Tp ch KHKT M - a cht, s 42, 4/2013, tr.

1-8

DU KH (trang 1-21)
NGHIN CU TI CH CHT XC TC THI B T PHN XNG
REFORMING CA NH MY LC DU DUNG QUT V NH HNG
CHO QU TRNH X L KH THI CACBON MONOOXIT (CO)
ON VN HUN, PHM XUN NI, LNG VN SN

Trng i hc M - a cht
Tm tt: Xc tc sau mt thi gian s dng s mt hot tnh v c coi nh l mt loi
ph thi cn c loi b. iu ny gy lng ph v kinh t, nh hng ti mi trng v i
ngc li vi xu hng pht trin bn vng ca ngnh cng nghip ha cht hin nay.
Trong nghin cu ny, xc tc ca qu trnh Reforming t nh my lc du Dung Qut
c nghin cu ti s dng li. Xc tc thi sau khi t cc c ha tan vi nc
cng toan tch Platin v thu hi li cht mang -Al2O3. Xc tc 2 chc nng mi
(Pt-CuO/ -Al2O3) c tng hp da trn c s ca xc tc thi bng phng php ng
kt ta s c th hot tnh cho phn ng x l kh CO. Cc phng php c s dng
trong nghin cu ny bao gm: phng php nhiu x tia X (XRD) xc nh cu trc ca
xc tc, phng php ph tn sc nng lng EDX xc nh hm lng cc kim loi
trong mu rn, phng php ph hp th nguyn t (AAS) xc nh hm lng kim loi
trong dung dch, phng php BET xc nh din tch b mt ca xc tc sau khi tng
hp c. Kt qu nghin cu ch ra rng lng Platin thu c nhiu nht iu kin tin
hnh phn ng ti 75 oC trong 5 gi; dung mi c s dng l Aliquat 336; xc tc vi
hm lng 20% CuO, 2% Platin trn cht mang -Al2O3 c hot tnh tt khi x l CO trong
kh thi.
1. M u
mt trong nhng vn c quan tm nhiu
Trong cc xc tc c s dng ph bin hin nay.
hin nay, phi k n xc tc cho qu trnh
Xc tc cho qu trnh Reforming c s
reforming, y l mt qu trnh nhm chuyn dng hin nay trong nh my lc du Dung
ha phn on naphta nng c chng ct trc Qut mang tn R234 (Pt/Al2O3) vi thnh phn
tip t du th hoc t mt s qu trnh ch Pt chim khong 1% khi lng [2]. Sau qu
bin th cp khc nh FCC, hydrocracking, trnh s dng, xc tc c th b thay i tnh
visbreaking, c ch s octan thp (RON = 30 - cht vnh vin, l nhng thay i khng c
50) thnh hp phn c s ca xng thng kh nng ti sinh c na nh s thiu kt
phm c ch s octan cao (RON = 95 - 104). nhit cao m b mt ring xc tc v cu trc
Xng reforming thng chim khong 30% th ca Al2O3, phn tn ca Pt gim i [3].
tch trong xng thng phm [1]. Chnh v vy, Nhng thay i trn s lm lo ha v gim tui
xc tc cho qu trnh ny lun c u tin th ca xc tc. n mt thi gian no cn
nghin cu nhm tng hiu sut v ci thin phi thay th mt phn xc tc ny bng mt
cht lng sn phm. Tuy nhin, bn cnh vic lng xc tc mi c hot tnh cao hn nhm
nghin cu pht trin tnh cht ca xc tc ny, n nh hot tnh xc tc. Phn xc tc b thay
cn ch n vic pht trin vng i s dng th thng c thi trc tip gy nh hng
xc tc, iu ny nh hng khng nh n s khng nh n mi trng. Chnh v vy,
pht trin bn vng ca cng ngh ha hc - nghin cu ny tp trung vo vic ti ch cht

xc tc thi, tng hp xc tc mi v thu hi

lng kim loi qu c trong xc tc.
2. Thc nghim
Qu trnh thu hi Pt tinh khit gm 03 giai
on: (1) Tch Platin, (2) Chit tch Pt, (3) Ti
ch li kim loi Pt. Trong nghin cu ny, vi
quy m phng th nghim, chng ti tp trung
vo 02 qu trnh u tin, Pt sau khi tch ra s
c lm sch thu hi khi tin hnh vi
lng xc tc ln hn.
2.1. Qu trnh loi cc trong xc tc thi
Cc lng ng trn b mt cht xc tc
c loi b bng cch t chy trong dng
khng kh nhit 500 - 700 oC trong 4h, tc
gia nhit 1 oC/pht. Trong qu trnh nung,
cn ch trnh hin tng qu nhit cc b
lm gim din tch b mt, gim bn c hc
ca cht mang hoc lm tng qu trnh thiu kt
dn n gim phn tn kim loi.
2.2. Qu trnh tch Platin v ti sinh cht
mang Al2O3 trong xc tc thi
Ly 1 lng xc tc ha tan (khng
nghin) cho vo bnh cha dung dch nc
cng toan (t l HCl/HNO3=3). T l khi
lng lng/rn = 4 va ngm ngp xc
tc rn, ha tan Pt v khng ha tan
Al2O3. Khuy nh ( trnh lm v xc tc)
trong 20 pht n 5 gi ti nhit 25 - 100 oC.
Lc kt ta, ra vi 50ml nc ct thu c
dung dch A. Kt ta em sy 150oC trong 2h.
Phn ng: 8H+ + 8Cl- + 2NO3- + Pt ->
PtCl62- + 4H2O + 2NOCl
Kt ta c em i o bng phng php
XRD v EDX xc nh cu trc v hm
lng kim loi c trong mu rn. Mu dung
dch c em c c v xc nh hm lng
Platin cho qu trnh thu hi Platin tinh khit
cng nh qu trnh tng hp xc tc mi.
2.3. Qu trnh thu hi Platin tinh khit
Trong nghin cu ny, chng ti tin hnh
thu hi Pt trong xc tc thi bng dung dch
Aliquat 336 (CH3(CH3(CH2)7)3N+Cl-) v NH4Cl,
xc tc c gi nguyn hnh dng ban u
(hnh cu d=1.5mm).
Ha tan hn hp 15% th tch Aliquat 336
trong du ha c dung dch B [4]. Chit tch
Pt trong dung dch A bng dung dch B, qu
trnh c thc hin 25 oC v t l th tch

dung dch B/dung dch A l 1:1. Sau khi cho

dung dch B vo dung dch A thu c hn hp
phn lp, platin tp trung trong pha hu c ni
bn trn hn hp v c mu vng c dung
dch C, dung dch bn di c mu trng c
tp trung Al3+ (khi cho dung dch NaOH pH = 8
9 thu c kt ta trng). Dung dch Na 2S2O3
nng 0,75 mol/l c thm vo dung dch
C theo t l th tch 1:1, trc khi tin hnh
phn ng cn thm dung dch NaOH 12,5 mol/l
vo dung dch C pH=9 trnh s phn hy
ca anion to ra cc kh c SO2 v do trong
phn ng ca H2PtCl6 vi Aliquat 336 to ra H+
lm gim pH ca hn hp. Sau phn ng hn
hp tch lp to ra Pt (II) tp trung pha bn
trn c mu xanh en, phn ny s chit ra c
dung dch D. Dung dch D c phn ng vi
bt Magie (Mg) nhit 40 50 oC trong
15 20 pht thu c kt ta Pt o mu en,
trong qu trnh tin hnh phn ng, do c kh
thot ra nn cn thc hin phn ng trong t ht
m bo an ton.
Cc phn ng c th xy ra trong qu trnh:
(Aliquat 336: R3RN+Cl-) [4]
2R3RN+Cl-+H2PtCl6 (R3RN+)2PtCl62-+2HCl,(1.1)
(R3RN+)2PtCl62-+Na2S2O
3

40 50o C

Pt(II), (1.2)

Pt(II) + Mg Pto + Mg2+ ,

(1.3)
2.4. Qu trnh tng hp xc tc mi
Cht mang -Al2O3 (mu trng) thu c
trong xc tc thi sau khi tch Pt c ha tan
vi dung dch Cu(NO3)2.6H2O (M= vC) vi
lng tnh ton trc t thnh phn Cu
chim 20% trong xc tc. Qu trnh tm c
tin hnh nhit phng v khuy lin tc
trong 30 pht ri n nh trong 5 gi cng
nhit phng. Dung dch thu c tip tc
c n nh v sy kh nhit 120oC trong
24 gi. Cc mu xc tc sau khi sy kh c
nung trong l nung Lenton nhit tng 10 oC/1
pht cho ti khi t 300oC, khi t 300oC th
mu c duy tr trong 1 gi. Sau th tng
nhit 10oC/pht t ti 500 oC v duy tr
nhit ny trong 6 gi. Trong bc ny, hu
ht cc nitrat b phn hy to thnh nit oxit.
Mu xc tc sau nung tip tc c tm
platin, xc tc sau nung (c mu en ca CuO)
c tm dung dch H2PtCl6 vi lng th tch

c tnh ton trc m bo lng platin cn

thit trong mu xc tc. Cc bc tin hnh
cng tng t nh tm dung dch mui
Cu(NO3)2, xc tc sau tm c khuy lin tc
trong 30 pht nhit phng 25oC m
bo tt c cc platin c hp ph trnCuO/Al2O3 v n nh trong 5 gi sau c n
nh v sy kh 120oC trong 24 gi. Cc mu
xc tc sau khi tm platin c nung trong l
nung Lenton nhit tng 10oC/1 pht cho ti
khi t 300oC, khi t 300oC th mu c duy
tr trong 1 gi. Sau th tng nhit
10oC/pht t ti 500oC v duy tr nhit
ny trong 6 gi. Mu xc tc thu c k hiu
ln lt l B1, B2, B3, B4.
2.5. Qu trnh x l CO trong kh thi
Hot tnh xc tc ca h xc tc PtCuO/Al2O3 c tng hp trn c s xc tc
thi c nh gi qua phn ng oxi ha CO.
Phn ng c thc hin khong nhit 250
o
C v 300 oC trong iu kin p sut kh quyn.
Phn ng c thc hin trong 10 pht. Sn
phm phn ng c phn tch trn my sc k
kh, detector dn nhit (GC/TCD). Nguyn liu
(N2, CO, CO2, O2), t l O2/CO = 1/4, lng xc
tc 0,1 gam (kch thc ht 200 - 250 m).
Bng 1. Thi gian lu v thnh phn cc kh
trong dng nguyn liu
Peak

O2 v N2

CO

CO2

Thi gian lu (min)

6,08

7,75

15,23

%V

66,45

17,69

15,86

3. Kt qu v lun gii
3.1. Kt qu c trng xc tc thi sau khi
nung
Kt qu o EDX (bng 2) ca xc tc thi
R234 t phn xng Reforming cho thy Pt
trong xc tc chim 1.27% khi lng. Cc kim
loi c xc nh bng phng php ny bao
gm: Al, Sn, Re, Pt. Cc mu rn thu c u
s dng phng php ny kt lun v hm
lng Pt tch ra c.

Bng 2. Kt qu o EDX ca xc tc thi R234

O
Al
Cl Sn Re Pt Tng %
khi
lng
42,97 45,09 6,79 0,02 3,86 1,27 100
3.2. Kt qu kho st nhit nung
3.2.1. Kho st nhit vi sai xc tc thi R-234
tm c khong nhit t cc thch
hp chng ti tin hnh o nhit vi sai ca mu
xc tc thi R-234. Kt qu o c th hin
qua hnh sau:

Hnh 1. Kt qu o nhit vi sai mu xc tc thi

cha t cc
Kt qu phn tch nhit vi sai cho thy t 0
o
C n 800 oC c 2 nhit mt khi lng.
46.79 oC c s mt khi lng y chng ti
cho rng y l s bay hi ca dung mi. T
46.79 oC n 460 oC khng c s tn tht khi
lng. n 461,59 oC c s mt khi lng
y chng ti cho rng y chnh l s kh cc.
S mt khi lng ch dng li khi nhit ln
hn 750 oC.
Do vy chng ti xc nh vng kh cc l
nm khong nhit t 461,59 750 oC iu
ny hon ton hp l v nhit t cc thc t
ca phn xng CCR nh my lc du Dung
Qut l 479 oC nm trong vng t cc chng
ti gi nh.
3.2.2. Kho st nhit t cc
Chng ti tin hnh o XRD kho st
nhit t cc 3 nhit 500 oC, 650 oC,
700 oC. Kt qu c th hin qua cc hnh sau:

Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Mau M2-500C

300
290
280
270
260

d=1.391

250
240
230

d=1.984

220
210
200

170
160
150

d=2.750

Lin (Cps)

180

140
130

d=2.267

d=2.421

190

120
110

d=1.517

100
90
80
70
60
50
40
30
20
10
0
20

30

40

50

60

70

80

2-Theta - Scale

Hnh 2. Kt qu XRD ca mu xc tc sau khi nung cc nhit khc nhau

Nung 500 oC
Nung 650 oC
Nung 700 oC
Kt qu nhiu x tia X ca mu xc tc thi
75
0,98
2934,0
sau khi thc hin nung cc nhit khc nhau
90
1,41
4647,2
t 500 - 700 oC. Trn ph X-Ray gc ln nhn
Mu xc tc sau khi loi b cc c ha
thy c xut hin cc pic ln 2 = 38 o, 46o, 67o. tan bng nc cng toan trong 20 pht ti cc
y l cc pic c trng cho vt liu -Al 2O3. nhit t 20 90oC vi cng mt lng xc
Cng t kt qu XRD cho thy hm lng tc ( sai lch di 0.01). Kt qu cho thy ti
-Al2O3 gi li c nhiu nht (71,27%) nhit l 75oC, lng cht rn b gim nhiu
650 oC. iu ny c th c gii thch l ti nht, lng Pt trong mu rn cng b gim
nhit cao (hn 650 oC) cu trc ca -Al2O3 nhiu nht (0,98% so vi 1,27% lc cha phn
bt u b ph hy v chuyn thnh -Al2O3 ng). iu c th khng nh, ti nhit
mc d lng cc c loi ra nhiu hn.
75oC, lng Pt b ha tan nhiu nht vi dung
Bng 3. Kt qu kho st hm lng -Al2O3
dch nc cng toan. Lng Al trong dung
cc nhit nung khc nhau
dch chim 2934 mg/l, iu ny cho thy ti
Nhit nung
Hm lng -Al2O3 (%)
nhit trn, Al2O3 cha phn ng nhiu vi
dung dch nc cng toan.
Cha nung
72,16
3.2.2. Kho st thi gian tch
500 oC
63,96
Xc tc c phn ng vi nc cng
toan
ti nhit 75oC t 20 pht ti khong
650 oC
71,27
thi gian 5h. Kt qu cho thy trong thi gian
o
phn ng l 5h, Pt b phn ng ht vi nc
700 C
71,26
cng toan. iu cho thy, phng php ha
3.2. Kt qu kho st kh nng tch Pt v ti
tan ny ph hp vi vic tch Pt v thu hi
sinh cht mang Al2O3
-Al2O3 trong xc tc thi.
3.2.1. Kho st nhit tch
Bng 4. Kt qu sau khi tin hnh phn ng
trong 20 pht cc nhit khc nhau
KL Al trong
Nhit
% KL Pt trong
cht lng
phn ng (oC)
cht rn
(mg/l)
Cha phn
1,27
ng
20
1,148
<1000
50
1,32
2078,5
File: Son DH Mo mau M2-500C.raw - Type: Locked Coupled - Start: 20.000 - End: 80.000 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 17 s - 2-Theta: 20.000 - Theta: 10.000 00-004-0858 (D) - Aluminum Oxide - gamma-Al2O3 - Y: 63.96 % - d x by: 1. - WL: 1.5406 -

Hnh 3. Kt qu sau khi tin hnh phn ng

Kt
o BET
ca gian
xc tc
khi tch Pt c a ra bng 5. Kt qu cho thy sau khi
75 oqu
C trong
cc thi
khcsau
nhau
tch Pt, din tch b mt ca xc tc tng ln so vi xc tc thi. iu ny c gii thch Pt
phn tn trn b mt xc tc gy nn s co cm gia cc lp xc tc lm tng din tch b mt ca
xc tc gim i.
Bng 5. Kt qu BET ca xc tc trc v sau khi tch Pt
Thng s
Th tch l xp (ml/g)
Din tch b mt (m2/g)

Xc tc mi
0,34
130

Xc tc thi
0,27
120

Xc tc sau khi tch Pt

0,5
130,81

3.3. Kho st phng php thu hi Platin

Hnh 2 th hin kt qu XRD ca mu xc tc sau khi nung v mu xc tc sau khi tch Pt. Kt
qu cho thy cu trc tinh th ca -Al2O3 vn c gi nguyn sau khi tch Pt.
Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Mau M22

270
260
250

d=1.397

240
230
220

d=1.977

210
200
190
180

150

d=2.746

140
130
120
110
100

d=1.519

Lin (Cps)

160

d=2.282

d=2.409

170

90
80
70
60
50
40
30
20
10
0
20

30

40

50

60

70

80

2-Theta - Scale

Hnh 4. Kt qu XRD ca mu xc tc sau khi nung v mu xc tc sau khi tch Pt

File: Son DH Mo mau M22.raw - Type: Locked Coupled - Start: 20.000 - End: 80.000 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 14 s - 2-Theta: 20.000 - Theta: 10.000 - Chi:
00-004-0858 (D) - Aluminum Oxide - gamma-Al2O3 - Y: 65.21 % - d x by: 1. - WL: 1.5406 -

Bng 6. Kt qu o EDX mu Platin sau khi thu hi bng Aliquat 336

Ln
o

Na

Mg

Al

Pt

Tng
(%KL)

0,21

0,2

0,23

99,36

100

0,9

0,99

0,32

97,79

100

0,74

1,41

0,27

97,58

100

0,7

2,1

0,21

96,99

100

0,73

15,46

0,38

83,43

100

TB

0,656

4,032

0,282

95,03

100

Kt qu EDX cho thy rng Platin thu hi bng Aliquat 336 c tinh khit cao (95.03%),
hiu sut ca c qu trnh thu hi t gn 80%.
3.4. c trng xc tc mi
3.4.1. Kt qu XRD
T lng cht mang -Al2O3 ti sinh t cht xc tc thi b, chng ti tin hnh tm 2% Pt
v 20% CuO. Kt qu nhiu x XRD ca mu xc tc c th hin qua hnh 5.
Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Mau b4

500

d=2.328

d=2.530

400

Lin (Cps)

300

d=1.303

d=1.269

d=1.406
d=1.399

d=1.378

d=1.507

d=1.584

d=1.718

d=1.863

d=1.991
d=1.966

d=2.430

100

d=2.269

d=2.750

200

0
20

30

40

50

60

70

80

2-Theta - Scale
File: Son DH mo mau b4.raw - Type: Locked Coupled - Start: 20.000 - End: 80.000 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 12 s - 2-Theta: 20.000 - Theta: 10.000 - Chi: 0
01-089-2529 (C) - Tenorite, syn - CuO - Y: 76.15 % - d x by: 1. - WL: 1.5406 - Monoclinic - a 4.68320 - b 3.42880 - c 5.12970 - alpha 90.000 - beta 99.309 - gamma 90.000 - Base-centered - C2/c (15) - 4 - 81
00-004-0858 (D) - Aluminum Oxide - gamma-Al2O3 - Y: 22.26 % - d x by: 1. - WL: 1.5406 -

Hnh 5. Kt qu XRD ca mu xc tc 2%Pt-20%CuO/Al2O3

T kt qu XRD, c th thy cc nh pic ca Al 2O3 khng c s thay i, chng t rng khi
tm CuO ln Al2O3 th khng lm thay i cu trc vt liu. ng thi trn bng kt qu phn tch
ph X-Ray ta nhn thy khi tm CuO ln Al2O3 th thy rt r pha ca teronit ca CuO . Ngoi ra, c
th thy rng chn ca cc pic nh hn, iu ny chng t ht xc tc c kch thc ng u hn.
3.4.2. Kt qu BET
Bng 7. Kt qu BET ca mu xc tc 2%Pt-20%CuO/Al2O3
Mu xc tc
Din tch b mt
(m2/g)
2%Pt-20%CuO/Al2O3
204.083

Hnh 6. ng ng nhit hp ph N2 ca mu xc tc 2%Pt-20%CuO/Al2O3

Mu xc tc tng hp c c b mt ring 204.083 m 2/g. Nh vy, vi vic phn tn pha hot
tnh Pt-CuO trn din tch b mt ring ln s lm tng hot tnh cng nh bn xc tc v nh
chng ta bit qu trnh xc tc l mt hin tng b mt, hot tnh v bn xc tc ph thuc
rt nhiu vo din tch b mt ring ca n, b mt ring cng ln th hot tnh v bn xc tc
cng cao.
3.4.3. Kt qu SEM
thy c mc ht phn tn, c bit l tinh th ca pha hot tnh chng ti tin hnh
chp SEM ca mu xc tc 2%Pt-20%CuO/Al2O3

Kt qu SEM ca mu xc tc Kt qu SEM ca mu xc tc Kt qu SEM ca mu xc tc

2%Pt-20%CuO/Al2O3 vi
2%Pt-20%CuO/Al2O3 vi
2%Pt-20%CuO/Al2O3 vi
phng i trung bnh
phng i ln
phng i cc ln
Hnh 7. Kt qu SEM ca mu xc tc 2%Pt-20%CuO/Al2O3
Qua nh SEM nhn thy mu xc tc tng hp c c b mt tng i bng phng, trng
thi ht v nh hnh v bn tinh th. Kt qu ny hon ton ph hp vi kt qu chp XRD. Kt
qu SEM cng cho thy cc ht Pt-CuO c phn tn tng i ng u trn cht mang. Vi
gc chp 5 m (hnh 7c), c th thy kch thc trung bnh ca cc ht Pt-CuO vo khong 1m.
3.4.4. Kho st phn tn Pt ln nn -Al2O3
kho st phn tn Pt-CuO trn nn -Al2O3 cng nh kch thc ht phn tn, chng ti
tin hnh chp hin vi in t truyn qua (TEM) ca mu xc tc Pt-CuO/-Al2O3 tng hp c t
ngun xc tc ti sinh. Kt qu c ch ra hnh 8.

Hnh 8. Kt qu chp TEM ca mu xc tc tng hp Pt-CuO/-Al2O3

T hnh 8, c th nhn thy s phn phn ch rng, phn ng oxy ha CO y din ra
tn ca kim loi Pt-Cu trn cht mang Al 2O3 trong iu kin thiu O2 (t l O2/CO = ).
tng i ng u vi kch thc ht c nano
- Pt phn tn tt trn cht mang -Al2O3 vi
mt.
hm lng gii hn 2% Pt. Chnh v vy, y
3.5. Th hot tnh xc tc mi
cng l tnh u vit trong vic s dng kim loi
Phn ng oxi ha CO vi xc tc mi c qu vi hm lng thp phn tn trn cht
kim tra ti 02 nhit khc nhau: 250 oC v mang.
300oC. Kt qu phn ng oxi ha CO c cho
- Xc tc hin ang s dng cho qu trnh
bng 8.
ny l CuO-ZnO/TiO2 cng iu kin cho
chuyn ha l 49.5% [5]. iu ny cho thy xc
Bng 8. Kt qu th hot tnh vi xc tc
tc mi sau khi ti sinh c hon ton c th
2%Pt-20%CuO/Al2O3
thay th cho xc tc hin thi.
Nhit
Thnh phn

4. Kt lun
phn ng cc kh sn phm (%V) chuyn
Sau khi tin hnh thc nghim, nghin cu
(oC)
ha (%)
O2 v N2 CO
CO2
thu c cc kt qu sau:
250
65,82
8,79 25,39 50,34
- c trng c xc tc thi CCR theo
cng ngh ca UOP c k hiu R234 c thi
300
59,74
8,07 32,33 53,50
ra t thng 09 nm 2011ca nh my lc du
Nhn xt:
Dung Qut. Kt qu cho thy xc tc phn
- Qua nghin cu c th thy rng, h xc no mt hot tnh.
tc Pt-CuO/Al2O3 c hot tnh tt cho phn ng
- kho st c nhit ti u cho qu
oxy ha chuyn ha CO. iu ny chng t
trnh oxy ha nhm loi b cc ca xc tc v
din tch b mt -Al2O3 rt quan trng n kh
thu c ti a lng -Al2O3 m khng lm
nng phn tn ca kim loi ln cht mang. Cn
hng cu trc ca xc tc. Theo , nhit
nung ti u vi dng khng kh l 600oC.

- nghin cu qu trnh tch Platin ra

khi xc tc v thu hi cht mang Al2O3. Kt
qu cho thy Platin c tch ra ti a khi ha
tan vi nc cng toan 75oC trong 5h. Cht
mang Al2O3 vn gi nguyn c cu trc
gamma th hin qua kt qu chp XRD.
- tng hp c thnh cng xc tc
Pt-CuO/-Al2O3 (CuO chim 20%; Pt chim 2%
khi lng) t H2PtCl6 (hm lng Pt:
1g/500ml) v -Al2O3 t xc tc thi. Kt qu
cho thy, kch thc cng nh tinh th ca
pha hot tnh phn tn tng i n nh trn
cht mang.
- kim tra hot tnh ca cc mu xc tc
tng hp c trn phn ng oxy ha chn lc
CO trong kh thi. Kt qu cho thy xc tc c
hot tnh cao ngay c trong iu kin thiu oxy
ti nhit phn ng l 300 oC, iu ny mt
ln na cho thy xc tc mi c tng hp
thnh cng t vt liu xc tc thi.

[1]. George H. ANTOS, Abdullah M. AITANI,

Catalytic Naphtha Reforming, Second Edition,
Marcel Dekker Inc., Nes York.
[2]. Ti liu hng dn vn hnh Nh my Lc
Du Dung Qut.
[3]. M.A. Barakat, M.H.H. Mahmoud, 2004.
Recovery of Platin from spent catalyst,
Hydrometallurgy 72, tr. 179 184.
[4]. Morteza Baghalha, Homa Khosravian Gh,
Hamid Reza Mortaheb, 2009. Kinetics of Platin
extraction from spent reforming catalysts in
aqua-regia solutions, Hydrometallurgy 95, tr.
247 253.
[5]. Elisa Moretti, Loretta Storaro, Aldo Talon,
Pasquale Patrono, Fulvia Pinzari, Tania
Montanari, Gianguido Ramis, Maurizio
Lenarda, 2008. Preferential CO oxidation (COPROX) over CuO-ZnO/TiO2 catalysts, Applied
Catalysis A: General 344, 165174.
(xem tip trang 21)

TI LIU THAM KHO

SUMMARY
Regeneration of spent reforming catalysts from Dung Quat Refinery and using the new
synthesized catalyst in selective oxidation of Carbon monooxide (CO)
Doan Van Huan, Pham Xuan Nui, Luong Van Son
Hanoi University of Mining and Geology
In this study, the spent catalyst of the Reforming unit from Dung Quat Refinery is regenerated.
After coke burning, the catalyst is dissolved with an aqua regia to leach Platin and -Al2O3. The
new bifunctional catalyst (PtCuO/-Al2O3) based on the spent catalyst is prepared by deposition
method and its performance is evaluated for the selective oxidation of carbon monooxide. The
characterization techniques are subjected are X-ray diffraction (XRD) analysis, Energy Dipersive
X-ray (EDX) spectrocopy, Atomic Absorption Spectrometry (AAS), BET surface area. The result
shows that the optimal condition of reaction is in temperature of 75 degree Celcius during 5 hours
with solvent Aliquat 336. The new catalyst with 20% wt CuO and 2% wt Platin is a good catalyst in
the reaction of transferization carbon monooxide in waste gas.