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962/1
STPM
2012 FIRST TERM EXAMINATION
CHEMISTRY
PAPER 1
One and a half hours
Instructions to candidates:
DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE
TOLD TO DO SO.
There are fifteen questions in Section A. For each question, four choices
of answers are given. Choose one correct answer and indicate it on the
Multiple-choice Answer Sheet provided. Read the instructions on the
Multiple-choice Answer Sheet very carefully. Answer all questions. Marks
will not be deducted for wrong answers.
Answer all questions in Section B.
provided.
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Relative
intensity
C.
34
B.
35
36
37 m/e
D.
Relative
intensity
34
35
36
Relative
intensity
37 m/e
34
35
36
37 m/e
34
35
36
37 m/e
Relative
intensity
2.
A.
B.
C.
D.
3. How many possible electronic transitions can be obtained from emission spectrum of Lyman and
Balmer series with the following energy levels?
Energy
n=5
n=4
n=3
n=2
n=1
A.
B.
C.
D.
Lyman Series
3
4
4
5
Balmer Series
4
3
5
4
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4.
A.
B.
C.
D.
5. An element in Group 15 of the Periodic table forms a gaseous hydride. The shape of this hydride
molecule may be
A.
linear
B.
6.
A.
H2S
B.
bent
C.
NH3
C.
trigonal planar
CO2
D.
D.
trigonal pyramidal.
CH2Cl2
7. Boron nitride, BN can exists in two different forms P and Q. P has a layered giant molecular
lattice with weak forces between layers. Q has a giant lattice in which each atom is bonded to another
tetrahedrally by covalent bonds. The following statements are about P and Q.
I
II
III
IV
I and II
B.
I and III
C.
II and IV
D.
III and IV
8. The change in concentration of a reactant with time in a chemical reaction is shown in the graph
below.
Concentration
( mol dm-3)
1.00-
0.750.500.250
|
0.5
|
1.0
Time(s)
Determine the numerical value of the rate constant for this chemical reaction.
A.
B.
C.
D.
9.
Which of the following statements is true about the effect of a catalyst on a reversible reaction?
A.
B.
C.
D.
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10. Which of the following equilibrium shifts to the right when the pressure is increased while
maintaining a constant temperature?
A.
B.
C.
D.
2HI(g)
H2(g) + I2(g)
SO2Cl2(g)
SO2(g) + Cl2(g)
O2(g) + 4F2(g)
F4(g) + 2F2O(g)
4NH3(g) + 5O2(g)
6H2O(g) + 4NO(g)
11.
A.
I only
B.
III only
C. I and II
D.
I, II and III
12. Silver sulphate, Ag2SO4 and strontium sulphate, SrSO4 are added to water. Which of the
following statements is true about the saturated solution obtained?
[The solubility product, Ksp of Ag2SO4 is 1.50 x 10-5 mol3dm-9 and SrSO4 is 2.80 x 10-7 mol2dm-6 at
25 ]
A. SrSO4 is more soluble than Ag2SO4.
B. SrSO4 is the source of the sulphate ions in the saturated solution.
C. Ag2SO4 contributes minimal sulphate ions.
D. The solubility of Ag2SO4 is decreased when silver nitrate is added.
13.
A.
Lewis acid
B.
Lewis base
Bronsted-Lowry acid
D.
Bronsted-Lowry base
14. When 0.10 mol dm-3 of ammonia solution is diluted with water at room temperature, the
following properties may change.
I
II
III
IV
A.
B.
C.
D.
pH
Base dissociation constant
Degree of dissociation
Kw
I and III
I and IV
II and III
III and IV
15. Hydrazine, N2H4 is a weak base. The base dissociation constant, Kb of this base is 3.00 x 10-6
mol dm-3. What is the pH value of a sample of 0.100 mol dm-3 aqueous solution of hydrazine?
A.
3.26
B.
7.50
C.
9.46
D.
10.7
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Section B [ 15 marks]
Answer all questions in this section
16 (a) The figure below shows the Lyman series in the hydrogen emission spectrum in the
visible region. The spectrum is composed of discrete lines.
Q
frequency
[ 1 mark]
(ii) Draw a labelled energy diagram to show how the lines marked P and Q are produces
[ 2 marks]
[ 2 marks]
(b) (i) Name one species that would produce similar emission spectrum as the hydrogen atom.
[ 1 mark]
.
(ii) Give a reason for b (i)
[ 1 mark ]
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17. Hydrogen peroxide, H2O2 decomposes very slowly at room temperature according to the equation
2 H2O2 (aq)
An investigation of the decomposition of hydrogen peroxide,H2O2 is carried at 298 K and gives the
following information.
Time/min
[H2O2] /mol dm-3
0
6.00
2
4.20
4
2.80
6
1.85
10
0.80
[ 1 mark ]
[ 2 marks]
[ 1 mark ]
(iii) Give a reason why the decomposition of hydrogen peroxide is very slow at room temperature.
[ 1 mark ]
..
(b) In another separate experiment at 298 K with the presence of potassium iodide ,the decomposition
of hydrogen peroxide is faster .Assume that the reaction is first order with respect to the concentration
of iodide.
(i) Write an expression for the rate equation.
[ 1 mark ]
(ii) Calculate the value of rate constant, k for the decomposition of hydrogen peroxide.
[ 2 marks ]
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Section C [ 30 marks]
Answer any two questions in this section.
18. (a) The table below refers to a compound X.
Temperature/K
Pressure/kPa
Triple point
216
505
Critical point
304
7370
From the table, the critical point of X is at 304 K and 7370 kPa.
(i)
[1 mark]
(ii)
[4 marks]
(iii)
[2 marks]
(b) (i)
[1mark]
(ii)
32.5 g of a sample gas X occupies a volume of 6.1 x 10-3 m3 at 25 C and 300 kPa.
Calculate the molecular mass of X and give the identity for gas X.
[5marks]
(iii)
Give two reasons why real gases such as X deviate from ideality.
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[2 marks]
19. (a) Ethanoic acid is a weak acid and dissociates in water according to the equation
CH3COOH (aq) + H2O (l)
(i)
Write an expression for the acid dissociation constant,Ka for ethanoic acid.
[1 mark]
(ii)
(iii)
The acid dissociation constant for citric acid is 7.5 x 10 -4 mol dm-3 at 298 K. What can
you deduce from the different in values of Ka compared to ethanoic acid.
[2 marks]
(b) A mixture of ethanoic acid and its solution salt acts as a buffer solution.
(i)
(ii)
Calculate the pH of 500 cm3 of buffer solution containing 0.2 mol of ethanoic acid
and 8.2 g of sodium ethanoate.( Given Ka for ethanoic acid at 298 K is 1.80 x 10-5
mol dm-3)
[4 marks]
(iii)
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[1 mark]
[5 marks]
20. (a) Ethene, C2H4 is a hydrocarbon molecule with a carbon-carbon double bond.
(i) State the hybridisation of carbon atom in ethene.
[1mark]
(ii) Draw a labelled diagram showing the overlapping of orbitals in ethene. [3 marks]
(iii) Explain what is meant by sigma and pie bond in ethene molecule.
[3 marks]
(b) The table below shows the boiling points of three compounds.
Compound
Methane
Ammonia
Water
Boiling points, C
-165
- 33
100
[3 marks]
(ii) Explain for the trend of boiling points for the three compounds.
[5 marks]
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Answers to Section B
16. (a) (i) The energy levels in the hydrogen atom are quantized
(ii)
1m
n=6
n=5
n=4
n=3
n=2
n=1
Q
Label energy level
Show transition
Show lines produced
(iii)
2m
1
= 1.097 x 107 (1/12-1/22 )
wavelength
1
= 0.822275 x 10 7
Wavelength
Wavelength = 1.215 x 10-7 m
1m
Hz
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1m
(b) (i)
(ii)
He + /
Li 2+
1m
1m
Total.7 marks
1m
1m
1m
1m
1m
(b)
(i) Rate = k [H2O2][I-]
1m
Curve
k = ln 2
4 min
= 0.173 min-1
2m
Total.8 marks
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Section C
18. (a)
(i)
1m
(ii)
(iii)
(b)
(i)
(ii)
(iii)
PV = nRT
1m
1m
1m
1m
= 43.97
Identity of X is carbon dioxide
1m
1m
2m
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19. (a)
(b)
(i)
Ka = [ CH3COO-][H3O+]
[CH3COOH]
(ii)
1m
1m
1m
(iii)
(i)
1m
(iii)
1m
H2CO3 (aq)
H+ (aq) + HCO3-(aq)
1m
1m
1m
1m
1m
1m
H2CO3 /explanation
3m
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1m
20.(a) (i) sp
1m
(ii)
3m
(iii)
(b) (i)
(ii)
X
H x C x H
x
xx
H xNx H
x
xx
H x Oxx
x
3m
3m
Ammonia and water have intermolecular hydrogen bonding between the molecules.
Their boiling points are higher.
1m
Methane has weak van der waals forces between the molecules.
So methane has lowest boiling point.
1m
Water has two lone pair of electrons compared to only one for ammonia.1m
Water can form more intermolecular hydrogen bonding with
1m
one another.
In water,oxygen atom being more electronegative than nitrogen
Forms stronger hydrogen bond.
1m
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