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The International Maritime Dangerous Goods (Imdg) Code: International Safety Panel Briefing Pamphlet No 3
The International Maritime Dangerous Goods (Imdg) Code: International Safety Panel Briefing Pamphlet No 3
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The International Safety Panel Research Paper series consists of the following
research papers:
No. 1
No. 2
No. 3
No. 4
No. 5
No. 6
No. 7
Semi-Automatic Twistlocks
Fumes in Ships Holds (revised)
Health & Safety Assessments in Ports (revised)
Container Top Safety, Lashing and Other Related Matters (partly
under revision as BP#34)
Port & Terminal Accident Statistics (revised)
Safe Handling of Radioactive Materials in Ports and Harbour Areas
(revised)
Ship Design Considerations for Stevedore Safety (revised)
No. 17
General Series
No. 1
No. 2
No. 3
No. 4
No. 5
No. 6
No. 7
CONTENTS
Item
Page
Status/Background
Classification
Product Containment
Documentation
Competent Authorities
Warning
ISBN: 978-1-85330-001-1
First Published:
1st Revision
2nd Revision
3rd Revision
4th Revision
5th Revision
6th Revision
7th Revision
1993
1995
2000
2003
2005
2007
2009
2011
Background
The International Maritime Organization (IMO) is the specialised United
Nations agency with responsibility for international maritime affairs. Like all
United Nations agencies, the IMO is made up of Member States who are
obliged to become contracting parties to IMOs various international
conventions. In addition to the Member States, there are a number of
international organizations who are concerned with maritime issues and who
have Non-Governmental Organization (NGO) status at IMO. ICHCA
International Limited has such status at IMO.
1.1
1.1.1
The International Convention for the Safety of Life at Sea, 1974 (1974 SOLAS
Convention), as amended, Chapter VII of which deals with the safety aspects
of the transport of dangerous goods by sea; and
1.1.2
1.2
1.3
The requirements of the IMDG Code are based upon the Model Regulations
(known as the Orange Book) produced by the United Nations Committee of
Experts on the Transport of Dangerous Goods in Geneva, together with a
number of recommendations for good practice. The requirements of the IMDG
Code are published in 2 volumes with an additional Supplement volume,
which contains a number of individual IMO related publications.
1.4
Most parts of the IMDG Code became mandatory on 1st January 2004, under
the mandatory requirements of the SOLAS Convention. While most Member
States have incorporated the requirements of the IMDG Code without further
amendment into their national legislation, others have applied some different
(usually more stringent) national requirements in addition to those of the
IMDG Code. When shipping dangerous goods, it is important to be aware of
any further restrictions or requirements, which may apply in a particular
country, in addition to the IMDG Code.
1.5
1.7
2.1
2.1.1
2.1.2
2.1.3
2.1.4
2.1.5
2.1.6
2.1.7
3.1
The Code is composed of 7 parts, each part covering one of the principles .1
to .7 outlined above. Central to the IMDG Code is the Dangerous Goods List
(DGL) which is the core of the Code. This contains a list of all the dangerous
goods assigned under the United Nations system in numerical (UN Number)
order, together with their specific transport requirements in a coded system.
3.2
The Code is presented in two books, Volume 1 and Volume 2 with a third
Supplement volume containing related IMO publications and IMO resolutions.
It is necessary to use the first two volumes to obtain the required information
when shipping dangerous goods by sea. The IMDG Code adopts a standard
reference book format with an introduction, main contents, appendices and an
index. Its layout has been harmonised with that of the United Nations Model
Regulations (the Orange Book) which forms the basis of all international
modal regulations covering the transport of dangerous goods (i.e. road, rail,
inland waterway, air and sea). Consequently, the multimodal shipper should
be able to find the same information in the same part of the international
regulations, no matter what form of transport is being used.
Volume One
Volume 1 contains Parts 1, 2, 4, 5, 6 and 7. Details of the contents of each of
these parts are reproduced in the Appendix of this briefing pamphlet.
3.4
Volume Two
Volume 2 is comprised mainly of Part 3 which contains the DGL, a central
index of all the dangerous goods listed in UN Number order, together with
their transport requirements in a coded system presented in 18 columns. The
transport requirements contained in the DGL include:
3.5
2.
Medical First Aid Guide (MFAG) for use on ships in accidents involving
dangerous goods.
3.
4.
5.
6.
INF Code.
7.
Classification
4.1
The purpose of the IMDG Codes classification system is concerned with the
safety of people and is:
Explosives
Class 2
Class 2.1
Flammable gases
Class 2.2
Non-flammable gases
Class 2.3
Toxic gases
Class 3
Flammable liquids
Class 4
Class 4.1
Flammable solids
Class 4.2
Class 4.3
Class 5
Class 5.1
Oxidizing substances
Class 5.2
Organic peroxides
Class 6
Class 6.1
Toxic substances
Class 6.2
Infectious substances
Class 7
Radioactive material
Class 8
Corrosives
Class 9
4.3
Some dangerous goods may present hazards associated with more than one
class. For example, some flammable liquids (class 3) may also be toxic (class
6.1) and some flammable liquids (class 3) may also be toxic (class 6.1) and
corrosive (class 8). When classifying dangerous goods, the main hazard
presented is considered to be the primary hazard and any other hazards (up
to a maximum of 2) are considered to be subsidiary hazards. Dangerous
goods must always be labelled to show all the hazards (i.e. primary and
subsidiary) they present in transport (see 4.4 and 4.5 below).
4.4
Class 5.2 (Organic Peroxides) and self-reactive substances in class 4.1 are
divided into five types (B to F) and further sub-divided according to whether
they are solid or liquid and whether they require temperature control during
transport. This results in 20 group UN Numbers being available to ship both
organic peroxides and self-reactive substances (e.g. UN 3101 for Organic
Peroxide Type B, Liquid and UN 3235 for Self-reactive liquid, Type D,
Temperature-Controlled).
4.6
4.7
As a consequence of MARPOL 73/78 Annex III (see 1.3 above), since 1st
January 1991 items which are harmful to the marine environment, but not to
people or the ship (hitherto the only basis for inclusion in the Code) have
been included in Class 9. All marine pollutants, whether in Class 9 (because
they do not fall under the criteria of classes 1-8) or one of the other classes,
must carry the triangular marine pollutant mark.
4.8
5.1
Dangerous goods in most classes have been sub-divided into three packing
groups (PG) reflecting the degree of danger they present in transport.
Packing Group (PG) I - represents great danger;
Packing Group (PG) II - represents medium danger; and
Packing Group (PG) III - represents minor danger.
5.2
Product containment
Product containment is dealt with in six distinct categories, as follows:a)
b)
c)
Large Packagings
Large packagings consist of an outer packaging having a capacity
exceeding 400 kg net mass or 450 litres capacity up to a volume of not
more than 3m3 and containing either inner packagings or articles.
They are designed to be handled by mechanical means.
If Large Packagings are permitted to be used for all dangerous goods
they are coded into large packing instructions (LP codes) which are
given in column 8 of the DGL. Any special large packing provisions
which apply are coded (LP codes) in column 9 of the DGL. Full details
of the large Packaging Instructions and Special Packing provisions are
found in Chapter 4.1.4.3 of Volume I of the IMDG Code. Details of
testing and examples of large packaging codes are given in Chapter
6.6 of Volume 1 of the IMDG Code.
d)
Bulk Containers
Certain solid dangerous goods may be transported in closed bulk
packagings when indicated in the DGL by the code "BK2" in column
13 of the DGL. Closed bulk containers include freight containers,
skips, offshore bulk containers, bulk bins, swap bodies, trough-shaped
f)
Limited Quantities
When certain dangerous goods are packed in small quantities (as
given in column 7 (a) of the DGL) and the package gross mass does
not exceed 30 kg, they are exempt from the full requirements of the
Code provided they meet the requirements given in Chapter 3.4 of
Volume 2. For more hazardous dangerous goods, including all PG I
dangerous goods, this exemption does not apply and the word None
appears in column 7 (a) of the DGL. This indicates that the full
requirements of the IMDG Code apply and there is no exemption
quantity
g)
Exempted Quantities
A new Chapter 3.5 has been added in the latest edition of the Code
and this is reflected in column 7 (b) of the DGL. This column will
provide an alpha numeric code which indicates the maximum quantity
per inner and outer packaging for transporting dangerous goods as
exempted quantities. The codes are E0 to E5 and the criteria for each
is explained in Chapter 3.5. Excepted quantities of dangerous goods
of certain classes meeting the provisions of this Chapter are not
subject to any other provisions of the Code except for:
1. The training provisions in Chapter 1.3
2. The classification procedures and packing group
criteria in Part 2 Classification
3. The relevant packaging provisions in Part 4
4. The provisions for documentation in Chapter 5.4
Where dangerous goods in excepted quantities for which different
codes are assigned are packaged together, the total quantity per outer
packaging shall be limited to that corresponding to the most restrictive
code. Paragraphs 3.5.2 and 3.5.3 deal with packagings to be used for
excepted quantities and tests for those packagings
Documentation
7.1
8.1
Stowage refers to where (on deck or under deck) and on what sort of ship
(cargo or passenger) different dangerous goods may be stowed, or whether
they are prohibited. There are 5 stowage categories (A to E) and the stowage
category indicating the applicable requirements for each UN Number appear
in column 16 of the DGL (volume 1, chapter 7.1).
8.2
Dangerous goods, which may interact dangerously with each other, need to
be separated (i.e. segregated) from each other. This is achieved by
maintaining a safe distance between:
dangerous goods in the same class (e.g. some acids from alkalis, both
being corrosives (class 8)); and
8.3
The Code specifies four separation distances (3m, 6m, 12m and 24m) which
are coded into a segregation table (volume 1, chapter 7.2), together with
information in the Dangerous Goods List (column 16). These enable the
required level of segregation to be established for different dangerous goods
in various types of shipment (e.g. break bulk, container ships, Ro-Ro etc.).
Segregation within cargo transport units (e.g. freight containers, vehicles) is
also dealt with in chapter 7.2. Similar principles should be applied on shore
when such cargoes are stowed with other dangerous goods and other
cargoes
Competent Authorities
9.1
WARNING
The foregoing necessarily represents a very brief summary of some of the
important aspects dealt with in the IMDG Code. For detailed advice it is
essential to refer to the latest version of the Code itself, read in conjunction
with national legislation etc.
NOTE: ICHCA International provides a technical summary to its members of each set
of changes made to the IMDG Code and also offers a technical advisory service to
answer any queries that might arise
Page
Preamble
iii
Contents
3
9
25
30
33
Part 2 Classification
Chapter 2.0
Chapter 2.1
Chapter 2.2
Chapter 2.3
Chapter 2.4
Introduction
39
Class 1 Explosives
44
Class 2 Gases
52
Class 3 Flammable liquids
55
Flammable Solids; substances liable to spontaneous
combustion; Substances, which in contact with water,
emit flammable gases
59
Chapter 2.5 Class 5 Oxidizing substances and organic peroxides 69
Chapter 2.6 Toxic and infectious substances
84
Chapter 2.7 Class 7 Radioactive materials
92
Chapter 2.8 Class 8 Corrosive substances
112
Chapter 2.9 Class 9 Miscellaneous dangerous substances
and articles
114
Chapter 2.10 Marine pollutants
124
225
230
239
243
254
259
278
295
300
318
337
344
385
389
393
410
453
456
460
462
465
469
471
VOLUME 2
Part 3 - Dangerous Goods List and Limited Quantity Exceptions
Chapter 3.1 General
Chapter 3.2 Dangerous Goods List
Chapter 3.3 Special provisions applicable to certain substances,
materials or articles
Chapter 3.4 Limited quantities
Chapter 3.5 Exempted quantities
195
214
217
223
237
Index
247
3
20