. In an X-ray tube, electrons of charge e are accelerated through a potential difference of V. The anode is
cooled by water of mass m with specific heat c. If n
electrons per second strike the anode, what is the
maximum possible rise in the temperature of the
water after 100 s?
A.
B.
C.
D.
nVe/100mc
100Ve/mc
100n(Ve + mc)
100nVe/mc
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Table 1
Formula
Compound
A researcher in a molecular biology lab planned to carry
out an extraction procedure known as an alkaline plasmid
prep, which is designed to purify plasmids, small pieces of
the hereditary material DNA, from bacterial cells. The bacteria are first placed into a test tube containing liquid nutrient
medium and allowed to grow until they reach a high population density. The culture, which consists of solid cells suspended in the medium, is then centrifuged; a solid pellet is
formed. The supernatant is poured out, leaving the pellet
behind, and the cells are resuspended in a mL of lysis buffer
solution (50 mM glucose, 25 mM Tris buffer and 10 mM
ethylenediaminetetraacetic acid (EDTA), with 5 mg of the
enzyme lysozyme added). They are then incubated for 30
minutes at 0C, during which time the bacterial cell walls
break down and the cell contents are released into the solution. After incubation, 1 mL of 0.4 N sodium hydroxide and
1 mL of 2% sodium dodecyl sulfate (SDS) are added, and the
solution is again incubated on ice for 10 minutes. 2 mL of 3
M sodium acetate are added and the mixture is incubated for
30 minutes at 0C. The test tube is centrifuged once more and
the supernatant is decanted into a clean tube, leaving behind
the protein and most other cell components in the pellet.
MW
Stock
Tris
(CH2OH)3CNH2
121 1M (pH 8)
EDTA
(HOOCCH2)4(CNH2)2
Sodium
hydroxide NaOH
40 5 N
SDS
C11H23CH2OSO3Na+
288 10%
Sodium
acetate
CH3COONa+
82 3 M (pH 5.2)
Ethanol
CH3CH2OH
46 95%
Finally, 10 mL of pure ethanol are added to the supernatant from the previous step to precipitate out the DNA,
and the test tube is incubated at 20C for 60 minutes, during which the mixture remains liquid. The mixture is centrifuged a final time and the supernatant removed. The
translucent precipitate that results is washed with 70%
ethanol (70% ethanol and 30% water by volume), allowed
to dry, and resuspended in 1 mL of TE buffer (10 mM Tris,
1 mM EDTA).
145 g
146 g
186 g
187 g
In preparation for this experiment, the researcher prepared stock solutions of the various chemicals that she will
need in the experiment. Stock solutions are highly concentrated solutions of commonly used chemicals in water from
which dilute solutions are prepared for daily use. Table 1
shows the chemicals, their molecular formulas and weights,
and the composition of commonly used stock solutions.
0.028 m
0.100 m
0.347 m
0.385 m
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22
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A.
B.
C.
D.
333 mL
350 mL
368 mL
475 mL
1.0
4.74
5.2
6.0
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69. The mass in the first experiment is pulled down a distance A from its equilibrium position and then
released from rest. The mass will then oscillate with
simple harmonic motion. As the mass moves up and
down, energy is dissipated due to factors such as air
resistance and internal heating of the spring. The
mass will no longer oscillate when the total energy
dissipated equals:
A.
B.
C.
D.
kL2/2
kA2/2
k(L + A)2/2
kL02/2
In both experiments the masses of the springs are negligible, and the elastic limits of the springs are never
exceeded.
A.
B.
C.
D.
71. In the first experiment, when a 5-kg mass is oscillating, the frequency of oscillation is 2 Hz. What is the
value of the spring constant?
A.
B.
C.
D.
5/2 N/m
20 N/m
402 N/m
802 N/m
kL/g
kL0/g
k(L L0)/g
k/g
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1/2
1
2
2
B.
C.
D.
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A.
B.
C.
D.
10
30
100
1000
75. A given volume of a diprotic acid is completely neutralized by twice that volume of a 0.3 N NaOH solution. What is the molarity of the acid?
A.
B.
C.
D.
0.15 M
0.30 M
0.60 M
1.20 M
Dispersion forces
Resonance
Hydrogen bonding
Dipole interactions
mg
m(g + a)
m(g a)
ma
26
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Verbal Reasoning
Time: 85 Minutes
Questions 78137
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VERBAL REASONING
DIRECTIONS: There are nine passages in this Verbal
Reasoning Section. Each passage is followed by several questions. After reading a passage, select the one
best answer to each question. If you are not certain of
an answer, eliminate the alternatives that you know to
be incorrect and then select an answer from the
remaining alternatives. Indicate your selection by
blackening the corresponding oval on your answer
document.
Passage I (Questions 7884)
40
10
15
In the early nineteenth century a large number of communal experiments, both secular and religious, sprang up
in the northeastern United States. Perhaps the most famous
secular commune was Brook Farm, founded by transcendentalists George Ripley and William H. Channing to promote the pursuit of leisure and culture through the proper
application of time and labor. Its members (among the
more notable were Nathaniel Hawthorne and Margaret
Fuller) pursued field labor by day, art and philosophy by
night. For a time the system worked so well that two afternoons a week were set aside for leisure and Brook Farm
began outcompeting local farmers at the produce market.
But by nature the Farms members were thinkers, not
workers; despite their success they remained mainly interested in the theoretical and philosophical implications of
the experiment. Thus, when a devastating fire brought the
community considerable financial burdens in its fifth year,
the members felt little compunction about closing shop
and returning to their comfortable Boston homes.
45
50
55
60
20
25
30
35
78. The passage implies that the end of the Brook Farm
experiment was probably brought on by:
A.
B.
C.
D.
28
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A.
B.
C.
D.
sexual practices.
equality of men and women.
personal property.
contact with the outside world.
complex marriage.
maintenance of order through social pressure.
belief in present grace.
shared living quarters.
A.
B.
C.
D.
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Page 30
55
60
15
20
25
30
35
40
45
Of the three major movements in the course of 20thcentury psychology, psychoanalysis is the oldest and most
introspective. Conceived by Sigmund Freud as a means of
treating mental and emotional disorders, psychoanalysis is
based on the theory that people experience unresolved
emotional conflicts in infancy and early childhood. Years
later, although these experiences have largely disappeared
from conscious awareness, they may continue to impair a
persons ability to function in daily life. The patient experiences improvement when the psychoanalyst eventually
unlocks these long-repressed memories of conflict and
brings them to the patients conscious awareness.
In the heyday of behaviorism, which occurred between
the two world wars, the psychoanalytic movement was
heavily criticized for being too concerned with inner subjective experience. Behavioral psychologists, dismissing
ideas and feelings as unscientific, tried to deal only with
observable and quantifiable facts. They perceived the
human being merely as an organism which generated
responses to stimuli produced by its body and the environment around it. Patients neuroses no longer needed analysis; they could instead by modified by behavioral
conditioning. Not even babies were safe: B.F. Skinner
devised a container in which infants could be raised under
ideal conditionsif a sound-proof box can be considered the ideal environment for child-rearing.
65
70
75
80
85. If the author of this passage met a Freudian psychoanalyst who felt that it was important for patients to
consider themselves capable of fundamental change,
he would most likely conclude that the psychoanalyst
was:
A.
B.
C.
D.
30
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Page 31
86. The author states that not even babies were safe
(line 35) most probably in order to:
A.
B.
C.
D.
A.
emphasize that the use of even very young subjects is considered valid among most psychologists.
indicate the pervasive influence of behaviorists
on the field of psychology.
show that behaviorists were anxious to apply
their theories to a wide range of subjects.
warn of the dangers of psychoanalysis for children.
B.
C.
D.
B.
C.
D.
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Page 32
mitigate globulation; however this procedure also seriously curtails the PFCs oxygen capacity.
55
60
65
70
91. The author mentions all of the following as weaknesses of synthetic bloods EXCEPT:
A.
B.
C.
D.
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Page 33
C.
D.
A.
B.
C.
D.
94. We can infer that all of the synthetic blood technologies discussed in this passage:
A.
B.
C.
D.
50 cc
100 cc
150 cc
300 cc
B.
C.
D.
01 MCAT FL Test1
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50
55
60
65
70
75
80
4:30 p.m.
8:15 a.m.
3:00 p.m.
1:15 p.m.
01 MCAT FL Test1
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A.
B.
C.
D.
a paradoxical phenomenon.
an unnecessary evil.
a violation of privacy.
a pleasurable diversion.
01 MCAT FL Test1
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10
A combination of several factors have made it particularly difficult to deal with the threat posed by this aphid.
First, Russian aphids reproduce asexually at a phenomenal
rate. This process, known as parthenogenesis, often results
25 in as many as twenty generations of insects in a single
year. Although most generations remain in a limited geographic area because they have no wings, a few generations are born with wings, allowing the insect to spread to
new areas. Second, because wheat is a crop with a very
30 low profit margin, most American farmers do not spray it
with pesticides; it simply is not economical to do so. And
since the Russian aphid has only recently entered the
United States, it has no natural enemies among North
American insects or animals. As a result, there have been
35 no man-made or natural obstacles to the spread of the Russian aphid in the United States.
C.
D.
36
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C.
D.
What measures were taken to combat the Hessian fly during the 18th century?
Why does the Russian wheat aphid cause less
damage in the Soviet Union than in other
countries?
Is it logical for American farmers to use pesticides in order to attempt to protect their wheat
crops from the Russian aphid?
What sorts of solutions have agricultural
researchers investigated in their efforts to curb
the destructiveness of the Russian wheat aphid?
108. The author suggests the best way to control the Russian aphid population in the United States is to:
A.
B.
C.
D.
C.
D.
01 MCAT FL Test1
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50
55
Wovokas Ghost Dance doctrine forbade Indian violence against whites or other Indians; it also involved the
wearing of ghost shirts, which supposedly rendered the
wearers invulnerable to the white mans bullets. In 1890,
when the Ghost Dance spread to the Sioux Indians, both
the ghost shirts and the movement itself were put to the
test. Violent resistance to white domination had all but
ended among the Sioux by the late 1880s, when government-ordered reductions in the size of their reservations
infuriated the Sioux, and made them particularly responsive to the millenialist message of the Ghost Dance. As the
Sioux organized themselves in the cult of the dance, an
alarmed federal government resorted to armed intervention
which ultimately led to the massacre of some 200 Sioux
men, women and children at Wounded Knee, South
Dakota in December of 1890. The ghost shirts had been
worn to no avail, and Wounded Knee marked the end of
the second Ghost Dance cult.
60
65
70
A.
B.
C.
D.
A.
B.
C.
D.
38
01 MCAT FL Test1
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A.
B.
C.
D.
A.
B.
C.
D.
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55
60
65
70
118. According to the passage, the location of the olfactory and emotional centers of the brain helps explain
all of the following EXCEPT:
A.
B.
C.
Even though we are not always conscious of the presence of odors, and are often unable to either articulate or
remember their unique characteristics, our brains always
register their existence. In fact, such a large amount of
human brain tissue is devoted to smell that scientists sur40 mise the role of this sense must be profound. Moreover,
neurobiological research suggests that smell must have an
important function because olfactory neurons can regenerate themselves, unlike most other nerve cells. The importance of this sense is further supported by the fact that
45 animals experimentally denied the olfactory sense do not
develop full and normal brain function.
35
D.
The significance of olfaction is much clearer in animals than in human beings. Animal behavior is strongly
40
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A.
B.
C.
D.
121. The sense of smell in animals is different from olfaction in humans in that animals:
A.
B.
C.
D.
A.
B.
C.
D.
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Bebop lives! cries the newest generation of jazz players. During the 1980s, musicians like Wynton Marsalis
revived public interest in bebop, the speedy, angular music
that first bubbled up out of Harlem in the early 1940s,
5 changing the face of jazz. That Marsalis and others thought
of themselves as celebrating and preserving a noble tradition is, in one sense, inevitable. After the excesses of
experimental or free jazz in the 1960s and the electronic
jazz-rock fusion of the 70s, it is hardly surprising that
10 people should hearken back to a time when jazz was
purer, perhaps even at the apex of its development. But
the recent enthusiasm for bebop is also ironic in light of the
musics initial public reception.
55
60
65
15
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A.
B.
C.
D.
128. It can be inferred from the passage that the innovations of Fletcher Henderson (lines 27-34) were
inspired primarily by:
A.
B.
C.
D.
01 MCAT FL Test1
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10
15
20
45
In the twentieth century, studies comparing photosynthesis in green plants and in certain sulfur bacteria yielded
important information about the photosynthetic process.
Because water is both a reactant and a product in the central reaction, it had long been assumed that the oxygen
released by photosynthesis comes from splitting the carbon dioxide molecule. In the 1930s, however, this popular
view was decisively altered by the studies of C. B. Van
Niel. Van Niel studied sulfur bacteria, which use hydrogen
sulfide for photosynthesis in the same way that green
plants use water, and produce sulfur instead of oxygen.
Van Niel saw that the use of carbon dioxide to form carbohydrates was similar in the two types of organisms. He
reasoned that the oxygen produced by green plants must
derive from waterrather than carbon dioxide, as previously assumedin the same way that the sulfur produced
by the bacteria derives from hydrogen sulfide. Van Niels
finding was important because the earlier belief had been
that oxygen was split off from carbon dioxide, and that
carbon then combined with water to form carbohydrates.
The new postulate was that, with green plants, hydrogen is
removed from water and then combines with carbon dioxide to form the carbohydrates needed by the organism.
50
25
30
35
40
132. Which of the following can be inferred about the scientists discussed in the passage?
A.
B.
C.
D.
44
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A.
B.
C.
D.
135. Which of the following statements about photosynthesis would most probably NOT have been made by
de Saussure?
A.
B.
C.
D.
45
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01 MCAT FL Test1
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Writing Sample
Time: 60 Minutes
2 Items, Separately Timed:
30 Minutes Each
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WRITING SAMPLE
DIRECTIONS: This section is a test of your writing skills. The
section contains two parts. You will have 30 minutes to complete
each part.
Your responses to the prompts given in the Writing Sample will
be written in the ANSWER DOCUMENT. Your response to Part 1
must be written only on the answer sheets marked 1, and your
response to Part 2 must be written only on the answer sheets
marked 2. You may work only on Part 1 during the first 30 minutes of the test and only on Part 2 during the second 30 minutes.
If you finish writing on Part 1 before the time is up, you may
review your work on that part, but do not begin writing on Part 2.
If you finish writing on Part 2 before the time is up, you may
review your work only on Part 2.
Use your time efficiently. Before you begin writing a response,
read the assignment carefully and make sure you understand
exactly what you are being asked to do. You may use the space
below each writing assignment to make notes in planning your
responses.
Because this is a test of your writing skills, your response to each
part should be an essay composed of complete sentences and
paragraphs, as well organized and clearly written as you can
make it in the allotted time. You may make corrections or additions neatly between the lines of your responses, but do not write
in the margins of the answer booklet.
There are six pages in your answer booklet to write your
responses, three pages for each part of the test. You are not
required to use all of the pages, but to be sure that you have
enough space for each essay, do not skip lines.
Essays that are illegible cannot be scored. In addition, essays
that are not written in English will not be scored.
01 MCAT FL Test1
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Part 1
Consider the following statement:
It is each citizen's duty to obey the laws of the nation.
Write a unified essay in which you perform the following tasks. Explain what you think the above
statement means. Describe a specific situation in which a citizen might not have a duty to obey a law.
Discuss what you think determines when citizens have a duty to obey the laws of the nation and when
they do not.
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Part 2
Consider the following statement:
Heroes are ordinary people made heroic by circumstance.
Write a unified essay in which you perform the following tasks. Explain what you think the above
statement means. Describe a specific situation in which someone might be heroic because of something
other than circumstance. Discuss what you think determines when heroism is dependent on circumstance
and when it is not.
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Biological Sciences
Time: 100 Minutes
Questions 138214
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BIOLOGICAL SCIENCES
DIRECTIONS: Most of the questions in the following
test are organized into groups, with a descriptive passage preceding each group of questions. Study the
passage, then select the single best answer to each
question in the group. Some of the questions are not
based on a descriptive passage; you must also select
the best answer to these questions. If you are unsure
of the best answer, eliminate the choices that you
know are incorrect, then select an answer from the
choices that remain. Indicate your selection by blackening the corresponding circle on your answer sheet.
A periodic table is provided below for your use with the
questions.
2
He
4.0
3
Li
6.9
4
Be
9.0
5
B
10.8
6
C
12.0
7
N
14.0
8
O
16.0
9
F
19.0
10
Ne
20.2
11
Na
23.0
12
Mg
24.3
13
Al
27.0
14
Si
28.1
15
P
31.0
16
S
32.1
17
Cl
35.5
18
Ar
39.9
19
K
39.1
20
Ca
40.1
21
Sc
45.0
22
Ti
47.9
23
V
50.9
30
Zn
65.4
31
Ga
69.7
32
Ge
72.6
33
As
74.9
34
Se
79.0
35
Br
79.9
36
Kr
83.8
37
38
Sr
87.6
39
Y
88.9
40
Zr
91.2
50
Rb
85.5
55
Cs
132.9
56
Ba
137.3
57
La *
138.9
72
Hf
178.5
87
Fr
(223)
88
Ra
226.0
89
Ac
227.0
24
Cr
52.0
25
Mn
54.9
26
Fe
55.8
27
Co
58.9
28
Ni
58.7
29
Cu
63.5
41
42
Nb
92.9
Mo
95.9
43
Tc
(98)
44
45
48
Rh
102.9
46
Pd
106.4
47
Ru
101.1
Ag
107.9
Cd
112.4
49
In
114.8
Sn
118.7
51
Sb
121.8
52
Te
127.6
53
I
126.9
Xe
131.3
73
Ta
180.9
74
W
183.9
75
Re
186.2
76
Os
190.2
77
Ir
192.2
78
Pt
195.1
79
Au
197.0
80
Hg
200.6
81
Tl
204.4
82
Pb
207.2
83
Bi
209.0
84
Po
(209)
85
At
(210)
86
Rn
(222)
104
Rf
(261)
105
Ha
(262)
106
Unh
(263)
107
Uns
(262)
108
Uno
(265)
109
Une
(267)
58
Ce
140.1
59
Pr
140.9
60
Nd
144.2
61
Pm
(145)
62
Sm
150.4
63
Eu
152.0
64
Gd
157.3
65
Tb
158.9
66
Dy
162.5
67
Ho
164.9
68
Er
167.3
69
Tm
168.9
70
Yb
173.0
71
Lu
175.0
90
Th
232.0
91
Pa
(231)
92
U
238.0
93
Np
(237)
94
Pu
(244)
95
Am
(243)
96
Cm
(247)
97
Bk
(247)
98
Cf
(251)
99
Es
(252)
100
Fm
(257)
101
Md
(258)
102
No
(259)
103
Lr
(260)
54
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Page 53
Hemoglobin (Hb) and myoglobin (Mb) are the O2- carrying proteins in vertebrates. Hb, which is contained
within red blood cells, serves as the O2 carrier in blood and
also plays a vital role in the transport of CO2 and H+. Vertebrate Hb consists of four polypeptides (subunits) each
with a heme group. The four chains are held together by
noncovalent attractions. The affinity of Hb for O2 varies
between species and within species depending on such factors as blood pH, stage of development, and body size. For
example, small mammals give up O2 more readily than
large mammals because small mammals have a higher
metabolic rate and require more O2 per gram of tissue.
A.
B.
C.
D.
Curve A
Curve B
Curve C
Curve D
The binding of O2 to Hb is also dependent on the cooperativity of the Hb subunits. That is, binding at one heme
facilitates the binding of O2 at the other hemes within the
Hb molecule by altering the conformation of the entire
molecule. This conformational change makes subsequent
binding of O2 more energetically favorable. Conversely,
the unloading of O2 at one heme facilitates the unloading
of O2 at the others by a similar mechanism.
A.
B.
C.
D.
Curve A
Curve B
Curve C
Curve D
A.
B.
C.
D.
Figure 1
Myoglobin facilitates O2 transport in muscle and
serves as a reserve store of O2. Mb is a single polypeptide
chain containing a heme group, with a molecular weight of
18 kd. As can be seen in Figure 1, Mb (Curve D) has a
greater affinity for O2 than Hb.
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A.
B.
C.
D.
4 moles
8 moles
12 moles
16 moles
Curve A
Curve B
Curve C
Curve D
0.0
0.125
0.25
0.75
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A.
B.
C.
D.
A.
B.
C.
D.
A
B
C
D
glycolysis.
fatty acid catabolism.
the urea cycle.
nucleic acid degradation.
Albumin
Sodium
Urea
Potassium
After ADH
765
765
400
180
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Page 56
A.
B.
C.
D.
Patient A
Patient B
Patient C
Patient D
Patient A
Patient B
Patient C
Patient D
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Page 57
Electromagnetic radiation from space constantly bombards the earth. Most wavelengths are absorbed by the
atmosphere; however, there are two windows of nonabsorption through which significant amounts of radiation
reach the ground. The first transmits ultraviolet and visible
light, as well as infrared light or heat; the second transmits
radio waves. As a result, terrestrial organisms have
evolved a number of pigments that interact with light in
various ways: some capture light energy, some provide
protection from light-induced damage, and some serve
camouflage or signaling purposes.
A.
B.
C.
D.
Color
blue
yellow
red
s orbitals.
orbitals.
d orbitals.
f orbitals.
Subtraction Color
orange
violet
green
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155. Many crustaceans produce a blue or green caroteneprotein complex. What is the most likely cause of the
color change from green to orange when a lobster is
boiled?
A.
B.
C.
D.
I.
II.
III.
IV.
A.
B.
C.
D.
I, II, III, IV
IV, III, II, I
III, II, I, IV
IV, I, II, III
01 MCAT FL Test1
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Page 59
A.
A.
B.
C.
D.
B.
I.
NH2
III.
COOH
COOH
O
H
C.
Cl
II.
OH
COOH
NH2
OH
A.
B.
C.
D.
IV.
H3C
D.
CH2CH3
CH3
Cl
antibonding orbitals.
resonance.
polarity.
optical activity.
C2H5
OH
OH
HOOC
CH3
H
I and III
II and IV
I and II
II, III, and IV
Epididymis
Prostate
Urethra
Ureter
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Spermatogonium
Spermatid
Zygote
Primary oocyte
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A.
B.
C.
D.
Figure 1
0%
25%
50%
100%
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Page 62
25%
33%
50%
75%
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Aerobic respiration is the major process used by oxygen-requiring organisms to generate energy. During respiration, glucose is metabolized to generate chemical energy
in the form of ATP:
I. G1
II. S
III. G2
IV. M
A. IV only
B. I and III only
C. II and IV only
D. I, II, III, and IV
170. Scientists have demonstrated that human mitochondrial DNA mutates at a fairly slow rate. Because
mitochondria play such an important role in the cell,
these mutations are most likely to be:
A.
B.
C.
D.
The nature of the mitochondrial genome and proteinsynthesizing machinery has led many researchers to postulate that mitochondria may have arisen as the result of the
ingestion of a bacterium by a primitive cell millions of
years ago. It is postulated that the two may have entered
into a symbiotic relationship and eventually became
dependent on each another; the cell sustained the bacterium, while the bacterium provided energy for the cell.
Gradually, the two evolved into the present-day eukaryotic
cell, with the mitochondrion retaining some of its own
DNA. This is known as the endosymbiotic hypothesis.
Because mitochondrial DNA is inherited in a nonMendelian fashion (mitochondria are inherited from the
maternal parent, who supplies most of the cytoplasm to the
fertilized egg), it has been used to look at evolutionary
relationships among different organisms.
point mutations.
frameshift mutations.
lethal mutations.
nondisjunctions.
171. Which of the following mitochondrial genome characteristics differs most from the characteristics of the
nuclear genome?
A.
B.
C.
D.
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172. What is the net number of ATP molecules synthesized by an obligate anaerobe per molecule of glucose?
A.
B.
C.
D.
2 ATP
6 ATP
8 ATP
36 ATP
A.
B.
C.
D.
endosymbiotic hypothesis.
non-Mendelian inheritance of mitochondrial
DNA.
recombination of mitochondrial DNA during
organelle replication.
presence of genetic material in the mitochondria
that is distinct from nuclear DNA.
Erythrocytes
Epidermal cells
Skeletal muscle cells
Intestinal cells
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Page 65
A.
B.
C.
D.
O
R
OH
177. The rate of the reaction is negligible without the acid
catalyst. The catalyst:
H+
O
A.
B.
R
OH
C.
R'OH
D.
OH
R
R'
attacks the carbonyl oxygen, permitting the nucleophilic group to attack the carbonyl carbon.
attacks the carbonyl carbon, permitting the nucleophilic group to attack the carbonyl oxygen.
attacks the carbonyl oxygen, permitting the electrophilic group to attack the carbonyl carbon.
attacks the carbonyl carbon, permitting the electrophilic group to attack the carbonyl oxygen.
OH
O
A.
B.
C.
D.
OH
R
R'
OH2
COOHCH2CH2OH
COOHCH2CH2CH2OH
COOHCH2CH2CH2CH2OH
COOHCH2CH2CH2CH2CH2OH
O
H2O
OH
OR'
H+
O
OR'
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CH3CH2COOH
ClCH2CH2COOH
ClCH2CH2CH2COOH
Cl2CHCH2COOH
CH3CH2CH2Cl
CH3Cl
(CH3)2CHCl
CH3CH2Cl
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Page 67
A.
B.
C.
D.
183. A couple decide to have a child. If the fathers genotype is AO and the mother has type B blood of
unknown genotype, which of the following are possible blood types for their child?
I. A
II. B
III. AB
IV. O
A. I and II only
B. I, II, and III only
C. I, II, and IV only
D. I, II, III, and IV
These antigens become most important when an individual comes into contact with foreign blood. Because of
the presence of naturally occurring substances that closely
mimic the A and B antigens, individuals who do not have
these antigens on their red blood cells will form antibodies
against them. This is inconsequential until situations such
as blood transfusion, organ transplant, or pregnancy occur.
184. A new virus has been discovered that evades detection by the immune system of only those individuals
with type A or type AB blood. Which of the following best accounts for this observation?
A.
B.
C.
D.
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Page 68
A.
B.
C.
D.
Anti-B antibody
Anti-A antibody
Anti-Rh antibody
Both anti-A and anti-Rh antibodies
A.
B.
C.
D.
Rh antigen
An immunosuppressive drug
Anti-Rh antibody
Iron pills
A.
B.
C.
D.
01 MCAT FL Test1
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Page 69
O
190. A certain chemical is found to inhibit the synthesis of
all steroids. The synthesis of which of the following
hormones would NOT be affected when a dose of
this chemical is administered to a laboratory rat?
A.
B.
C.
D.
H2O
Cortisol
Aldosterone
Epinephrine
Testosterone
A.
B.
C.
D.
191. A biochemist grows two cultures of yeastone aerobically and the other anaerobicallyand measures
the amount of ATP produced by each culture. He
finds that the aerobically-grown yeast produce about
18 times as much ATP as the anaerobically-grown
yeast. These observations are consistent with the fact
that in the aerobically grown yeast:
A.
B.
C.
D.
CH3CH=CHCHO
HOOCCH2CH(CH3)2
CH3CH(CH3)2
HOCH2CH(CH3)2
para-nitrophenol
meta-nitrophenol
ortho-nitrophenol
A.
B.
C.
H3O+
D.
Solubility per
100g H2O
Melting point
(C)
1.7
1.4
0.2
114
97
44
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Page 70
COOH
A.
CH2OH
CH2CH3
C.
CH2OH
COOH
OCH3
B.
OCH3
D.
A.
B.
C.
D.
195. The correct formula for this compound could be:
A.
B.
C.
D.
C7H10O3.
C8H10O2.
C9H13O.
C7H21O2.
Methyl
Phenol
Carboxyl
Aldehyde carbonyl
GO ON TO THE NEXT PAGE.
70
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Page 71
201. Based on the experimental results, what is the genotype of the female in Cross 5?
A.
B.
C.
D.
Male
brown
brown
red
brown
brown
red
red
brown
brown
Female
red
white
white
brown
brown
red
red
red
red
Bb
BB or Bb
BB or Bw
BB, Bb, or Bw
3:1
1:3
1:1
2:1
203. If it were discovered that the alleles for red and white
hair were actually incompletely dominant and produced a pink hair color in rats with one copy of each
allele, what would be the expected phenotypic ratio
in a cross between a Bb male and a pink female?
Offspring
all brown
all brown
all red
3 brown : 1 red
all brown
all red
3 red : 1 white
2 brown : 1 red : 1 white
1 brown : 1 red
A.
B.
C.
D.
199. Based on the experimental results, what is the genotype of the male in Cross 6?
A.
B.
C.
D.
bw
bb
bw or bb
Bb or bw
6.25%
8.33%
12.5%
25%
01 MCAT FL Test1
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CH3
OH
OH
OH
naphthol
phenanthrol
CH(CH3)2
thymol
206. Which of the following shows the order of decreasing acidity among the four compounds below?
CH3
OH
OH
NO2
H3PO4
+
OH
OH
O 2N
NO2
OH
NO2
CH(CH3)2
NO2
CH3
NO2
II
III
IV
thymol
m-cresol
A.
B.
C.
D.
Reaction A
thymol
OH
H2/Ni
high
pressure
I, III, IV, II
IV, I, II, III
IV, III, II, I
IV, II, I, III
OH
menthol
Reaction B
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208. What simple chemical test could be used to distinguish between the following two compounds?
207. The reaction of phenol with dilute nitric acid produces which of the following compounds?
OH
OH
II
OH
CH2OH
NO2
+
A.
NO2
CH3
OH
A.
B.
C.
D.
B.
NO2
OH
NO2
C.
OH
OH
O2N
+
D.
NO2
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COOH
A.
OH
B.
Br
OH
Br
C.
O
D.
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A.
B.
C.
D.
CH3CH2CH2Cl
(CH3)3COH
CH3CH2CH3
(CH3CH2)3CBr
213. Destroying the cerebellum of a cat would cause significant impairment of normal:
A.
B.
C.
D.
urine formation.
sense of smell.
coordinated movement.
thermoregulation.
1
2
3
4
D.
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