PERHITUNGAN

1. Pembuatan larutan NaOH 0,2 M

N
0,2
=0,2 M
M = ek = 1
M=

gr 1000
.
Mr V

0,2 M =

Massa 1000 ml
.
40 gr /mol 100 ml

Massa =

8 gr
=0,8 gr
10

2. Pembuatan larutan H2C2O4 0,0125 M

N
0,025
=
M = ek =
0,0125 M
2
M=

gr 1000
.
Mr V

Massa
1000 ml
.
0,0125 M = 126 gr /mol 100 ml
Massa =

1,575 gr
10

Massa = 0,1575 gr = 0,2 gr

3. Standarisasi NaOH
Diketahui : V H2C2O4= 5mL
M H2C2O4 = 0,0125 M
V NaOH rata-rata = 1 mL
Ditanya : M NaOH ?...
2 NaOH + H2C2O4
n NaOH = 2. n H2C2O4
n NaOH = 2 . (M . V)
= 2. (0,0125 M . 5 mL)
= 0,125 mol
n NaOH
M NaOH = v rataratatitrasi
M NaOH =

0,125mol
1mL

M NaOH = 0,125 M
4. Kelarutan H2C2O4 sebagai fungsi suhu
a. T = 60 0C
Diketahui :
V H2C2O4 = 5 mL

Na2C2O4 + 2H2O

M NaOH standarisasi = 0,125 M

V NaOH rata rata = 11,15 mL
Ditanya : n H2C2O4
2 NaOH + H2C2O4
Na2C2O4 + 2H2O
n H2C2O4= n NaOH
M H2C2O4 . V H2C2O4 = M NaOH standarisasi . V NaOH
M H2C2O4 5 mL = 0,125 M x 11,15 mL
0,696 mol
M H2C2O4 =
5 mL
M H2C2O4 = 0,139 M
n H2C2O4 = M H2C2O4. V H2C2O4
= 0,1392 M . 5 mL
= 0,696 mol
0
b. T = 50 C
Diketahui :
V H2C2O4 = 5 mL
M NaOH standarisasi = 0,125 M
V NaOH rata rata = 10,05 mL
Ditanya : n H2C2O4
2 NaOH + H2C2O4
Na2C2O4 + 2H2O
n H2C2O4 = . n NaOH
M H2C2O4 . V H2C2O4 = M NaOH standarisasi . V NaOH
M H2C2O4 5 mL = 0,125 M . 10,05 mL
0,628 mol
=0,1256 M
M H2C2O4=
5 mL
n H2C2O4= M H2C2O4. V H2C2O4
= 0,1256 M . 5 mL
= 0,628 mol
0
c. T = 40 C
Diketahui : V H2C2O4 = 5 mL
M NaOH = 0,125 M
V NaOH rata rata = 6,35 mL
2 NaOH + H2C2O4
Na2C2O4 + 2H2O
n H2C2O4 = . n NaOH
M H2C2O4 . V H2C2O4 = M NaOH standarisasi . V NaOH
M H2C2O45 mL = 0,125M . 6,35 mL
0,396 mol
=0,0792 M
M H2C2O4=
5 mL
n H2C2O4= M H2C2O4. V H2C2O4
= 0,0792M . 5 mL
= 0,396 mol
d. T = 30 0C
Diketahui : V H2C2O4 = 5 mL
M NaOH = 0,125 M
V NaOH rata rata = 3,4 mL
2 NaOH + H2C2O4
Na2C2O4 + 2H2O
n H2C2O4 = . n NaOH
M H2C2O4 . V H2C2O4 = M NaOH standarisasi . V NaOH
M H2C2O45 mL = 0,125M . 3,4 mL

M H2C2O4=

0,212mol
=0,0424 M
5 mL

n H2C2O4= M H2C2O4. V H2C2O4

= 0,0424M . 5 mL
= 0,212 mol

T (K)

1/T (K)

Mol

Log Mol

333

3,0 . 10-3

0,696

-0,157

323

3,1 . 10-3

0,628

-0,202

313

3,2 . 10-3

0,396

-0,402

303

3,3. 10-3

0,212

-0,673

Grafik Kelarutan sebagai Fungsi Suhu

0
-0.1
-0.2

0
0
0
0
f(x) = - 1748x + 5.15
-0.16
R = 0.92 -0.2

0
Log Mol

-0.3
-0.4

Linear (Log Mol)

-0.4

-0.5
-0.6
-0.7
-0.8

-0.67

Y= mx + c
Log mol =

Hps 1
x
2,303 R T

Hps = m x 2,303 x R
Hps=1748 x 2,303 x 0,959

Hps = -3.860,59 J/mol