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The Basics of

Lubricants and lubrication


Hussam Adeni
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Meaning of lubrication
Friction - is created when there is

relative motion between two surfaces


Resistance to motion is defined as
friction
Lubrication is use of a material
between surfaces to reduce friction
Any material used is called a lubricant
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Methods of lubrication
Two main methods

Hydrodynamic lubrication
Boundary lubrication
Hydrodynamic lubrication
Also called complete or full flow
Occurs when two surfaces are
completed separated by a fluid film
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Methods of lubrication

cont..

Two main methods

Hydrodynamic lubrication
Boundary lubrication
Boundary lubrication
Occurs when Hydrodynamic lubrication
fails.
By adsorption or chemical reaction
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Types of Lubricant - Physical


Liquid
Solid
Semi solid
Gases

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Types of Lubricant - Physical


Liquid
Typical lubricants are liquid/fluids
Mineral oil or synthetic oils

Solid
Graphite, MoS2

Semi solid
Greases

Gases
Atomised 2 stroke oils

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Typical lubricants - Application


Engine oils
Gear Oils
Turbine Oils
Hydraulic Oils
Metal working oils
Cutting oils
Forming Oils
Rust preventives
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Typical lubricants - Application


Heat Transfer Oils
Heat Treatment Oils
Quenching Oils
Tempering Oils
Refrigeration Oils
Rubber Process Oils
Ink process Oils
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Lubricant - Components
Base Oils
Mineral by-products of crude oil refining
process.
Base oils are polymerized or
synthesized further and called synthetic
Additives
Natural
Synthetic
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Function of a lubricant
Lubricate - Reduce friction
Cooling - Heat transfer
Cleaning - Detergency
Noise pollution - dampening
Sealing prevent leakage
Protection prevent wear

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Lubricate reduce friction


The effects of friction
Metal to metal contact
Leads to wear and tear
Generates heat
Results in Power loss
Lubricant reduces friction by

forming a film

Reduces ill effect of friction


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Cooling
When fuel is burnt in an engine
33% is useful power
33% removed by cooling water
33% by lube oil and radiation
Lube oil removes heat from all areas and

brings it to the engine sump.


Improper cooling can lead to over
heating, lead to wear, distortion and
failure.
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Cleaning
Cleans carbon and varnish deposits
Flushes the entire system removing

Soot
Deposits
Acids
Wear products
Moisture

Removes external contaminants dust,

moisture (external)

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Noise reduction
Reduce noise
By preventing metal to metal contact
Dampens noise
As between camshaft and tappet

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Sealing
Oil film
Between piston ring and liner
Helps in creating a gas tight seal

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Protection
Protection against acids and

moisture

Very important to increase life of

component and equipment

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Properties of lubricants
Kinematic viscosity
Viscosity index
Pour Point
Flash Point
Total Base Number (TBN)

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Properties of lubricants
Kinematic viscosity
Measure of internal resistance to flow
Thickness of fluid (in laymen terms)
Decreases with increase in temperature
Important in lubricant selection
Increase in used oil indicates oxidation
Specified at 40C and 100C
Measured in Centi Stokes (CSt)
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Kinematic Viscosity Recommendations


Low Viscosity oils used
High speeds
Low pressure
Low temperature
High Viscosity oils used
Low speeds
High pressure
High temperature
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Properties of lubricants
Viscosity index
Measure of fluids change of viscosity
with temperature.
Empirical number
Higher the VI lower will be the
change of viscosity with temperature
Indicator of temperature range of
operations
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Properties of lubricants
Pour Point
Lowest temperature at which the fluid
will flow
Indicates lowest operating
temperature
Measured in C

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Properties of lubricants
Flash Point
Lowest temperature at which the vapor
above the liquid will ignite under flame
Indicated safe maximum temperature of
operation.
Indicator of volatility
Test method - COC and PMCC
Measured in C
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Properties of lubricants
Total Base Number (TBN)
Measured the acid neutralizing reserve
in oil.
Important for deciding discard of oil
Decreases due to
Oxidation of oil
Water contamination
Fuel contamination

Measured in Mg KOH/gm of oil


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Lab Tests - for lubricants

Kinematic viscosity
Viscosity index
Pour Point
Flash Point
Total Base Number
(TBN)
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ASTM
ASTM
ASTM
ASTM
ASTM
ASTM

D
D
D
D
D
D

445
2250
97
92 (COC)
93 (PMCC)
664

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What are additives


Lubricant additives
classified on their functional capability
Enhance existing property
Suppress undesirable property
Impart new property

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What are additives


What they do in Engine Oils
Protect metal surfaces
-

(rings, bearings, gears, etc.)

Extend the range of lubricant


applicability
Extend lubricant life

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Surface Protective additives


Anti wear and EP Agent
Corrosion & Rust inhibitor
Detergent
Dispersant
Friction modifier

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Surface Protective additives


- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Anti wear & EP Agent


Reduce friction & wear.
Prevent scoring & seizure
ZDDP, Organic Phosphates, acid
phosphates, organic sulfur and
chlorine compounds etc.
Chemical reaction with metal surface
and forms a film.
Prevents metal-to-metal contact

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Surface Protective additives


- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Corrosion and Rust Inhibitor


Prevent corrosion and rusting of the
metallic parts in contact with lubricant
ZDDP, Metal phenolates, Basic Metal
sulphonates, fatty acid & Amines.
Preferential adsorbtion of polar
constituent on metal surface.
Provide protective film
Neutralize corrosive acids
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Surface Protective additives


- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Detergents
Keep surface free of deposits
Metallo organic compounds of Sodium,
Calcium and Magnesium phenolates
Phosphonates and sulphonates
Chemical reaction with sludge and
varnish percursors to neutralize them
and keep them soluble

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Surface Protective additives


- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Dispersant
Keep insoluble contaminants dispersed
in the lubricant
Alkylsuccinimides, alkylsuccinic esters
and mannich reaction products
Contaminants are bonded by polar
attraction to dispersant molecules.
Prevented from agglomerating
Kept in suspension due to solubility of
dispersant
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Surface Protective additives


- Automotive Lubricants
Additive type
Purpose
Typical

compounds

Function

Friction modifier
Alters coefficient of friction
Organic fatty acids and amides.
Lard Oil, high molecular weight
organic phosphorus.
Phosphoric acid esters
Preferential adsorbtion of surface
active materials

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Lube.specialist@gmail.com

Performance additives
- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Pour Point Depressant


Enable lubricant to flow at lo
temperature
Alkylated naphthalene
Phenolic polymers, Ploymethacrylates
Maleate/fumerate copolymer esters
Modify wax crystal formation to reduce
interlocking

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Performance additives
- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Seal swell Agent


Swell elastomeric seals, gaskets
Organic phosphates
Aromatic hydro carbons
Chemical reaction with with elastomer
to cause slight swell.

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Performance additives
- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Viscosity modifier
Reduce the rate of viscosity change
with temperature
Polymers and copolymers of olefins,
methacrylates, dienes
Alkylated styrenes.
Polymers expand with increasing
temperatures
This counteract oil thinning

Hussam Adeni

Lube.specialist@gmail.com

Performance additives
- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Antifoamant
Prevent lubricant from forming a
persistent foam
Silicone polymers
Organic copolymers
Reduce Surface tension to speed
collapse of foam

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Lube.specialist@gmail.com

Performance additives
- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Antioxidant
Retard oxidative decomposition
ZDDP,
Hindered phenols, Aromatic Amines,
sulfurized phenols
Decompose peroxides
Terminates free-radical reactions

Hussam Adeni

Lube.specialist@gmail.com

Performance additives
- Automotive Lubricants
Additive type
Purpose
Typical

compounds
Function

Metal deactivator
Reduce catalytic effect of metals on
oxidation rate
Organic complexes containing nitrogen
or sulfur
Amines, sulphides and Phosphates
Forms inactive film on metal surfaces
by complexing with metallic ions

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Lubricant - Nomenclature
and Specifications

Nomenclature
Crankcase oils - SAE numbers
Viscosity classification ISO 3448
Grease NLGI Numbers

Performance
Crankcase oils - Performance levels
Crankcase oils OEM Specifications
US Military US-MIL-2104
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ISO VG

AGMA

SAE
Engine
Oils

SAE
Gear
Oils
10000

5000

Viscosity Grade Classification


Systems

3000

2000

ISO Industrial Oils


cSt @ 40C

1000

AGMA Industrial Gear Oils


cSt @ 40C

SAE Engine Oils


cSt @100C, cP @150C

500
400
300
200

cP @ -10C to -40C

SAE Gear Oils


cSt @100C
cP @ -12C to -55C

100

60

Lubricant - Specifications

Crankcase oils - SAE numbers


Crankcase oils - Performance levels
Crankcase oils OEM Specifications
Viscosity classification
Grease specification

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Major specifying
organizations
SAE Society of Automotive Engineers

(USA)
API - American Petroleum Institute
US Military Specs US - MIL 2104 CCMC European Specification
ISO International Standard Organization
ISO 3348
NLGI National Lubricating Grease Institute

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SAE viscosity grades for


engine oils
Designated
With corresponding viscosity
For high temperature application
Warmer areas/regions
SAE 20
SAE 30
SAE 40
SAE 10
SAE 50
SAE 60
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SAE viscosity grades for


engine oils
Designated
With corresponding viscosity
For low temperature application
Colder areas/regions
SAE 0 W
SAE 5 W
SAE 10 W
SAE 15 W
SAE 20 W
SAE 25 W
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SAE viscosity grades for


Mono grades - Engine Oils
Mono grades are designated
with single SAE number

SAE 10, 20, 30, 40, 50


SAE 5W,10W, 15W,20W,25W
Can be used either in summer season or in
winter seasons.
Gradual shift to multi grades.
Shift also due to lower oil consumption by
multi grades
Available as Engine oil and Gear Oils
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SAE viscosity grades for


Multi grades - Engine Oils
Multi grades are designated
with two SAE number
Widely in use today
SAE 10w/30, 15w/30, 25w/50
SAE 5W/30, 20W/40
Suitable for use in winter and summer
months or seasons
Available in Engine oils & Gear oil

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SAE Crankcase Oil - Viscosity


classification Winter Service
SAE
Viscosity
Grade

Low temp viscosities


High temp viscosities
Max. Temp for Vis. at 100C,
Engine cranking
High shear
(cP) 150C
Max. cPs at Temp pumping viscosity cSt
of 60,000 cP(C)
(C)
Min
Max & 106 S-
Min

Winter Service
6200@ -35
0W

-40

3.8

5W

6200@ -30

-35

3.8

10W

7000@ -25

-30

4.1

15W

7000@ -20

-25

5.6

20W

9500@ -15

-20

5.6

25W

13000@ -10

-15

9.3

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--

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SAE Crankcase Oil - Viscosity


classification Summer Service
SAE
Viscosity
Grade

Low temp viscosities


High temp viscosities
Max. Temp for Vis. at 100C, cSt
Engine
High shear
pumping
(cP) 150C &
cranking Max.
Min
Max 106 S- Min
viscosity of
cPs at Temp
60,000 cP(C)
(C)

Summer Service
20

--

5.6

<9.3

2.6

30

--

9.3

<12.5

2.9

40

--

12.5

<16.3

3.5

40

--

12.5

<16.3

3.7

50

--

16.3

<21.9

3.7

60

--

21.9

<26.1

3.7

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API Automotive Gasoline Engine


Service Categories SA, SB,
Category

SA

Related Ind
Definitions
Straight Min None

Engine Test Requirements

SB

Inhibited only CRC L-4

Sequence IIA

Sequence IIIA

SC

1964 Models

CRC L-38
Sequence IV

Sequence IIA
Sequence V

Sequence IIIA
Fuel -1% S

SD

1968 Models

CRC L-38
Sequence IIB
Sequence IV
Sequence VB
Caterpillar L-1 Caterpillar IH

Sequence IIIB
Falcon Rust

SE

1972 Models

CRC-L-38
Sequence IIB
Sequence IIID Sequence VC

Sequence IIIC
Sequence VD

SF

1980 Models

CRC-L-38
Sequence IID
Sequence IIIE Sequence VD

Sequence IIID

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API Automotive Gasoline Engine


Service Categories SA, SB,
Category

SG
SH

Related Ind
Engine Test Requirements
Definitions
1989 Models CRC-L-38
Sequence IID
Sequence IIIE
Sequence VE Caterpillar IH2
1994 Models

CRC-L-38
Sequence VE

Sequence IID

Sequence IIIE

Category SA, SB, SC, SD, SE,SF,SG,SH have been declared as obsolete.

SJ

1997 Models

CRC-L-38
Sequence VE

Sequence IID

SL

2001 Models

Sequence IIIF Sequence IVA


Sequence VIII

Sequence VG

SM

2004 Models

Sequence IIIG Sequence IVA


Sequence VIII

Sequence VG

Sequence IIIE

Category SJ, SL, SM, are currently valid.


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API Automotive Diesel Engine


Service Categories CA, CB,
Category

CA
CB
CC
CD
CD-II

Related
US Mil spec
MIL-L-2104A

Engine Test Requirements


CRC L-38

MIL-L-2104A
CRC
Supplement 1
MIL-L-2104B
CRC
MIL-L-46152B
MIL-L-2104C/D/E, CRC
MIL-L-45199B,
Series 3
MIL-L-2104D/E
CRC
2 stroke Hvy Dty

Caterpillar L-1

Fuel 0.4% S

L-38

Caterpillar L-1

Fuel 0.4% S

L-38

Sequence IID

Caterpillar IH2

L-38

Caterpillar I G2

L-38

Caterpillar 1 G2 Detroit Diesel


6V53T
Caterpillar 1 G2 Cummins NTC 400
Mack T-7

CE

None

CRC L-38
Mack T-6

CF

None

CRC L-38
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API Automotive Diesel Engine


Service Categories CA, CB,
Category

CF-2

Related Ind
Engine Test Requirements
Spec
None
CRC L-38 Detroit Diesel 6V92TA Caterpillar 1M-PC

CF-4

None

CRC L-38 Cummins NTC-400


Mack T-7
CRC L-38 Sequence IIIE
Mack T-8 RFWT
Mack T8E Sequence IIIE
RFWT
Mach T-9

Caterpillar 1K

CG-4

None

CH-4

None

CI-4

None

RFWT
EOAT

Cummins M11 EGR


Mack T-8E, T-10

Caterpillar 1R, 1K
Sequence IIIF

CI-4Plus

None

RFWT
EOAT

Cummins M11 EGR


Caterpillar 1R, 1K
Mack T-8E, T-10,T-11 Sequence IIIF

Caterpillar 1N
Caterpillar 1P, 1K
Cummins M 11

CA to CE obsolete; CF onwards are currently valid


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ISO 3448 Kin Vis - CSt 40C


vs SUS 100F (40C)
Midpoint

Minimum

VG 2

2.2

1.98

2.42

VG 3

3.2

2.88

3.52

VG 5

4.6

4.14

5.06

VG 7

6.8

6.12

7.48

VG 10

10

11

60

VG 15

15

13.5

16.5

75

VG 22

22

19.8

24.2

105

VG 32

32

28.8

35.2

150

VG 46

46

41.4

50.6

215

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Maximum

SUS 100F

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ISO 3448 Kin Vis - CSt 40C


versus SUS 100F (40C)
Midpoint

Minimum

Maximum

SUS 100F

68

61.2

74.8

315

VG 100

100

90

110

465

VG 150

150

135

165

700

VG 220

220

198

242

1000

VG 320

320

288

352

1500

VG 460

460

414

506

2150

VG 680

680

612

748

3150

VG 1000

1000

900

1100

4650

VG 1500

1500

1350

1650

7000

VG 68

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National Lubricating Grease


Institute - NLGI Numbers
NLGI Grade Number

ASTM worked penetration 77F


(25C)

000

445

475

00

400

430

355

385

310

340

265

295

220

250

175

205

130

160

85
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Thank you

Hussam Adeni

Lube.specialist@gmail.com

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