SAIGONPAPER CORP.

| 1

Tm tt c s ha hc
qu trnh kh mc
I. C TNH CA MC IN
Thnh phn ha hc v phng php lm kh mc in quyt nh kh nng kh
mc ca giy loi. Mc cho in offset ngui thng c c cng thc ph hp cho
TM TT C S HA HC QU TRNH KH MC

phng php lm kh bng cch thm ht. Giy sau khi in thng d c kh mc.
In Rotogravure s dng cc dung mi c tnh bay hi cao nh toluene. Phng
php lm kh khng thay i cu trc ha hc ca mc khin cho giy c kh
mc trong mi trng kim.
Trong phng php sy kh c nh mc ca in offset nng, du khong b bay
hi. Nha mc nng chy v bm vo t giy. Giy ti thu hi ca loi ny cng d
c kh mc khi thi gian lu tr khng lu.
Giy loi t phng php in Flexographic thng kh kh mc bng cng ngh
tuyn ni trong mi trng kim. Cht gn kt ca mc nc cho phng php in
flexographic (thng l nha acrylate) b ha tan v gii phng nhng ht mc rt
nh. Do kch thc nh ca mnh, mc flexo c loi b hiu qu hn bng phng
php ra.

Mc in vi thnh phn cu to ph hp cho phng php lm kh bng oxy ha

nh du lanh hoc nha alkyd. Nhng thnh phn ny hp th oxi trong khng kh,
b oxy ha v to ra phn t lin kt mng khng ha tan. Chng bm rt cht vo
giy. V l do ny, mc lm kh bng oxy ha kh c loi b. Phng php lm kh
mc in bng bc x cng lm cc cht gn kt trong mc kh tch khi s si.
Tnh nng kh mc ca giy loi gim i theo thi gian. N cng chu nh hng
nhiu bi cc tc ng mi trng nh nhit , m, bc x

II. STICKY
Sticky l hn hp cc hp cht hu c dnh c trong giy thu hi. Chng c th
c loi ra khi huyn ph bt. Chng d dng kt ta, gy deposit trong qu trnh
thu hi, trn my giy hoc trn sn phm. Sticky c phn loi theo:

SAIGONPAPER CORP.| 2

* Kch c - Loi - Phn ng: Kch c - Sticky ln thng c gi li trn sng c

kch thc khe 0.15 mm v c th b loi b bng h thng sng lc ca my giy.
Micro sticky khng th loi b bng sng.
* Loi Loi nguyn thy, loi th cp: Cc iu kin sc v mt ha hc, vt l
ca my giy thng to ra sticky th cp. Thay i pH, in tch gy kt t cc
thnh phn hu c dng ha tan hoc dng keo. Loi sticky th cp ny thng
gy deposits trn my giy hoc mn li. Tng tc ca vi thnh phn ha hc
hoc axit nha ng vai tr chnh trong vic to thnh sticky th cp.
TM TT C S HA HC QU TRNH KH MC

* Phn ng tng tc gia s si nguyn thy, ph gia ha cht, cc thnh

phn trong s si thu hi c th gy deposit: Ngun gc ca sticky thng phc tp.
Cc cht dnh phn tn, dung mi, hot melts l ngun chnh ca stickies. Mc in
c cho l nguyn nhn chnh ca sticky mc d cha c nghin cu chnh thc.
Cc cht kt dnh trong giy trng v nhng dn xut t g l ngun gy dnh
chnh. Bt nguyn thy, c bit l bt c cng l ngun gc gy dnh. N ph
thuc vo lng v thnh phn ha hc ca nha v cc cht trch ly trong g. Cc
cht ph gia trong ngnh giy c th tng tc vi nhau hoc vi cc cht trong
huyn ph bt to thnh sticky th cp. iu ny c thy r khi vng tun hon
nc c khp kn, cc cht hu c tch t tng ln.
V d: Cc cht tng bn t mang c tnh cation phn ng vi cc cht mang
mu anion to nn sticky. Lng silicate d tc ng mnh ti hiu qu ca cationic
polyamine v polyethylenceimine polymers trong h bo lu ca my giy. Tuy
nhin Bentonite polyacrylamide t b nh hng bi tc ng ca silicat.
Cc ha cht tuyn ni d c th c chuyn sang my giy. Chng c mt
trong deposit. Tuy nhin c th chng khng phi l nguyn nhan trc tip gy ra
vn ny. Vic a vo cc ion nc cng c the gy ra deposit bng cch kt ta
huyn ph nha, to cc mui canxi ca axit bo v hoc axit nha.

III. PHNG PHP NH LNG STICKY V DEPOSIT

1. Phng php trch ly
Li ch ca phng php trch ly tng giai on l tt c cc thnh phn sticky
c ha tan. Ethanol l ha cht c s dng rng ri v c dng u tin v
hu ht cc cht nha trong g, du hydro carbon, cc cht ha do tan tt trong

SAIGONPAPER CORP.| 3

ethanol nng. Kt qu phn tch trch ly khng ch r thnh phn sticky. N ch c

tnh nh lng. Hm lng cc cht trch ly cao ch ra nguy c cao gy sticky v
deposit.
2. Phng php kim tra handsheet
Trong phng php ny, phn mm phn tch hnh nh c s dng xc nh
lng sticky.
3. Phng php sng
TM TT C S HA HC QU TRNH KH MC

y l phng php c s dng rng ri v kt qu thu c ng thi phn

nh kh nng loi b sticky bng sng ca h thng x l giy loi. Ch , trong
phng php ny, nhng thnh phn sticky nh hn khe sng khng c xc nh.
Nhng tp cht l nh cao su, plastic cng nh hng n kt qu th nghim.
4. Phng php kt ta
Phng php ny c s dng xc nh sticky th cp bng cch to ra bin
ng l ha khin cc cht keo t in tch m kt ta. phng php ny, 2 mnh
li ca my giy lm t polyester hoc polyamid c vo dung dich bt c
khuy trn. Nhu cu in tch dng (cationic demand) ca dung dch c xc
nh trc... Cationic polyethyleneimin c b sung vi th tch 1/3, 2/3 so vi nhu
cu kt ta cc cht keo. Sau mnh li c ra nh v sy kh. Kt qu
c nh gi bng % din tch li b bt kn.

IV. CNG CA NC
cng ca nc l mt thng s quan trong nh hng ti tuyn ni v ha
hc phn t ca my giy. cng nc gy ra bi ion kim loi a ha tr. Ion ny
c kh nng phn ng vi x phng to kt ta, hoc phn ng vi cc anion khc
to cn. Nhng ion ny thng l calcium, magnesium, strontium, Mn.
cng nc thng c th hin bng n v CaCO 3. Phng php chun
EDTA l phng php tiu chun hin nay xc nh cng. Trong phng php
ny, dung dich ethylenediaminetetraacetic acid (EDTA) hoc mui kim ca n c
dung lm cht chun .
cng tm thi l cng c th b loi b bng cc un si dung dch hoc
b sung vi (calcium hydroxide). Calcium bicarbonate ha tan trong nc l nguyn
nhn chnh.

SAIGONPAPER CORP.| 4

cng tht khng th loi b bng phng php un si. N gy ra bi canxi

v magnesium sulfates trong nc.
IV. C S HA HC CA KH MC
Tuyn ni hoc ra l 2 phng php chnh c s dng tuyn ni. C nhiu
nghin cu v kh mc, tuy nhin c s l thuyt vn cha r rng. Thng thng
kh mc bao gm 2 giai on. Tch mc khi s si v kh mc khi dung dch bt.
2 giai on ny c nhiu tng tc gia cc ht m trong ha hc b mt c

TM TT C S HA HC QU TRNH KH MC

nhng nh hng quan trng

Nhng tng tc ny bao gm:

Mng mc in b mt s si (tch mc)

Ht mc ht mc (phn tn, kt t)
Ht mc s si (ti kt t)
Ht mc ht thu gom (tuyn ni)
Ht mc - bng kh (tuyn ni)
S si, cht n bong kh (tuyn ni)

1. Tch mc - Ink release

Trong h quy, 2 phn ng din ra ng thi to micelles. X phng ha du
ca ht mc bi kim v hp th a nc, k nc ca x phng ln b mt ca du
mc.

Sau khi hp th phn axit k nc ca phn t x phng, phn t x phng b

solvate ha, ht mc tr nn a nc v b ko ra khi s si. Ph thuc vo thi
gian lu tr ca giy loi cng nh mc oxy ha ca ht mc bi khng kh, qu
trnh x phng ha ny c th kh hay d xy ra.
Kim trong h quy ci thin s tch mc khi s si v gim s phn r ca ht
mc. Tuy nhin vi hn hp giy c cha mc in nc flexo, iu kin kim thng
thng s cho kt qu km v iu kin pH trung ha l cn thit. iu kin ny
s t lm phn r ht mc, t tp cht anion, t ti kt ta ht mc.
tch mc khi s si, cc qu trnh sau cn phi t c:
- B mt mc phi c lm t hon ton bi nc, nc c th thm vo gia
mc v s si.
- Mng mc in c phn r nh d tch khi s si. Nu mng mc i qu
su vo s si, chng s b kt v kh tch khi s si.
Nc kh lm t b mt ht mc du. S lm t ny c ci thin bi:

SAIGONPAPER CORP.| 5

- Hp th cht hot ng b mt ln ht mc
- Hp th cht hot ng c ngun gc t bt c, giy trng ph
Cht hot ng b mt phn tn h tr qu trnh tch mc khi s si v cn tr
hin tng ti kt ta ca mc trong qu trnh tuyn ni.
Cht hot ng b mt khng in tch nh ethoxylated linear alcohols,
ethoxylated alkyl phenols, ethoxylated fatty acids, oligoethylene-oxide alkyl ether
v polyethyleneoxide alkyl ether c s dng rng ri trong nh my kh mc v
TM TT C S HA HC QU TRNH KH MC

chng khng chu nh hng ca nc cng v tnh cht a nc k nc ca

chng d kim sot bi qu trnh tng hp.
Mt trong nhng cht hot ng b mt thng c dng trong tuyn ni kh
mc l x phng ca axit bo. Thng thng axit bo phn ng vi calcium ions
trong h thng to thnh x phng canxi. X phng ny c th hp th ln b
mt ht mc v to ra phn ng thu gom (collector action). X phng ca axit bo
khng c tnh phn tn tt. Ch c dng axit t do, axit bo mi c tnh phn tn.
Nha alkyd b x phng ha mt phn bi mi trng kim phn r mng phim
mc thnh nhng phn nh. Qu trnh trng n, s si v cc tc ng c hc y
nhanh s tch mc khi s si.
Tuy nhin, mc ca giy loi lu ngy ca phng php in offset, xerographic l,
mc n nh bng tia UV kh b loi b v chng bn v mm do. Mt lng ln
mc b gi trn s si (m mc) mc t giy trng ph d c tch ra hn giy
thng thng v mng phim mc nm trn lp trng. Lp trng ny d c tch
khi s si trong iu kin ca h quy.
Mc ch c th tch hiu qu trong giai on tuyn ni nu ht mc khng b
phn r qu nh. Ht mc ln khng i su vo bn trong s si v b loi b.
Bn cht ca cht hot ng b mt nh hng nhiu n hin tng phn r mc.
S dng giy tp ch nh mt phn nguyn liu lm gim hin tng ny.
Trong iu kin kh mc thng thng, sodium silicat lm gim hin tng phn
r mc, thm ch ngay c khi khng c cht hot ng b mt. Sodium silicate, l
mt polimer tan trong nc, n c th kt hp vi cc ion a ha tr. N cn c vai
tr nh l cht kt t (collector) cht n nh. N ci thin tnh phn tn ca mc,
gim hin tng ti kt ta mc. Tuy nhin hot ng ca chng b nh hng bi
cc cht hot ng b mt cation.

SAIGONPAPER CORP.| 6

Hiu tng tc gia cc ha cht kt hp vi cc thng s cng ngh s to iu

kin kh mc tt nht. Cht hot ng b mt khng in tch hot ng tt khi
lng s dng silicat nh, nhit h quy cao. Tri li, axit bo tch mc tt hn
khi lng s dng silicate cao hn. Thi gian lu h quy ti thiu s gim lng
mc b phn r v ti kt ta. Lng mc bm trn s si s gim (ERIC gim, khi
lng ha cht kh mc tng, mc dng kim tng, nhit h quy tng.
Mc tch ra khi s si c th ti kt ta trn s si. Hydrogen peroxide and
EDTA c cho vo h quy gim hin tng lm en bt trong mi trng kim.
TM TT C S HA HC QU TRNH KH MC

2. Tuyn ni
Sau khi tch ra khi s si, mc cn c tch ra khi dung dch bt. Tnh cht
b mt ca ht mc nh hng n hiu qu kh mc. Cc ht mc a nc thch
hp cho phng php ra. Phng php tuyn ni yu cu cc ht mc c tnh k
nc. Trong thit b tuyn ni cc ht mc bm vo bong kh v ni ln trn. Mc
tch ra t s si thng c kch thc nh (<10 m) v c tnh a nc, khng thch
hp cho tuyn ni. Kch thc ti u cho tuyn ni ca cc ht mc trong khong 10
- 100 m. Cht kt t (collector) s kt t cc ht mc thnh cc ht c kch thc
to hn ng thi to cho cc ht ny c tnh k nc v bm vo bong kh. Nhiu
loi cht k t (collector) hin ang c s dng nh fatty axit, bn tng hp, tng
hp. Axit bo thng c s dng lm cht kt t (collector) do chng c kh nng
to xa phng vi ion canxi, x phng ny c i lc vi cc ht mc. Nhm chc axit
cui mch phn t d dng to phc vi ion canxi to x phng kt ta. X phng
ny cui cng kt hp vi cc ht mc to cho chng tnh k nc.
RCOOH + NaOH -> RCOONa (tan) + H20
2RCOONa + Ca(OH)2 -> (RCOO)2Ca + 2NaOH

Mui ca x phng vi canxi kt ta trn b mt s si to cho mc c tnh k

nc. N cng kt t cc ht mc nh thnh cc ht mc c kch thc ln hn v
c kh nng gn vo cc bng kh. Khi stearate/ink v stearate/bong kh va chm,
canxi s ti sp xp to cu ni gn kt mc vi bong kh. X phng yu cu
cng nc cng ngh ti thiu hot ng tt. N vo khong 10dH (hoc 100 200ppm).
Hin ti x phng axit bo c dng rng ri kh mc hn hp giy bo c
v tp ch c (ONPOMG). Vi c ch ha hc trn, x phng hot ng tt, trng

SAIGONPAPER CORP.| 7

cui cng bt cao. N phn ng tt vi nhng bin ng trong nguyn liu giy, tuy
nhin n c mt s nhc im sau:
- Mc dng cao hn so vi ha cht kt t tng hp v bn tng hp, lng ha
cht d c th nh hng n phn t ca my giy.
- Do hot ng tt, x phng cn c hm lng canxi. Lng canxi ny c th
dn ti cc vn cn bm v canxi d to kt ta vi silicate, oxalate, carbonate,
x phng, nha thng.

TM TT C S HA HC QU TRNH KH MC

Nhiu cht kt t tng hp c s dng, tuy nhin c ch hot ng cha r

rng. Mt nhm cht kt t khng in tch nh ethoxylated Fatty acids hoc cc
bin th ethoxylated, propoxylated hydroxy esters ca axit bo hoc polyethylene
oxide v polypropylene oxide copolymers.
Yu t chung cho cc cht hot ng b mt khng in tch ny l s c mt
lin kt ester. Lin kt ny d b thy phn trong mi trng kim. C th trong giai
on u, chng hot ng nh cc cht phn tn. Sau khi thy phn v mt chui
ethoxylate, chng tr thnh cht kt t k nc. S c mt ca lin kt ester cng
l mt li ch v chng ngn cn s tch t qu mc ca ha cht trong nc cng
ngh. Tng t x phng, cht hot ng b mt tng hp c phn k nc v phn
a nc.

Cht kt t tng hp c th hot ng tt m khng chu nh hng ca nc

cng. Do nguy c cu cn gim. Yu im ca chng l chng hot ng khng
tt trong thit b tuyn ni v thng cho trng bt thp hn xa phng.
Cht hot ng b mt tng hp c th l anion, trung tnh hay cation. Anionic
c tnh tan cao, iu ny gy nguy c tch t ha cht trong nc. Chng to bt
nhiu gy gim hiu xut tuyn ni, lng s si tht thot cao. Cationic surfactants
d dng hp th ln s si cng gy tht thot s si cao. Cht kt t bn tng hp
dng nh tng (emulsion) d tan trong nc. Thnh phn chnh ca chng l
acid bo v cc dn xut ca chng, cht hot ng b mt, nc. Kt hp gia x
phng v nh tng cho kt qu:
So snh vi x phng:
- t lng ha cht d ti my giy.
- Hot ng cng nc thp hn.
- Hiu xut thu hi bt cao hn

SAIGONPAPER CORP.| 8

So snh vi nh tng:
- Kim sot bt tt
- trng bt cao
Nguyn liu c hm lng tro cao lm r iu ny, v d, 100% nh tng c th
gy lng bt rt nhiu.
Sau khi la chn ha cht ph hp, c nhiu yu t khc nh hng n hiu
qu tuyn ni nh kh nng tch mc ra khi s si, va chm gia mc v bong kh,
TM TT C S HA HC QU TRNH KH MC

nng lng b mt din tch tip xc ca mc v bng kh, bn ca bt

Tc tuyn ni ph thuc v kch thc ca ht mc v kch thc bng kh.
Tc ni tng khi kch thc ht tng. iu ny gii thch ti sao cc ht mc nh
di 5 m rt kh ni. ngoi ra, cc ht mc nh kh c tch ra khi mc l do
chng thiu ng nng cn thit bm ln cc bng kh. i vi nhiu loi mc,
di tc ng ca nng lng v ha hc, ht mc tch ra khi s si c kch thc
rt nh do mc b phn r. iu ny x ra vi mc in offset lu ngy, xerographic
toners v phn li cc loi mc nc ca phng php in flexo. Ngoi vic ti u
ha giai on tch mc gim thiu hin tng phn r mc ti kch thc nh,
bin php khc ci thin tnh hnh l s dng ha cht, kt t cc ht mc ti
kch thc to hn.
Bt kh nh s lm tng kh nng ni cho cc ht mc nh. Tuy nhin chng c
th kt trong s si v gy tiu hao bt cao. Nu bong kh ln, chng ch gn kt vi
mt vi ht mc ln. Nu lin kt gia mc v s si cao, s si s b tn tht. Bng
kh phi c kch thc ti u (kch thc bng kh trung bnh khong 0.25 mm).
Thit b tuyn ni to ra bng kh c kch thc phn b rng c th tch b ng
thi nhng ht mc nh v ln.
Tnh cht to bt ca bt rt quan trng cho vic kim sot qu trnh tuyn ni.
Kh nng to bt chu nh hng bi nhiu yu t. Mt trong yu t quan trng nht
l lng giy tp ch c trng ph hoc khng trng ph c trong nguyn liu. Ngi
ta gi nh cc cht n trong loi giy ny cng vi cc cht hu c c trong lp
trng c vai tr quan trng trong vic n nh bt ca dung dch. Thng thng rt
t bt hoc mc c loi b khi trong nguyn liu khng c OMG. Bt nhiu v
lng s si tht thot cao. Cn bng gia lng cht khong (t OMG) v mc in
du ca OMP l yu t quan trng cho hiu qu tuyn ni. Trc tin cc cht
khong to thun li cho vic loi b lp ph trn bt kh. Sau mc du c hp

SAIGONPAPER CORP.| 9

th ln cc thnh phn khong ca OMG. Tc ng ph bt ca mc du trong ONP

b gim nhiu. V vy to ra lng bt cn thit tuyn ni hiu qu. Cht hot
ng b mt trung tnh c s dng rng ri nh cht to bt trong tuyn ni v n
c tnh to bt cao v hot ng c lp vi cng ca nc. H thng s dng
axit bo c th hot ng nh cht kt t cng nh cht to bt v cht phn tn
khi vn cn lng axit bo t do trong dung dch bt. Thc t ch ra rng bn ca
bt rt quan trng cho vic tch mc. Hiu qu tch mc tng khi bn ca bt
tng. Tuy nhin vic tng nng cht to bt c th tng s hp th cc cht hot
TM TT C S HA HC QU TRNH KH MC

ng b mt ln cc ht mc. iu ny dn ti gim tnh k nc ca mc v gim

hiu qu tch mc. Do cn c nng ti u cho chng.
Vai tr ca cht n l quan trng. iu ny c th gii thch ti sao kt qu
tuyn ni tng khi lng OMG c b sung. Tuy nhin hot ng ca cht n vn
cn ang c bn lun. Mt vi nghin cu cho rng bt tals hoc cao lanh tr
gip bt kh ni ln b mt. Khng c chng, bt kh khng c lc ni. Bt kh c
th c kch thc ln v cn s lng nhiu hn loi b cng mt lng mc. Yu
t ny lm gim hiu qu ca thit b tuyn ni. Tng gi thnh vn hnh. Tale v
cao lanh cng c nhiu nhm hydroxyl mang in tch trn b mt ca chng.
Chng c th trung ha in tch dng ca canxi trn b mt ht mc, gim i lc
gia ht mc v s si mang in tch m. Tng hiu qu tuyn ni. Vic s dng
lng OMG l cch r tin b xung cao lanh.
Loi s si cng c nhng tc ng, tuy nhin c ch hot ng vn cn ang
c tranh ci. Mt vi nghin cu cho rng bt c hc d ni hn bt ha nh s
c mt ca nhm lignin k nc v cc cht nha khc. Nhng nghin cu khc ch
ra rng hn hp bt c v bt ha c kh nng ni cao hn. Nghin cu ca Micheal
Ajersch v Robert Pelton cho thy, tht thot bt xy ra ngay c khi khng c s kt
dnh gia bt kh v s si. S tht thot ny x ra khi bt kh b kt c hc gia
mng s si.
in th Zeta cng nh hng n hiu qu tuyn ni. Bt kh v cc ht mc
u mang in tch m v y nhau. trng thi ny, mc khng th ni ln do
khng th gn kt vo bt kh. Khi x phng canxi kt ta trong iu kin d ion
canxi, x phng s kt ta trn b mt ht mc v to cho ht mc c tnh k nc.
in tch ca ht mc cng gim. X phng canxi cng kt t cc ht mc nh

SAIGONPAPER CORP.| 10

thnh cc ht mc ln do tng kh nng va chm v gn kt ht mc ln bt kh,

tng hiu qu tuyn ni.
Cc cht hot ng b mt sulfonate v cc cht hot ng b mt khng in
tch vi chui ethoxylate di c tc ng xu n kh nng ni ca mc. iu ny
c th do lc y steric ngn cn s ph v mng phim cht lng bao quanh bng
kh v ht mc.
bn ca lin kt ht mc bng kh c quyt nh bi cn bng gia lc
gn kt v lc ph hy do tc ng xo trn ca h thng. Lc gn kt ph thuc
TM TT C S HA HC QU TRNH KH MC

tnh k nc ca ht mc. cng ca nc c nh hng mnh ti hiu qu kh

mc v hiu xut ca cht n. Vi h thng s dng x phng hoc hn hp x
phng v nh tng. Tng cng ca nc s tng hiu qu kh mc. cng
nc cn t gi tr nht nh xa phng hot ng. ngun nc c cng
thp, lng tch t x phng trong vng tun hon nc s cao. Do cn ti u
ha gia cng ca nc v mc dng x phng.
Canxi c th phn ng vi sodium silicate v x phng to kt ta. iu ny nh
hng n qu trnh kh mc. cng cao h quy lm gim kt qu kh mc. V
vy ion calcium c hi trong giai on u (h quy) nhng rt cn thit giai on
sau (tuyn ni). C gi nh rng vi tr quan trng nht ca sodium silicate trong
kh mc l n phn ng vi canxi h quy v gim tc ng ca canxi. iu ny
cho php x phng c mt trong pha lng nh l tc nhn phn tn v n nh ht
mc v chng khng chu tc ng kt ta ca canxi. Khi bt ti thit b tuyn ni,
dung dch xy ra s bin i ha hc ln. Nng b pha long 10 ln, pH gim t
10 n 8,5. Di iu kin nh vy, silicate gii phng canxi v kh nng bao bc
ca chng gim. iu ny tng lng canxi t do m lng canxi ny c vai tr nh
cht kt t. Trong qu trnh tuyn ni, nu cng nc thp, ion Ca++ cn c
b sung. Lng Ca++ ny c th gy hin tng cn bm trn thit b.
cng nc nh hn 30 dH (50ppm CaCO 3), hiu xut cht n c lp vi
cng nc. cng nc cao hn, lng cht n b loi b tng ln cng vi
cng nc. pH cao c tc dng tt ti hiu qu kh mc. Silicate trong nhiu
trng hp lm gim hiu qu kh mc c th do phn ng to phc vi canxi.
Khi ht mc c tch ra khi s si v phn tn. C kh nng chng s b ti
kt ta ln s si nu n nh ca chng khng cao. Hin tng ti kt ta ny
khng thun nghch v c th c cn tr bi vic b sung cc ha cht c kh

SAIGONPAPER CORP.| 11

nng to tc ng lm bn steric. Mt vi cht trch ly tch t khi khp kn h thng

nc c tc ng tt v gim hin tng ti kt ta ny.
Ngy nay, xu hng chuyn sang cng ngh pH trung tnh cho php qu trnh
kh mc thch ng vi thnh phn mc mi v ci thin cht lng bt. Bt cht
lng cao c sn xut vi cng ngh trung tnh quy m cng nghip. Bt t
th nghim cng ngh trung tnh c phn ng vi tc ng ca tc nhn ty tng
t vi bt t cng ngh kim tnh. trng cui cng sau ty t 60+. Kt qu ny
gi rng cng ngh kim tnh kt hp vi giai on ty sau s gim chi ph so vi
TM TT C S HA HC QU TRNH KH MC

cng ngh kh mc kim tnh thng thng (ph thuc vo thit b v gi thnh ha
cht). Kt qu o c hm lng micro v macro sticky cho thy bt c sn xut
vi cng ngh trung tnh c lng sticky t hn so vi cng ngh kim tnh. Vic x
l nc cng ngh cng d hn do lng cht ha keo to ra t hn giai on h
quy.

3. Kh mc bng phng php ra

Kh mc bng phng php ra l qu trnh tch nc nng bt nh v
di iu kin xo ng cao. iu kin ny s to thnh lp bt lc b cn tr.
phng php kh mc ny, mc, s si mn v cc phn t i nc khc b cun tri
qua lp bt xo trn. X phng c hot ng tt nht do chng to thnh micelles
bn trong nc mm. Qu trnh ra yu cu ht mc phi c phn tn tt v
khng ti kt ta trn s si.
Do qu trnh ra tiu th lng nc ln nn tuyn ni c s dng nhiu hn.
Nc cng ngh c ti s dng sau khi c lm sch bi thit b DAF.

VI. NH GI HIU QU QU TRNH

nh gi kh nng kh mc in bao gm s dng cc c tnh quang hc nh
trng, mu Bin php khc l xc nh hm lng mc hiu qu c trong bt
(effective residual ink concentration - ERIC). Phng php o da trn phn x ca
t giy vng nh sng 950.
Phng php phn tch hnh nh c s dng rng ri nh gi cc tp cht
c trong bt kh mc. Phng php ny xc nh s lng v kch thc cc ht
mc, nh gi sch c bt. N cng c dng xc nh hiu qu ca tng
giai on kh mc.

SAIGONPAPER CORP.| 12

T khi lng nguyn liu u vo, lng bt sch ra, lng tp cht loi, ta xc
nh c hiu xut ca qu trnh. Hiu sut ny ph thuc vo nhiu yu t cng
ngh, ha hc.

VII. TY TRNG BT KH MC
V l do kinh t, bt ch c ty khi c yu cu trng cao. Ty bng peroxide
c s dng rng ri. Hiu qu ty ph thuc nhiu vo n nh ca peroxide.
TM TT C S HA HC QU TRNH KH MC

Tuy nhin, tc ng lm trng ca peroxide l c hn. Nu yu cu bt c trng

cao hn. Giai on ty kh l cn thit

(1)

(1) Theo Vietpaper

Ti liu ny do Cng ty CP Giy Si Gn tng hp da trn c s cc thng tin tin cy. Tuy nhin chng ti khng
m bo v tnh chnh xc, hon chnh ca cc thng tin ti liu ny. Ti liu ny lu hnh rng ri nhm mc ch
cung cp thng tin lin quan ti ngnh giy v khng nhm phc v nhu cu ring ca bt k ngi c c th no.
Mi sao chp thng tin trong ti liu ny phi trch dn ngun t Cng ty CP Giy Si Gn.