Calculations:

Standardization:

(.1003 / 204.2g/mol x .998 )

.119561445 M
( 4.1mL/1000mL)
(.0998/ 204.2g/mol x .998 )
M of NaOH
.1189656243 M
( 4.1mL/1000mL)
M of NaOH

(.0998 / 204.2g/mol x .998 )

.1189656243M
( 4.1mL/1000mL)
.119561445 M + .1189656243 M+ .1189656243 M
Average M of NaOH
.1191642977 M
3
M of NaOH

Percent Purity:

.1191642977 M x (13.5 mL / 1000 mL)

x 100% 65.71318653%
( .4999 g/204.2 g/mol)
.1191642977 M x (13.65 mL / 1000 mL)
% purity of sample
x 100% 66.4433305%
( .4999 g/204.2 g/mol)
% purity of sample

.1191642977 M x (12.82 mL / 1000 mL)

x 100% 62.3782327%
( .5001 g/204.2 g/mol)
62.3782327 + 66.4433305 + 65.71318653
Average % purity of sample
64.8437801000%
3

% purity of sample

pKa:

trial 1: y .12x + 4.1

eq/2

6.75

y = pK a = 4.91
trial 2: y .12x + 4.08

eq/2

6.825

y = pK a = 4.899
trial 3: y .14x + 3.98

eq/2

6.425

y = pK a = 4.8795
Average pK a

4.91 + 4.899 + 4.8795

4.89616667
3

RSD

.015446

x1000 ppt
X
.015446

x1000 ppt
4.896167
3.154742076
n

XX
SD

i 1

Confidence Limit X

= 4.896167

4.30 .015446

3
4.896167 .03834633471

n1

4.91 4.896167 4.899 4.896167 4.8795 4.896167

2

tSD

= .015446

31