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Berapakah pH campuran :
100 mL 0.1 M NaOH + 100 mL 0.3 M CH3COOH + 100 mL 0.1 M KOH
Diketahui : 100 mL NaOH 0.1 M
= 10 mmol
100 mL CH3COOH 0.3 M = 30 mmol
100 mL KOH 0.1 M
= 10 mmol
Ka CH3COOH
= 1 x 10-5
Ditanyakan : pH campuran ... ?
Dijawab :
NaOH(aq) + CH3COOH(aq)
CH3COONa(aq) + H2O(l)
m
10
30
0
0
r
10
10
10
10
s
0
20
10
10
CH3COONa(aq) + KOH(aq)
m
10
10
r
10
10
s
0
0
CH3COOK(aq)
0
10
10
mol asamlemah
mol basa konjugasi
[H ] = Ka x
= 1x10-5 x
10 mmol
20 mmol
= 5 x 10-6 M
pH
NaOH(aq)
0
10
10
= - log [H+]
= - log (5 x 10-6)
= 6 log 5
= 5.301
2. Berapakah pH campuran :
100 mL 0.1 M CH3COONa + 100 mL 0.1 M CH3COOH + 100 mL 0.02M NaOH
Diketahui : 100 mL CH3COONa 0.1 M = 10 mmol
100 mL CH3COOH 0.1 = 10 mmol
100 mL NaOH 0.02M = 2 mmol
Ditanyakan : pH campuran ... ?
Dijawab :
CH3COOH(aq) + NaOH(aq)
CH3COONa(aq)
+
H2O(l)
m
10
2
0
0
r
2
2
2
2
s
8
0
2
2
mol asamlemah
mol basa konjugasi
[H ] = Ka x
= Ka x
(6.67 x 10-6)
-5
= 1x10 x
8 mmol
2 mmol+10 mmol
pH
= - log [H+]
=
= 6 log 6.67
log
= 1x10-5 x
8 mmol
12 mmol
= 5.176
= 6.67 x 10-6
3. 100 mL 0.1 M AgNO3 + 100 mL 0.2 M NaOH
a. Endapan apa yang mungkin terbentuk ?
b. Terbentukkah endapannya ?
c. Berapa endapan yang terbentuk ?
Diketahui :
100 mL AgNO3 0.1 M = 10 mmol
100 mL NaOH 0.2 M = 20 mmol
Ditanyakan :
a. Endapan yang terbentuk ... ?
b. terbentrukkah endapan ... ?
c. berapa endapan yang terbentuk ... ?
Dijawab :
AgNO3(aq)
+
NaOH(aq)
AgOH(s)
+
a. Endapan yang mungkin terbentuk = AgOH(s). (Ksp = 2 x 10-8)
NaNO3(aq)
[Ag+](aq) + [OH-](aq)
10 mmol
10 mmol
n
[Ag+] = v total
=
10 mmol
200 mL
= 5 x 10-2 M
NaOH(aq)
20 mmol
n
[OH-] = v total
=
Na+(aq)
[OH-](aq)
20 mmol
20 mmol
200 mL
= 1 x 10-1 M
Qc = [Ag+] . [OH-]
= (5 x 10-2).( 1 x 10-1)
= 5 x 10-3
Ksp = 2 x 10-8
Qc > Ksp, maka terbentuk endapan AgOH(s).
c. Endapan yang terbentuk sebanyak :
AgNO3(aq)
+
NaOH(aq)
AgOH(s)
m
10
20
0
r
10
10
10
s
0
10
10
massa AgOH(s) = n x Mr
= 10 mmol x 125 gram/mol
= 1250 mgram
AgOH(aq)
[Ag+](aq) + [OH-](aq)
NaNO3(aq)
0
10
10
s
Ksp = [Ag+].[OH-]
= s2
s = Ksp
2 x 108
[Ag+](aq) + [OH-](aq)
10
10
10
n
[Ag+] = v total
=
10 mmol
200 mL
= 5 x 10-2 M
NH4OH(aq)
NH4+(aq) +
OH-(aq)
0.2M
0.2M
0.2 M
[OH-] = Kb x Mb
=
1 x 106 x 0.2
= 0.447 x 10-3 M
Mol = 0.447 x 10-3 x 100 mL
= 44.7 x10-3 mmol
OH
[OH-]=
mmol
44.7 x 103
200
= 2.236 x 10-4 M
Qc = [Ag+] . [OH-]
= (5 x 10-2).( 2.236 x 10-4)
= 11.18 x 10-6
Ksp = 2 x 10-8
Qc > Ksp, maka terbentuk endapan AgOH(s).
c. Endapan yang terbentuk sebanyak :
AgNO3(aq) + NH4OH(aq)
m 10
44.7 x10-3
0
-3
r 10
44.7 x10
0
0
n Ag(NH)2NO3
massa Ag(NH)2NO3
Ag(NH)2NO3(aq)
H2O(l)
0
44.7 x10-3
44.7 x10-3
Zn2+ (aq) +
2NO3-(aq)
10 mmol
10 mmol
20 mmol
n
[Zn2+] = v total
=
10 mmol
200 mL
= 5 x 10-2 M
NaOH(aq)
Na+(aq)
[OH-](aq)
44.7 x10-3 s
44.7 x10-3
40 mmol
[OH-] =
=
40 mmol
n
v total
40 mmol
200 mL
= 2 x 10-1 M
Zn(OH)2(aq)
Zn+ +
2 OH+
- 2
Qc = [Zn ] . [OH ]
= (5 x 10-2).( 2 x 10-1)2
= 2 x 10-3
Ksp = 4.5 x 10-17
Qc > Ksp, maka terbentuk endapan Zn(OH)2(s).
c. Endapan yang terbentuk sebanyak :
Zn(NO3)2(aq) + 2NaOH(aq)
m 10
40
r 10
20
s 0
20
Zn(OH)2(s)
m 10
r
5
s
5
2NaOH(aq)
10
10
0
Zn(OH)2(s)
0
10
10
+ 2NaNH3(aq)
0
20
20
Na2ZnO2(aq) + 2H2O(l)
0
0
5
10
5
10
n Zn(OH)2(s)
= 5 mmol
massa Zn(OH)2(s) = 5 mmol x 99 gram/mol
= 495 mgram
Zn(OH)2(aq)
Zn+(aq) +
2 OH-(aq)
s
s
s
+
- 2
Ksp = [Zn ].[2OH ]
= 4s3
3 Ksp
s =
4
=
=
3 4.5 x 1017
4
3 11. 25 x 101 8
= 2.241 x 10-6 M
Mol = 2.241 x 10-6 M x 0.2L
= 0.448 x 10-6 mol
Massa = mol x Mr
= 0.448 x 10-6 mol x 125 gram/mol
= 56.0174 x 10-6 gram
= 56.0174 x 10-3 mgram
Massa endapan yang terbentuk = 495 mgram - 56.0174 x 10-3 mgram
= 494.944 mgram
6. 100 mL 0.1 M Zn(NH3)2 + 100 mL 0.4 M NH4OH
a. Endapan apa yang mungkin terbentuk ?
b. Terbentukkah endapannya ?
c. Berapa endapan yang terbentuk ?
Diketahui :
100 mL Zn(NH3)2 0.1 M = 10 mmol
100 mL NH4OH 0.4 M = 40 mmol
Ditanyakan :
a. Endapan yang terbentuk ... ?
b. terbentrukkah endapan ... ?
c. berapa endapan yang terbentuk ... ?
Dijawab :
Zn(NO3)2(aq) + NH4OH(aq) Zn(OH)2(s)
+ NH4NO3(l)
a. Endapan yang mungkin terbentuk = Zn(OH)2(s). (Ksp = 4.5 x 10-17)
b. Syarat terbentuk endapan Zn(OH)2(s) adalah Qc > Ksp
Zn(OH)2(aq)
Zn+ +
2 OHn
[Zn+] = v total
=
10 mmol
200 mL
= 5 x 10-2 M
NH4OH(aq)
NH4+(aq) +
OH-(aq)
0.4M
0.4M
0.4 M
[OH-] = Kb x Mb
=
1 x 106 x 0. 4
= 0.632 x 10-3 M
Mol = 0.632 x 10-3 x 100 mL
= 0.632 x10-1 mmol
OH
[OH-]=
mmol
0.632 x 10
200
= 3.16 x 10-4 M
Zn(OH)2(aq)
Zn+ +
2 OH+
- 2
Qc = [Zn ] . [OH ]
= (5 x 10-2).( 3.16 x 10-4)2
= 49.928 x 10-10
Ksp = 4.5 x 10-17
Qc > Ksp, maka terbentuk endapan Zn(OH)2(s).
c. Endapan yang terbentuk sebanyak :
4H2O(l)
0
0.632 x10-1
0.632x10-1