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TRUNG TM LUYN THI I HC
S 11 Ngch 98 Ng 72 Tn Tht Tng ng a HN
KHAI THC TRIT PHNG PHP BO TON NGUYN T

(T liu hc bi Phn I)
V d 1.Cho phn ng: Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 + H2O
Tng h s ca cc cht (l nhng s nguyn, ti gin) trong phng trnh phn ng l
A. 23.
B. 27.
C. 47.
D. 31.
V d 2.Cho phn ng: FeSO4 + KMnO4 + KHSO4 Fe2(SO4)3 + MnSO4 + K2SO4 + H2O
Tng h s ca cc cht (l nhng s nguyn, ti gin) trong phng trnh phn ng l
A. 36.
B. 48.
C. 52.
D. 54.
V d 3.Xt phn ng: FexOy + H2SO4 Fe2(SO4)3 + SO2 + H2O
H s cn bng ca H2SO4 l
A. 3x y.
B. 3x 2y.
C. 6x y.
D. 6x 2y.
V d 4.Cho phng trnh ho hc: Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O
Sau khi cn bng phng trnh ho hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca
HNO3 l
A. 13x 9y.
B. 46x 18y.
C. 45x 18y.
D. 23x 9y.
V d 5.Cho hn hp X gm 0,3 mol Fe, 0,15 mol Fe2O3 v 0,1 mol Fe3O4 tc dng ht vi dung dch H2SO4
long thu c dung dch Y. Cho dung dch Y tc dng vi dung dch NaOH d, lc kt ta em nung trong
khng kh n khi lng khng i thu c m gam cht rn Z. Gi tr ca m l:
A. 70.
B. 72.
C. 65.
D. 75.
V d 6.Cho m gam mt oxit st phn ng va vi 0,75 mol H2SO4, thu c dung dch ch cha mt mui
duy nht v 1,68 lt kh SO2 (ktc, sn phm kh duy nht ca S+6). Gi tr ca m l
A. 10,8.
B. 24,0.
C. 34,8.
D. 46,4.
V d 7.Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh),
thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li
mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (ktc). Gi tr ca V l
A. 2,80.
B. 3,36.
C. 3,08.
D. 4,48.
V d 8.Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu c dung
dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l
A. 0,04.
B. 0,075.
C. 0,12.
D. 0,06.
V d 9.Hn hp X gm a mol Fe, b mol FeCO3 v c mol FeS2. Cho X vo bnh dung tch khng i cha
khng kh (d), nung n cc phn ng xy ra hon ton sau a v nhit u thy p sut trong bnh
bng p sut trc khi nung. Quan h ca a, b, c l:
A. a = b + c.
B. 4a + 4c = 3b.
C. b = c + a.
D. a + c = 2b.
V d 10. Cho t t 62 gam Ca3(PO4)2 vo 100 ml dung dch H2SO4 5M. Khi lng mui (khan) thu c l
A. 111,0 gam.
B. 91,4 gam.
C. 43,0 gam.
D. 23,4 gam.
Bin son: Thy L PHM THNH
ng k LUYN THI ONLINE ti: Moon.vn
Bin son: Thy L Phm Thnh (0976.053.496)
https://www.facebook.com/thanh.lepham
Kho hc PHNG PHP v K THUT GII NHANH mn HO HC - Thy L PHM THNH (0976.053.496)
PP 04. PHNG PHP BO TON IN TCH

(T liu hc bi)
V d 1. Dung dch X c cha a mol Na+ ; b mol Mg2+ ; c mol Cl v d mol SO 24 . Biu thc
lin h gia a, b, c, d l
A. a + 2b = c + 2d.
B. a + 2b = c + d.
C. a + b = c + d.
D. 2a + b = 2c + d.
V d 2. Mt dung dch X gm 0,01 mol Na+; 0,02 mol Ca2+; 0,02 mol HCO3 v a mol ion X
(b qua s in li ca nc). Ion X v gi tr ca a l
A. NO3 v 0,03
B. Cl v 0,01
C. CO 32 v 0,03
D. OH v 0,03
V d 3. Dung dch X c cha Ba2+ (x mol ); H+ (0,2 mol), Cl (0,1 mol) v NO 3 (0,4 mol).
Cho t t dung dch K2CO3 1M vo X n khi lng kt ta ln nht thy tiu tn V lt. Gi tr
ca V l
A. 0,15.
B. 0,25.
C. 0,30.
D. 0,50.
V d 4. Dung dch X c cha: 0,07 mol Na+; 0,02 mol SO 24 v x mol OH. Dung dch Y c
cha C lO 4 , NO3 v y mol H+; tng s mol ion trong Y l 0,04. Trn X v Y c 100 ml
dung dch Z. Dung dch Z c pH (b qua s in li ca H2O) l
A. 2.
B. 13.
C. 1.
D. 12.
V d 5. Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton
vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M
va phn ng ht vi Y l
A. 50 ml.
B. 57 ml.
C. 75 ml.
D. 90 ml.
V d 6. Cho m gam hn hp X gm Mg, Fe, Zn dng bt tc dng hon ton vi oxi thu
c 2,81 gam hn hp Y gm cc oxit. Ha tan hon ton lng Y trn vo axit H2SO4
long (va ). Sau phn ng, c cn dd thu c 6,81 gam hn hp mui sunfat khan. Gi tr
ca m l
A. 1,21
B. 1,81
C. 2,01
D. 6,03
V d 7. Dung dch E gm x mol Ca2+, y mol Ba2+, z mol HCO3 . Cho t t dung dch Ca(OH)2
nng a mol/l vo dung dch E n khi thu c lng kt ta ln nht th va ht V lt dung
dch Ca(OH)2. Biu thc lin h gia cc gi tr V, a, x, y l
xy
x 2y
A. V
B. V
C. V 2a(x y)
D. V a(2x y)
a
a
Tham gia trn vn kho LTH v LUYN ti www.moon.vn t im cao nht trong k thi TSH !
V d 8. Cho dung dch X gm: 0,007 mol Na+; 0,003 mol Ca2+; 0,006 mol Cl; 0,006 mol
HCO3 v 0,001 mol NO 3 . loi b ht Ca2+ trong X cn mt lng va dung dch cha a
gam Ca(OH)2. Gi tr ca a l
A. 0,180.
B. 0,120.
C. 0,444.
D. 0,222.
V d 9. Dung dch X gm a mol Na+, b mol HCO3 , c mol CO 32 , d mol S O 24 . Cn dng 100
ml dung dch Ba(OH)2 c nng l xM cho vo dung dch X th c lng kt ta ln
nht. Biu thc lin h gia x vi a, b l:
A. x = (3a + 2b)/0,2.
B. x = (2a + b)/0,2.
C. x = (a b)/0,2.
D. x = (a + b)/0,2.
V d 10. Mt dung dch cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl v y mol SO 24 . Tng
khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l:
A. 0,01 v 0,03.
B. 0,05 v 0,01.
C. 0,03 v 0,02.
D. 0,02 v 0,05.
V d 11. Mt dung dch cha cc ion: a mol M3+, 0,2 mol Mg2+, 0,3 mol Cu2+, 0,6 mol SO 24 ,
0,4 mol NO3 . C cn dung dch ny thu c 116,8 gam hn hp cc mui khan. M l
A. Cr.
B. Fe.
C. Al.
D. Zn.
V d 12. Mt dung dch X c cha 0,01 mol Ba2+; 0,01 mol NO3 , a mol OH v b mol Na+.
trung ho 1/2 dung dch X ngi ta cn dng 200 ml dung dch HCl 0,1M. Khi lng cht
rn thu c khi c cn dung dch X l:
A. 1,68 gam.
B. 3,36 gam.
C. 2,52 gam.
D. 5,04 gam.
V d 13. Chia hn hp X gm hai kim loi c ho tr khng i thnh hai phn bng nhau.
Phn 1: Ho tan hon ton bng dung dch HCl d thu c 1,792 lt H2 (ktc).
Phn 2: Nung trong khng kh d, thu c 2,84 gam hn hp rn ch gm cc oxit.
Khi lng ca hn hp X l
A. 1,56 gam.
B. 1,8 gam.
C. 2,4 gam.
D. 3,12 gam.
V d 14. Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va
), thu c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l
A. 0,04.
B. 0,075.
C. 0,12.
D. 0,06.
Bin son: Thy L PHM THNH (https://www.facebook.com/thanh.lepham)

PP 05. KT HP BO TON IN TCH

VI CC PHNG PHP KHC (T liu hc bi)
V d 1. Sc 4,48 lt kh CO2 (ktc) vo 1 lt dung dch hn hp Ba(OH)2 0,12M v NaOH
0,06M. Sau khi cc phn ng xy ra hon ton thu c m gam kt ta. Gi tr ca m l
A. 19,70.
B. 23,64.
C. 7,88.
D. 13,79.
V d 2. Hp th hon ton 2,688 lt kh CO2 (ktc) vo 2,5 lt dung dch Ba(OH)2 nng a
mol/l, thu c 15,76 gam kt ta. Gi tr ca a l
A. 0,032.
B. 0,04.
C. 0,048.
D. 0,06.
V d 3. t chy hon ton m gam FeS2 bng mt lng O2 va , thu c kh X. Hp th
ht X vo 1 lt dung dch cha Ba(OH)2 0,15M v KOH 0,1M, thu c dung dch Y v 21,7
gam kt ta. Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l
A. 23,2.
B. 12,6.
C. 18,0.
D. 24,0.
V d 4. t chy hon ton 6,2 gam P trong kh O2 d, thu c cht rn X. Cho X vo 200
ml dung dch NaOH 1,25M. Khi lng mui to thnh trong dung dch l
A. 18,0 gam NaH2PO4 v 7,1 gam Na2HPO4. B. 14,2 gam Na2HPO4 v 16,4 gam Na3PO4.
C. 7,1 gam Na2HPO4 v 8,2 gam Na3PO4.
D. 6,0 gam NaH2PO4 v 21,3 gam Na2HPO4.
V d 5. Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha
Na2CO3 0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l
A. 0,010.
B. 0,015.
C. 0,020.
D. 0,030.
V d 6. Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng thi
khuy u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung
dch X thy c xut hin kt ta. Biu thc lin h gia V vi a, b l:
A. V = 22,4(a b).
B. V = 11,2(a b)
C. V = 11,2(a + b).
D. V = 22,4(a + b).
V d 7. Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng
kt ta thu c l 15,6 gam. Gi tr ln nht ca V l
A. 1,2.
B. 1,8.
C. 2,0.
D. 2,4.
V d 8. Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol
H2SO4 n khi phn ng hon ton thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c
lng kt ta trn l
A. 0,45.
B. 0,35.
C. 0,25.
D. 0,15.
V d 9. Dung dch X cha a mol NaOH v 0,3 mol Na[Al(OH)4]. Cho t t n ht 1,0 mol
HCl vo X thu c 15,6 gam kt ta. Gi tr nh nht ca a l
A. 0,8.
B. 0,7.
C. 0,6.
D. 0,4.
V d 10. Thm dung dch HCl vo 100ml dung dch hn hp gm NaOH 1M v Na[Al(OH)4]
1M. Khi kt ta thu c l 6,24 gam th s mol HCl dng l
A. 0,08 hoc 0,16.
B. 0,18 hoc 0,26.
C. 0,18 hoc 0,22.
D. 0,26 hoc 0,36.
V d 11. Ha tan hon ton 15,95 gam hn hp Ag, Zn v Al bng dung dch H2SO4 c, nng
thu c 7,84 lt kh SO2 (sn phm kh duy nht, o ktc). C cn dung dch sau phn ng
thu c khi lng mui khan l
A. 150,35 gam.
B. 116,75 gam.
C. 83,15 gam.
D. 49,55 gam.
V d 12. Ho tan hon ton 12,0 gam hn hp X gm Fe v Cu bng dung dch HNO3 d, kt
thc th nghim thu c hn hp kh gm 0,1 mol NO v 0,2 mol NO2. Khi lng mui nitrat
(khng c NH4NO3) to thnh trong dung dch l
A. 43,0 gam.
B. 30,6 gam.
C. 55,4 gam.
D. 39,9 gam.
V d 13. Hn hp X gm hai kim loi Cu v Ag. Ha tan hon ton m gam hn hp X trong
dung dch cha 2 axit HNO3, H2SO4 thu c dung dch Y cha 7,06 gam mui v hn hp kh
Z cha 0,05 mol NO2 v 0,01 mol SO2. Gi tr ca m l
A. 2,58.
B. 3,06.
C. 3,00.
D. 3,32.
V d 14. Ha tan hon ton 8,9 gam hn hp gm Mg v Zn bng lng va 500 ml dung
dch HNO3 1M. Sau khi cc phn ng kt thc, thu c 1,008 lt kh N2O (ktc) duy nht v
dung dch X cha m gam mui. Gi tr ca m l
A. 34,10.
B. 31,32.
C. 34,32.
D. 33,70.
V d 15. Cho 29 gam hn hp gm Al, Cu v Ag tc dng va vi 950 ml dung dch HNO3
1,5M, thu c dung dch cha m gam mui v 5,6 lt hn hp kh X (ktc) gm NO v N2O.
T khi ca X so vi H2 l 16,4. Gi tr ca m l
A. 98,20
B. 97,20
C. 98,75
D. 91,00
V d 16. Cho 6,72 gam Fe vo dung dch cha 0,3 mol H2SO4 c, nng (gi thit SO2 l sn
phm kh duy nht). Sau khi phn ng xy ra hon ton, thu c
A. 0,12 mol FeSO4.
B. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4.
C. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.
D. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.
V d 17. Cho x mol Fe tan hon ton trong dung dch cha y mol H2SO4 (t l x : y = 2:5), thu
c mt sn phm kh duy nht v dung dch ch cha mui sunfat. S mol electron do lng
Fe trn nhng khi b ho tan l
A. 2x.
B. 3x.
C. 2y.
D. y.

PP 07. PHNG PHP S DNG PHNG TRNH ION THU GN

(T liu hc bi)
V d 1. Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M,
thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y c pH l
A. 1.
B. 6.
C. 7.
D. 2.
V d 2. Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm
NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l
A. 13,0.
B. 1,2.
C. 1,0.
D. 12,8.
V d 3. Cho hai dung dch: dung dch X cha hai axit H2SO4 0,1M v HCl 0,2M; dung dch Y cha hai baz
NaOH 0,2M v KOH 0,3M. Th tch (ml) dung dch Y cn phi thm vo 100ml dung dch X c mt
dung dch c pH bng 7 l:
A. 60ml.
B. 120ml.
C. 100ml.
D. 80ml.
V d 4. Cn trn dung dch X cha HCl 0,1M v H2SO4 0,1M vi dung dch Y cha NaOH 0,3M v Ba(OH)2
0,1M theo t l th tch nh th no thu c dung dch c pH = 13 ?
A. VX/VY = 1/3.
B. VX/VY = 1/2.
C. VX/VY = 2/1.
D. VX/VY = 1/1.
V d 5. Dung dch X cha hn hp NaOH 0,20M v Ba(OH)2 0,10M; dung dch Y cha hn hp H2SO4
0,05M v HNO3 0,04M. Trn V lt dung dch X vi V lt dung dch Y thu c dung dch Z c pH = 13. T l
V/V l:
A. 1,33.
B. 1,25.
C. 0,8.
D. 0,75.
V d 6. Dung dch X cha NaOH 0,2M v Ca(OH)2 0,1M. Sc 7,84 lt kh CO2 (ktc) vo 1,0 lt dung dch X
th lng kt ta thu c l
A. 0 gam.
B. 5 gam.
C. 15 gam.
D. 10 gam.
V d 7. Hp th hon ton V lt CO2 (ktc) vo 400ml dung dch NaOH a M th thu c dung dch X. Cho
t t v khuy u 150ml dung dch HCl 1M vo X thu c dung dch Y v 2,24 lt kh (ktc). Cho Y tc dng
vi Ca(OH)2 d xut hin 15 gam kt ta. Gi tr ca a l
A. 1,0.
B. 1,5.
C. 0,75.
D. 2,0.
V d 8. Ha tan ht 0,15 mol P2O5 vo 200 gam dung dch H3PO4 9,8%, thu c dung dch X. Cho X tc
dng ht vi 750 ml dung dch NaOH 1M, thu c dung dch Y. Hi trong Y c cha nhng hp cht no ca
photpho v khi lng tng ng l bao nhiu (b qua s thy phn ca cc mui trong dung dch) ?
A. 45,0 gam NaH2PO4; 17,5 gam Na2HPO4.
B. 30,0 gam NaH2PO4; 35,5 gam Na2HPO4.
C. 14,2 gam Na2HPO4; 41,0 gam Na3PO4.
D. 30,0 gam Na2HPO4; 35,5 gam Na3PO4.
V d 9. t chy hon ton m gam qung pirit st (cha 80% FeS2 v khi lng, cn li l tp cht tr) bng
mt lng oxi d. Ly ton b lng SO2 thu c cho hp th ht vo 100 ml dung dch cha Ba(OH)2 1,5M
v NaOH 1M th thu c 26,04 gam kt ta. Gi tr ln nht ca m l
A. 16,80.
B. 18,00.
C. 13,44.
D. 21,00.
V d 10. Trn 100ml dung dch cha KHCO3 1M v K2CO3 1M vi 100ml dung dch cha NaHCO3 1M v
Na2CO3 1M c 200ml dung dch X. Nh t t 100ml dung dch Y cha H2SO4 1M v HCl 1M vo dung dch
X c V lt CO2 (ktc) v dung dch Z. Cho Ba(OH)2 d vo Z th thu c m gam kt ta. Gi tr ca V v m
ln lt l
A. 5,6 v 59,1.
B. 1,12 v 82,4.
C. 2,24 v 59,1.
D. 2,24 v 82,4.
V d 11. Dung dch X cha cc ion: Ca2+, Na+, HCO3 v Cl, trong s mol ca ion Cl l 0,1. Cho 1/2 dung
dch X phn ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi
dung dch Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m
gam cht rn khan. Gi tr ca m l
A. 9,21.
B. 9,26.
C. 8,79.
D. 7,47.
V d 12. Cho m gam NaOH vo 2 lt dung dch NaHCO3 nng a mol/l, thu c 2 lt dung dch X. Ly 1 lt
dung dch X tc dng vi dung dch BaCl2 (d) thu c 11,82 gam kt ta. Mt khc, cho 1 lt dung dch X
vo dung dch CaCl2 (d) ri un nng, sau khi kt thc cc phn ng thu c 7,0 gam kt ta. Gi tr ca a, m
tng ng l
A. 0,08 v 4,8.
B. 0,04 v 4,8.
C. 0,14 v 2,4.
D. 0,07 v 3,2.
V d 13. Cho hn hp K2CO3 v NaHCO3 (t l mol 1 : 1) vo bnh dung dch Ba(HCO3)2 thu c kt ta X
v dung dch Y. Thm t t dung dch HCl 0,5M vo bnh n khi khng cn kh thot ra th ht 560 ml. Bit
ton b Y phn ng va vi 200 ml dung dch NaOH 1M. Khi lng kt ta X l
A. 3,94 gam.
B. 7,88 gam.
C. 11,28 gam.
D. 9,85 gam.
V d 14. Cho t t tng git ca dung dch cha b mol HCl vo dung dch cha a mol Na2CO3 thu c V lt
kh CO2. Ngc li, cho t t tng git ca dung dch cha a mol Na2CO3 vo dung dch cha b mol HCl thu
c 2V lt kh CO2 (cc th tch kh o cng iu kin). Mi quan h gia a v b l:
A. a = 0,75b.
B. a = 0,8b.
C. a = 0,35b.
D. a = 0,5b.
V d 15. Hp th ht 4,48 lt CO2 (ktc) vo dung dch cha x mol KOH v y mol K2CO3 thu c 200 ml
dung dch X. Ly 100 ml X cho t t n ht vo 300 ml dung dch HCl 0,5M thu c 2,688 lt kh (ktc). Mt
khc, 100 ml X tc dng vi dung dch Ba(OH)2 d thu c 39,4 gam kt ta. Gi tr ca x l:
A. 0,15.
B. 0,20.
C. 0,05.
D. 0,10.
V d 16. Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl3; 0,016 mol Al2(SO4)3
v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l
A. 2,568.
B. 1,560.
C. 4,128.
D. 5,064.
V d 17. Ho tan hon ton m gam ZnSO4 vo nc c dung dch X. Nu cho 110 ml dung dch KOH 2M
vo X th thu c 3a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th thu c 2a gam
kt ta. Gi tr ca m l
A. 17,17.
B. 16,10.
C. 14,49.
D. 24,15.
V d 18. Cho 150 ml dung dch Ba(OH)2 1M vo 250 ml dung dch Al2(SO4)3 x (mol/lt) thu c 42,75 gam
kt ta. Thm tip 200 ml dung dch Ba(OH)2 1M vo hn hp phn ng th lng kt ta thu c l 94,2375
gam. Gi tr ca x l
A. 0,45.
B. 0,30.
C. 0,25.
D. 0,15.

PP 08. PHNG PHP S DNG PHNG TRNH ION ELECTRON

V d 1. Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M. Sau
khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A. 0,672
B. 0,448
C. 0,746
D. 1,792
V d 2. Thc hin hai th nghim:
1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO.
2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO.
Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l
A. V2 = V1.
B. V2 = 2V1.
C. V2 = 2,5V1.
D. V2 = 1,5V1.
V d 3. Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi cc
phn ng xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A. 6,72.
B. 8,96.
C. 4,48.
D. 10,08.
V d 4. Dung dch X cha 0,4 mol HCl v 0,05 mol Cu(NO3)2. Cho m gam bt Fe vo dung dch, khuy u
cho n khi phn ng kt thc c cht rn Y gm 2 kim loi c khi lng 0,8m gam. Gi thit sn phm kh
HNO3 ch c NO. Gi tr ca m l
A. 30.
B. 40.
C. 35.
D. 45.
V d 5. Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc
phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht,
ktc). Gi tr ca m v V ln lt l
A. 17,8 v 4,48.
B. 17,8 v 2,24.
C. 10,8 v 4,48.
D. 10,8 v 2,24.
V d 6. Cho 5,8 gam FeCO3 tc dng va vi dung dch HNO3 c hn hp 2 kh khng mu ha nu
ngoi khng kh v dung dch X. Thm dung dch H2SO4 long d vo X th dung dch thu c ha tan ti a
m gam Cu (bit rng phn ng to sn phm kh duy nht l NO). Gi tr ca m l
A. 16
B. 14,4
C. 1,6
D. 17,6.
V d 7. Ha tan hon ton 0,1 mol FeS2 trong 200 ml dung dch HNO3 4M, sn phm thu c gm dung
dch X v mt cht kh thot ra. Dung dch X c th ha tan ti a m gam Cu. Bit trong cc qu trnh trn, sn
phm kh duy nht ca N+5 u l NO. Gi tr ca m l
A. 12,8
B. 6,4
C. 9,6
D. 3,2.
V d 8. Cho 7,68 gam Cu vo 200ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi cc phn ng xy
ra hon ton (sn phm kh duy nht l NO), c cn cn thn ton b dung dch sau phn ng th khi lng
mui khan thu c l:
A. 19,76 gam.
B. 20,16 gam.
C. 19,20 gam.
D. 22,56 gam.
V d 9. Ha tan 9,6 gam bt Cu bng 200ml dung dch hn hp gm HNO3 0,5M v H2SO4 1M. Sau khi
phn ng xy ra hon ton c kh NO (sn phm kh duy nht) v dung dch X. C cn cn thn X c khi
lng mui khan l:
A. 35 gam
B. 28,2 gam
C. 24 gam
D. 25,4 gam
V d 10. Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H2SO4 0,1M. Sau khi cc
phn ng xy ra hon ton, thu c 0,32 gam cht rn v 448 ml kh (ktc) thot ra. Thm tip vo bnh 0,425
gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi
lng mui trong dung dch l
A. 0,224 lt v 3,750 gam B. 0,112 lt v 3,750 gam C. 0,112 lt v 3,865 gam D. 0,224 lt v 3,865 gam

Tuyn sinh lp TNG N LUYN LUYN PHNG PHP GII NHANH Thy L
Phm Thnh (0976.053.496)
M001. CU TO NGUYN T
(T liu hc bi Phn I)
V d 1. (C9) Mt nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52 v c s khi l 35.

S hiu nguyn t ca nguyn t X l
A. 18.
B. 23.
C. 17.
D. 15.
V d 2. (A10) Nhn nh no sau y ng khi ni v 3 nguyn t:
26
13
X,
55
26
Y,
26
12
Z ?
A. X v Z c cng s khi.
B. X, Z l 2 ng v ca cng mt nguyn t ho hc.
C. X, Y thuc cng mt nguyn t ho hc.
D. X v Y c cng s ntron.
V d 3. (B7) Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng s electron
ca anion v tng s electron trong XY l 20. Bit trong mi hp cht, Y ch c mt mc oxi ha duy nht.
Cng thc XY l
A. MgO.
B. AlN.
C. LiF.
D. NaF.
V d 4. (C8) Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang
in ca mt nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 8 ht. Cc nguyn t X v Y ln
lt l (bit s hiu nguyn t ca nguyn t: Na = 11; Al = 13; P = 15; Cl = 17; Fe = 26)
A. Fe v Cl.
B. Na v Cl.
C. Al v Cl.
D. Al v P.
V d 5. Hp cht v c T c cng thc phn t XY2. Tng s cc ht trong phn t T l 66, trong s ht
mang in nhiu hn s ht khng mang in l 22 ht. S khi ca Y nhiu hn X l 4. S ht trong Y nhiu
hn s ht trong X l 6 ht. Cng thc phn t ca T l:
B. NO2.
C. OF2.
D. CO2.
A. ON2.
+
2
V d 6. Mt hp cht ion to ra t ion M v ion X . Trong phn t M2X c tng s cc ht l 140, trong
s ht mang in nhiu hn s ht khng mang in l 44. S khi ca M+ ln hn s khi ca X2 l 23. Tng
s ht trong M+ nhiu hn trong X2 l 31. Tm in tch ht nhn, s khi ca M v X. Cng thc phn t ca
M2X l:
A. K2O.
B. Na2O.
C. Na2S.
D. Li2S.
V d 7. Trong phn t MX2, trong M chim 46,67% v khi lng. Ht nhn M c s ntron nhiu hn s
proton l 4 ht. Trong ht nhn X s ntron bng s proton. Tng s proton trong phn t MX2 l 58. Cng thc
phn t ca MX2 l
A. FeS2.
B. NO2.
C. SO2.
D. CO2.
V d 8. Mt nguyn t X c tng s electron cc phn lp s l 6 v tng s electron lp ngoi cng l 7.
X l nguyn t no sau y ?
A. F (Z = 9).
B. P (Z = 15).
C. S (Z = 16).
D. Cl (Z = 17).
V d 9. Nguyn t ca nguyn t X c tng s electron cc phn lp p l 11. Nguyn t X thuc loi
nguyn t
A. s.
B. p.
C. d.
D. f.
C s I: Ng 72 - Tn Tht Tng (gn H Y H Ni) C s II: S 27 - T Hiu - H ng (gn Cu en)
Phm Thnh (0976.053.496)
V d 10. Bit rng cc electron ca nguyn t X c phn b trn bn lp electron (K, L, M, N), lp ngoi
cng c 5 electron. S electron lp M trong nguyn t X l
A. 8.
B. 18.
C. 11.
D. 13.
V d 11. Cho bit s hiu nguyn t ca cc nguyn t X v Y ln lt l ZX = 24, ZY = 29. Cu hnh electron
nguyn t ca X, Y ln lt l
A. [Ar] 3d44s2 v [Ar] 3d94s2.
B. [Ar] 3d54s1 v [Ar] 3d94s2.
C. [Ar] 3d44s2 v [Ar] 3d104s1.
D. [Ar] 3d54s1 v [Ar] 3d104s1.
V d 12. Cho cc nguyn t K (Z = 19), Sc (Z = 21), Cr (Z = 24), Cu (Z = 29). Cc nguyn t c s electron
lp ngoi cng bng nhau l
A. K, Sc.
B. Sc, Cr, Cu.
C. K, Cr, Cu.
D. K, Sc, Cr, Cu.
V d 13. Nguyn t nguyn t X c tng s ht (p, n, e) l 76, trong s ht mang in nhiu hn s ht
khng mang in l 20 ht. Cu hnh electron nguyn t ca nguyn t X l
B. [Ar] 3d44s2.
C. [Ar] 4s13d5.
D. [Ar] 4s23d4.
A. [Ar] 3d54s1.
V d 14. Nguyn t X c tng s electron cc phn lp s l 7. S hiu nguyn t ca nguyn t X c th l
A. 19 hoc 24.
B. 19 hoc 29.
C. 24 hoc 29.
D. 19, 24 hoc 29.
V d 15. Cu hnh electron trng thi c bn ca nguyn t no sau y c electron c thn obitan s ?
A. Cr (Z = 24).
B. Mn (Z = 25).
C. Fe (Z = 26).
D. Co (Z = 27).
V d 16. Cu hnh electron trng thi c bn ca nguyn t no sau y c 4 electron c thn obitan d ?
A. Cr (Z = 24).
B. Mn (Z = 25).
C. Fe (Z = 26).
D. Co (Z = 27).
V d 17. Nguyn t X c 3 electron c thn phn lp 3d. S hiu nguyn t ca X l
D. 21 hoc 27.
A. 21.
B. 23.
C. 23 hoc 27.
V d 18. Nguyn t ca nguyn t no sau y c s electron c thn l ln nht ?
A. Cl (Z = 17).
B. Ca (Z = 20).
C. Al (Z = 13).
D. C (Z = 6).
V d 19. Trong 20 nguyn t u tin ca bng tun hon, s nguyn t c 1 electron c thn trong cu hnh
electron nguyn t l
A. 5.
B. 6.
C. 7.
D. 8.
V d 20. Trong 20 nguyn t u tin ca bng tun hon, s nguyn t c 2 electron c thn trong cu hnh
electron nguyn t l
A. 4.
B. 6.
C. 8.
D. 10.
2+
V d 21. Cho bit st c s hiu nguyn t l 26. Cu hnh electron ca ion Fe l
A. 1s22s22p63s23p63d64s2.
B. 1s22s22p63s23p63d6.
C. 1s22s22p63s23p63d54s1.
D. 1s22s22p63s23p63d44s2.
ca X v Y2+ ln lt l
A. [Ar] 3d44s2 v [Ar] 3d44s2.
B. [Ar] 3d54s1 v [Ar] 3d6.
C. [Ar] 3d54s1 v [Ar] 3d54s1.
D. [Ar] 3d54s1 v [Ar] 3d64s2.
24
19
V d 23. Cho 3 ion: Na+, Mg2+, F (vi: 23
11 Na, 12 Mg, 9 F ). Cu no sau y khng ng ?
A. 3 ion trn c cu hnh electron ging nhau.
B. 3 ion trn c s ht ntron khc nhau.
C. 3 ion trn c s ht electron bng nhau.
D. 3 ion trn c s ht proton bng nhau.
2+
3+
V d 24. (A11) Cu hnh electron ca ion Cu v Cr ln lt l
A. [Ar] 3d9 v [Ar] 3d14s2.
B. [Ar] 3d74s2 v [Ar] 3d14s2.
C. [Ar] 3d9 v [Ar] 3d3.
D. [Ar] 3d74s2 v [Ar] 3d3.
Phm Thnh (0976.053.496)
M001. CU TO NGUYN T
(T liu hc bi Phn II)
V d 26. Cho dy cc kim loi: Na, K, Mg, Ca, Ba, Al, Cu, Ag, Au, Fe. S kim loi c kiu tinh th lp
phng tm khi, lp phng tm din v lc phng ln lt l:
A. 3; 4; 3.
B. 3; 5; 2.
C. 4; 4; 2.
D. 4; 5; 1.
V d 27. Ba dng tinh th ph bin ca kim loi v s nguyn t kim loi (N) trong mi c s tng ng l
A. lp phng tm khi (2) ; lp phng tm din (4) ; lc phng (6).
B. lp phng tm khi (5) ; lp phng tm din (4) ; lc phng (2).
C. lp phng tm khi (5) ; lp phng tm din (5) ; lc phng (6).
D. lp phng tm khi (2) ; lp phng tm din (4) ; lc phng (2).
V d 28. Trong mng tinh th lp phng tm din, cc nguyn t tip xc nhau mt bn. ng cho ca
mt c di bng 4 ln bn knh ca nguyn t. % chim ch ca nguyn t kim loi trong loi mng ny l
A. 68%.
B. 72%.
C. 74%.
D. 76%.
V d 29. Bit tinh th kim loi K c cu trc lp phng tm khi. Khi lng ca mt c s ca K l (cho:
K = 39, NA = 6,02.1023)
A. 0,65.1022 gam.
B. 1,30.1022 gam.
C. 2,59.1022 gam.
D. 3,89.1022 gam.
V d 30. (A11) Khi lng ring ca canxi kim loi l 1,55 g/cm3. Gi thit rng trong tinh th canxi cc
nguyn t l nhng hnh cu chim 74% th tch tinh th, phn cn li l khe rng. Bn knh nguyn t canxi
tnh theo l thuyt l:
A. 0,196 nm.
B. 0,185 nm.
C. 0,168 nm.
D. 0,155 nm.
V d 31. Kim loi Ni c cu trc mng tinh th theo kiu lp phng tm din. Bn knh nguyn t ca Ni l
0,124 nm. Khi lng ring ca niken l (Cho Ni = 58,7)
A. 7,19 g/cm3.
B. 7,87 g/cm3.
C. 8,90 g/cm3.
D. 9,06 g/cm3.
V d 32. Trong t nhin hiro c 2 ng v bn l 1H, 2H ; clo c hai ng v bn l 35Cl, 37Cl. S loi phn t
HCl khc nhau c th to thnh t cc ng v trn l
A. 2.
B. 4.
C. 6.
D. 8.
Phm Thnh (0976.053.496)
V d 33. Trong t nhin oxi c 3 ng v l 16O, 17O, 18O ; cn cacbon c 2 ng v l 12C, 13C. S loi phn t
kh cacbonic ti a c th to thnh t cc ng v trn l
A. 6.
B. 12.
1
C. 9.
2
D. 18.
16
V d 34. Hiro c 3 ng v H, H, H. Oxi c 3 ng v l
O,
17
O,
18
O. S loi phn t nc khc nhau
c to thnh l
A. 9.
B. 12.
C. 18.
D. 27.
63
V d 35. (C7) Trong t nhin, nguyn t ng c hai ng v l
29
Cu v
65
ng l 63,54. Thnh phn phn trm tng s nguyn t ca ng v

A. 27%.
B. 50%.
29
65
29
Cu . Nguyn t khi trung bnh ca
Cu l
C. 54%.
D. 73%.
V d 36. Trong t nhin magie c 3 ng v bn 24Mg chim 78,99%, 25Mg chim 10,00% v 26Mg. Nguyn t
khi trung bnh ca Mg l
A. 24,00.
B. 24,11.
C. 24,32.
D. 24,89.
79
V d 37. Nguyn t khi trung bnh ca nguyn t X l 79,91. Bit X c hai ng v trong ng v
chim 54,5% s nguyn t. Nguyn t khi ca ng v cn li l

A. 80.
B. 81.
C. 82.
D. 83.
V d 38. Nguyn t khi trung bnh ca Ne l 20,19. Bit Ne c ba ng v trong ng v
20
Ne chim
21
90,48% v ng v Ne chim 0,27% s nguyn t. Nguyn t khi ca ng v cn li l

A. 18.
B. 19.
C. 22.
D. 23.
V d 39. Nguyn t X c hai ng v X1 v X2. Tng s ht khng mang in trong X1 v X2 l 90. Nu cho
1,2 gam Ca tc dng vi mt lng X va th thu c 5,994 gam hp cht CaX2. Bit t l s nguyn t X1 :
X2 = 9 : 11. S khi ca X1, X2 ln lt l
A. 81 v 79.
B. 75 v 85.
C. 79 v 81.
V d 40. Trong t nhin st gm 4 ng v
54
chim 0,28%. Brom l hn hp hai ng v
79
Fe chim 5,8%,
56
D. 85 v 75.
Fe chim 91,72%,
Br chim 50,69% v
81
57
Fe chim 2,2% v
58
Fe
Br chim 49,31%. Thnh phn % khi
lng ca 56Fe trong FeBr3 l

A. 17,36%.
B. 18,92%.
V d 41. (B11) Trong t nhin clo c hai ng v bn:

Thnh phn % theo khi lng ca
A. 8,92%
37
17
37
17
D. 27,55%.
Cl chim 24,23% tng s nguyn t, cn li l
35
17
Cl .
Cl trong HClO4 l (Cho: H = 1, O = 16):
B. 8,43%
10
C. 27,03%.
C. 8,56%
D. 8,79%
11
V d 42. Bo c 2 ng v l B v B vi nguyn t khi trung bnh l 10,81. Thnh phn % v khi lng
ca ng v 11B cha trong H3BO3 l (Cho: H = 1, O = 16)
A. 14,00%.
B. 14,16%.
C. 14,42%.
D. 15,00%.

Phm Thnh (0976.053.496)
M002. NH LUT TUN HON

(T liu hc bi Phn I)
V d 1. (A7) Anion X v cation Y2+ u c cu hnh electron lp ngoi cng l 3s23p6. V tr ca cc
nguyn t trong bng tun hon cc nguyn t ha hc l:
A. X c s th t 17, chu k 4, nhm VIIA; Y c s th t 20, chu k 4, nhm IIA.
B. X c s th t 18, chu k 3, nhm VIA; Y c s th t 20, chu k 4, nhm IIA.
C. X c s th t 17, chu k 3, nhm VIIA; Y c s th t 20, chu k 4, nhm IIA.
D. X c s th t 18, chu k 3, nhm VIIA; Y c s th t 20, chu k 3, nhm IIA.
V d 2. (A9) Cu hnh electron ca ion X2+ l 1s22s22p63s23p63d6. Trong bng tun hon cc nguyn t ho
hc, nguyn t X thuc
A. chu k 4, nhm VIIIA. B. chu k 4, nhm IIA.
C. chu k 3, nhm VIB.
D. chu k 4, nhm VIIIB.
V d 3. (C9) Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca
nguyn t Y cng c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y
c s electron hn km nhau l 2. Nguyn t X, Y ln lt l
A. kim loi v kim loi.
B. phi kim v kim loi.
C. kim loi v kh him.
D. kh him v kim loi.
V d 4. Trong bng tun hon c 16 nhm nguyn t (8 nhm A, 8 nhm B), s nhm nguyn t c cha kim
loi v s nhm nguyn t ch cha kim loi ln lt l:
A. 11; 9.
B. 11; 10.
C. 14; 9.
D. 14; 10.
V d 5. Hai nguyn t X v Y ng k tip nhau trong mt chu k c tng s proton trong hai ht nhn nguyn
t l 25. X v Y thuc chu k v cc nhm no sau y ?
A. Chu k 2 ; cc nhm IA v IIA.
B. Chu k 3 ; cc nhm IA v IIA.
C. Chu k 2 ; cc nhm IIA v IIIA.
D. Chu k 3 ; cc nhm IIA v IIIA.
V d 6. X v Y l hai nguyn t trong cng mt nhm v hai chu k lin tip ca bng tun hon. Tng s
proton trong ht nhn ca hai nguyn t X v Y bng 32. Hai nguyn t l
A. Mg (Z = 12) v Ca (Z = 20).
B. Al (Z = 13) v K (Z = 19).
C. Si (Z = 14) v Ar (Z = 18).
D. Na (Z = 11) v Sc (Z = 21).
V d 7. Cu hnh electron trng thi c bn ca nguyn t nhm no sau y c 4 electron c thn obitan
d?
A. IVA.
B. VIA.
C. VIB.
D. VIIIB.
V d 8. Trong s cc nguyn t di y, nguyn t no th hin tnh kim loi r nht ?
A. Na.
B. Mg.
C. Ca.
D. K.
V d 9.(B8) Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l:
A. P, N, O, F.
B. P, N, F, O.
C. N, P, O, F.
D. N, P, F, O.
V d 10. Trong cc hiroxit di y, cht no c tnh axit mnh nht ?
A. H2SO4.
B. H2SeO4.
C. HClO4.
D. HBrO4.
V d 11. Tnh axit ca cc oxi axit thuc nhm VA theo trt t gim dn l
A. H3SbO4 > H3AsO4 > H3PO4 > HNO3.
B. HNO3 > H3PO4 > H3AsO4 > H3SbO4.
C. H3SbO4 > H3AsO4 > HNO3 > H3PO4.
D. HNO3 > H3PO4 > H3SbO4 > H3AsO4.
V d 12. Trong bng tun hon (tr cc nguyn t nhm VIIIA), nguyn t c nng lng ion ha I1 nh nht
v ln nht ln lt l
A. Li v At.
B. F v Fr.
C. At v Li.
D. Fr v F.
Phm Thnh (0976.053.496)
V d 13. Trong cc nguyn t chu k III: 11Na, 12Mg, 13Al, 15P, 16S, nng lng ion ha th nht I1 ca cc
nguyn t trn tun theo trt t no sau y ?
A. Na < Mg < Al < P < S. B. Na < Al < Mg < S < P. C. Na < Al < Mg < P < S. D. S < P < Al < Mg < Na.
V d 14. Dy cc nguyn t nguyn t no sau y c sp xp theo chiu tng dn m in ?
A. Mg < Si < S < O.
B. O < S < Si < Mg.
C. Si < Mg < O < S.
D. S < Mg < O < Si.
V d 15. C cc nguyn t : Na, O, Al, P, N. Hy sp xp cc nguyn t trn theo chiu tng dn ca m
in.
A. Na < Al < P < N < O. B. Al < Na < P < N < O. C. Na < Al < N < P < O. D. Al < Na < N < P < O.
V d 16. (C7) Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in ca cc
nguyn t tng dn theo th t
A. Y < M < X < R.
B. R < M < X < Y.
C. M < X < Y < R.
D. M < X < R < Y.
V d 17. (C10) Cc kim loi X, Y, Z c cu hnh electron nguyn t ln lt l: 1s22s22p63s1; 1s22s22p63s2;
1s22s22p63s23p1. Dy gm cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l
A. X, Y, Z.
B. Z, X, Y.
C. Z, Y, X.
D. Y, Z, X.
V d 18. (A8) Bn knh nguyn t ca cc nguyn t: 3Li, 8O, 9F, 11Na c xp theo th t tng dn t tri
sang phi l
A. F, Na, O, Li.
B. F, Li, O, Na.
C. F, O, Li, Na.
D. Li, Na, O, F.
V d 19. Th t so snh bn knh nguyn t ca cc nguyn t 14Si, 17Cl, 20Ca, 37Rb l:
A. rSi < rCl < rCa < rRb.
B. rCl < rSi < rCa < rRb.
C. rSi < rCl < rRb < rCa.
D. rCl < rSi < rRb < rCa.
V d 20. (B9) Cho cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Dy gm cc nguyn t
c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l:
A. N, Si, Mg, K.
B. K, Mg, Si, N.
C. K, Mg, N, Si.
D. Mg, K, Si, N.
2
3+
V d 21. C cc tiu phn sau : O , Al , Ca, Mg. Hy sp xp cc tiu phn trn theo chiu gim dn kch
thc (bn knh).
A. Mg > Ca > Al3+ > O2. B. Ca > Mg > Al3+ > O2. C. Mg > Ca > O2 > Al3+. D. Ca > Mg > O2 > Al3+.
V d 22. Cc ion hoc nguyn t sau u c 18 electron : P3, S2, Cl, Ar, K+, Ca2+. Chiu gim dn bn knh
ca cc tiu phn trn l
A. P3 > S2 > Cl > Ar > K+ > Ca2+.
B. Ca2+ > K+ > Ar > Cl > S2 > P3.
C. Cl > S2 > P3 > Ar > K+ > Ca2+.
D. Ca2+ > K+ > Ar > P3 > S2 > Cl.
V d 23. Cho cc ion sau: 3Li+, 11Na+, 17Cl, 19K+, 35Br, 53I. Chiu tng dn bn knh ca cc ion l :
A. Li+ < Na+ < K+ < Cl < Br < I.
B. Li+ < Na+ < Cl < K+ < Br < I.
C. K+ < Cl < Br < I < Na+ < Li+.
D. Na+ < K+ < Cl < Br < I < Li+.
V d 24. (A10) Cc nguyn t t Li n F, theo chiu tng ca in tch ht nhn th
B. bn knh nguyn t v m in u tng.
A. bn knh nguyn t tng, m in gim.
C. bn knh nguyn t gim, m in tng.
D. bn knh nguyn t v m in u gim.
V d 25. (B7) Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm VIII), theo
chiu tng ca in tch ht nhn nguyn t th
A. m in gim dn, tnh phi kim tng dn.
B. tnh phi kim gim dn, bn knh nguyn t tng dn.
C. tnh kim loi tng dn, m in tng dn.
D. tnh kim loi tng dn, bn knh nguyn t gim dn.
V d 26. C 2 nguyn t 25X v 35Y. iu khng nh no di y l khng ng?
A. Tnh kim loi ca X mnh hn ca Y.
B. Nng lng ion ha th nht (I1) ca Y ln hn X.
C. m in ca X nh hn Y.
D. Y c s electron c thn nhiu hn X.
Phm Thnh (0976.053.496)
M002. NH LUT TUN HON

V d 27. Khi cho 1,17 gam kim loi X (thuc nhm IA) tc dng ht vi nc to ra 0,336 lt kh hiro (ktc).
Kim loi X l
A. Li (7).
B. Na (23).
C. K (39).
D. Rb (85).
A. Mg (Z = 12) v Ca (Z = 20).
B. Al (Z = 13) v K (Z = 19).
C. Si (Z = 14) v Ar (Z = 18).
D. Na (Z = 11) v Sc (Z = 21).
V d 29. Cho 8,8 gam hn hp hai kim loi nm hai chu k lin tip nhau v thuc nhm IIIA, tc dng vi
HCl d thu c 6,72 lt kh hiro (ktc). Tn ca hai kim loi l
A. B v Al.
B. Al v Ga.
C. Ga v In.
D. In v Tl.
V d 30. Cho 11,2 gam hn hp hai kim loi nhm IIA, thuc hai chu k lin tip, tc dng ht vi dung dch
H2SO4 d thu c 4,48 lt kh hiro (ktc). Cc kim loi l
A. Be v Mg.
B. Mg v Ca.
C. Ca v Sr.
D. Sr v Ba.
V d 31. Hai nguyn t X v Y ng k tip nhau trong mt chu k c tng s proton trong hai ht nhn
nguyn t l 25. X v Y thuc chu k v cc nhm no sau y ?
V d 32. Hai nguyn t ca nguyn t X v Y c cu hnh electron lp ngoi cng l 4pa v 4sb. Tng s
electron hai phn lp ngoi cng ca X v Y l 7. Bit X khng phi l kh him. Vy Y v X ln lt l:
A. K v Br.
B. Ca v Br.
C. K v S.
D. Ca v S.
V d 33. Nguyn t X c 7 electron p. Nguyn t Y c tng s ht mang in nhiu hn tng s ht mang
in ca X l 8 ht. S electron trong phn t hp cht to thnh gia X v Y l :
A. 30.
B. 76.
C. 34.
D. 64.
V d 34. Oxit cao nht ca nguyn t R c dng R2O5. Trong hp cht vi hiro, R chim 91,18% v khi
lng. R l nguyn t no di y ?
A. Nit (N).
B. Photpho (P).
C. Asen (As).
D. Antimon (Sb).
V d 35. Hp cht kh vi H ca nguyn t R l RH4. Oxit cao nht ca n cha 46,7% R v khi lng.
Nguyn t R l
A. C.
B. Si.
C. O.
D. S.
V d 36. (B8) Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3. Trong oxit m R c
ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R l
A. As.
B. N.
C. S.
D. P.
Phm Thnh (0976.053.496)
V d 37. (A9) Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns2np4. Trong hp cht
kh ca nguyn t X vi hiro, X chim 94,12% khi lng. Phn trm khi lng ca nguyn t X trong
oxit cao nht l
A. 50,00%.
B. 27,27%.
C. 60,00%.
D. 40,00%.
V d 38. Oxit ca nguyn t X nhm IIB cha 19,75% oxi v khi lng. Nguyn t X l
A. Cu.
B. Fe.
C. Ni.
D. Zn.
V d 39. R l kim loi nhm IIA. T l % khi lng ca R trong hp cht vi hiro v oxit l 4 : 3. Kim loi
R l
A. Be.
B. Mg.
C. Ca.
D. Sr.
V d 40. R l kim loi nhm IA. T l % khi lng ca R trong hp cht vi hiro v oxit l 1,291 : 1. Kim
loi R l
A. Li.
B. Na.
C. K.
D. Rb.
V d 41. Hp cht R c to bi 2 nguyn t X, Y u thuc nhm A c MR = 76 vC. Ha tr trong hp
cht vi hiro ca X, Y ln lt l n, m ; ha tr cao nht trong hp cht vi oxi l n v 3m. Bit rng trong R
nguyn t X c ha tr cao nht. Cng thc ca R l
A. SiO2.
B. CaF2.
C. CS2.
D. Na2S.
V d 42. X l nguyn t thuc nhm VIIA. Oxit cao nht ca n c phn t khi l 183 vC. Y l kim loi
nhm IIA. Cho 10,08 lt kh X (ktc) tc dng va vi Y thu c 93,6 gam mui. Y l kim loi no di
y ?
A. Be.
B. Mg.
C. Ca.
D. Ba.
V d 43. Oxit cao nht ca nguyn t R c khi lng phn t l 108. Nguyn t R l:
A. Si
B. N
C. P
D. C.
V d 44. Oxit cao nht ca nguyn t R c khi lng phn t l 80. Nguyn t R l:
A. Si
B. N
C. P
D. Cu v S.
V d 45. (A12) Phn trm khi lng ca nguyn t R trong hp cht kh vi hiro (R c s oxi ha thp
nht) v trong oxit cao nht tng ng l a% v b%, vi a : b = 11 : 4. Pht biu no sau y l ng?
A. Oxit cao nht ca R iu kin thng l cht rn.
B. Nguyn t R ( trng thi c bn) c 6 electron s.
C. Trong bng tun hon cc nguyn t ha hc, R thuc chu k 3.
D. Phn t oxit cao nht ca R khng c cc.
V d 46. M l mt nguyn t nhm VA, X l hp cht ca M vi hiro, Y l oxit cao nht ca M. t chy
mt lng X cn va 6,4 gam oxi thu c 7,1 gam Y. Kt lun no v M l sai ?
A. M chu k 3.
B. M c nhiu dng th hnh.
C. Lp v nguyn t ca M c 5 electron c thn trng thi c bn.
D. Nguyn t khi ca M l 31u.
Phm Thnh (0976.053.496)
M004. GII TON BNG PHNG PHP BO TON ELECTRON

(T liu hc bi)
V d 1. (C9) t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn hp
kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hn hp kh phn ng l 5,6 lt ( ktc).
Kim loi M l
A. Mg.
B. Ca.
C. Be.
D. Cu.
V d 2. (C8) Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng
kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn
li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (ktc). Gi tr ca V l
A. 2,80.
B. 3,36.
C. 3,08.
D. 4,48.
V d 3. (B12) Dn lung kh CO i qua hn hp gm CuO v Fe2O3 nung nng, sau mt thi gian thu c
cht rn X v kh Y. Cho Y hp th hon ton vo dung dch Ba(OH)2 d, thu c 29,55 gam kt ta. Cht rn
X phn ng vi dung dch HNO3 d thu c V lt kh NO (sn phm kh duy nht ktc). Gi tr ca V l
A. 2,24
B. 4,48
C. 6,72
D. 3,36.
V d 4. Trn 0,54 gam bt Al vi hn hp bt Fe2O3 v CuO ri tin hnh phn ng nhit nhm nhit
cao trong iu kin khng c khng kh mt thi gian thu c hn hp rn X. Ha tan X trong dung dch
HNO3 c d th thu c V lt kh NO2 (sn phm kh duy nht) ktc. Gi tr ca V l
A. 0,672.
B. 0,896.
C. 1,120.
D. 1,344.
V d 5. (C12) Ha tan hon ton 2,7 gam hn hp X gm Fe, Cr, Al bng dung dch HCl d, thu c 1,568
lt kh H2 (ktc). Mt khc, cho 2,7 gam X phn ng hon ton vi kh Cl2 d, thu c 9,09 gam mui. Khi
lng Al trong 2,7 gam X l bao nhiu ?
A. 0,54 gam
B. 0,81 gam
C. 0,27 gam
D. 1,08 gam
V d 6. Cho 23,52 gam hn hp X gm Mg, Fe, Cu vo 200ml dung dch HNO3 3,4M. Khuy u thy thot
ra kh NO (sn phm kh duy nht), trong dung dch cn d mt kim loi cha tan ht; tip t t dung dch
H2SO4 5M vo, cht kh trn li thot ra cho n khi kim loi va tan ht th cn va ht 44ml, thu c dung
dch Y. Ly 1/2 dung dch Y, cho dung dch NaOH d vo, lc ly kt ta, nung trong khng kh n khi
lng khng i c cht rn Z nng 15,6 gam. S mol Fe c trong hn hp X l
A. 0,06.
B. 0,12.
C. 0,24.
D. 0,36.
C s I: Ng 72 - Tn Tht Tng (gn H Y H Ni) C s II: S 16A (i din cng ph THPT Nguyn Hu c)
Phm Thnh (0976.053.496)
V d 7. (B7) Cho 0,01 mol mt hp cht ca st tc dng ht vi H2SO4 c nng (d), ch thot ra 0,112 lt
(ktc) kh SO2 (l sn phm kh v kh duy nht). Cng thc ca hp cht st l
A. FeS.
B. FeS2.
C. FeO.
D. FeCO3.
V d 8. (A9) Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 1 mol Ag+ n khi
cc phn ng xy ra hon ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi tr
no ca x tho mn trng hp trn ?
A. 1,8.
B. 1,5.
C. 1,2.
D. 2,0.
V d 9. Cho 0,05 mol Al v 0,02 mol Zn tc dng hon ton vi 2 lt dung dch HNO3 long, sau phn ng thu
c 0,112 lt kh khng mu (ktc). Phn dung dch em c cn thu c 15,83 gam mui khan. Nng mol
ca dung dch HNO3 dng l
A. 0,1125M.
B. 0,1450M.
C. 0,1150M.
D. 0,1175M.
V d 10. Ha tan hon ton 30,0 gam hn hp X gm Mg, Al, Zn trong dung dch HNO3, sau phn ng hon
ton thu c dung dch Y v hn hp kh Z gm 0,1 mol N2O v 0,1 mol NO. C cn dung dch sau phn ng
thu c 127 gam hn hp mui. S mol HNO3 b kh trong phn ng trn l bao nhiu ?
A. 0,30 mol.
B. 0,35 mol.
C. 0,40 mol.
D. 0,45 mol.
V d 11. Cho dng kh CO i qua ng s cha 0,3 mol hn hp FeO v Fe3O4 nung nng, sau phn ng thu
c 3,36 lt CO2 ( ktc). Hn hp cht rn cn li trong ng s nng 51,2 gam, ha tan hn hp cht rn ny
vo dung dch HNO3 d thu c V lt kh NO (sn phm kh duy nht). Th tch V (o ktc) l
A. 2,24 lt.
B. 4,48 lt.
C. 6,72 lt.
D. 8,96 lt.
V d 12. Cho dng kh CO i qua ng s ng 0,12 mol hn hp X gm FeO v Fe2O3 nung nng, thu c
14,352 gam hn hp rn Y v 0,138 mol CO2. Ha tan ht Y vo dung dch HNO3 d c V lt kh NO (sn
phm kh duy nht, ktc). Gi tr ca V l
A. 0,224.
B. 0,672.
C. 2,285.
D. 6,857.

C s I: Ng 72 - Tn Tht Tng (gn H Y H Ni) C s II: S 16A (i din cng ph THPT Nguyn Hu c)
TRUNG TM BI DNG KIN THC v LUYN THI I HC Thy L Phm Thnh (0976.053.496)
M012. MT S VN M U V HA HC HU C
(T liu hc bi)
V d 1. Cho dy cc cht sau: CaC2, C2H2, C2H5OH, NaOH, CH3CN, HCN, CO2, HCOONa, NaHCO3,
CF2Cl2. S hp cht hu c c trong dy trn l
A. 4.
B. 5.
C. 6.
D. 7.
V d 2. C cc phng php s ch hp cht hu c:
(a) Gi l cy chm, cho vo nc, lc ly dung dch mu nhum si, vi.
(b) Nu ru ung.
(c) Ngm ru thuc, ru rn.
(d) Lm ng ct, ng phn t nc ma.
(e) Nu nc l xng hi.
(g) Mui da, mui c.
(h) un si du th tch ring nha ng, du nhn, du iezen, du ha, xng,
(i) Nu cao ng vt (h, trn, ).
S phng php s ch thuc loi chng ct, chit, kt tinh ln lt l:
A. 2; 3; 2.
B. 2; 3; 3.
C. 3; 2; 2.
D. 3; 3; 2.
V d 3. C cc m t sau:
(a) Phn t phi cha C.
(b) D bay hi, kh chy.
(c) Thng km bn vi nhit.
(d) Thng khng tan hoc t tan trong nc.
(e) Lin kt ha hc thng l cng ha tr khng phn cc.
S c im chung ca cc hp cht hu c l:
A. 2.
B. 3.
C. 4.
D. 5.
V d 4. Cho dy cc cht sau: C4H10, CF2Cl2, C2H4, C2H5OH, C6H6, CH3CHO, CH2O3, C12H22O11, HCN,
CH8O3N2. S dn xut ca hirocacbon c trong dy trn l
A. 4.
B. 5.
C. 6.
D. 7.
V d 5. Cho tn gi ca cc cht sau: butan (1); axeton (2); imetyl ete (3); axit lactic (4); saccaroz (5); ancol
etylic (6); anehit oxalic (7); pheromon (8); propan-1,2,3-triol (9); axit butyric (10).
S cht c gi theo tn h thng l
A. 4.
B. 5.
C. 6.
D. 7.
V d 6. Khng nh no sau y khng ng khi ni v c im ca cc phn ng ca cc hp cht hu c ?
A. Phn ng ca cc hp cht hu c thng xy ra chm v khng hon ton.
B. Phn ng ca cc hp cht hu c thng xy ra khng theo mt hng nht nh.
C. cho phn ng ca cc hp cht hu c xy ra c, ngi ta thng un nng v dng cc cht xc tc.
D. a s cc hp cht hu c bn vi nhit , khng b chy khi t.
Lin h hc offline ti H Ni: Thy L Phm Thnh (E-mail: thanh.lepham@gmail.com Phone: 0976.053.496)
M013. PHNG PHP LP CTPT HP CHT HU C

(T liu hc bi)
V d 1. Thnh phn cc nguyn t trong hp cht hu c c c im l

A. Gm c C, H v cc nguyn t khc.
B. Gm tt c cc nguyn t trong bng tun hon.
C. Thng c C, H hay gp O, N sau n halogen, S, P.
D. Nht thit phi c cacbon, thng c H, hay gp O, N sau n halogen, S, P...
V d 2. Nung mt hp cht hu c X vi lng d cht oxi ha CuO ngi ta thy thot ra kh CO2, hi H2O
v kh N2. Kt lun chnh xc nht v X l:
A. X l hp cht ca 3 nguyn t C, H, N.
B. X chc chn c cha C, H; c th c N.
D. X l hp cht ca 4 nguyn t C, H, N, O.
C. X chc chn cha C, H, N; c th c O.
V d 3. nhn bit nguyn t H trong phn t hp cht hu c X, ngi ta oxi ha hon ton X bng CuO
d, ri dn hn hp sn phm thu c qua bnh cha
A. nc vi trong d.
B. P2O5 khan.
C. H2SO4 c.
D. CuSO4 khan.
V d 4. t chy mt hp cht hu c X (cha C, H, O) bng lng O2 d c hn hp kh Z. Mun tch
O2 d ra khi Z th dn hn hp kh Z qua bnh cha lng d
A. Photpho trng.
B. P2O5 khan.
C. dung dch kim.
D. H2SO4 c.
V d 5. Khi t chy hon ton 0,29 gam cht hu c X gm C, H, O, sn phm chy cho qua bnh ng CaO
d, khi lng bnh tng 0,93 gam, nhng nu qua bnh ng P2O5 d th khi lng bnh ch tng 0,27 gam.
Thnh phn % khi lng ca nguyn t O trong X l
A. 27,59%.
B. 33,46%.
C. 42,51%.
D. 62,07%.
V d 6. Khi phn tch 0,5 gam cht hu c X, kh NH3 to thnh cho qua bnh ng 30 ml dung dch H2SO4
0,5M, sau phn ng lng axit d c trung ha bi 4,5 ml dung dch NaOH 1M. Thnh phn % v khi
lng ca nguyn t N trong X l
A. 3,57%.
B. 7,14%.
C. 35,7%.
D. 71,4%.
V d 7. (B7) Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi
ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l
A. C2H5COOCH3 v HCOOCH(CH3)2.
B. HCOOC2H5 v CH3COOCH3.
C. C2H3COOC2H5 v C2H5COOC2H3.
D. HCOOCH2CH2CH3 v CH3COOC2H5.
V d 8. Paracetamol (X) l thnh phn chnh ca thuc h st v gim au. Oxi ha hon ton 5,285 gam X
bng CuO d, dn sn phm chy ln lt qua bnh 1 ng H2SO4 c, bnh 2 ng Ba(OH)2 d. Sau khi kt
thc th nghim thy khi lng bnh 1 tng 2,835 gam, bnh 2 to thnh 55,16 gam kt ta v cn 0,392 lt
kh (ktc) thot ra. CTPT (trng vi cng thc n gin nht) ca paracetamol l
A. C4H9N.
B. C4H9O2N.
C. C8H9N.
D. C8H9O2N.
V d 9. Vitamin A l mt cht dinh dng thit yu cho con ngi. Trong thc phm, vitamin A tn ti
dng chnh l retinol (cha C, H, O) trong thnh phn % khi lng H v O tng ng l 10,49% v
5,594%. Bit retinol cha 1 nguyn t Oxi, cng thc phn t ca retinol l
A. C18H30O.
B. C20H30O.
C. C21H18O.
D. C22H30O.
V d 10. (A9) Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp

cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm
ng vi cng thc phn t ca X l
A. 3.
B. 6.
C. 4.
D. 5.
V d 11. Cho 5 ml hirocacbon X th kh vi 30 ml O2 (ly d) vo kh k ri bt tia la in t sau lm

lnh thy trong kh k cn 20 ml kh trong c 15 ml kh b hp th bi dung dch KOH, phn cn li hp th
bi P trng. Cng thc phn t ca X l:
B. C2H6.
C. C3H8.
D. C4H10.
A. CH4.
V d 12. (B7) Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp
i s mol cn cho phn ng chy) 139oC, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v
nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l
A. C2H4O2.
B. C3H6O2.
C. C4H8O2.
D. CH2O2.

M014. HIN TNG NG NG NG PHN

(T liu hc bi)
Dng 1. Lin kt trong phn t hp cht hu c

V d 1. Chn nh ngha ng nht v lin kt cng ha tr.
Lin kt cng ha tr l lin kt
A. gia cc phi kim vi nhau.
B. trong cp electron chung b lch v mt nguyn t.
C. c hnh thnh gia 2 nguyn t bng cc electron chung.
D. c hnh thnh do s dng chung electron ca 2 nguyn t khc nhau.
V d 2. Lin kt xichma () l lin kt ho hc trong trc ca obitan lin kt
A. trng vi ng ni tm ca hai nguyn t lin kt.
B. song song vi ng ni tm ca hai nguyn t lin kt.
C. vung gc vi ng ni tm ca hai nguyn t lin kt.
D. to vi ng ni tm ca hai nguyn t lin kt mt gc 45o.
V d 3. Lin kt pi l lin kt
A. c s xen ph trc ca cc cp electron dng chung gia hai nguyn t.
B. c s cho nhn cc electron gia hai nguyn t.
C. c s xen ph trc ca cc obitan lin kt gia hai nguyn t.
D. c s xen ph bn ca cc obitan lin kt gia hai nguyn t.
V d 4. Lin kt ba l lin kt ho hc gm
A. ba lin kt xichma .
B. hai lin kt xichma v mt lin kt pi .
C. mt lin kt xichma v hai lin kt pi .
D. mt lin kt xichma , mt lin kt pi v mt lin kt cho nhn.
V d 5. (C10) S lin kt (xch ma) c trong mi phn t: etilen; axetilen; buta-1,3-ien ln lt l
A. 3; 5; 9.
B. 5; 3; 9.
C. 4; 2; 6.
D. 4; 3; 6.
V d 6. S lng lin kt xch ma () v lin kt pi () trong phn t benzen (C6H6) l
A. 3 lin kt v 3 lin kt .
B. 3 lin kt v 12 lin kt .
C. 3 lin kt v 9 lin kt .
D. 3 lin kt v 6 lin kt .
Dng 2. Lai ha v cu trc phn t
V d 7. Cc nguyn t trong phn t benzen C6H6 cng nm trn mt mt phng, iu chng t trong phn
t benzen, cc nguyn t cacbon trng thi
C. lai ho sp3.
D. khng lai ha.
A. lai ho sp.
B. lai ho sp2.
V d 8. Cho cng thc cu to ca vinylaxetilen :
Trng thi lai ha ca cc nguyn t C (theo th t t tri qua phi) l

A. sp, sp, sp2, sp2.
B. sp2, sp2, sp, sp.
C. sp2, sp, sp2, sp.
D. sp, sp2, sp, sp2.
V d 9. Xt hai phn t cht hu c X v Y :
Nhn xt no di y l ng ?
A. Phn t X v Y c s lin kt v s lin kt bng nhau.
B. Phn t X c s lin kt nhiu hn, nhng s lin kt t hn Y.
C. Phn t X c s lin kt t hn, nhng s lin kt nhiu hn Y.
D. S lin kt v trong phn t X u nhiu hn Y.
V d 10. Cho cc phn t cht hu c: CH3-CH3 (X) ; CH2=CH2 (Y) ; CHCH (Z).
Nhn xt no di y l ng ?
A. di lin kt cacbon-cacbon tng theo th t: Z < Y < X.
B. S lin kt trong cc phn t trn l bng nhau.
C. Gc lin kt HCC trong cc phn t ny l bng nhau.
D. Kh nng tham gia phn ng ca cc cht tng theo trt t: Z < Y < X.
Dng 2. ng ng
V d 11. nh ngha ng ng no sau y l ng ?
A. Nhng cht ng ng l nhng hp cht c thnh phn phn t hn km nhau mt hay nhiu nhm CH2 nhng
c tnh cht ho hc tng t nhau.
B. Nhng cht ng ng l nhng n cht c thnh phn phn t hn km nhau mt hay nhiu nhm CH2
nhng c tnh cht ho hc tng t nhau.
C. Nhng cht ng ng l nhng hp cht c thnh phn phn t hn km nhau mt nhm CH2 nhng c tnh
cht ho hc tng t nhau.
D. Nhng cht ng ng l nhng hp cht c thnh phn phn t hn km nhau mt hay nhiu nhm CH2
nhng c tnh cht ho hc khc nhau.
V d 12. (B8) Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng
phn t ca X. Cc cht X, Y, Z thuc dy ng ng
A. xicloankan.
B. ankin.
C. anken.
D. anken hoc xicloankan.
V d 13. (A7) Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp
i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2
(d), thu c s gam kt ta l
A. 20.
B. 40.
C. 30.
D. 10.
Dng 3. ng phn
V d 14. nh ngha ng phn no sau y l ng ? ng phn l
A. nhng hp cht khc nhau nhng c cng cng thc phn t.
B. nhng n cht khc nhau nhng c cng cng thc phn t.
C. nhng hp cht ging nhau v c cng cng thc phn t.
D. nhng hp cht khc nhau nhng c cng dng cng thc cu to.
V d 15. S ng phn ng vi c cng thc phn t C4H10O l:
A. 4.
B. 5.
C. 6.
D. 7.
V d 16. S ng phn ng vi c cng thc phn t C4H11N l:

A. 4.
B. 6.
C. 7.
D. 8.
V d 17. (A10) Cht c nhiu ng phn cu to trong s: C3H8, C3H7Cl, C3H8O v C3H9N l
A. C3H9N.
B. C3H7Cl.
C. C3H8O.
D. C3H8.
V d 18. (C10NC) Cht no sau y c ng phn hnh hc ?

A. But-2-in.
V d 19. (C9NC)
B. But-2-en.
Cho
cc
cht
C. 1,2-icloetan.
sau:
CH2=CH-CH=CH2;
D. 2-clopropen.
CH3-CH2-CH=C(CH3)2;
CH3-CH=CH2;
CH3-CH=CH-CH=CH2; CH3-CH=CH-COOH. S cht c ng phn hnh hc l

A. 4.
B. 3.
C. 2.
D. 1.
V d 20. S hirocacbon c cng thc phn t C4H8 l:

A. 3.
B. 4.
C. 5.
D. 6.

M015. PHNG PHP GII BI TP V PHN NG TH CA HIROCACBON

(T liu hc bi)
V d 1. (A8) Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l
A. 2.
B. 4.
C. 3.
D. 5.
V d 2. Khi cho 2-metylbutan tc dng vi Cl2 theo t l mol 1:1 th to ra sn phm chnh l
A. 1-clo-2-metylbutan.
B. 2-clo-2-metylbutan.
C. 2-clo-3-metylbutan.
D. 1-clo-3-metylbutan.
V d 3. (B7) Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi
hiro l 75,5. Tn ca ankan l
A. 3,3-imetylhexan.
B. isopentan.
C. 2,2-imetylpropan.
D. 2,2,3-trimetylpentan.
V d 4. (B8) Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba
trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut).
Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l
A. 3.
B. 4.
C. 5.
D. 2.
V d 5. Sn phm ch yu trong hn hp thu c khi cho cumen phn ng vi Cl2 theo t l s mol 1:1 (c
chiu sng) l
A. m-clocumen.
B. 1-clo-1-phenylpropan.
C. o-clocumen v p-clocumen.
D. 2-clo-2-phenylpropan.
V d 6. Ankin C6H10 c bao nhiu ng phn phn ng vi dung dch AgNO3/NH3 ?

A. 3.
B. 4.
C. 5.
D. 6.
V d 7. Mt hirocacbon X mch thng c cng thc phn t l C6H6. Khi cho X tc dng vi dung dch
AgNO3 trong NH3 th thu c hp cht hu c Y c MY MX = 214u. Cng thc cu to ca X l
A. CHCCH2CH2CCH.
B. CH3CCCH2CCH.
C. CH3CH2CCCCH.
D. CHCCH(CH3)CCH.
V d 8. (A11) Cho 13,8 gam cht hu c X c cng thc phn t C7H8 tc dng vi mt lng d dung dch
AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn ?
A. 4.
B. 6.
C. 2.
D. 5.
V d 9. (C11) Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s mol
1:1 (c mt bt st) l
A. o-bromtoluen v p-bromtoluen
B. benzyl bromua
C. p-bromtoluen v m-bromtoluen
D. o-bromtoluen v m-bromtoluen
V d 10. Cht hu c H (cha 2 nguyn t X, Y); 150 < MH < 170. t chy hon ton m gam H c m gam
H2O. H khng tc dng vi dung dch brom, cng nh vi brom (Fe, to), nhng tc dng vi brom (chiu sng)
to thnh mt dn xut monobrom duy nht. Tn gi ca H l
A. naphtalen.
B. 1,3,5trimetylbenzen.
C. 1,3,5trietylbenzen.
D. hexametylbenzen.

M016. PHNG PHP GII BI TP V PHN NG TCH CA HIROCACBON

(T liu hc bi)
V d 1. Khi un nng kh metan vi xc tc thch hp, khng th to thnh sn phm no di y ?

B. C.
C. C2H2.
D. C2H6.
A. H2.
V d 2. Nhit phn metan thu c hn hp X gm C2H2, CH4 v H2. T khi hi ca X so vi H2 bng 5.
Hiu sut qu trnh nhit phn l:
A. 50%.
B. 60%.
C. 70%.
D. 80%.
V d 3. Thc hin phn ng tch H2 t n-butan (Ni, to) thu c hn hp X ch gm cc anken v H2. S
anken ti a c th c trong X l:
A. 1.
B. 2.
C. 3.
D. 4.
(1) Ngoi vic tch trc tip t qu trnh chng ct du m, xicloankan cn c iu ch t ankan.
(2) Trong cng nghip, etilen, propilen v butilen c th iu ch bng phn ng tch H2 t ankan tng ng.
(3) Hin nay trong cng nghip butaien v isopren c iu ch t ankan tng ng.
(4) Tecpen, (C5H8)n (n 2) c th iu ch bng phn ng tch H2 t C5H12.
(5) Phng php chnh iu ch axetilen trong cng nghip hin nay l i t metan.
(6) Benzen, toluen, xilen, c th iu ch t ankan hoc xicloankan.
S m t ng l:
A. 2.
B. 3.
C. 4.
D. 5.
V d 5. Hn hp kh gm etan v propan c t khi so vi hiro l 20,25 c nung trong bnh kn vi cht
xc tc thc hin phn ng hiro ha. Sau mt thi gian thu c hn hp kh c t khi hi so vi H2 l
16,2 gm ankan, anken v hiro. Bit rng tc phn ng ca etan v propan l nh nhau, hiu sut phn ng
hiro ha l:
A. 25%.
B. 30%.
C. 40%.
D. 50%.
V d 6. (A8) Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o
cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. X l
A. C5H12.
B. C3H8.
C. C4H10.
D. C6H14.
V d 7. Crackinh 5,8 gam C4H10 c hn hp kh X. Khi lng nc thu c khi t chy hon ton X l:
A. 9 gam
B. 4,5 gam
C. 18 gam
D. 36 gam
V d 8. Crackinh 0,1 mol n-pentan c hn hp X. t chy ht X ri hp th sn phm chy bi nc vi

trong d. Hi khi lng dung dch cui cng thu c tng hay gim bao nhiu ?
B. Gim 10,8 gam.
C. Tng 10,8 gam.
D. Tng 17,2 gam.
A. Gim 17,2 gam
V d 9. Nhit phn 8,8 gam C3H8 ta thu c 0,38 mol hn hp X gm CH4, C2H4, C3H6, H2 v C3H8 d
cha b nhit phn. T khi ca hn hp X so vi H2 l ?
A. 11,0.
B. 11,6.
C. 22,0.
D. 23,2.
V d 10. Crackinh V lt butan thu c 35 lt hn hp X gm H2, CH4, C2H6, C2H4, C3H6, C4H8 v mt phn
butan cha b crackinh. Cho hn hp X li rt t t qua bnh ng nc brom d, thy th tch cn li 20 lt. %
butan phn ng l ?
A. 25%
B. 60%
C. 75%
D. 85%.
V d 11. Crackinh 560 lt butan, xy ra ng thi cc phn ng:
Sau phn ng thu c 896 lt hn hp kh X. Th tch C4H10 c trong hn hp X l (cc th tch kh o cng
iu kin)
A. 336 lt.
B. 168 lt.
C. 280 lt.
D. 224 lt.
V d 12. (C12) Nung mt lng butan trong bnh kn (c xc tc thch hp) thu c hn hp kh X gm
ankan v anken. T khi ca X so vi kh hiro l 21,75. Phn trm th tch ca butan trong X l
A. 33,33%
B. 50,00%
C. 66,67%
D. 25,00%

M017. PHNG PHP GII BI TP V PHN NG CNG CA HIROCACBON

(T liu hc bi)
V d 1. Cho dy cc hirocacbon: xiclopropan (1); xiclobutan (2); propen (3); butaien (4); xilen (5); stiren
(6); butin (7). S cht c phn ng vi H2 (Ni, to) v s cht c th lm mt mu dung dch brom ln lt l:
A. 5; 4.
B. 5; 5.
C. 7; 5.
D. 7; 7.
V d 2. (C11) Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohexan, xiclopropan v xiclopentan.
Trong cc cht trn, s cht phn ng c vi dung dch brom l:
A. 4.
B. 3.
C. 5.
D. 6.
V d 3. (B11) S ng phn cu to ca C5H10 phn ng c vi dung dch brom l:

A. 8.
B. 9.
C. 5.
D. 7.
V d 4. (A12) Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c th
c ca X l
A. 6.
B. 5.
C. 7.
D. 4.
V d 5. (A7) Hirat ha 2 anken ch to thnh 2 ancol. Hai anken l

A. 2-metylpropen v but-1-en.
B. propen v but-2-en.
C. eten v but-2-en.
D. eten v but-1-en.
V d 6. (A10) Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l

A. 3-etylpent-3-en.
B. 2-etylpent-2-en.
C. 3-etylpent-2-en.
D. 3-etylpent-1-en.
V d 7. (A11) Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn
cu to v ng phn hnh hc) thu c l:
A. 1.
B. 3.
C. 2.
D. 4.
V d 8. (B9) Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu
c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau.
Tn gi ca X l
A. but-1-en.
B. xiclopropan.
C. but-2-en.
D. propilen.
V d 9. (C10) Cho 3,12 gam ankin X phn ng vi 0,1 mol H2 (xc tc Pd/PbCO3, to), thu c hn hp Y
ch c hai hirocacbon. Cng thc phn t ca X l
A. C2H2.
B. C5H8.
C. C4H6.
D. C3H4.
V d 10. (A12) Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng, thu c hn

hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ha l
A. 70%
B. 60%
C. 50%
D. 80%
V d 11. (B9) Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T
khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp
kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l
A. CH2=C(CH3)2.
B. CH2=CH2.
C. CH2=CH-CH2-CH3.
D. CH3-CH=CH-CH3.
V d 12. (A7) Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung
dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam.
Cng thc phn t ca 2 hirocacbon l
A. C2H2 v C4H6.
B. C2H2 v C4H8.
C. C3H4 v C4H8.
D. C2H2 v C3H8.
V d 13. (A10) un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni),
thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng
bnh tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l
A. 0,585.
B. 0,620.
C. 0,205.
D. 0,328.
V d 14. (B12) Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp X (xc tc Ni) mt
thi gian, thu c hn hp Y c t khi so vi H2 bng 10. Dn hn hp Y qua dung dch Brom d, sau khi
phn ng xy ra hon ton, khi lng brom tham gia phn ng l
A. 0 gam
B. 24 gam
C. 8 gam
D. 16 gam.
V d 15. (B11) Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6, H2. T
khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l
A. 0,48 mol.
B. 0,36 mol.
C. 0,60 mol.
D. 0,24 mol.

M018. PHNG PHP GII BI TP V PHN NG OXI HA CA HIROCACBON

(T liu hc bi)
V d 1. t chy hon ton m gam hn hp X (gm metan, etilen, axetilen, buta-1,3-ien v benzen) thu
c hn hp sn phm Y. Dn t t Y qua dung dch H2SO4 c d, thy khi lng dung dch tng 10,8 gam.
Mt khc, khi dn t t Y qua dung dch nc vi trong d, thy khi lng dung dch gim 56,4 gam. Gi tr
ca m l
A. 13,6.
B. 14,6.
C. 15,6.
D. 16,6.
V d 2. (C7) t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh
(trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng
kh (ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l
A. 56,0 lt.
B. 70,0 lt.
C. 78,4 lt.
D. 84,0 lt.
V d 3. (A12) t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b
sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 39,4 gam kt ta v
khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l
A. C3H4.
B. CH4.
C. C2H4.
D. C4H10.
V d 4. (C8) t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc
dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l
A. 2-metylbutan.
B. etan.
C. 2,2-imetylpropan.
D. 2-metylpropan.
V d 5. t chy hon ton 0,15 mol hirocacbon X thu c 16,8 lt kh CO2 (ktc) v 13,5 gam H2O. S
ng phn ca X l
A. 9.
B. 11.
C. 10.
D. 12.
V d 6. t chy hon ton hn hp X gm 2 hirocacbon mch h thu c 19,712 lt kh CO2 (ktc) v 8,1
gam H2O. Hai hirocacbon trong hn hp X thuc dy ng ng
A. ankaien.
B. ankin.
C. ankylbenzen.
D. ankaien hoc ankin.
V d 7. t chy hon ton 0,1 mol hn hp gm CH4, C2H4 v C4H10 thu c 0,14 mol CO2 v 0,23 mol
H2O. S mol ca ankan v anken trong hn hp ln lt l
A. 0,09 v 0,01.
B. 0,08 v 0,02.
C. 0,01 v 0,09.
D. 0,02 v 0,08.
V d 8. (B12) t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c cng thc n gin
nht khc nhau, thu c 2,2 gam CO2 v 0,9 gam H2O. Cc cht trong X l
A. mt ankan v mt ankin
B. hai ankaien
C. hai anken.
D. mt anken v mt ankin.
V d 9. (C10) t chy hon ton 6,72 lt (ktc) hn hp gm hai hirocacbon X v Y (MY > MX), thu c
11,2 lt CO2 (ktc) v 10,8 gam H2O. Cng thc ca X l
A. C2H6.
B. C2H4.
C. CH4.
D. C2H2.
V d 10. (B8) t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt

hi H2O (cc th tch kh v hi o cng iu kin T, P). CTPT ca X l
A. C2H4.
B. C3H8.
C. C2H6.
D. CH4.
V d 11. (B10) Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy

hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt
l
A. CH4 v C2H4.
B. C2H6 v C2H4.
C. CH4 v C3H6.
D. CH4 v C4H8.
V d 12. (B11) Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy

hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi
lng bnh tng thm m gam. Gi tr ca m l:
A. 5,85.
B. 3,39.
C. 6,6.
D. 7,3.
V d 13. (C8) t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch
CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh
hiro l
A. 12,9.
B. 25,8.
C. 22,2.
D. 11,1.
V d 14. (C9) kh hon ton 200 ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt kh
C2H4 ( ktc). Gi tr ti thiu ca V l
A. 2,240.
B. 2,688.
C. 4,480.
D. 1,344.
V d 15. (B11) Cho phn ng:

C6H5-CH=CH2 + KMnO4
C6H5-COOK + K2CO3 + MnO2 + KOH + H2O
Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ha hc ca phn ng trn l:

A. 27.
B. 31.
C. 24.
D. 34.
V d 16. Cn bng phng trnh phn ng:

CH 2 -CH=CH2
COOH
+ CO 2 + MnSO 4 + K2SO4 + H 2O
+ KMnO4 + H2SO4
Tng h s ca cc cht tham gia trong phng trnh phn ng trn (l cc s nguyn nh nht) l
A. 45.
B. 46.
C. 47.
D. 48.

M019. DN XUT HALOGEN CA HIROCACBON

(T liu hc bi)
V d 1. S ng phn ca C4H9Br l:
A. 4.
B. 2.
C. 3.
D. 5.
V d 2. X l hn hp cc ng phn ca C3H5Cl. S cht ti a c trong X l:
A. 2
B. 3
C. 4
D. 5
V d 3. C bao nhin dn xut clo bc I l ng phn ca nhau c cng thc phn t C5H11Cl ?
A. 3
B. 4
C. 5
D. 6
V d 4. Cho cc cht sau: C6H5CH2Cl ; CH3CHClCH3 ; Br2CHCH3 ; CH2=CHCH2Cl. Tn gi ca cc cht
trn ln lt l:
A. benzyl clorua ; isopropyl clorua ; 1,1-ibrometan ; anlyl clorua.
B. benzyl clorua ; 2-clopropan; 1,2-ibrometan; 1-cloprop-2-en.
C. phenyl clorua; isopropylclorua; 1,1-ibrometan; 1-cloprop-2-en.
D. benzyl clorua; n-propyl clorua; 1,1-ibrometan; 1-cloprop-2-en.
V d 5. t chy hon ton mt lng cht hu c cha C, H, Cl sinh ra 0,22 gam CO2 v 0,09 gam H2O.
Khi phn tch nh lng clo ca cng mt lng cht bng dung dch AgNO3, ngi ta thu c 1,435 gam
AgCl. CTPT ca hp cht trn l:
A. CH2Cl2.
B. CH3Cl.
C. C2H4Cl4
D. C2H4Cl2
V d 6. un mt ancol X vi dung dch hn hp gm KBr v H2SO4 c th trong hn hp sn phm thu
c c cht hu c Y. Hi ca 12,5 gam cht Y ni trn chim 1 th tch ca 2,80 gam nit trong cng iu
kin. Cng thc cu to ca X l
A. C2H5OH.
B. C3H6(OH)2.
C. C3H7OH.
D. C2H4(OH)2.
V d 7. un nng 13,875 gam mt ankyl clorua Y vi dung dch NaOH, tch b lp hu c, axit ha phn
cn li bng dung dch HNO3, nh tip dung dch AgNO3 n d thy to thnh 21,525 gam kt ta. Cng thc
phn t ca Y l:
A. C2H5Cl.
B. C3H7Cl.
C. C4H9Cl.
D. C5H11Cl.
V d 8. Cho cc dn xut halogen sau: C2H5F (1); C2H5Br (2); C2H5I (3); C2H5Cl (4). Th t gim dn nhit
si l:
A. (3) > (2) > (4) > (1)
B. (1) > (4) > (2) > (3)
C. (1) > (2) > (3) > (4)
D. (3) > (2) > (1) > (4)
V d 9. Cho cc cht:
Cl
(X)
(Y)
Dy sp xp theo chiu tng dn nhit si l:
A. X < Y < Z < T.
B. X < T < Z < Y.
V d 10. Cho cc cht:
CH3 Cl
CH3
H
C Br
CH3
Br
(Z)
(T)
C. Y < X < Z < T.
CH3
H
C Cl
CH3
D. Y < Z < T < X.
CH3 CH2 Cl
(X)
(Y)
(Z)
(T)
Dy sp xp theo chiu tng dn nhit si l:
A. X < Y < Z < T.
B. T < X < Y < Z.
C. X < T < Z < Y.
D. Y < X < Z < T.
V d 11. Cho cc cht: CH2=CHCl (1), CH3CH2Cl (2), CH2=CHCH2Cl (3), CH3CHClCH3 (4).
Kh nng phn ng vi AgNO3/NH3 tng dn theo th t
A. (1) < (2) < (3) < (4).
B. (1) < (2) < (4) < (3).
C. (4) < (2) < (3) < (1).
D. (1) < (3) < (2) < (4).
V d 12. Nh dung dch AgNO3 vo ng nghim cha CH2=CHCH2Cl, lc nh. Hin tng xy ra l:
A. Thot ra kh mu vng lc.
B. Xut hin kt ta trng.
C. Dung dch tch lp.
D. Xut hin kt ta vng.
V d 13. (C10NC) Kh nng phn ng th nguyn t clo bng nhm OH ca cc cht c xp theo chiu
tng dn t tri sang phi l:
A. anlyl clorua, phenyl clorua, propyl clorua.
B. anlyl clorua, propyl clorua, phenyl clorua.
C. phenyl clorua, anlyl clorua, propyl clorua.
D. phenyl clorua, propyl clorua, anlyl clorua.
V d 14. (C11) un si hn hp propyl bromua, kali hiroxit v etanol thu c sn phm hu c l
A. propin.
B. propan-2-ol.
C. propan.
D. propen.
xt
C 4 H 8 + HBr
V d 15. Xt phn ng: CH 3 -CHBr-CH 2 -CH 3
to
C cc nhn xt sau v phn ng:
(a) Phn ng to ra hn hp 2 anken.
(b) Sn phm chnh ca phn ng l CH2=CH-CH2-CH3.
(c) Hng chnh ca phn ng tch HBr tun theo quy tc Maccopnhicop.
(d) Xc tc ca phn ng l: KOH/C2H5OH.
S nhn xt ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 16. Cho cc cht: butyl clorua, anlyl clorua, phenyl clorua, vinyl clorua. un si cc cht vi dung
dch NaOH, sau trung ho NaOH d bng HNO3 ri nh vo vi git dung dch AgNO3. S dung dch
khng to thnh kt ta l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 17. X l ng phn ng vi CTPT l C6H13Br. Bit khi un nng X vi dung dch kim/etanol th thu
c 3 anken (tnh c ng phn hnh hc) v cc anken cng nc (xc tc axit) thu c sn phm chnh
khng b oxi ha bi CuO. S cht tha mn X l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 18. Hn hp X gm 0,1 mol anlyl clorua; 0,3 mol benzyl bromua; 0,1 mol hexyl clorua; 0,15 mol phenyl
bromua. un si X vi nc n khi phn ng xy ra hon ton, chit ly phn nc lc, ri cho tc dng vi
dung dch AgNO3 d thu c m gam kt ta. Gi tr ca m l
A. 57,4
B. 14,35
C. 70,75
D. 28,7
V d 19. (B9NC) Cho s chuyn ho:
H 2SO 4 c
+ HBr
+ Mg, ete khan
Butan - 2 - ol
X (anken)
Y
Z
to
Trong X, Y, Z l sn phm chnh. Cng thc ca Z l

A. (CH3)3C-MgBr.
B. CH3-CH2-CH2-CH2-MgBr.
D. (CH3)2CH-CH2-MgBr.
C. CH3-CH(MgBr)-CH2-CH3.
t
HBr + C2H5OH
C2H4 + Br2
C2H4 + HBr
C2H6 + Br2
V d 20. (B8) Cho cc phn ng:
askt (1:1mol)
S phn ng to ra C2H5Br l:
A. 1.
B. 3.
C. 2.
D. 4.
V d 21. Khi cho toluen tc dng vi clo (trong iu kin thch hp) thu c cht no sau y khng phi l
sn phm chnh ?
A. 2-clotoluen.
B. 3-clotoluen.
C. 4-clotoluen.
D. benzyl clorua.
V d 22. Quy trnh sn xut PVC theo s sau:
Th tch etilen v kh clo (ktc) sn xut 1 tn PVC theo s trn (gi s H = 100%) l:
A. 358400 lit ; 358400 lit B. 179200 lit ; 358400 lit C. 358400 lit ; 179200 lit D. 179200 lit ; 358400 lit
Phm Thnh (0976.053.496)
M020. ANCOL: NG PHN DANH PHP TNH CHT VT L

(T liu hc bi)
V d 1. Cho cc cht: C2H5OH (1); CH2=CH-OH (2); CH3-CH(OH)2 (3); HO-CH2-CH2-OH (4); C6H5OH (5);
CH3-O-CH3 (6); C6H5-O-CH3 (7); CH2=CH-CH2-OH (8). S ancol trong dy trn l:
A. 3.
B. 4.
C. 5.
D. 6.
V d 2. S ng phn ancol v tng s ng phn ca C4H10O ln lt l:
A. 3; 6.
B. 3; 7.
C. 4; 6.
D. 4; 7.
V d 3. Ancol X c cng thc n gin nht l C2H5O. S ng phn ancol ca X l:
A. 5.
B. 6.
C. 7.
D. 8.
V d 4. S ng phn ancol ca C4H8O l:
A. 6.
B. 7.
C. 8.
D. 9.
V d 5. S ng phn ancol bc II ca C6H14O l:
A. 4.
B. 5.
C. 6.
D. 7.
V d 6. S ng phn ca C5H12O c kh nng to lin kt H vi H2O l:
A. 8.
B. 10.
C. 12.
D. 14.
V d 7. Chiu gim dn linh ng ca nguyn t H (t tri qua phi) trong nhm OH ca ba hp cht:
C6H5OH (1); C2H5OH (2); H2O (3) l
A. (3) > (1) > (2).
B. (1) > (3) > (2).
C. (2) > (1) > (3).
D. (2) > (3) > (1).
V d 8. Trong hn hp etanol v nc, kiu lin kt hiro no l bn nht ?
O H ... O H
H
A. C2H5
O H ... O H
C2H5
B. C2H5
O H ... O H
C2H5
C. H
O H ... O H
H
D. H
V d 9. Cho cc cht: C4H9OH (1); C3H7OH (2); CH3-O-C2H5 (3); CH3-O-CH3 (4). Chiu tng dn nhit
si ca cc cht l:
A. (4) < (3) < (2) < (1).
B. (4) < (2) < (3) < (1).
C. (3) < (4) < (2) < (1).
D. (3) < (4) < (1) < (2).
V d 10. Cho cc cht: C4H9OH (1); C3H7OH (2); CH3-O-C2H5 (3); CH3-O-CH3 (4). Chiu tng dn tan
ca cc cht trong nc l:
A. (4) < (3) < (2) < (1).
B. (3) < (4) < (2) < (1).
C. (4) < (3) < (1) < (2).
D. (3) < (4) < (1) < (2).
M020. XC NH CTPT CTCT GI TN ESTE

(T liu hc bi)
Dng 1. Bin lun xc nh CTPT
V d 1. Este X c CTGN l C2H4O. S ng phn este ca X l:
A. 2.
B. 4.
C. 6.
V d 2. CTGN ca este X l C5H8O3. Cng thc phn t ca X l:
A. C5H8O3.
B. C10H16O6.
C. C15H24O9.
Dng 2. ng phn Danh php
V d 3. S ng phn este ca C5H10O2 l:
A. 7.
B. 8.
C. 9.
V d 4. S ng phn n chc ca C4H8O2 l:
A. 3.
B. 4.
C. 5.
V d 5. S ng phn este mch h ca C4H6O2 l:
A. 3.
B. 4.
C. 5.
V d 6. S ng phn este cha vng benzen ca C8H8O2 l:
A. 3.
B. 4.
C. 5.
D. 8.
D. C20H32O12.
D. 10.
D. 6.
D. 6.
D. 6.
Dng 3. Bin lun xc nh CTCT

V d 7. Hp cht hu c mch h X c cng thc phn t C6H10O4. Thu phn X to ra hai ancol n chc
c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l
A. CH3OCO-CH2-COOC2H5.
B. C2H5OCO-COOCH3.
C. CH3OCO-COOC3H7.
D. CH3OCO-CH2-CH2-COOC2H5.
(Trch TSH Khi B 2010)
V d 8. Thu phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt phn
ng c th chuyn ho X thnh Y. Cht Z khng th l
A. metyl propionat.
B. metyl axetat.
C. etyl axetat.
D. vinyl axetat.
V d 9. Este X l hp cht thm c cng thc phn t l C9H10O2. Cho X tc dng vi dung dch NaOH, to
ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l
A. CH3COOCH2C6H5.
B. HCOOC6H4C2H5.
C. C6H5COOC2H5.
D. C2H5COOC6H5.
V d 10. Cho s phn ng:
+AgNO3 /NH 3
+NaOH
+NaOH
Este X (C4HnO2)
Y
Z
C2H3O2Na.
to
to
to
Cng thc cu to ca X tha mn s cho l
A. CH2=CHCOOCH3.
B. CH3COOCH2CH3.
C. HCOOCH2CH2CH3.
D. CH3COOCH=CH2.
(Trch TSC 2012)

M021. ANCOL: PHN NG TH

(T liu hc bi)
V d 1. Trong tt c cc ng phn ca C5H12O, s cht tc dng c vi Na l

A. 6.
B. 7.
C. 8.
D. 9.
V d 2. (C11) S hp cht ng phn cu to ca nhau c cng thc phn t C8H10O, trong phn t c vng
benzen, tc dng c vi Na, khng tc dng c vi NaOH l
A. 4.
B. 6.
C. 7.
D. 5.
V d 3. Cho cc cht: C2H5OH (1); H2O (2); C6H5OH (phenol) (3). Dy sp xp cc cht theo chiu tng dn
kh nng phn ng vi Na l
A. (2) < (3) < (1).
B. (3) < (2) < (1).
C. (2) < (1) < (3).
D. (1) < (2) < (3).
V d 4. Cho Na tc dng hon ton vi 18,8 gam hn hp hai ancol no, n chc k tip nhau trong dy ng
ng sinh ra 5,6 lt kh H2 (ktc). CTPT ca hai ancol l
A. C3H7OH v C4H9OH.
B. CH3OH v C2H5OH.
C. C2H5OH v C3H7OH.
D. C4H9OH v C5H11OH.
V d 5. Cho 1,24 gam hn hp hai ancol n chc tc dng va vi Na thy thot ra 336 ml kh H2 (ktc).
Hn hp cc cht rn cha Na c to ra c khi lng bao nhiu ?
A. 1,90 gam.
B. 1,585 gam.
C. 1,93 gam.
D. 1,57 gam.
V d 6. (A07) Cho 15,6 gam hn hp hai ancol n chc, k tip nhau trong dy ng ng tc dng ht vi
9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l
A. C3H5OH v C4H7OH.
B. C2H5OH v C3H7OH.
C. C3H7OH v C4H9OH.
D. CH3OH v C2H5OH.
V d 7. (B12) Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X thu
c 6,72 lt kh CO2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh H2 (ktc).
Gi tr ca V l
A. 3,36
B. 11,20
C. 5,60
D. 6,72
V d 8. Hn hp X gm metanol, etanol, propan-1-ol v H2O. Cho m gam X tc dng Na d thu c 15,68 lit
H2 (ktc). Mt khc t chy hon ton m gam X thu c V lit CO2 (ktc) v 46,8 gam H2O. Gi tr m v V
ln lt l:
A. 19,6 v 26,88
B. 42 v 26,88
C. 42 v 42,56
D. 61,2 v 26,88.
V d 9. (C10) Cho 10 ml dung dch ancol etylic 46o phn ng ht vi kim li Na (d), thu c V lt kh H2
(ktc). Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml. Gi tr ca V l
A. 4,256.
B. 0,896.
C. 3,360.
D. 2,128.
V d 10. Cho 12,8 gam dung dch ancol X (trong nc) c nng 71,875% tc dng vi lng Na d thu
c 5,6 lt kh (ktc). Cng thc ca ancol X l
A. CH3OH.
B. C2H4 (OH)2.
C. C3H5(OH)3.
D. C4H7OH.
HBr + C2H5OH
C2H4 + Br2
C2H4 + HBr
C2H6 + Br2
to
askt (1:1mol)
S phn ng to ra C2H5Br l:
A. 1.
B. 3.
C. 2.
D. 4.
V d 12. Mt ancol n chc X mch h tc dng vi HBr c dn xut Y cha 58,4% brom v khi lng.
un X vi H2SO4 c 170oC c 3 anken. Tn X l
A. pentan-2-ol.
B. butan-1-ol.
C. butan-2-ol.
D. 2-metylpropan-2-ol.
V d 13. un nng ancol no mch h X vi hn hp KBr v H2SO4 c (ly d) thu c cht hu c Y

(cha C, H, Br). Bit 12,3 gam Y c th tch bng th tch ca 2,8 gam N2 cng iu kin. X c cng thc cu
to l
A. CH3OH.
B. C2H5OH.
C. CH3CH(OH)CH3.
D. CH2=CHCH2OH.
V d 14. un nng ancol no, n chc X vi hn hp KBr v H2SO4 c, thu c cht hu c Y (cha C, H,
Br), trong Br chim 73,39% v khi lng. Cng thc phn t ca X l
A. C3H7OH.
B. C3H5OH.
C. CH3OH.
D. C2H5OH.
V d 15. un mt ancol X vi dung dch hn hp gm KBr v H2SO4 c th trong hn hp sn phm thu

c c cht hu c Y. Hi ca 13,9 gam cht Y ni trn chim th tch bng th tch ca 2,80 gam nit trong
cng iu kin. Cng thc cu to ca X l
A. C2H5OH.
B. C3H6(OH)2.
C. C3H7OH.
D. C2H4(OH)2.

M021. BI TON T CHY ESTE

(T liu hc bi)
V d 1. Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy
ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O2 (ktc), thu c 5,6 lt kh CO2
(ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l
A. CH3COOCH3 v 6,7.
B. HCOOC2H5 v 9,5.
C. HCOOCH3 v 6,7.
D. (HCOO)2C2H4 v 6,6.
(Trch TSC 2010)
V d 2. Hn hp X gm: CH3COOC2H5, HCOOC3H5, HCOOC3H3 (d X/O2 = 2, 7). t chy hon ton 0,015
mol X, tng khi lng CO2 v H2O thu c l
A. 3,450 gam.
B. 3,720 gam.
C. 3,180 gam.
D. 3,504 gam.
V d 3. t chy hon ton 6,6 gam hn hp X gm HCOOC3H7, C2H5COOCH3 ri hp th hon ton sn
phm chy vo m1 gam dung dch Ba(OH)2 d. Sau phn ng thu c m gam kt ta. Lc, tch kt ta thu
c m2 gam dung dch nc lc. Gi tr m1 m2 l
A. 45,90.
B. 53,70.
C. 54,45.
D. 40,50.
V d 4. Hn hp X gm 1 este n chc, khng no c mt ni i (C=C) mch h v 1 este no, n chc
mch h. t chy hon ton 0,15 mol X ri cho ton b sn phm chy hp th hon ton vo bnh ng dung
dch Ca(OH)2 d. Sau phn ng thy khi lng bnh tng 23,9 gam v c 40 gam kt ta. CTPT ca 2 este l
A. C2H4O2, C3H4O2.
B. C2H4O2, C4H6O2.
C. C2H4O2, C5H8O2.
D. C3H6O2, C5H8O2.
V d 5. t chy hon ton m gam este X cn 5,6 lt O2 (ktc) thu c 12,4 gam hn hp Y gm kh CO2 v
hi nc ( d Y/H2 = 15,5 ). Mt khc cho X qua LiAlH4, to thu c mt cht hu c duy nht. X l
A. metyl propionat.
B. propyl propionat
C. etyl axetat.
D. metyl fomat.
V d 6. Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c
2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l:
A. 25%.
B. 27,92%.
C. 72,08%.
D. 75%.
V d 7. t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri
hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v dung
dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no?
A. Tng 2,70 gam.
B. Gim 7,74 gam.
C. Tng 7,92 gam.
D. Gim 7,38 gam.
(Trch TSH Khi A 2011)
V d 8. Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm
chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH)2 th vn thu c kt ta. Thu
phn X bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn
trm khi lng ca oxi trong X l:
A. 43,24%
B. 53,33%
C. 37,21%
D. 36,36%
(Trch TSC 2011)
Phm Thnh (0976.053.496)
M022. ANCOL: PHN NG TCH

(T liu hc bi)
V d 1. (A8) Khi tch nc t ancol 3-metylbutan-2-ol, sn phm chnh thu c l

A. 2-metylbut-3-en.
B. 2-metylbut-2-en.
C. 3-metylbut-2-en.
D. 3-metylbut-1-en.
V d 2. (A7) Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn ca
nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l
A. (CH3)3COH.
B. CH3OCH2CH2CH3.
C. CH3CH(OH)CH2CH3.
D. CH3CH(CH3)CH2OH.
V d 3. (B7) Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch
nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng
vi cng thc phn t C8H10O, tho mn tnh cht trn l
A. 2.
B. 4.
C. 1.
D. 3.
V d 4. (A12) Trong ancol X, oxi chim 26,667% v khi lng. un nng X vi H2SO4 c thu c anken
Y. Phn t khi ca Y l
A. 56.
B. 70.
C. 28.
D. 42.
V d 5. (A10NC) Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol

mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y l
A. CH3-CH2-CH(OH)-CH3.
B. CH3-CH2-CH2-OH.
C. CH3-CH2-CH2-CH2-OH.
D. CH3-CH(OH)-CH3.
V d 6. Trong tt c cc ancol c s nguyn t C 4, s ancol khi tch H2O ch to thnh 1 anken duy nht l:
A. 5.
B. 6.
C. 7.
D. 8.
V d 7. (C8) Khi un nng hn hp ancol gm CH3OH v C2H5OH (xc tc H2SO4 c 140oC) th s ete thu
c ti a l
A. 4.
B. 2.
C. 1.
D. 3.
V d 8. (B8) un nng hn hp gm hai ancol n chc, mch h, k tip nhau trong dy ng ng vi

H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng
thc phn t ca hai ancol trn l
A. C3H5OH v C4H7OH.
B. CH3OH v C2H5OH.
C. C2H5OH v C3H7OH.
D. C3H7OH v C4H9OH.
Phm Thnh (0976.053.496)
V d 9. (C11) t chy hon ton mt lng hn hp X gm 3 ancol thuc cng dy ng ng thu c 6,72
lt kh CO2 (ktc) v 9,90 gam H2O. Nu un nng cng lng hn hp X nh trn vi H2SO4 c nhit
thch hp chuyn ht thnh ete th tng khi lng ete thu c l:
A. 6,45 gam
B. 5,46 gam
C. 7,40 gam
D. 4,20 gam
V d 10. (A9) un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete.
Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O.
Hai ancol l
A. C2H5OH v CH2=CH-CH2-OH.
B. C2H5OH v CH3OH.
C. CH3OH v C3H7OH.
D. CH3OH v CH2=CH-CH2-OH.
V d 11. un nng mt ancol n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra
cht hu c Y, t khi hi ca Y so vi X l 1,4375. Cng thc phn t ca X l
A. C4H8O.
B. C3H8O.
C. CH4O.
D. C2H6O.
cht hu c Y, t khi hi ca Y so vi X l 0,7568. Cng thc phn t ca X l
A. C4H10O.
B. C3H8O.
C. CH4O.
D. C2H6O.
cht hu c Y, t khi hi ca X so vi Y l 0,5918. Cng thc phn t ca X l
A. C4H8O.
B. C3H6O.
C. C3H8O.
D. C2H6O.
V d 14. (B8) un nng mt ancol n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp
sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca X l
A. C4H8O.
B. C3H8O.
C. CH4O.
D. C2H6O.
V d 15. (B11) Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn ca Y) l ng

ng k tip thnh hai phn bng nhau:
- t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O.
- un nng phn 2 vi H2SO4 c 140oC to thnh 1,25 gam hn hp ba ete. Ha hi hon ton hn hp ba
ete trn, thu c th tch ca 0,42 gam N2 (trong cng iu kin nhit , p sut).
Hiu sut ca phn ng to ete ca X, Y ln lt l:
A. 30% v 30%.
B. 25% v 35%.
C. 40% v 20%.
D. 20% v 40%.

M022. BI TON THY PHN ESTE

(T liu hc bi)
V d 1. Ha hi hon ton 4,4 gam mt este X mch h, thu c th tch hi bng th tch ca 1,6 gam kh
oxi (o cng iu kin). Mt khc, thy phn hon ton 11 gam X bng dung dch NaOH d, thu c 10,25
gam mui. Cng thc ca X l
A. C2H5COOCH3.
B. CH3COOC2H5.
C. C2H5COOC2H5.
D. HCOOC3H7.
(Trch TSC 2012)
V d 2. X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui
ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l
A. CH3COOCH3 v CH3COOC2H5.
B. C2H5COOCH3 v C2H5COOC2H5.
C. CH3COOC2H5 v CH3COOC3H7.
D. HCOOCH3 v HCOOC2H5.
V d 3. Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M. Sau
phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l
A. CH2=CHCH2COOCH3. B. CH3COOCH=CHCH3. C. C2H5COOCH=CH2.
D. CH2=CHCOOC2H5.
(Trch TSC 2009)
V d 4. t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O2, thu c
23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn
dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z
(MY < MZ). Cc th tch kh u o iu kin tiu chun. T l a : b l
A. 2 : 3.
B. 4 : 3.
C. 3 : 2.
D. 3 : 5.
V d 5. t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th
tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng
hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan.
Gi tr ca m l
A. 10,56.
B. 7,20.
C. 8,88.
D. 6,66.
V d 6. Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi
100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn
ca X l
A. CH3OOC-(CH2)2-COOC2H5.
B. CH3OOC-CH2-COO-C3H7.
C. CH3COO-(CH2)2-OOCC2H5.
D. CH3COO-(CH2)2-COOC2H5.
V d 7. Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c
mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l
A. HCOOH v C2H5COOH.
B. HCOOH v CH3COOH.
C. C2H5COOH v C3H7COOH.
D. CH3COOH v C2H5COOH.
M023. ANCOL: PHN NG OXI HA

(T liu hc bi)
V d 1. (C7) t chy hon ton mt ancol X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch
kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t
ca X l
A. C3H8O.
B. C3H8O3.
C. C3H4O.
D. C3H8O2.
V d 2. (C8) t chy hon ton hn hp M gm hai ancol X v Y l ng ng k tip ca nhau, thu c

0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n
0,15 mol H2. Cng thc phn t ca X, Y l:
A. C2H6O2 v C3H8O2.
B. C2H6O v CH4O.
C. C3H6O v C4H8O.
D. C2H6O v C3H8O.
V d 3. (C7) Khi thc hin phn ng tch nc i vi ancol X, ch thu c mt anken duy nht. Oxi ho
hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu cng thc cu to ph
hp vi X ?
A. 2.
B. 4.
C. 3.
D. 5.
V d 4. (A9) Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton
hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l
A. C3H5(OH)3 v C4H7(OH)3.
B. C2H5OH v C4H9OH.
C. C2H4(OH)2 v C4H8(OH)2.
D. C2H4(OH)2 v C3H6(OH)2.
V d 5. (C7) Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu
c hn hp Z gm hai ancol X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn
phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M.
Cng thc cu to thu gn ca X v Y l (th tch dung dch thay i khng ng k)
A. C4H9OH v C5H11OH.
B. C2H5OH v C4H9OH.
C. C3H7OH v C4H9OH.
D. C2H5OH v C3H7OH.
V d 6. (B7) X l mt ancol no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc
v 6,6 gam CO2. Cng thc ca X l
A. C3H7OH.
B. C3H6(OH)2.
C. C3H5(OH)3.
D. C2H4(OH)2.
V d 7. (A10) t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy ng ng, thu c
3,808 lt kh CO2 (ktc) v 5,4 gam H2O. Gi tr ca m l
A. 5,42.
B. 5,72.
C. 4,72.
D. 7,42.
V d 8. (B10) t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc, mch h, c cng s
nhm -OH) cn va V lt kh O2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc th tch kh o ktc). Gi
tr ca V l
A. 14,56.
B. 15,68.
C. 11,20.
D. 4,48.
V d 9. (A9) Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2
( ktc) v a gam H2O. Biu thc lin h gia m, a v V l:
A. m = 2a
V
.
22,4
B. m = 2a +
V
.
11,2
C. m = a +
V
.
5,6
D. m = a
V
.
5,6
V d 10. (B12) t chy hon ton hn hp X gm hai ancol no, hai chc, mch h cn va V1 lt kh O2,
thu c V2 lt kh CO2 v a mol H2O. Cc kh u o iu kin tiu chun. Biu thc lin h gia cc gi tr
V1, V2, a l
A. V1 = 2V2 11,2a
B. V1 = V2 + 22,4a
C. V1 = V2 22,4a
D. V1 = 2V2 + 11,2a
V d 11. Xt tt c cc ancol no, n chc, mch h c 4C. S ancol khi oxi ha bi CuO to thnh anehit
v xeton ln lt l:
A. 4; 2.
B. 5; 2.
C. 4; 3.
D. 5; 3.
V d 12. (C8NC) Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l
xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l
A. CH3-CHOH-CH3.
B. CH3-CH2-CHOH-CH3.
C. CH3-CO-CH3.
D. CH3-CH2-CH2-OH.
V d 13. Oxi ha 13,2 gam ancol n chc X thu c 15,6 gam sn phm (gm anehit Y v H2O). S ancol
tha mn X l
A. 2.
B. 4.
C. 6.
D. 8.
V d 14. (B7) Cho m gam mt ancol no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng
hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5.
Gi tr ca m l
A. 0,64.
B. 0,46.
C. 0,32.
D. 0,92.
V d 15. Oxi ha 4,0 gam ancol n chc X bng O2 (c mt xc tc) thu c 5,6 gam hn hp H gm
anehit, ancol d v nc. Tn ca X v hiu sut phn ng l
A. metanol; 80%.
B. etanol; 80%.
C. metanol; 75%.
D. etanol; 75%.
V d 16. (B10) Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn
ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l
A. 0,60.
B. 0,36.
C. 0,54.
D. 0,45.

M023. BI TON THY PHN ESTE C BIT

(T liu hc bi)
V d 1. Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht
rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 trong dung dch NH3 thu c cht hu c T. Cho cht T
tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l
B. HCOOCH=CH2.
C. CH3COOCH=CH-CH3. D. CH3COOCH=CH2.
A. HCOOCH3.
(Trch TSC 2007)
V d 2. Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu
c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l
A. HCOOC(CH3)=CHCH3.
B. CH3COOC(CH3)=CH2.
C. HCOOCH2CH=CHCH3.
D. HCOOCH=CHCH2CH3.
V d 3. Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng
ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X ?
A. 5.
B. 4.
C. 3.
D. 2.
(Trch TSC 2007)
V d 4. Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit axetylsalixylic
(o-CH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit
axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l
A. 0,48.
B. 0,72.
C. 0,24.
D. 0,96.
V d 5. Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th
lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu
to ca X tha mn cc tnh cht trn l:
A. 4
B. 5
C. 6
D. 2
V d 6. Este n chc X (cha C, H, O v khng c nhm chc khc) c t khi hi i vi oxi bng 3,125.
Cho 0,15 mol X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 21 gam mui
khan Z. Cho Z tc dng vi dung dch axit long thu c cht hu c T khng phn nhnh. CTCT ca X l
A. C2H5COOCH=CH2.
B. HCOOC6H5.
C.
.
D.
.
V d 7. Cho 3,36 gam mt este n chc X tc dng va vi 100ml KOH 0,4M thu c 5,6 gam mui Y.
Axit ha Y thu c cht Z. Z c cng thc phn t l
A. C4H4O2
B. C4H6O3
C. C5H6O2
D. C5H8O3
Phm Thnh (0976.053.496)
M024. ANCOL: RU IU CH ANCOL

(T liu hc bi)
V d 1. Trn nhn chai ru c ghi Ru 45o, cch ghi c ngha l

A. Trong 100 ml ru c cha 45 ml ru nguyn cht.
B. Trong 100 gam ru c cha 45 gam ru nguyn cht.
C. Trong 100 ml nc c ha tan 45 ml ru nguyn cht.
D. Trong 100 gam nc c ha tan 45 gam ru nguyn cht.
V d 2. Pha 160 gam C2H5OH (D = 0,8 g/ml) vo nc c 0,5 lt ru c ru l
A. 40o.
B. 66,6o.
C. 25,6o.
D. 9,6o.
V d 3. Khi lng etanol c trong 1 lt ru 90o l (khi lng ring ca etanol l 0,8 g/ml)
A. 980 gam.
B. 900 gam.
C. 800 gam.
D. 720 gam.
V d 4. Ha tan 92 gam C2H5OH vo nc thu c 250 ml dung dch X. Bit khi lng ring ca ru
nguyn cht l D = 0,8 g/ml. ru ca dung dch X l
A. 29,44o.
B. 36,8o.
C. 46o.
D. 50o.
V d 5. Pha m gam ru etylic nguyn cht (D = 0,8 g/ml) vo nc c 80ml ru 25o. Gi tr ca m l

A. 40 gam.
B. 20 gam.
C. 32 gam.
D. 16 gam.
V d 6. Cho 1,0 lt cn 95o tc dng vi Na d. Bit rng ru nguyn cht c khi lng ring D = 0,8 g/ml.
Th tch H2 to ra ktc l
A. 432,3 lt.
B. 370 lt.
C. 216,2 lt.
D. 185 lt.
V d 7. Phng php tng hp ancol etylic trong cng nghip thch hp nht l
+ H 2 (Ni, t )
+ Cl 2 (askt)
+ H O (OH )
C2H6
C2H5Cl

C2H5OH
o
A. C2H4
+ H (Pd, t o )
t
H 2 O (t , p)
2
C2H4 +
C2H5OH
B. CH4 C2H2
o
+ H O (H + , t o , p)
C. C2H4 2 C2H5OH
+ HCl
+ NaOH, t o
D. C2H4 C2H5Cl C2H5OH

V d 8. (B12) Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm chnh l
A. 2-metybutan-2-ol
B. 3-metybutan-2-ol
C. 3-metylbutan-1-ol
D. 2-metylbutan-3-ol
V d 9. (B10) C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng

cng H2 (xc tc Ni, to) ?
A. 3.
B. 5.
C. 2.
D. 4.
Phm Thnh (0976.053.496)
V d 10. Cho 7,872 lt kh C2H4 (o 27oC, 1atm) hp th nc c xc tc, hiu sut 80%, thu c ru X.
Ha tan X vo nc thnh 245,3 ml dung dch Y. Cho etanol nguyn cht c khi lng ring l 0,8 g/ml.
ru trong dung dch Y l
A. 7,5o.
B. 6,0o.
C. 4,8o.
D. 9,4o.
V d 11. Hin nay do s cn kit ngun du m, con ngi bt u chuyn sang s dng nhin liu thay th l
etanol. Vi mc ch ny, etanol c sn xut ch yu bng phng php no di y?
A. Thy phn etyl halogenua trong mi trng kim.
B. Hiro ha (kh) axetanehit vi xc tc Ni.
C. Ln men tinh bt.
D. Hirat ha etilen thu c t qu trnh sn xut du m.
V d 12. (C12) Ln men 90 kg glucoz thu c V lt ancol etylic (D = 0,8 g/ml) vi hiu sut ca qu trnh
ln men l 80%. Gi tr ca V l
A. 71,9
B. 46,0
C. 23,0
D. 57,5
V d 13. Cho s iu ch ancol etylic t tinh bt:

+
+ H 2 O/H , t
men ancol, t
Tinh bt
Ancol etylic
Glucoz
Ln men 3,24 kg tinh bt vi hiu sut cc giai on ln lt l 75% v 80%. Th tch dung dch ancol etylic
20o thu c l (bit khi lng ring ca ancol etylic nguyn cht l 0,8 gam/ml)
A. 3,45 lt.
B. 19,17 lt.
C. 6,90 lt.
D. 9,58 lt.
V d 14. T 1 tn khoai c cha 20% tinh bt, sn xut c 100 lt ancol etylic nguyn cht c D = 0,8 g/ml.
Hiu sut ca ton b qu trnh l
A. 78,2%.
B. 88%.
C. 70,4%.
D. 100%.
V d 15. Sau khi ln men nc qu nho ta thu c 100 lt ru vang 10o (bit hiu sut phn ng ln men
t 95% v ancol etylic nguyn cht c khi lng ring l 0,8 g/ml). Gi thit trong nc qu nho ch c mt
loi ng l glucoz. Khi lng glucoz c trong lng nc qu nho dng l
A. 15,652kg.
B. 20,595kg.
C. 19,565kg.
D. 16,476kg.

M024. PHN NG ESTE HA IU CH ESTE

(T liu hc bi)
Ch 1. Phng php iu ch este
V d 1. S este mch h c cng thc C4H6O2 c to ra t axit v ancol tng ng l:
A. 2.
B. 3.
C. 4.
D. 5.
V d 2. Cho cc este: vinyl axetat, vinyl benzoat, etyl axetat, isoamyl axetat, phenyl axetat, anlyl axetat, s
este c th iu ch trc tip bng phn ng ca axit v ancol tng ng (c H2SO4 c lm xc tc) l:
A. 5
B. 3
C. 2
D. 4.
V d 3. Cht no sau y khng to este trong phn ng vi axit axetic ?
B. HOCH2CH2OH
C. C2H2
D. C6H5OH
A. C2H5OH
V d 4. Axit salixylic (axit o-hiroxibenzoic) tc dng vi cht X c xc tc H2SO4 to ra metyl salixylat dng
lm thuc xoa bp, cn tc dng vi cht Y to ra axit axetyl salixylic (aspirin) dng lm thuc cm. Cc cht
X v Y ln lt l:
A. metan v anhirit axetic.
B. metan v axit axetic.
C. metanol v anhirit axetic.
D. metanol v axit axetic.
Ch 2. Cn bng este ha
V d 5. Khi thc hin phn ng este ha 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l
2/3 mol. t hiu sut cc i l 90% (tnh theo axit), khi tin hnh este ha 1 mol CH3COOH cn s mol
C2H5OH l (bit cc phn ng este ho thc hin cng nhit )
A. 0,342.
B. 2,925.
C. 2,412.
D. 0,456.
V d 6. Bit hng s cn bng ca phn ng este ho gia axit axetic v ancol etylic bng 4. Nu cho 0,625 mol
axit axetic tc dng vi 1 mol ancol etylic (c xc tc H2SO4 c) th khi t n trng thi cn bng, hiu sut phn
ng este ho l bao nhiu ?
A. 62,5%.
B. 66,67%.
C. 80%.
D. 82,5%.
V d 7. un nng axit axetic vi isoamylic (CH3)2CH-CH2-CH2OH c H2SO4 c xc tc thu c isoamyl
axetat (du chui). Lng du chui thu c khi un nng 132,35 gam axit axetic vi 200 gam ancol
isoamylic l (Bit hiu sut phn ng t 68%)
A. 195,0 gam.
B. 200,9 gam.
C. 286,8 gam.
D. 295,5 gam.
V d 8. t chy hon ton m gam hn hp X gm hai ancol n chc, cng dy ng ng, thu c 15,68
lt kh CO2 (ktc) v 17,1 gam nc. Mt khc, thc hin phn ng este ha m gam X vi 15,6 gam axit axetic,
thu c a gam este. Bit hiu sut phn ng este ha ca hai ancol u bng 60%. Gi tr ca a l
A. 15,48.
B. 25,79.
C. 24,80.
D. 14,88.
(Trch TSC 2012)
M025. ANCOL: ANCOL A CHC

(T liu hc bi)
V d 1. (C8) t chy hon ton mt ancol a chc, mch h X, thu c H2O v CO2 vi t
l s mol tng ng l 3:2. Cng thc phn t ca X l
A. C2H6O2.
B. C2H6O.
C. C3H8O2.
D. C4H10O2.
V d 2. Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy
hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l
B. C2H5OH v C4H9OH.
V d 3. (B7) X l mt ancol no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu
c hi nc v 6,6 gam CO2. Cng thc ca X l
A. C2H4(OH)2.
B. C3H7OH.
C. C3H5(OH)3.
D. C3H6(OH)2.
V d 4. t chy hon ton hn hp X (gm hai ancol a chc, cng dy ng ng) cn V lt
O2 (ktc), thu c 0,616 lt CO2 v 0,675 gam H2O. Gi tr ca V l
A. 0,924.
B. 1,624.
C. 0,812.
D. 0,7.
V d 5. t chy hon ton m gam ancol X ri cho sn phm chy vo bnh ng dung dch
Ca(OH)2 d thy khi lng ca bnh tng ln p gam v c t gam kt ta. Bit rng: p = 0,71t
v t = [(m + p)/1,02] th ancol X l:
A. C2H5OH .
B. C2H4(OH)2.
C. C3H5(OH)3.
D. C4H8(OH)3
V d 6. S ng phn ancol ti a ng vi CTPT C3H8Ox l
A. 4.
B. 5.
C. 6.
D. 7.
V d 7. Ancol X tc dng vi Na d cho s mol H2 bng s mol X dng. t chy hon
ton X c m CO2 = 1,956m H 2O . S ng phn tha mn X l
A. 4.
B. 5.
C. 6.
D. 7.
V d 8. Ancol no X c phn t khi l 62 vC. Khi cho 15,5 gam X tc dng vi lng Na d
thu c 5,6 lt H2 (ktc). S nhm OH trong phn t X l
A. 1.
B. 3.
C. 2.
D. 4.
V d 9. Ancol X mch h c s nguyn t cacbon bng s nhm chc. Cho 9,2 gam ancol X
tc dng vi Na d, thu c 3,36 lt kh (ktc). Cng thc cu to ca X l
A. CH3OH.
B. CH3CH2OH.
C. HOCH2CH2OH.
D. HOCH2CH(OH)CH2OH.
V d 10. Hn hp X gm 2 ancol, c t khi hi so vi He l 17,25. Cho 24,15 gam X tc
dng vi Na d thu c 7,84 lt H2 (ktc). Hai ancol trong X ln lt l
B. C2H5OH v C3H5(OH)3.
C. C2H5OH v C2H4(OH)2.
D. C3H7OH v C4H9OH.
V d 11. Thc hin cc th nghim sau:

TN1: Trn 0,015 mol ancol no X vi 0,02 mol ancol no Y ri cho tc dng ht vi Na th thu
c 1,008 lt H2.
TN2: Trn 0,02 mol ancol X vi 0,015 mol ancol Y ri cho hp tc dng ht vi Na th thu
c 0,952 lt H2.
TN3: t chy hon ton mt lng hn hp ancol nh trong th nghim 1 ri cho tt c sn
phm chy i qua bnh ng CaO mi nung, d thy khi lng bnh tng thm 6,21 gam. Bit
th tch cc khi o ktc. Cng thc 2 ancol l
B. C2H4(OH)2 v C3H5(OH)3.
V d 12. (C7) Cho cc cht c CTCT nh sau: HOCH2-CH2OH (X); CH3-CH2-CH2OH (Y);
HOCH2-CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). S cht tc
dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l
A. 1.
B. 3.
C. 2.
D. 4.
V d 13. (B9) Cho cc hp cht sau:
(a) HOCH2-CH2OH.
(b) HOCH2CH2CH2OH.
(c) HOCH2-CH(OH)-CH2OH.
(e) CH3-CH2OH.
(f) CH3-O-CH2CH3.
(d) CH3CH(OH)CH2OH.
S cht tc dng c vi c Na v Cu(OH)2 l:
A. 2.
B. 4.
C. 3.
D. 5.
V d 14. (A9) t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh
O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh
dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l
A. 9,8 v propan-1,2-iol.
B. 4,9 v propan-1,2-iol.
C. 4,9 v propan-1,3-iol.
D. 4,9 v glixerol.
2
Y ancol anlylic. X l cht no
V d 15. Cho s phn ng: X
sau y ?
A. Propan.
B. Xiclopropan.
C. Propen.
D. Propin.
V d 16. Trong cng nghip, sn xut glixerol ngi ta i theo s no trong s cc s
di y?
A. Propan Propanol Glixerol
B. Propen Anlyl clorua 1,3iclopropan2ol Glixerol
C. Butan Axit butanoic Glixerol
D. Metan Etan Propan Glixerol.
+Cl , 500o C
+NaOH

M026. X PHNG HA CHT BO CH S CA CHT BO

(T liu hc bi)
V d 1. Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol v hai loi axit bo. Hai loi axit bo
l
A. C15H31COOH v C17H33COOH.
B. C17H33COOH v C15H31COOH.
C. C17H31COOH v C17H33COOH.
D. C17H33COOH v C17H35COOH.
V d 2. trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH 0,1M. Ch
s axit ca mu cht bo trn l
A. 5,5.
B. 4,8.
C. 6,0.
D. 7,2.
(Trch TSC 2007)
V d 3. trung ho 15 gam mt loi cht bo c ch s axit bng 7, cn dng dung dch cha a gam NaOH.
Gi tr ca a l
A. 0,150.
B. 0,280.
C. 0,075.
D. 0,200.
(Trch TSC 2010)
V d 4. Khi x phng ho hon ton 1,26 gam mt mu cht bo cn 45ml dung dch KOH 0,1 M. Ch s x
phng ho ca mu cht bo l
A. 150.
B. 200.
C. 250.
D. 300.
V d 5. Mt loi cht bo c cha 1,42% axit stearic, 1,28% axit panmitic cn li l triglixerit. phn ng
va vi 100 gam mu cht bo ny th cn 350ml dung dch NaOH 1M. Ch s este ca mu cht bo l
A. 5,6.
B. 190,4.
C. 196.
D. 201,6.
V d 6. Khi cho 9 gam mt mu cht bo c thnh phn chnh l triolein phn ng vi iot th thy cn 1,524
gam iot. Ch s iot ca mu cht bo trn l
A. 169,3.
B. 74,67.
C. 37,33.
D. 16,93.
V d 7. X phng ho hon ton 17,24 gam cht bo trung ha cn va 0,06 mol NaOH. C cn dung dch
sau phn ng thu c khi lng x phng l
A. 18,24 gam.
B. 16,68 gam.
C. 18,38 gam.
D. 17,80 gam.
V d 8. Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c
207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l:
A. 31 gam.
B. 32,36 gam.
C. 30 gam.
D. 31,45 gam.
Phm Thnh (0976.053.496)
M026. PHENOL
(T liu hc bi)
V d 1. (B10) Cho cc cht: (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4-metylbenzen;
(5) 4-metylphenol; (6) -naphtol. Cc cht thuc loi phenol l:
A. (1), (3), (5), (6).
B. (1), (2), (4), (6).
C. (1), (2), (4), (5).
D. (1), (4), (5), (6).
V d 2. (A9) Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp

cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm
ng vi cng thc phn t ca X l
A. 3.
B. 6.
C. 4.
D. 5.
V d 3. S ng phn thuc loi phenol ca C6H6O2 l:

A. 1.
B. 2.
C. 3.
D. 4.
V d 4. (B8) nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia
phenol vi
A. dung dch NaOH.
B. Na kim loi.
C. nc Br2.
D. H2 (Ni, nung nng).
V d 5. nh hng ca gc C6H5- n nhm -OH trong phn t phenol th hin qua phn ng gia phenol vi
A. dung dch NaOH.
B. Na kim loi.
C. nc Br2.
D. H2 (Ni, nung nng).
V d 6. (B7NC) Dy gm cc cht u phn ng vi phenol l:

A. nc brom, anehit axetic, dung dch NaOH.
B. dung dch NaCl, dung dch NaOH, kim loi Na.
C. nc brom, axit axetic, dung dch NaOH.
D. nc brom, anhirit axetic, dung dch NaOH.
V d 7. (B7) S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung
dch NaOH l
A. 3.
B. 1.
C. 4.
D. 2.
V d 8. (A11) Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht.
Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th
thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha
mn cc tnh cht trn?
A. 10.
B. 9.
C. 7.
D. 3.
V d 9. (C7) Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi
Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn
ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l
A. HOC6H4CH2OH.
B. CH3C6H3(OH)2.
C. CH3OC6H4OH.
D. C6H5CH(OH)2.
Phm Thnh (0976.053.496)
V d 10. (C11) Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri (d), thu c 2,24
lt kh H2 (ktc). Mt khc, phn ng hon ton vi m gam X cn 100 ml dung dch NaOH 1M. Gi tr ca m
l:
A. 7,0
B. 14,0
C. 10,5
D. 21,0
V d 11. (C12) Cho dung dch cha m gam hn hp gm phenol (C6H5OH) v axit axetic tc dng va vi
nc brom, thu c dung dch X v 33,1 gam kt ta 2,4,6-tribromphenol. Trung ha hon ton X cn va
500 ml dung dch NaOH 1M. Gi tr ca m l
A. 21,4
B. 24,8
C. 33,4
D. 39,4
V d 12. (C9) Trong thc t, phenol c dng sn xut

A. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D.
B. nha rezol, nha rezit v thuc tr su 666.
C. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric.
D. nha rezit, cht dit c 2,4-D v thuc n TNT.
V d 13. (A12) Cho cc pht biu sau v phenol (C6H5OH):
(a) Phenol tan nhiu trong nc lnh.
(b) Phenol c tnh axt nhng dung dch phenol trong nc khng lm i mu qu tm.
(c) Phenol c dng sn xut phm nhum, cht dit nm mc.
(d) Nguyn t H ca vng benzen trong phenol d b thay th hn nguyn t H trong benzen.
(e) Cho nc brom vo dung dch phenol thy xut hin kt ta.
S pht biu ng l
A. 5.
B. 2.
C. 3.
D. 4.
2
X
Y
Z
V d 14. (A7) Cho s : C6 H6
Fe, t o
t o cao, P cao
+ Cl (1:1)
+ NaOH, du
+ HCl
Hai cht hu c Y, Z ln lt l:
A. C6H6(OH)6, C6H6Cl6.
B. C6H4(OH)2, C6H4Cl2.
C. C6H5OH, C6H5Cl.
D. C6H5ONa, C6H5OH.
V d 15. (B8) Cho s chuyn ho sau:

+ Br2 (1:1mol), Fe, t
+ NaOH (d ), t , p
+ HCl (d )
Toluen
X
Y
Z
o
Trong X, Y, Z u l hn hp ca cc cht hu c, Z c thnh phn chnh gm :

A. m-metylphenol v o-metylphenol
B. benzyl bromua v o-bromtoluen
C. o-bromtoluen v p-bromtoluen
D. o-metylphenol v p-metylphenol.
Phm Thnh (0976.053.496)
M027. ANEHIT XETON AXIT: NG PHN TNH CHT VT L

(T liu hc bi)
V d 1. S ng phn anehit v xeton ng vi cng thc phn t C5H10O ln lt l

A. 3 v 3.
B. 4 v 3.
C. 3 v 4.
D. 4 v 4.
V d 2. S ng phn anehit ng vi cng thc phn t C4H6O l
A. 3.
B. 4.
C. 5.
D. 6.
V d 3. S ng phn xeton ng vi cng thc phn t C6H12O l
A. 3.
B. 4.
C. 5.
D. 6.
V d 4. S ng phn anehit (c vng benzen) ng vi cng thc phn t C8H8O l
A. 2.
B. 4.
C. 3.
D. 5.
V d 5. Anehit X c cng thc n gin nht l C4H3O (ch c lin kt C-C trong vng benzen). S ng
phn anehit ca X l
A. 2.
B. 3.
C. 4.
D. 5.
V d 6. Axit no, mch h X c cng thc n gin nht l C2H3O. S ng phn axit ti a c th c ca X l
A. 3.
B. 4.
C. 5.
D. 6.
V d 7. Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n. S ng phn axit ti a c th
c ca X l
A. 3.
B. 4.
C. 5.
D. 6.
V d 8. Cho cc cht: axetanehit (1); axeton (2); ancol etylic (3); axit fomic (4). Dy sp xp cc cht theo
chiu nhit si tng dn l
A. (1) < (2) < (3) < (4).
B. (2) < (1) < (3) < (4).
C. (1) < (2) < (4) < (3).
D. (2) < (1) < (4) < (3).
V d 9. Cho cc cht: fomanehit (a); axetanehit (b); axeton (c); ancol metylic (d); ancol etylic (e); ancol
isopropylic (g); axit fomic (h); axit axetic (i); axit propionic (k). S cht tan v hn trng nc l:
A. 6.
B. 7.
C. 8.
D. 9.
V d 10. C cc mnh sau:
(a) Fomanehit v axetanehit l cht kh; axeton l cht lng.
(b) Fomalin (hay fomon) l dung dch c nng 37 40% ca fomanehit trong nc.
(c) Cc anehit v xeton thng c mi ring bit.
(d) Dung dch cc axit thng c v chua.
(e) Trong cc cht: ancol etylic, fomanehit, axeton, axit axetic; c 4 cht to c lin kt hiro vi nc.
(g) Trong cc cht lng nguyn cht: ancol etylic, fomanehit, axeton, axit axetic; ch c 2 cht to c lin
kt hiro lin phn t.
(h) trng thi nguyn cht, cc phn t axit cacboxylic to c lin kt hiro theo c 2 kiu: ime v polime.
S mnh ng l:
A. 4.
B. 5.
C. 6.
D. 7.
M027. L THUYT TRNG TM V CACBOHIRAT

(T liu hc bi)
V d 1. Cacbohirat nht thit phi cha nhm chc ca

A. xeton.
B. este.
C. anehit.
D. ancol.
V d 2. Hp cht no di y l monosaccarit ?
(1) CH2OH-(CHOH)4CH-CH2OH
(2) CH2OH-(CHOH)4CH=O
(3) CH2OH-CO-(CHOH)3CH2OH
(4) CH2OH-(CHOH)4-COOH
(5) CH2OH-(CHOH)3-CH=O
A. (2), (3), (5).
B. (1), (2), (3).
C. (1), (4), (5).
D. (1), (3).
V d 3. chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch glucoz
phn ng vi
A. kim loi Na.
B. AgNO3 trong dung dch NH3, un nng.
C. Cu(OH)2 trong NaOH, un nng.
D. Cu(OH)2 nhit thng.
V d 4. Th nghim no sau y chng t trong phn t glucoz c 5 nhm hiroxyl ?
A. Kh hon ton glucoz thnh hexan.
B. Cho glucoz tc dng vi Cu(OH)2.
C. Tin hnh phn ng to este ca glucoz vi anhirit axetic.
D. Thc hin phn ng trng bc.
V d 5. Cht no sau y khng c dng mch vng ?
B. CH2(OCH3)-[CH(OCH3]4-CHO.
A. CH2(OCH3)-CH(OH)-[CH(OCH3)]3-CHO.
C. CH2OH-(CHOH)4-CHO.
D. CH2OH(CHOH)3-CO-CH2OH.
V d 6. Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng
A. thy phn.
B. trng gng.
C. trng ngng.
D. ho tan Cu(OH)2.
V d 7. Thu phn hon ton tinh bt trong dung dch axit v c long, thu c cht hu c X. Cho X phn
ng vi kh H2 (xc tc Ni, to), thu c cht hu c Y. Cc cht X, Y ln lt l
A. glucoz, saccaroz.
B. glucoz, sobitol.
C. glucoz, fructoz.
D. glucoz, etanol.
(Trch TSC 2010)
V d 8. Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, mantoz. S cht trong dy tham gia phn
ng trng gng l
A. 3.
B. 4.
C. 2.
D. 5.
(Trch TSC 2008)
V d 9. Cho dy cc cht: glucoz, xenluloz, saccaroz, fructoz, tinh bt, mantoz. S cht trong dy c
phn ng vi CH3OH/HCl l
A. 2.
B. 3.
C. 4.
D. 5.
V d 10. Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi
axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong dung dch axit
un nng (6). Cc tnh cht ca xenluloz l:
A. (2), (3), (4) v (5).
B. (3), (4), (5) v (6).
C. (1), (2), (3) v (4).
D. (1), (3), (4) v (6).
V d 11. Pht biu khng ng l
A. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O.
B. Sn phm thy phn xenluloz (xc tc H+, to) c th tham gia phn ng trng gng.
C. Thy phn (xc tc H+, to) saccaroz cng nh mantoz u ch cho cng mt monosaccarit.
D. Dung dch fructoz ho tan c Cu(OH)2.
V d 12. Pht biu no sau y khng ng ?
A. Glucoz tc dng c vi nc brom.
B. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH.
C. Glucoz tn ti dng mch h v dng mch vng.
D. dng mch h, glucoz c 5 nhm OH k nhau.
V d 13. Pht biu no sau y l ng ?
A. Saccaroz lm mt mu nc brom.
B. Xenluloz c cu trc mch phn nhnh.
C. Amilopectin c cu trc mch phn nhnh.
D. Glucoz b kh bi dung dch AgNO3 trong NH3.
V d 14. Cho cc pht biu sau:
(1) Fructoz v glucoz u c kh nng tham gia phn ng trng bc;
(2) Saccaroz v tinh bt u khng b thy phn khi c axit H2SO4 (long) lm xc tc;
(3) Tinh bt c to thnh trong cy xanh nh qu trnh quang hp;
(4) Xenluloz v saccaroz u thuc loi isaccarit;
Pht biu ng l
A. (3) v (4).
B. (1) v (3).
C. (1) v (2).
D. (2) v (4).
(Trch TSC 2012)
V d 15. Cho cc pht biu sau v cacbohirat:
(a) Tt c cc cacbohirat u c phn ng thy phn.
(b) Thy phn hon ton tinh bt thu c glucoz.
(c) Glucoz, fructoz v mantoz u c phn ng trng bc.
(d) Glucoz lm mt mu nc brom.
S pht biu ng l:
A. 3.
B. 4.
C. 1.
D. 2.
Phm Thnh (0976.053.496)
M028. ANEHIT XETON AXIT: PHN NG OXI HA

(T liu hc bi)
V d 1. (B9) Cho cc hp cht hu c:

(1) ankan;
(2) ancol no, n chc, mch h;
(3) xicloankan;
(4) ete no, n chc, mch h;
(5) anken;
(6) ancol khng no (c mt lin kt i C=C), mch h;
(7) ankin;
(8) anehit no, n chc, mch h;
(9) axit no, n chc, mch h;
(10) axit khng no (c mt lin kt i C=C), n chc.
S cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l:
A. 4.
B. 6.
C. 5.
D. 7.
V d 2. (B7) t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( ktc), thu c
0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l
A. 8,96.
B. 6,72.
C. 4,48.
D. 11,2.
V d 3. (B9) t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 (
ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l
A. O=CH-CH=O.
B. CH2=CH-CH2-OH.
C. CH3COCH3.
D. C2H5CHO.
V d 4. (B10) Hn hp M gm anehit X (no, n chc, mch h) v hirocacbon Y, c tng s mol l 0,2
(s mol ca X nh hn ca Y). t chy hon ton M, thu c 8,96 lt kh CO2 (ktc) v 7,2 gam H2O.
Hirocacbon Y l
A. CH4.
B. C2H2.
C. C3H6.
D. C2H4.
V d 5. (B9) t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi
Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l
A. HO-CH2-CH2-CH=CH-CHO.
B. HOOC-CH=CH-COOH.
C. HO-CH2-CH=CH-CHO.
D. HO-CH2-CH2-CH2-CHO.
V d 6. (C8) Cho dy cc cht: fomanehit; axetilen; axit axetic; but-2-in; axit fomic; ancol etylic;
vinylaxetilen; natri fomat. S cht trong dy tham gia phn ng trng gng v s cht c phn ng vi dung
dch AgNO3/NH3 to kt ta ln lt l
A. 2 v 4.
B. 2 v 5.
C. 3 v 5.
D. 3 v 6.
V d 7. (C8) t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O. Nu cho X tc
dng vi lng d AgNO3 trong dung dch NH3, sinh ra s mol Ag gp bn ln s mol X phn ng. Cng
thc ca X l
A. HCHO.
B. CH3CHO.
C. (CHO)2.
D. C2H5CHO.
V d 8. (B7) t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O
(bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit
A. khng no c mt ni i C=C, n chc.
B. no, n chc.
C. khng no c hai ni i C=C, n chc.
D. no, hai chc.
V d 9. (A7) Cho 0,1 mol anehit X tc dng vi lng d AgNO3 trong dung dch NH3, un nng thu c
43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu
gn ca X l
A. HCHO.
B. CH3CH(OH)CHO.
C. OHC-CHO.
D. CH3CHO.
Phm Thnh (0976.053.496)
V d 10. (C8) Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d AgNO3 trong
dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l
A. 43,2 gam.
B. 10,8 gam.
C. 64,8 gam.
D. 21,6 gam.
V d 11. (C9) Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng
ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X
l
B. HCHO v CH3CHO.
A. HCHO v C2H5CHO.
C. C2H3CHO v C3H5CHO.
D. CH3CHO v C2H5CHO.
V d 12. (A10) Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam CuO. Cho
ton b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3, thu c 23,76 gam Ag. Hai
ancol l:
A. CH3OH, C2H5CH2OH. B. CH3OH, C2H5OH.
C. C2H5OH, C3H7OH.
D. C2H5OH, C2H5CH2OH.
V d 13. (B8) Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm
X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d dung dch AgNO3 trong NH3, c
12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l
A. 65,5%.
B. 80,0%.
C. 76,6%.
D. 70,4%.
V d 14. (C10NC) Cho 4,6 gam mt ancol no, n chc phn ng vi CuO nung nng, thu c 6,2 gam hn
hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi lng d dung
dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l
A. 16,2.
B. 43,2.
C. 10,8.
D. 21,6.
V d 15. (A8) Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng
tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2
l 13,75). Cho ton b Y phn ng vi mt lng d dung dch AgNO3 trong NH3 un nng, sinh ra 64,8 gam
Ag. Gi tr ca m l
A. 9,2.
B. 7,8.
C. 7,4.
D. 8,8.
V d 16. (A10) Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO3
trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca
m l
A. 9,5.
B. 10,9.
C. 14,3.
D. 10,2.
V d 17. (B9NC) Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi
ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn
phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr
ca m l
A. 15,3.
B. 13,5.
C. 8,1.
D. 8,5.
V d 18. (A9) Cho 0,25 mol mt anehit mch h X phn ng vi lng d AgNO3 trong dung dch NH3, thu
c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi
0,25 mol H2. Cht X c cng thc ng vi cng thc chung l
A. CnH2n(CHO)2 (n 0). B. CnH2n + 1CHO (n 0). C. CnH2n 1CHO (n 2). D. CnH2n 3 CHO (n 2).

M028. PHNG PHP XC NH CU TO CA CACBOHIRAT

(T liu hc bi)
V d 1. (A10) Mt phn t saccaroz c

A. mt gc -glucoz v mt gc -fructoz.
B. mt gc -glucoz v mt gc -fructoz.
C. hai gc -glucoz.
D. mt gc -glucoz v mt gc -fructoz.
V d 2. (B10NC) Cht X c cc c im sau: phn t c nhiu nhm OH, c v ngt, ha tan Cu(OH)2
nhit thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l
A. xenluloz.
B. mantoz.
C. glucoz.
D. saccaroz.
V d 3. Hp cht hu c X l cht bt mu trng, khng tan trong nc, trng ln trong nc nng to
thnh h; sn phm cui cng ca qu trnh thu phn l cht Y. Di tc dng ca men lactic hay enzim cht
Y to thnh cht Z c cha hai loi nhm chc. X l cht no di y ?
A. Saccaroz.
B. Mantoz.
C. Tinh bt.
D. Xenluloz.
V d 4. Cacbohirat X tham gia chuyn ho:
Cu(OH) /OH
2
dung dch xanh lam
kt ta gch
X
Vy X khng th l cht no trong cc cht cho di y ?
A. Glucoz.
B. Fructoz.
C. Saccaroz.
D. Mantoz.
V d 5. Cho s sau:
to
Cu(OH) 2 /OH
dd HCl
X
Yduy nht
Z (dung dch xanh lam) t T ( gch)
to
Cht X c th l
A. glucoz.
B. saccaroz.
C. mantoz.
D. saccaroz hoc mantoz.
V d 6. Cho s : Tinh bt X Y Z, cc phn ng u c enzim xc tc.
Cc cht X, Y, Z ln lt l:
A. extrin, mantoz, glucoz.
B. extrin, glucoz, axit axetic.
C. extrin, saccaroz, glucoz.
D. extrin, saccaroz, mantoz.
V d 7. (A12) Cho s phn ng:
Y
(a) X + H2O
(b) Y + AgNO3 + NH3 + H2O amoni gluconat + Ag + NH4NO3
xc tc
(c) Y
xc tc
E+Z
X+G
(d) Z + H2O
cht dip lc
nh sng
X, Y, Z ln lt l:
A. Tinh bt, glucoz, etanol.
C. Xenluloz, saccaroz, cacbon ioxit.
B. Tinh bt, glucoz, cacbon ioxit.

D. Xenluloz, fructoz, cacbon ioxit.
V d 8. Cho 18,0 gam mt cacbohirat X tc dng ht vi dung dch AgNO3/NH3 thu c 25,92 gam Ag.
Bit X c kh nng lm mt mu dung dch Br2. X l cht no di y ?
A.
B.
C.
D.
V d 9. Cacbohirat X c phn ng trng gng. un nng a mol X trong dung dch HCl long d cc
phn ng xy ra hon ton thu c dung dch Y. Trung ho axit cn d, sau cho AgNO3 d trong NH3 vo
Y, ng thi un nng, sau khi phn ng hon ton thu c 4a mol Ag. X c th l cacbohirat no sau y ?
A. Xenluloz.
B. Mantoz.
C. Saccaroz.
D. Glucoz.
V d 10. un nng 8,55 gam cacbohirat X vi dung dch HCl n phn ng hon ton. Cho dung dch sau
phn ng tc dng vi lng d AgNO3/NH3, kt ta thu c c 10,8 gam Ag. X c th l cht no di y
(bit MX < 400 vC)?
A. Glucoz.
B. Fructoz.
C. Saccaroz.
D. Xenluloz.
V d 11. t chy hon ton 3,150 gam mt cacbohirat X thu c 2,352 lt CO2 (ktc) v 1,89 gam nc.
Bit X c kh nng tham gia phn ng trng gng. X l cht no di y ?
A. Glucoz.
B. Xenluloz.
C. 2-hiroxietanal.
D. Saccaroz.
V d 12. Khi t chy cacbohirat X ngi ta thu c t l khi lng H2O v CO2 l 3 : 8. Cng thc phn
t no di y l ca X ?
A. C6H12O6.
B. C12H22O11.
C. (C6H10O5)n.
D. Cn(H2O)n.

Phm Thnh (0976.053.496)
M029. ANEHIT XETON AXIT: PHN NG GC HIROCACBON

(T liu hc bi)
V d 1. (C10) ng vi cng thc phn t C3H6O c bao nhiu hp cht mch h bn khi tc dng vi kh H2
(xc tc Ni, to) sinh ra ancol ?
A. 3.
B. 2.
C. 1.
D. 4.
V d 2. (A10NC) Hiro ho cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn thay th l
D. 3-metylbutan-2-on.
A. 2-metylbutan-3-on.
B. metyl isopropyl xeton. C. 3-metylbutan-2-ol.
V d 3. (B10NC) Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi Na,
2
3
Y
Este c mi chui chn
tha mn s chuyn ha sau: X
H 2SO4 , c
Ni, t o
+H
+ CH COOH
Tn ca X l
D. 3-metylbutanal.
C. 2,2-imetylpropanal.
A. pentanal.
B. 2-metylbutanal.
V d 4. (B9) Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau
trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X
th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l
A. 17,8.
B. 24,8.
C. 10,5.
D. 8,8.
V d 5. (A8) un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton
ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut).
Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l
anehit
A. khng no (cha mt ni i C=C), hai chc.
B. no, hai chc.
C. khng no (cha mt ni i C=C), n chc.
D. no, n chc.
V d 6. (A9) Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng
xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v
7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l
A. 46,15%.
B. 35,00%.
C. 53,85%.
D. 65,00%.
V d 7. (C9NC) Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau
trong dy ng ng (MX < MY), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1 gam.
t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln lt l
A. HCHO v 50,56%.
B. CH3CHO v 67,16%. C. CH3CHO v 49,44%. D. HCHO v 32,44%.
V d 8. 0,1 mol hp cht cacbonyl X tc dng va vi 250 ml dung dch HCN 0,4M thu c 8,5 gam
xianohirin Y. X l cht no di y ?
A. CH3CHO.
B. OHCCHO.
C. CH3CH2CHO.
D. OHCCHO hoc CH3CH2CHO.
V d 9. (B7NC) Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc.
Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu
sut qu trnh to CH3CH(CN)OH t C2H4 l
A. 50%.
B. 60%.
C. 70%.
D. 80%.
Phm Thnh (0976.053.496)
V d 10. Ln lt cho cc cht: fomanehit, axetanehit, axeton, anehit acrylic vo dung dch Br2. S trng
hp xy ra phn ng cng vi Br2 l
A. 1.
B. 2.
C. 3.
D. 4.
V d 11. (B9) t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi
Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l
A. HO-CH2-CH2-CH=CH-CHO.
B. HOOC-CH=CH-COOH.
C. HO-CH2-CH=CH-CHO.
D. HO-CH2-CH2-CH2-CHO.
+H 2 O
+Br2
+CuO
X
Y
Z
V d 12. (B10NC) Cho s phn ng: Stiren
H+ , to
to
H+
Trong X, Y, Z u l cc sn phm chnh. Cng thc ca X, Y, Z ln lt l:

A. C6H5CHOHCH3, C6H5COCH3, C6H5COCH2Br.
B. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH.
C. C6H5CH2CH2OH, C6H5CH2CHO, m-BrC6H4CH2COOH.
D. C6H5CHOHCH3, C6H5COCH3, m-BrC6H4COCH3.
V d 13. (B8NC) Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z
u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm chc; cht
Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l:
A. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH.
B. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO.
C. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH.
D. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO.
V d 14. (A7NC) Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn ng c vi
(CH3)2CO l
A. 2.
B. 4.
C. 1.
D. 3.
V d 15. Cho chui phn ng:

CH3CH2COOH
+ Cl2 , 1 : 1, xt
+ NaOH, t
+ HCl d
+ dd KOH d
Vi T l:
A. CH3CH(OH)COOK.
B. CH2(OK)CH2COOK.
C. CH3CH(OK)COOK.
D. CH2(OH)CH2COOK.
V d 16. Cho chui phn ng:

KMnO 4
H3O
HNO3 /H 2SO4 , t
Toluen
X
Y
Z
(1:1)
H O, t o
+
Cht Z l:
A. o-NO2C6H4COOH.
B. m-NO2C6H4COOH.
C. p-NO2C6H4COOH.
D. o-NO2C6H4COOH v p-NO2C6H4COOH.
M029. BI TON THY PHN OXI HA CACBOHIRAT

(T liu hc bi)
V d 1. (H Khi A 2008) Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l
A. 1,44 gam.
B. 1,80 gam.
C. 1,82 gam.
D. 2,25 gam.
V d 2. (Cao ng 2007) Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO3
trong dung dch NH3 thu c 2,16 gam Ag kt ta. Nng mol ca dung dch glucoz dng l
A. 0,20M.
B. 0,10M.
C. 0,02M.
D. 0,01M.
V d 3. (Cao ng 2010) Thu phn hon ton 3,42 gam saccaroz trong mi trng axit, thu c dung
dch X. Cho ton b dung dch X phn ng ht vi lng d dung dch AgNO3 trong NH3, un nng, thu c
m gam Ag. Gi tr ca m l
A. 2,16.
B. 4,32.
C. 21,60.
D. 43,20.
V d 4. Dung dch X cha m gam hn hp glucoz v saccaroz.
Thc hin phn ng trng gng hon ton dung dch X thu c 0,02 mol Ag.
un nng X vi HCl long n phn ng hon ton, trung ha axit d thu c dung dch Y. un nng Y
vi lng d dung dch AgNO3 trong NH3 th thu c ti a 0,06 mol Ag.
Gi tr ca m l
A. 5,22.
B. 3,60.
C. 10,24.
D. 8,64.
V d 5. Chia 200 gam dung dch hn hp glucoz v fructoz thnh hai phn bng nhau.
Phn 1 tc dng ht vi lng d dung dch AgNO3 trong NH3 c 86,4 gam Ag.
Phn 2 tc dng va ht vi 35,2 gam Br2.
Nng % ca fructoz trong dung dch ban u l
A. 16,2%.
B. 32,4%.
C. 39,6%.
D. 40,5%.
V d 6. Chia mt hn hp gm tinh bt v glucoz thnh hai phn bng nhau.
Cho phn th nht vo nc d ri cho phn ng hon ton vi AgNO3 trong NH3 d th c 2,16 gam Ag.
un phn th hai vi HCl long n phn ng hon ton, sau trung ha bng NaOH ri cng cho tc dng
vi lng d dung dch AgNO3 trong NH3 th c 6,48 gam Ag.
Khi lng tinh bt trong hn hp u l
A. 3,24 gam.
B. 4,86 gam.
C. 6,48 gam.
D. 9,72 gam.
V d 7. (H Khi B 2012) Thy phn hn hp gm 0,01 mol saccaroz v 0,02 mol mantoz trong mi
trng axit, vi hiu sut u l 60% theo mi cht, thu c dung dch X. Trung ha dung dch X, thu c
dung dch Y, sau cho ton b Y tc dng vi lng d dung dch AgNO3 trong NH3, thu c m gam Ag.
Gi tr ca m l
A. 6,480.
B. 7,776.
C. 8,208.
D. 9,504.
V d 8. Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X
(hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch
nc brom th s mol Br2 phn ng ti a l
A. 0,025.
B. 0,0325.
C. 0,04.
D. 0,0475.
Phm Thnh (0976.053.496)
M030. AXIT CACBOXYLIC: PHN NG CA NHM -COOH

(T liu hc bi)
V d 1. Chiu tng dn lc axit ca 3 cht hu c: C6H5OH (X), CH3COOH (Y), H2CO3 (Z) l
A. X < Y < Z.
B. X < Z < Y.
C. Z < X < Y.
D. Z < Y < X.
V d 2. Cho cc cht sau:
C2H5OH (1),
CH3COOH (2),
HCOOH (3),
C6H5OH (4).
Chiu tng dn linh ng ca nguyn t hiro trong cc nhm chc ca 4 cht trn l
A. 1 < 4 < 3 < 2.
B. 4 < 1 < 3 < 2.
C. 4 < 1 < 2 < 3.
D. 1 < 4 < 2 < 3.
V d 3. Phn ng no chng minh axit axetic c lc axit mnh hn lc axit ca phenol ?
A. CH3COONa + C6H5OH
CH3COOH + C6H5ONa.
CH3COONa + C6H5OH.
B. CH3COOH + C6H5ONa
C. 2CH3COOH + Ca
(CH3COO)2Ca + H2.
C6H5ONa + H2O.
D. C6H5OH + NaOH
V d 4. Phn ng th hin axit axetic mnh hn axit cacbonic, nhng yu hn axit sunfuric l
A. axit sunfuric phn ng vi mui cacbonat, axit axetic phn ng vi mui natri sunfat.
B. axit cacbonic phn ng vi mui natri axetat, axit axetic phn ng vi mui natri sunfat.
C. axit axetic phn ng vi mui cacbonat, mui natri axetat phn ng vi axit sunfuric.
D. axit cacbonic phn ng vi mui natri axetat, mui natri axetat phn ng vi axit sunfuric.
V d 5. Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l:
A. axit axetic, axit fomic, axit oxalic.
B. axit axetic, axit oxalic, axit fomic.
C. axit fomic, axit axetic, axit oxalic.
D. axit oxalic, axit fomic, axit axetic.
V d 6. Trong cc cht di y, cht no c lc axit mnh nht ?
A. ClCH2CH2COOH.
B. CH3CH(Cl)COOH.
C. Cl2CHCH2COOH.
D. CH3C(Cl2)COOH.
V d 7. Trong cc cht di y, cht no c lc axit mnh nht ?
A. CH3COOH.
B. CCl3COOH.
C. CBr3COOH.
D. CF3COOH.
V d 8. (C11) Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l:
A. HCOOH, CH3COOH, CH3CH2COOH
B. CH3COOH, HCOOH, (CH3)2CHCOOH
C. C6H5OH, CH3COOH, CH3CH2OH
D. CH3COOH, CH2ClCOOH, CHCl2COOH
V d 9. Cho 4 axit: CH3COOH (X), Cl2CHCOOH (Y), ClCH2COOH (Z), BrCH2COOH (T)
Chiu tng dn lc axit ca cc axit trn l
A. X, T, Z, Y.
B. X, Z, T, Y.
C. Y, Z, T, X.
D. T, Z, Y, X.
V d 10. Xp theo th t phn cc tng dn ca lin kt O-H trong phn t ca cc cht sau: C2H5OH (1);
CH3COOH (2); C6H5OH (3); CH3C6H4OH (4); C6H5CH2OH (5) l
A. (1) < (5) < (4) < (3) < (2).
B. (1) < (5) < (3) < (4) < (2).
C. (1) < (4) < (5) < (3) < (2).
D. (1) < (2) < (3) < (4) < (5).
V d 11. C cc dung dch ring bit sau: HCOOH; CH3COOH; AgNO3/NH3 d; HCHO; CH3-CO-CH3. Ch
dng thm 1 ha cht no di y c th phn bit cc dung dch trn bng phng php ha hc (m khng
trn ln ngu nhin cc cht) ?
A. qu tm.
B. nc brom.
C. phenolphtalein.
D. dung dch NaOH.
Phm Thnh (0976.053.496)
V d 12. Cho dy cht: Na; Mg; Ag; NaOH; BaO; CuO; AgNO3/NH3 d; dung dch Br2; NaHCO3; CaCO3.
S cht phn ng vi HCOOH l
A. 7.
B. 8.
C. 9.
D. 10.
V d 13. (B9) Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi
NaHCO3 th u sinh ra a mol kh. Xt dy cc cht sau: etylen glicol, ancol o-hiroxibenzylic, axit aipic, axit
3-hiroxipropanoic; s cht tha mn X l
A. 1.
B. 2.
C. 3.
D. 4.
V d 14. X l hn hp ch cha axit cacboxylic no, mch h. t chy hon ton 0,3 mol hn hp X, thu
c 11,2 lt kh CO2 ( ktc). Nu trung ha 0,6 mol X th cn dng 400 ml dung dch NaOH 2,5M. S cht
ti a c trong X l:
C. 4.
D. 5.
A. 2.
B. 3.
V d 15. (A8) Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung
dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l
A. 4,90 gam.
B. 6,84 gam.
C. 8,64 gam.
D. 6,80 gam.
V d 16. (B8) Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm
KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t
ca X l
B. HCOOH.
C. CH3COOH.
D. C3H7COOH.
A. C2H5COOH.
V d 17. (C7) Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam
mui ca axit hu c. Cng thc cu to thu gn ca X l
A. CH2=CH-COOH.
B. HCC-COOH.
C. CH3-CH2-COOH.
D. CH3COOH.
V d 18. (C9) Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch
NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO3 trong NH3, un nng
th thu c 21,6 gam Ag. Tn gi ca X l
A. axit acrylic.
B. axit propanoic.
C. axit etanoic.
D. axit metacrylic.
V d 19. (C11) Hai cht hu c X, Y c thnh phn phn t gm C, H, O (MX < MY < 82). C X v Y u c
kh nng tham gia phn ng trng bc v u phn ng c vi dung dch KHCO3 sinh ra kh CO2. T khi
hi ca Y so vi X c gi tr l:
A. 1,47
B. 1,61
C. 1,57
D. 1,91
V d 20. (B9) Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia
X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon
ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn
hp X ln lt l
A. HOOC-CH2-COOH v 70,87%.
B. HOOC-CH2-COOH v 54,88%.
C. HOOC-COOH v 60,00%.
D. HOOC-COOH v 42,86%.
M030. TNG HP IU CH T CACBOHIRAT

(T liu hc bi)
V d 1. (H Khi B - 2008) Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ancol
etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml)
A. 5,0 kg.
B. 5,4 kg.
C. 6,0 kg.
D. 4,5 kg.
V d 2. (H Khi A - 2010) T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol
etylic (hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X.
trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l
A. 90%.
B. 10%.
C. 80%.
D. 20%.
V d 3. T 1,0 tn tinh bt c th iu ch c bao nhiu tn cao su buna (gm 80% l poli(buta-1,3-ien))
bit hiu sut c qu trnh l 30% ?
A. 0,5 tn.
B. 0,33 tn.
C. 0,125 tn.
D. 0,1 tn
V d 4. (H Khi A - 2009) Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht
vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so
vi khi lng dung dch nc vi trong ban u. Gi tr ca m l
A. 20,0.
B. 30,0.
C. 13,5.
D. 15,0.
V d 5. (H Khi A - 2007) Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng
CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k
dung dch X thu thm c 100 gam kt ta. Gi tr ca m l
A. 550.
B. 810.
C. 650.
D. 750.
V d 6. Tinh bt c to thnh trong cy xanh nh qu trnh quang hp t CO2 v hi nc. Bit rng CO2
chim 0,03% th tch khng kh. Mun c 40,5 gam tinh bt th th tch khng kh (ktc) cn dng cung cp
lng CO2 cho phn ng quang hp l
A. 112000,0 lt.
B. 18666,7 lt.
C. 112,0 lt.
D. 186,7 lt.
V d 7. (H Khi B - 2012) iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt
axit nitric 94,5% (D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l
A. 60.
B. 24.
C. 36.
D. 40.
o
V d 8. Cho xenluloz phn ng vi anhirit axetic (c H2SO4 c lm xc tc, t ) thu c 12,0 gam hn hp
X (gm xenluloz triaxetat, xenluloz iaxetat v 4,2 gam CH3COOH). Thnh phn % theo khi lng ca
xenluloz triaxetat v xenluloz iaxetat trong X ln lt l
A. 48,0 v 20,5%.
B. 24,0% v 41,0%.
C. 39,87% v 25,13%.
D. 45,26% v 34,06%.
M031. HNG DN GII MT S BI TP KH V CACBOHIRAT

(T liu hc bi)
M31.1. Hp cht X l cht bt mu trng khng tan trong nc, trng ln trong nc nng to thnh h. Sn
phm cui cng ca qu trnh thu phn l cht Y. Di tc dng ca enzim ca vi khun axit lactic, cht Y to
nn cht Z c hai loi nhm chc ho hc. Cht Z c th c to nn khi sa b chua. Cht no di y
khng th l mt trong cc cht X, Y, Z ?
A. Glucoz.
B. Axit lactic.
C. Tinh bt.
D. Ancol etylic.
M31.2. Cho cc cht sau: xenluloz, amiloz, amilopectin, t visco, t axetat, glicogen, mantoz, saccaroz.
S cht c cng thc l (C6H10O5)n ?
A. 4
B. 5
C. 6
D. 3
M31.3. Cho dy cc cht sau: metyl--glucozit; fructoz; saccaroz; metyl--glucozit; mantoz. S cht c
cu to dng mch h l:
A. 1.
B. 2.
C. 3.
D. 4.
M31.4. T nhn t bo ngi ta tch c riboz c cng thc phn t l C5H10O5. Riboz tc dng vi dung
dch AgNO3/NH3 (un nng) v lm mt mu nc brom. Mt khc, riboz tc dng vi (CH3CO)2O to
C5H6O(OOC-CH3)4. Cng thc cu to ca riboz l:
A.
B.
C.
D.
M31.5. Ha tan m gam hn hp saccaroz v mantoz vo nc c dung dch X. Chia X thnh 2 phn bng
nhau:
Phn 1 tc dng vi lng d dung dch [Ag(NH3)2]OH c 10,8 gam Ag.
Phn 2 un vi dung dch HCl long phn ng xy ra hon ton, thu c dung dch Y. Dung dch Y tc
dng va ht vi 30,4 gam Br2
Hm lng % ca saccaroz trong hn hp ban u l
A. 35,7%.
B. 47,3%.
C. 52,7%.
D. 64,3%.
M31.6. Thy phn hon ton m gam hn hp X gm saccaroz v mantoz thu c dung dch Y. Cho Y tc
dng vi lng d dung dch AgNO3 trong NH3 thu c 0,2 mol Ag. Mt khc, thy phn m gam hn hp X
mt thi gian (hiu sut thy phn mi cht u l 80%) thu c dung dch Z. Cho Z tc dng vi lng d
dung dch AgNO3 trong NH3 thu c 0,168 mol Ag. Thnh phn phn trm v khi lng ca saccaroz trong
hn hp l
A. 55%.
B. 40%.
C. 45%.
D. 60%.
M31.7. (B11) Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung
dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung
dch AgNO3 trong NH3 th lng Ag thu c l
A. 0,090 mol
B. 0,095 mol
M31.8. Cho s sau: Tinh bt
X1
C. 0,12 mol
X2
X3
X4
D. 0,06 mol.
X5
CH4. Bit rng X1, X2, X3, X4, X5
u c oxi trong phn t v X2, X3, X4, X5 u c s nguyn t cacbon bng nhau. Ch dng qu tm v
Cu(OH)2 c th nhn bit c bao nhiu cht t X1 n X5 ?
A. 2.
B. 5.
C. 3.
D. 4.
M31.9. Cho m gam xenluloz tc dng va vi 56,7 gam HNO3 c trong hn hp HNO3 c v H2SO4
c, to thnh 97,2 gam hn hp X gm xenluloz initrat v xeluloz trinitrat. Gi tr m v thnh phn phn
trm v khi lng ca xenluloz initrat trong X ln lt l:
A. 40,5 v 61,11%
B. 56,7 v 38,89%
C. 56,7 v 61,11%
D. 57,6 v 38,89%.
M31.10. Cho khi lng ring ca cn nguyn cht l D = 0,8 g/ml. Hi t 10 tn v bo (cha 80% xenluloz)
c th iu ch c bao nhiu tn cn thc phm 45o (bit hiu sut ca ton b qu trnh iu ch l 64,8%)?
A. 2,94 tn.
B. 7,44 tn.
C. 9,30 tn.
D. 11,48 tn.

M032. L THUYT TRNG TM V AMIN AMINO AXIT

(T liu hc bi)
DNG 1. CU TO NG PHN DANH PHP
V d 1. (B11) Ancol v amin no sau y cng bc ?
A. (C6H5)2NH v C6H5CH2OH
B. C6H5NHCH3 v C6H5CH(OH)CH3
D. (CH3)2CHOH v (CH3)2CHNH2
C. (CH3)3COH v (CH3)3CNH2
V d 2. S ng phn cu to ca amin c cng thc phn t C4H11N l
A. 4.
B. 6.
C. 7.
D. 8.
V d 3. S amin cha vng benzen ng vi cng thc phn t C7H9N l
A. 2.
B. 3.
C. 4.
D. 5.
V d 4. (B12) Alanin c cng thc l
A. C6H5-NH2.
B. CH3-CH(NH2)-COOH. C. H2N-CH2-COOH.
D. H2N-CH2-CH2-COOH.
V d 5. (C12) S nhm amino v s nhm cacboxyl c trong mt phn t axit glutamic tng ng l
A. 1 v 1.
B. 2 v 2.
C. 2 v 1.
D. 1 v 2.
V d 6. (C12) Cho cc cht hu c: CH3CH(CH3)NH2 (X) v CH3CH(NH2)COOH (Y). Tn thay th ca X
v Y ln lt l
A. propan-2-amin v axit aminoetanoic
B. propan-2-amin v axit 2-aminopropanoic
C. propan-1-amin v axit 2-aminopropanoic
D. propan-1-amin v axit aminoetanoic.
V d 7. (C12) Pht biu no sau y l ng ?
A. nhit thng, cc amino axit u l nhng cht lng.
B. Cc amino axit thin nhin hu ht l cc -amino axit.
C. Amino axit thuc loi hp cht hu c tp chc.
D. Axit glutamic l thnh phn chnh ca bt ngt.
V d 8. S ng phn amino axit c cng thc phn t C4H9O2N l:
A. 3.
B. 4.
C. 5.
D. 6.
DNG 2. PHNG PHP SO SNH SP XP
V d 9. (A12) Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l:
A. (4), (1), (5), (2), (3).
B. (3), (1), (5), (2), (4).
C. (4), (2), (3), (1), (5).
D. (4), (2), (5), (1), (3).
V d 10. Cho cc cht sau: ancol etylic (1), etylamin (2), metylamin (3), axit axetic (4). Chiu sp xp cc cht
c nhit si tng dn l:
A. (2) < (3) < (4) < (1).
B. (3) < (2) < (1) < (4).
C. (2) < (3) < (4) < (1).
D. (1) < (3) < (2) < (4).
V d 11. Nguyn nhn ch yu lm cho etylamin c nhit si cao hn so vi butan l:
A. etylamin c khi lng phn t thp hn butan.
B. etylamin c kh nng to ra lin kt hiro vi cc phn t H2O.
C. etylamin c khi lng phn t cao hn butan.
D. etylamin c kh nng to ra lin kt hiro gia cc phn t.
DNG 3. NH GI MI TRNG DUNG DCH

V d 12. (A11) Dung dch no sau y lm qu tm i thnh mu xanh ?
A. Dung dch lysin.
B. Dung dch alanin.
C. Dung dch glyxin.
D. Dung dch valin.
V d 13. (A12) Dung dch cht no sau y lm qu tm chuyn thnh mu hng ?

A. axit -aminoglutaric.
B. Axit ,-iaminocaproic.
C. Axit -aminopropionic.
D. Axit aminoaxetic.
V d 14. (A8) C cc dung dch ring bit sau: ClNH3-CH2-COOH (1), C6H5NH3Cl (phenylamoni clorua) (2),
HOOC-CH2-CH2-CH(NH2)-COOH (3), NH2-CH2-CH2-CH(NH2)-COOH (4), NH2-CH2-COONa (5). S lng
cc dung dch c pH < 7 l
A. 2.
B. 4.
C. 5.
D. 3.
V d 15. (B11) Cho ba dung dch c cng nng mol: (1) H 2 NCH 2 COOH, (2) CH 3 COOH,
(3) CH3CH2NH2. Dy xp theo th t pH tng dn l:
A. (3), (1), (2)
B. (1), (2), (3)
C. (2), (3), (1)
D. (2), (1), (3)
DNG 4. PHN BIT NHN BIT

V d 16. Cht no di y phn ng vi dung dch FeCl3 cho kt ta mu nu ?
A. CH3NH2.
B. C6H5OH.
C. C2H5OH.
D. CH3COOH.
V d 17. phn bit anilin v etylamin ng trong 2 l ring bit, ta dng thuc th no?
A. Dung dch Br2.
B. Dung dch HCl.
C. Dung dch NaOH.
D. Dung dch AgNO3.
V d 18. C 3 cht hu c: H2NCH2COOH, CH3CH2COOH v CH3[CH2]3NH2. phn bit dung dch ca ba

hp cht trn, ch cn dng thuc th no sau y:
A. NaOH.
B. phenolphtalein.
C. HCl.
D. Qu tm.
V d 19. C th nhn bit l ng dung dch CH3NH2 bng cch no trong cc cch sau y?
A. Nhn bit bng mi.
B. Thm vi git dung dch H2SO4.
C. Thm vi git dung dch Na2CO3.
D. a a thy tinh nhng vo dung dch HCl m c ln pha trn ming l ng dung dch CH3NH2
c.
V d 20. phn bit ba cht lng benzen, anilin, stiren ng trong 3 l mt nhn c th dng thuc th no
di y ?
A. dung dch phenolphtalein.
B. nc brom.
C. dung dch NaOH.
D. giy qu tm.
M032. L THUYT TRNG TM V AMIN AMINO AXIT

(T liu hc bi)
DNG 1. CU TO NG PHN DANH PHP
V d 1. (B11) Ancol v amin no sau y cng bc ?
A. (C6H5)2NH v C6H5CH2OH
B. C6H5NHCH3 v C6H5CH(OH)CH3
D. (CH3)2CHOH v (CH3)2CHNH2
C. (CH3)3COH v (CH3)3CNH2
V d 2. S ng phn cu to ca amin c cng thc phn t C4H11N l
A. 4.
B. 6.
C. 7.
D. 8.
V d 3. S amin cha vng benzen ng vi cng thc phn t C7H9N l
A. 2.
B. 3.
C. 4.
D. 5.
V d 4. (B12) Alanin c cng thc l
A. C6H5-NH2.
B. CH3-CH(NH2)-COOH. C. H2N-CH2-COOH.
D. H2N-CH2-CH2-COOH.
V d 5. (C12) S nhm amino v s nhm cacboxyl c trong mt phn t axit glutamic tng ng l
A. 1 v 1.
B. 2 v 2.
C. 2 v 1.
D. 1 v 2.
V d 6. (C12) Cho cc cht hu c: CH3CH(CH3)NH2 (X) v CH3CH(NH2)COOH (Y). Tn thay th ca X
v Y ln lt l
A. propan-2-amin v axit aminoetanoic
B. propan-2-amin v axit 2-aminopropanoic
C. propan-1-amin v axit 2-aminopropanoic
D. propan-1-amin v axit aminoetanoic.
A. nhit thng, cc amino axit u l nhng cht lng.
B. Cc amino axit thin nhin hu ht l cc -amino axit.
C. Amino axit thuc loi hp cht hu c tp chc.
D. Axit glutamic l thnh phn chnh ca bt ngt.
V d 8. S ng phn amino axit c cng thc phn t C4H9O2N l:
A. 3.
B. 4.
C. 5.
D. 6.
DNG 2. PHNG PHP SO SNH SP XP
V d 9. (A12) Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l:
A. (4), (1), (5), (2), (3).
B. (3), (1), (5), (2), (4).
C. (4), (2), (3), (1), (5).
D. (4), (2), (5), (1), (3).
V d 10. Cho cc cht sau: ancol etylic (1), etylamin (2), metylamin (3), axit axetic (4). Chiu sp xp cc cht
c nhit si tng dn l:
A. (2) < (3) < (4) < (1).
B. (3) < (2) < (1) < (4).
C. (2) < (3) < (4) < (1).
D. (1) < (3) < (2) < (4).
V d 11. Nguyn nhn ch yu lm cho etylamin c nhit si cao hn so vi butan l:
A. etylamin c khi lng phn t thp hn butan.
B. etylamin c kh nng to ra lin kt hiro vi cc phn t H2O.
C. etylamin c khi lng phn t cao hn butan.
D. etylamin c kh nng to ra lin kt hiro gia cc phn t.
DNG 3. NH GI MI TRNG DUNG DCH

V d 12. (A11) Dung dch no sau y lm qu tm i thnh mu xanh ?
A. Dung dch lysin.
B. Dung dch alanin.
C. Dung dch glyxin.
D. Dung dch valin.
V d 13. (A12) Dung dch cht no sau y lm qu tm chuyn thnh mu hng ?

A. axit -aminoglutaric.
B. Axit ,-iaminocaproic.
C. Axit -aminopropionic.
D. Axit aminoaxetic.
V d 14. (A8) C cc dung dch ring bit sau: ClNH3-CH2-COOH (1), C6H5NH3Cl (phenylamoni clorua) (2),
HOOC-CH2-CH2-CH(NH2)-COOH (3), NH2-CH2-CH2-CH(NH2)-COOH (4), NH2-CH2-COONa (5). S lng
cc dung dch c pH < 7 l
A. 2.
B. 4.
C. 5.
D. 3.
V d 15. (B11) Cho ba dung dch c cng nng mol: (1) H 2 NCH 2 COOH, (2) CH 3 COOH,
(3) CH3CH2NH2. Dy xp theo th t pH tng dn l:
A. (3), (1), (2)
B. (1), (2), (3)
C. (2), (3), (1)
D. (2), (1), (3)
DNG 4. PHN BIT NHN BIT

V d 16. Cht no di y phn ng vi dung dch FeCl3 cho kt ta mu nu ?
A. CH3NH2.
B. C6H5OH.
C. C2H5OH.
D. CH3COOH.
V d 17. phn bit anilin v etylamin ng trong 2 l ring bit, ta dng thuc th no?
A. Dung dch Br2.
B. Dung dch HCl.
C. Dung dch NaOH.
D. Dung dch AgNO3.
V d 18. C 3 cht hu c: H2NCH2COOH, CH3CH2COOH v CH3[CH2]3NH2. phn bit dung dch ca ba

hp cht trn, ch cn dng thuc th no sau y:
A. NaOH.
B. phenolphtalein.
C. HCl.
D. Qu tm.
V d 19. C th nhn bit l ng dung dch CH3NH2 bng cch no trong cc cch sau y?
A. Nhn bit bng mi.
B. Thm vi git dung dch H2SO4.
C. Thm vi git dung dch Na2CO3.
D. a a thy tinh nhng vo dung dch HCl m c ln pha trn ming l ng dung dch CH3NH2
c.
V d 20. phn bit ba cht lng benzen, anilin, stiren ng trong 3 l mt nhn c th dng thuc th no
di y ?
A. dung dch phenolphtalein.
B. nc brom.
C. dung dch NaOH.
D. giy qu tm.
M033. PHNG PHP GII BI TON OXI HA AMIN AMINO AXIT

(T liu hc bi)
DNG 1. T CHY
V d 1. (A7) t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh
o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui
NH2-CH2-COONa. Cng thc cu to thu gn ca X l
A. NH2-CH2-COO-C3H7.
B. NH2-CH2-COO-CH3.
C. NH2-CH2-CH2-COOH. D. NH2-CH2-COO-C2H5.
V d 2. (A10) t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm

kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit
nitr nhit thng, gii phng kh nit. Cht X l
A. CH3-CH2-CH2-NH2.
B. CH2=CH-CH2-NH2.
C. CH3-CH2-NH-CH3.
D. CH2=CH-NH-CH3.
V d 3. (B11) Hn hp X gm O2 v O3 c t khi so vi H2 l 22. Hn hp kh Y gm metylamin v

etylamin c t khi so vi H2 l 17,833. t chy hon ton V1 lt Y cn va V2 lt X (bit sn phm chy
gm CO2, H2O v N2, cc cht kh khi o cng iu kin nhit , p sut). T l V1 : V2 l:
A. 3 : 5.
B. 5 : 3.
C. 2 : 1.
D. 1 : 2.
V d 4. t chy hon ton m gam mt amin n chc X bng lng khng kh va thu c 1,76 gam
CO2; 1,26 gam H2O v V lt N2 (ktc). Gi thit khng kh ch gm N2 v O2 trong oxi chim 20% v th
tch khng kh. Cng thc phn t ca X v gi tr ca V ln lt l
A. X l C2H5NH2; V = 6,72 lt.
B. X l C3H7NH2; V = 6,944 lt.
C. X l C3H7NH2; V = 6,72 lt.
D. X l C2H5NH2; V = 6,944 lt.
V d 5. (B10) t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va thu c 0,5 mol hn
hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l
A. 0,1.
B. 0,4.
C. 0,3.
D. 0,2.
V d 6. Hn hp X gm ba amin n chc l ng ng k tip nhau. t chy hon ton 11,8 gam X thu
c 16,2 gam H2O v 13,44 lt CO2 v kh V lt kh N2 (ktc). Ba amin trn l:
A. CH2=CHNH2, CH3CH=CHNH2, CH3CH2CH=CHNH2.
B. CH3CH2NH2, CH3CH2CH2NH2, CH3CH2CH2CH2NH2.
C. CH2=CHNH2, CH2=CHCH2NH2, CH2=CHCH2CH2NH2.
D. CHCNH2, CHCCH2NH2, CHCCH2CH2NH2.
V d 7. (A10) Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn
ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol
N2. Cc gi tr x, y tng ng l
A. 7 v 1,0.
B. 8 v 1,5.
C. 8 v 1,0.
D. 7 v 1,5.
V d 8. (A12) Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip

(MX < MY). t chy hon ton mt lng M cn dng 4,536 lt O2 (ktc) thu c H2O, N2 v 2,24 lt CO2
(ktc). Cht Y l
A. etylmetylamin.
B. butylamin.
C. etylamin.
D. propylamin.
V d 9. (B12) t chy hon ton 50 ml hn hp kh X gm trimetylamin v 2 hirocacbon ng ng k

tip bng mt lng oxi va , thu c 375 ml hn hp Y gm kh v hi. Dn ton b Y i qua dung dch
H2SO4 c (d). Th tch kh cn li l 175 ml. Cc th tch kh v hi o cng iu kin. Hai hirocacbon
l
A. C2H4 v C3H6.
B. C3H6 v C4H8.
C. C2H6 v C3H8.
D. C3H8 v C4H10.
DNG 2. PHN NG VI HNO2

V d 10. (B8NC) Mui C6H5N2+Cl (phenyliazoni clorua) c sinh ra khi cho C6H5NH2 (anilin) tc dng
vi NaNO2 trong dung dch HCl nhit thp (0 - 5oC). iu ch c 14,05 gam C6H5N2+Cl (vi hiu
sut 100%), lng C6H5NH2 v NaNO2 cn dng va l
A. 0,1 mol v 0,4 mol.
B. 0,1 mol v 0,3 mol.
C. 0,1 mol v 0,1 mol.
D. 0,1 mol v 0,2 mol.
V d 11. (C11) Amin X c phn t khi nh hn 80. Trong phn t X nit chim 19,18% v khi lng. Cho
X tc dng vi dung dch hn hp gm KNO2 v HCl thu c ancol Y. Oxi ha khng hon ton Y thu c
xeton Z. Pht biu no sau y ng ?
A. Tch nc Y ch thu c mt anken duy nht.
B. Trong phn t X c mt lin kt .
C. Tn thay th ca Y l propan-2-ol.
D. Phn t X c mch cacbon khng phn nhnh.

M034. PHNG PHP GII BI TON TRUNG HA AMIN AMINO AXIT

(T liu hc bi)
Dng 1. AMIN
V d 1. (C7) trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung
dch HCl 1M. Cng thc phn t ca X l
A. C2H7N.
B. C3H7N.
C. C3H5N.
D. CH5N.
V d 2. (C12) Cho 20 gam hn hp gm hai amin no, n chc, mch h tc dng va vi V ml dung
dch HCl 1M, thu c dung dch cha 31,68 gam hn hp mui. Gi tr ca V l
A. 200.
B. 100.
C. 320.
D. 50.
V d 3. (A9) Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S
ng phn cu to ca X l
A. 4.
B. 8.
C. 5.
D. 7.
V d 4. (C10) Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng
ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l
A. CH3NH2 v C2H5NH2.
B. C2H5NH2 v C3H7NH2.
C. C3H7NH2 v C4H9NH2.
D. CH3NH2 v (CH3)3N.
V d 5. (B10NC) Trung ha hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng
axit HCl, to ra 17,64 gam mui. Amin c cng thc l
A. H2NCH2CH2CH2CH2NH2.
B. CH3CH2CH2NH2.
C. H2NCH2CH2CH2NH2.
D. H2NCH2CH2NH2.
Dng 2. AMINO AXIT

V d 6. (C8) Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc
dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc
ca X l
A. H2NC3H6COOH.
B. H2NCH2COOH.
C. H2NC2H4COOH.
D. H2NC4H8COOH.
V d 7. (A7) -aminoaxit X cha mt nhm NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c
13,95 gam mui khan. Cng thc cu to thu gn ca X l
A. NH2CH2COOH.
B. H2NCH2CH2COOH.
C. CH3CH2CH(NH2)COOH.
D. CH3CH(NH2)COOH.
V d 8. (B9) Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam
mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l
A. H2NC2H3(COOH)2.
B. H2NC3H5(COOH)2.
C. (H2N)2C3H5COOH.
D. H2NC3H6COOH.
V d 9. (A9) Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1
mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 m1 = 7,5. Cng thc
phn t ca X l
A. C5H9O4N.
B. C4H10O2N2.
C. C5H11O2N.
D. C4H8O4N2.
V d 10. (C12) Cho 14,55 gam mui H2NCH2COONa tc dng hon ton vi dung dch HCl d, thu c
dung dch X. C cn ton b dung dch X, thu c bao nhiu gam mui khan ?
A. 16,73 gam
B. 25,50 gam
C. 8,78 gam
D. 20,03 gam
Dng 3. BI TON HN HP
V d 11. (B10) Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch
NaOH (d), thu c dung dch Y cha (m + 30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton
vi dung dch HCl, thu c dung dch Z cha (m + 36,5) gam mui. Gi tr ca m l
A. 112,2.
B. 165,6.
C. 123,8.
D. 171,0.
V d 12. (B12) Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c
dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m gam
mui. Gi tr ca m l
A. 44,65
B. 50,65
C. 22,35
D. 33,50
V d 13. (A10) Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c
dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn
ng l
A. 0,70.
B. 0,50.
C. 0,65.
D. 0,55.
V d 14. Cho 26,7 gam hn hp X gm hai amino axit l NH2CH2CH2COOH v CH3CH(NH2)COOH tc

dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y tc dng va vi 500 ml dung
dch HCl 1M. Gi tr ca V l
A. 500.
B. 300.
C. 200.
D. 150.

M035. L THUYT TRNG TM V PEPTIT PROTEIN

(T liu hc bi)
Dng 1. Khi nim PEPTIT v PROTEIN

V d 1. (A12) Pht biu no sau y l ng ?
A. Mui phenylamoni clorua khng tan trong nc.
B. Tt c cc peptit u c phn ng mu biure.
C. H2N-CH2-CH2-CO-NH-CH2-COOH l mt ipeptit.
D. iu kin thng, metylamin v imetylamin l nhng cht kh c mi khai.
A. Amino axit l hp cht c tnh lng tnh.
B. Trong mi trng kim, ipetit mch h tc dng c vi Cu(OH)2 cho hp cht mu tm.
C. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit.
D. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit.
V d 3. (B7) Mt trong nhng im khc nhau ca protein so vi lipit v glucoz l
A. protein lun l cht hu c no.
B. protein lun cha chc hiroxyl.
C. protein c khi lng phn t ln hn.
D. protein lun cha nit.
V d 4. (B11) Pht biu khng ng l
A. Etylamin tc dng vi axit nitr nhit thng to ra etanol
B. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi chc triu
C. Metylamin tan trong nc cho dung dch c mi trng baz
D. ipeptit glyxylalanin (mch h) c 2 lin kt peptit
V d 5. (C12) Pht biu no sau y l sai ?
A. Tripeptit Gly-Ala-Gly c phn ng mu biure vi Cu(OH)2.
B. Trong phn t ipeptit mch h c hai lin kt peptit.
C. Protein n gin c to thnh t cc gc -amino axit.
D. Tt c cc peptit u c kh nng tham gia phn ng thy phn.
V d 6. (A11) Khi ni v peptit v protein, pht biu no sau y l sai ?
A. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit.
B. Thy phn hon ton protein n gin thu c cc -amino axit.
C. Protein c phn ng mu biure vi Cu(OH)2.
D. Tt c cc protein u tan trong nc to thnh dung dch keo.
V d 7. (A10) Pht biu ng l:
A. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m.
B. Khi thu phn n cng cc protein n gin s cho hn hp cc -aminoaxit.
C. Axit nucleic l polieste ca axit photphoric v glucoz.
D. Enzim amilaza xc tc cho phn ng thu phn xenluloz thnh mantoz.
Dng 2. Xc nh NG PHN CU TRC ca oligopeptit

V d 8. (A9) Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l
A. dung dch NaOH.
B. dung dch NaCl.
D. dung dch HCl.
C. Cu(OH)2 trong mi trng kim.
V d 9. C cc dung dch ring bit sau: glucoz, glixerol, metanol, lng trng trng. Thuc th phn bit
cc dung dch trn l
A. dung dch AgNO3/NH3.
B. Na.
D. nc brom.
C. Cu(OH)2/OH.
V d 10. (B8) un nng cht NH2-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau
khi cc phn ng kt thc thu c sn phm l:
A. NH2-CH2-COOH, NH2-CH(CH3)-COOH.
B. H3N+-CH2-COOHCl, H3N+-CH2-CH2-COOHCl.
C. H3N+-CH2-COOHCl, H3N+-CH(CH3)-COOHCl. D. H2N-CH2-COOH, NH2-CH2-CH2-COOH.

V d 11. (C10) Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu
ipeptit khc nhau ?
A. 3.
B. 2.
C. 1.
D. 4.
V d 12. (B10) Thu phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1
mol valin (Val) v 1 mol Phenylalanin (Phe). Thu phn khng hon ton X thu c ipeptit Val-Phe v
tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l
A. Gly-Phe-Gly-Ala-Val. B. Gly-Ala-Val-Val-Phe. C. Gly-Ala-Val-Phe-Gly. D. Val-Phe-Gly-Ala-Gly.
V d 13. Peptit X c cu to: H2NCH2CONHCH(CH3)CONHCH2COOH.
Tn gi ca peptit X l:
A. glixinalaninglyxin.
B. glixylalanylglyxin.
C. alaningyxylalanin.
D. alanylglyxylglyxyl.
V d 14. (B9) S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l
A. 3.
B. 1.
C. 2.
D. 4.
V d 15. Tin hnh trng ngng hn hp glyxin (Gly) v alanin (Ala). S tripeptit (c cu to t c hai amino axit trn) c th to thnh l:
A. 3.
B. 6.
C. 4.
D. 5.
V d 16. Nu phn t peptit cha n gc -amino axit khc nhau (u ch c 1 nhm -NH2 v 1 nhm -COOH)
th s ng phn loi peptit l
n!
A. n.
B. n2.
C.
.
D. n !.
2
V d 17. (A10) C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3
aminoaxit: glyxin, alanin v phenylalanin ?
A. 6.
B. 9.
C. 4.
D. 3.
V d 18. T ba -amino axit X, Y, Z (phn t u ch c 1 nhm -NH2 v 1 nhm -COOH) c th to bao
nhiu ipeptit cu to bi hai gc amino axit khc nhau ?
A. 3.
B. 4.
C. 6.
D. 9.
M036. PHNG PHP GII CC DNG TON TRNG TM V PEPTIT PROTEIN

(T liu hc bi)
V d 1. Bit mi phn t hemoglobin ch cha 1 nguyn t Fe, vi hm lng 0,4%. Phn t khi gn ng
ca mt hemoglobin (hng cu ca mu) l:
A. 1.396
B. 1.400
C. 13.963
D. 14.000
V d 2. Thy phn hon ton 500 gam protein X thu c 14,85 gam glyxin. Nu phn t khi ca X l
500.000 th s mt xch glyxin trong X l:
A. 166.
B. 198.
C. 209.
D. 261.
V d 3. Mt -aminoaxit c cng thc phn t l C2H5NO2, khi t chy 0,1 mol oligopeptit X to nn t
-aminoaxit th thu c 12,6 gam nc. Vy X l
A. ipeptit.
B. tetrapeptit.
C. tripeptit.
D. pentapeptit.
V d 4. Phn t khi ca mt pentapeptit bng 373. Bit pentapeptit ny c to nn t mt amino axit X
m trong phn t ch c cha mt nhm amino v mt nhm cacboxyl. Khi lng mol ca X l
A. 57,0.
B. 60,6.
C. 75,0.
D. 89,0.
V d 5. Thy phn mt tripeptit X sn phm thu c ch c alanin. t chy m gam X c 1,05 gam nit. Gi
tr ca m l:
A. 4,725.
B. 5,775.
C. 5,125.
D. 5,725.
V d 6. (B10) ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h,
trong phn t cha mt nhm NH2 v mt nhm COOH). t chy hon ton 0,1 mol Y, thu c tng khi
lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc
vi trong d, to ra m gam kt ta. Gi tr ca m l
A. 120.
B. 60.
C. 30.
D. 45.
V d 7. Cho 15 gam glyxin tc dng va vi 8,9 gam alanin thu c m gam hn hp tripeptit mch h.
Gi tr ca m l
A. 22,10.
B. 23,9.
C. 18,5.
D. 20,3.
V d 8. un nng hn hp gm: 22,5 gam glyxin ; 17,8 gam alanin ; 11,7 gam valin, vi xc tc thch hp,
sau khi phn ng xy ra hon ton thu c m gam hn hp X gm 6 tripeptit. Gi tr ca m l:
A. 44,8 gam.
B. 52 gam.
C. 43 gam.
D. 41,2 gam.
V d 9. (A11) Thy phn ht m gam tetrapeptit AlaAlaAlaAla (mch h) thu c hn hp gm 28,48
gam Ala, 32 gam AlaAla v 27,72 gam AlaAlaAla. Gi tr ca m l:
A. 111,74
B. 81,54
C. 90,6
D. 66,44
V d 10. (A11) Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm cc
amino axit (cc amino axit ch c mt nhm amino v mt nhm cacbonyl trong phn t). Nu cho 1/10 hn
hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l
A. 7,09 gam.
B. 16,30 gam.
C. 8,15 gam.
D. 7,82 gam.
V d 11. (C12) Thy phn hon ton m gam ipeptit Gly-Ala (mch h) bng dung dch KOH va , thu
c dung dch X. C cn ton b dung dch X thu c 2,4 gam mui khan. Gi tr ca m l
A. 1,22
B. 1,46
C. 1,36
D. 1,64.
V d 12. (B12) un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol tripeptit mch h Y vi
600 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch thu c 72,48 gam
mui khan ca cc amino axit u c mt nhm -COOH v mt nhm -NH2 trong phn t. Gi tr ca m l
A. 51,72
B. 54,30
C. 66,00
D. 44,48
M039. PHNG PHP XC NH CU TO POLIME

(T liu hc bi)
Dng 1. H s polime ha S lng mt xch

V d 1. Phn t khi trung bnh ca PE, nilon-6 v xenluloz ln lt l: 420000; 1582000 v 2106000. H
s polime ha ca chng khng th t gi tr no ?
A. 15000.
B. 14000.
C. 13000.
D. 12456.
V d 2. (A08) Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l
17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l
A. 113 v 152.
B. 113 v 114.
C. 121 v 152.
D. 121 v 114.
V d 3. S mt xch vinyl clorua c trong 100 gam poli(vinyl clorua) l
B. 9,63.1023.
C. 9,63.1022.
D. 9,63.1021.
A. 9,63.1024.
Dng 2. Xc nh cu to ca polime
V d 4. Polime X c khi lng mol phn t l 400.000 gam/mol v h s trng hp l n = 4000. X l polime
no di y?
CH2 CH2 n
CF2 CF2 n
A.
B.
CH2 CH
CH2 CH
C.
D.
Cl n
CH3 n
V d 5. Polime X cha 38,4% C, 4,8% H, cn li l Cl v khi lng. Cng thc phn t ca X l
A. (C2HCl3)n.
B. (C2H3Cl)n.
C. (CHCl)n.
D. (C3H4Cl2)n.
V d 6. Tin hnh phn ng trng hp buta1,3ien ngoi cao su Buna cn sinh ra sn phm ph X. X l
cht lng; 16,2 gam X lm mt mu va ht 200 ml dung dch Br2 1,5M. Cng thc cu to ca X l
A.
B.
C.
D.
Dng 3. Xc nh t l mt xch trong polime

V d 7. (A7) Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo
phn ng vi k mt xch trong mch PVC. Gi tr ca k l
A. 3.
B. 6.
C. 4.
D. 5.
V d 8. Cao su lu ha cha khong 2% lu hunh. C k mt xch isopren c mt cu ni isunfua SS,
bit rng S thay th cho H nhm metylen trong mch cao su. Gi tr ca k l
A. 23.
B. 24.
C. 46.
D. 48.
V d 9. C 2,844 gam cao su buna-S phn ng va ht vi 1,731 gam Br2 trong CCl4. T l mt xch butaien
v stiren trong cao su buna-S l
A. 1 : 3.
B. 1 : 2.
C. 2 : 3.
D. 3 : 5.
V d 10. Khi tin hnh ng trng hp buta-1,3-ien v acrilonitrin vi xc tc Na thu c mt loi cao su
buna-N cha 10,44 % nit v khi lng. T l s mol buta-1,3-ien v acrilonitrin trong cao su trn l
A. 2 : 3.
B. 2 : 1.
C. 3 : 2.
D. 4 : 3.
M040. PHNG PHP XC NH LNG CHT HIU SUT

TRONG PHN NG POLIME HA
(T liu hc bi)
Dng 1. Tnh hiu sut phn ng to polime

V d 1. Thc hin phn ng trng hp 25 gam vinyl clorua thu c hn hp X. Lng hn hp ny c kh
nng lm mt mu 80 ml dung dch brom 1,0M. Hiu sut ca phn ng trng hp l
A. 80%.
B. 65%.
C. 50%.
D. 40%.
V d 2. Thy phn 86,0 gam poli(vinyl axetat) iu ch poli(vinyl ancol) thu c 48,2 gam polime. %
khi lng ca polime cha b thy phn l
A. 20%.
B. 8%,
C. 2,5%.
D. 10%.
V d 3. Tin hnh tng hp PVC bng cch un nng 37,5 gam vinyl clorua vi mt lng nh (0,3 0,7%)
cht xc tc benzoyl peoxit. Cho ton b hn hp sau phn ng ( loi ht xc tc) vo 2,0 lt dung dch Br2
0,1M; sau cho thm KI d thy to thnh 20,32 gam I2. Hiu sut phn ng tng hp PVC l
A. 66,7%.
B. 80,0%.
C. 86,7%.
D. 93,3%.
V d 4. T nitron (olon) c sn xut t propan qua cc giai on sau:
CH3CH2CH3 CH2=CHCH3 CH2=CHCN T nitron
T 10000 m3 kh thin nhin (ktc), c cha 11% propan v th tch, tng hp c 1,60 tn t nitron. Nu coi
hiu sut ca mi giai on phn ng l nh nhau th hiu sut ca mi giai on l
A. 61,5%.
B. 85,0%.
C. 67,6%.
D. 87,8%.
Dng 4. Tnh lng cht to trong phn ng polime ha
V d 5. Trng ngng axit -aminocaproic thu c m kg polime v 12,6 kg H2O vi hiu sut phn ng H%.
Gi tr ca m l
A. 71,19.
B. 79,1.
C. 91,7.
D. 90,4.
V d 6. (A8) Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s
trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu
sut ca c qu trnh l 50%)
A. 224,0.
B. 286,7.
C. 358,4.
D. 448,0.
V d 7. iu ch 100 gam thu tinh hu c cn bao nhiu gam axit hu c v bao nhiu gam ancol, bit
hiu sut qu trnh phn ng t 80%.
A. 68,8 gam axit v 25,6 gam ancol.
B. 86,0 gam axit v 32 gam ancol.
C. 107,5 gam axit v 40 gam ancol.
D. 107,5 gam axit v 32 gam ancol.
V d 8. T tinh bt c th iu ch cao su buna theo s v hiu sut mi giai on nh sau:
Etanol
Buta-1,3-ien
Glucoz
poli(buta-1,3-ien)
Tinh bt
Khi s dng 24,3 tn tinh bt th khi lng cao su buna iu ch c l bao nhiu (gi thit cao su buna gm
70% l polibuta-1,3-ien) ?
A. 3280,5 kg.
B. 4686,4 kg.
C. 2296,35 kg.
D. 8100 kg.
90%
75%
75%
80%

M042. PHNG PHP XC NH V TR CU TO CA KIM LOI

(T liu hc bi)
A. 3; 4; 3.
B. 3; 5; 2.
C. 4; 4; 2.
D. 4; 5; 1.
A. 68%.
B. 72%.
C. 74%.
D. 76%.
K = 39, NA = 6,02.1023)
A. 0,65.1022 gam.
B. 1,30.1022 gam.
C. 2,59.1022 gam.
D. 3,89.1022 gam.
tnh theo l thuyt l:
A. 0,196 nm.
B. 0,185 nm.
C. 0,168 nm.
D. 0,155 nm.
A. 11; 9.
B. 11; 10.
C. 14; 9.
D. 14; 10.

A. [Ar] 3d44s2 v [Ar] 3d94s2.
B. [Ar] 3d54s1 v [Ar] 3d94s2.
C. [Ar] 3d44s2 v [Ar] 3d104s1.
D. [Ar] 3d54s1 v [Ar] 3d104s1.

ca X v Y2+ ln lt l
A. [Ar] 3d44s2 v [Ar] 3d44s2.
B. [Ar] 3d54s1 v [Ar] 3d6.
C. [Ar] 3d54s1 v [Ar] 3d54s1.
D. [Ar] 3d54s1 v [Ar] 3d64s2.
V d 9. (A11) Cu hnh electron ca ion Cu2+ v Cr3+ ln lt l

A. [Ar] 3d9 v [Ar] 3d14s2.
B. [Ar] 3d74s2 v [Ar] 3d14s2.
C. [Ar] 3d9 v [Ar] 3d3.
D. [Ar] 3d74s2 v [Ar] 3d3.
V d 10. (B10) Mt ion M3+ c tng s ht proton, ntron, electron l 79, trong s ht mang in nhiu hn
s ht khng mang in l 19. Cu hnh electron ca nguyn t M l
A. [Ar]3d54s1.
B. [Ar]3d64s2.
C. [Ar]3d64s1.
D. [Ar]3d34s2.

A. [Ar] 3d54s1.
B. [Ar] 3d44s2.
C. [Ar] 4s13d5.
D. [Ar] 4s23d4.
hc, nguyn t X thuc
A. chu k 4, nhm VIIIA.
B. chu k 4, nhm IIA.
A. Mg (Z = 12) v Ca (Z = 20).
B. Al (Z = 13) v K (Z = 19).
C. Si (Z = 14) v Ar (Z = 18).
D. Na (Z = 11) v Sc (Z = 21).
A. Cr (Z = 24).
B. Mn (Z = 25).
C. Fe (Z = 26).
D. Co (Z = 27).

M042. PHNG PHP XC NH V TR CU TO CA KIM LOI

(T liu hc bi)
A. 3; 4; 3.
B. 3; 5; 2.
C. 4; 4; 2.
D. 4; 5; 1.
A. 68%.
B. 72%.
C. 74%.
D. 76%.
K = 39, NA = 6,02.1023)
A. 0,65.1022 gam.
B. 1,30.1022 gam.
C. 2,59.1022 gam.
D. 3,89.1022 gam.
tnh theo l thuyt l:
A. 0,196 nm.
B. 0,185 nm.
C. 0,168 nm.
D. 0,155 nm.
A. 11; 9.
B. 11; 10.
C. 14; 9.
D. 14; 10.

A. [Ar] 3d44s2 v [Ar] 3d94s2.
B. [Ar] 3d54s1 v [Ar] 3d94s2.
C. [Ar] 3d44s2 v [Ar] 3d104s1.
D. [Ar] 3d54s1 v [Ar] 3d104s1.

ca X v Y2+ ln lt l
A. [Ar] 3d44s2 v [Ar] 3d44s2.
B. [Ar] 3d54s1 v [Ar] 3d6.
C. [Ar] 3d54s1 v [Ar] 3d54s1.
D. [Ar] 3d54s1 v [Ar] 3d64s2.
V d 9. (A11) Cu hnh electron ca ion Cu2+ v Cr3+ ln lt l

A. [Ar] 3d9 v [Ar] 3d14s2.
B. [Ar] 3d74s2 v [Ar] 3d14s2.
C. [Ar] 3d9 v [Ar] 3d3.
D. [Ar] 3d74s2 v [Ar] 3d3.
V d 10. (B10) Mt ion M3+ c tng s ht proton, ntron, electron l 79, trong s ht mang in nhiu hn
s ht khng mang in l 19. Cu hnh electron ca nguyn t M l
A. [Ar]3d54s1.
B. [Ar]3d64s2.
C. [Ar]3d64s1.
D. [Ar]3d34s2.

A. [Ar] 3d54s1.
B. [Ar] 3d44s2.
C. [Ar] 4s13d5.
D. [Ar] 4s23d4.
hc, nguyn t X thuc
A. chu k 4, nhm VIIIA.
B. chu k 4, nhm IIA.
A. Mg (Z = 12) v Ca (Z = 20).
B. Al (Z = 13) v K (Z = 19).
C. Si (Z = 14) v Ar (Z = 18).
D. Na (Z = 11) v Sc (Z = 21).
A. Cr (Z = 24).
B. Mn (Z = 25).
C. Fe (Z = 26).
D. Co (Z = 27).

M043. DY IN HA TNH CHT CHUNG CA KIM LOI

(T liu hc bi)
V d 1. Cho cc dy so snh sau:

(2) Tnh dn in: Cu < Ag < Au.
(1) Tnh do: Al < Ag < Au.
(3) Tnh dn nhit: Fe < Al < Cu.
(4) Khi lng ring: Li < Pb < Os.
(6) Tnh cng: Cs < Al < Cr.
(5) Nhit nng chy: Hg < Pt < W.
S so snh ng l:
A. 3.
B. 4.
C. 5.
D. 6.
V d 2. (B12) Pht biu no sau y l sai ?
A. Nguyn t kim loi thng c 1, 2 hoc 3 electron lp ngoi cng.
B. Cc nhm A bao gm cc nguyn t s v nguyn t p.
C. Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim.
D. Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy c.
V d 3. (C8) Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu.
Trong phn ng trn xy ra
A. s kh Fe2+ v s oxi ha Cu.
B. s kh Fe2+ v s kh Cu2+.
D. s oxi ha Fe v s kh Cu2+.
C. s oxi ha Fe v s oxi ha Cu.
V d 4. (C8NC) Hai kim loi X, Y v cc dung dch mui clorua ca chng c cc phn ng ha hc sau:
X + 2YCl3 XCl2 + 2YCl2
;
Y + XCl2 YCl2 + X
Pht biu ng l:
A. Ion Y2+ c tnh oxi ha mnh hn ion X2+.
B. Kim loi X kh c ion Y2+.
C. X c tnh kh mnh hn Y.
D. Ion Y3+ c tnh oxi ha mnh hn ion X2+.
V d 5. (A11) Cho cc phn ng sau:
Fe + 2Fe(NO3)3 3Fe(NO3)2
;
AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag
Dy sp xp theo th t tng dn tnh oxi ha ca cc ion kim loi l:
A. Fe2+, Fe3+, Ag+.
B. Ag+, Fe2+, Fe3+.
C. Fe2+, Ag+, Fe3+.
D. Ag+, Fe3+, Fe2+.
V d 6. (B8) Cho bit cc phn ng xy ra sau:
2FeBr2 + Br2 2FeBr3
2NaBr + Cl2 NaCl + Br2
Pht biu ng l:
A. Tnh kh ca Cl mnh hn Br.
B. Tnh oxi ho ca Br2 mnh hn Cl2.
2+
C. Tnh kh ca Br mnh hn Fe .
D. Tnh oxi ho ca Cl2 mnh hn ca Fe3+.
V d 7. Mui Fe2+ lm mt mu dung dch KMnO4 trong mi trng axit to ra ion Fe3+. Cn ion Fe3+ tc
dng vi I to ra I2 v Fe2+. Sp xp cc cht oxi ho Fe3+, I2 v MnO4 theo th t mnh dn l:
A. MnO4 < Fe3+ < I2.
B. MnO4 < I2 < Fe3+.
C. I2 < Fe3+ < MnO4 .
D. Fe3+ < I2 < MnO4 .
V d 8. (C7) Th t mt s cp OXH - kh nh sau: Fe2+Fe; Cu2+/Cu; Fe3+/Fe2+.

Cp cht khng phn ng vi nhau l
A. Cu v dung dch FeCl3.
B. dung dch FeCl2 v dung dch CuCl2.
C. Fe v dung dch CuCl2.
D. Fe v dung dch FeCl3.
V d 9. (C8) Cp cht khng xy ra phn ng ho hc l

A. Cu + dd FeCl3.
B. Fe + dd HCl.
C. Fe + dd FeCl3.
D. Cu + dd FeCl2.
V d 10. (C7) kh ion Cu2+ trong dung dch CuSO4 c th dng kim loi
A. K.
B. Na.
C. Fe.
D. Ba.
V d 11. (C7) kh ion Fe3+ trong dung dch thnh ion Fe2+ c th dng mt lng d
A. kim loi Cu.
B. kim loi Ag.
C. kim loi Ba.
D. kim loi Mg.
V d 12. (C9) Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c vi

dung dch AgNO3 ?
A. Fe, Ni, Sn.
B. Al, Fe, CuO.
C. Zn, Cu, Mg.
D. Hg, Na, Ca.
V d 13. (A10) Cc cht va tc dng c vi dung dch HCl va tc dng c vi dung dch AgNO3 l:
A. MgO, Na, Ba.
B. Zn, Ni, Sn.
C. Zn, Cu, Fe.
D. CuO, Al, Mg.
V d 14. (C12) Cho dy cc kim loi: Cu, Ni, Zn, Mg, Ba, Ag. S kim loi trong dy phn ng c vi dung
dch FeCl3 l
A. 3
B. 5
C. 6
D. 4
V d 15. Cho dy cc kim loi: Li, Be, Na, Mg, Al, K, Ca, Cr, Zn, Rb, Sr, Ba. S kim loi trong dy phn ng
c vi nc nhit thng l
A. 7.
B. 8.
C. 9.
D. 10.

M045. KIM LOI TC DNG VI HCl, H2SO4 long

(T liu hc bi)
V d 1. Ho tan hon ton 15,4 gam hn hp Mg v Zn trong dung dch HCl d thy c 6,72 lt kh thot ra
( ktc) v dung dch X. C cn dung dch X c bao nhiu gam mui khan ?
A. 26,05 gam.
B. 26,35 gam.
C. 36,7 gam.
D. 37,3 gam.
V d 2. (C8NC) Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch H2SO4 long
nng (trong iu kin khng c khng kh), thu c dung dch X v 7,84 lt kh H2 (ktc). C cn dung dch X
(trong iu kin khng c khng kh) c m gam mui khan. Gi tr ca m l
A. 42,6.
B. 45,5.
C. 48,8.
D. 47,1.
V d 3. Ha tan m gam hn hp X (gm Al, Fe, Zn v Mg) bng dung dch HCl d. Sau phn ng, khi
lng dung dch axit tng thm (m 2) gam. Khi lng (gam) ca mui to thnh trong dung dch sau phn
ng l
A. m + 34,5.
B. m + 35,5.
C. m + 69.
D. m + 71.
V d 4. Cho 33,4 gam hn hp bt mn X (gm Al, Cr, Fe, Cu v Ag) vo dung dch H2SO4 long, nng. Sau
khi cc phn ng xy ra hon ton, c 17,2 gam cht rn tch ra, ng thi thu c 11,2 lt kh (ktc). tng
khi lng ca dung dch sau phn ng so vi khi lng dung dch H2SO4 ban u l
A. 15,2 gam.
B. 15,7 gam.
C. 32,4 gam.
D. 32,9 gam.
V d 5. (A9) Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10%, thu
c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l
A. 101,68 gam.
B. 88,20 gam.
C. 101,48 gam.
D. 97,80 gam.
V d 6. (C7) Ho tan hon ton hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20%, thu
c dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76%. Nng phn trm ca MgCl2 trong dung
dch Y l
A. 24,24%.
B. 15,76%.
C. 28,21%.
D. 11,79%.
V d 7. (C8) Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp HCl 1M v H2SO4
0,28M thu c dung dch X v 8,736 lt kh H2 (ktc). C cn dung dch X thu c lng mui khan l
A. 38,93 gam.
B. 103,85 gam.
C. 25,95 gam.
D. 77,86 gam.
V d 8. (A7) Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4
0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y c pH l
A. 1.
B. 6.
C. 7.
D. 2.
V d 9. Cho m gam Na tan ht vo 100 ml dung dch gm (H2SO4 0,5M v HCl 1M) thu c 4,48 lt kh H2
( ktc). C cn dung dch sau phn ng khi lng cht rn thu c l
A. 18,55 gam.
B. 17,55 gam.
C. 20,95 gam.
D. 12,95 gam.
V d 10. Cho m gam hn hp Mg, Ni, Fe vo 500 ml dung dch X (cha hn hp axit HCl 2M v axit H2SO4
0,8M), thu c 15,68 lt H2 ( ktc) v dung dch Y. kt ta va ht cc ion c trong Y, cn dng t nht V
lt dung dch NaOH 2M. Gi tr ca V l
A. 0,7.
B. 0,9.
C. 1,4.
D. 1,8.
M046. KIM LOI TC DNG VI HNO3, H2SO4 c

(T liu hc bi Phn I)
V d 1. Cho 8,37 gam hn hp (Fe, Cu, Al) tc dng hon ton vi lng d axit H2SO4 c nng c 0,2
mol SO2 l sn phm kh duy nht. Khi lng mui to thnh l:
A. 27,57 gam.
B. 21,17 gam.
C. 46,77 gam.
D. 11,57 gam.
V d 2. Ha tan hon ton 11,90 gam hn hp 3 kim loi X, Y, Z bng dung dch H2SO4 c, nng thu c
7,616 lt kh SO2 (ktc), 0,640 gam S v dung dch T. C cn dung dch T thu c m gam mui khan. Gi tr
ca m l:
A. 50,30.
B. 30,50.
C. 35,00.
D. 30,05.
V d 3. Cho 7,40 gam hn hp kim loi Ag, Al, Mg tan ht trong dung dch H2SO4 c nng d thu c hn
hp sn phm kh X (gm 0,015 mol S v 0,0125 mol H2S) v dung dch Y. C cn dung dch Y thu c bao
nhiu gam mui khan ?
A. 12,65 gam.
B. 15,62 gam.
C. 16,52 gam.
D. 15,26 gam.
V d 4. Ha tan ht hn hp X gm 16,8 gam Fe ; 2,7 gam Al v 5,4 gam Ag tc dng vi H2SO4 c nng
d ch thot ra kh SO2 (sn phm kh duy nht ca S). S mol H2SO4 tham gia phn ng l
A. 1,20 mol.
B. 1,25 mol.
C. 1,45 mol.
D. 1,85 mol.
V d 5. (B7) Cho 6,72 gam Fe vo dung dch cha 0,3 mol H2SO4 c, nng (gi thit SO2 l sn phm kh
duy nht). Sau khi phn ng xy ra hon ton, thu c
A. 0,12 mol FeSO4.
B. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4.
C. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.
D. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.
V d 6. (B8) Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra
3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc
phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 12,3.
B. 15,6.
C. 10,5.
D. 11,5.
V d 7. (A7) Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt (ktc)
hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng
19. Gi tr ca V l
A. 2,24.
B. 4,48.
C. 5,60.
D. 3,36.
V d 8. Ha tan hon ton 12 gam hn hp X gm Al, Fe, Cu bng dung dch HNO3 d thu c 6,72 lt
(ktc) hn hp kh (NO, NO2) c khi lng 12,2 gam. Khi lng mui nitrat sinh ra l (bit ch xy ra 2 qu
trnh kh).
A. 30,6 gam
B. 39,9 gam
C. 43,0 gam
D. 55,4 gam
V d 9. (A11) un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung

dch HNO3. Khi cc phn ng kt thc, thu dc 0,75m gam cht rn, dung dch X v 5,6 lt hn hp kh (ktc)
gm NO v NO2 (khng c sn phm kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca
m l
A. 44,8.
B. 33,6.
C. 40,5.
D. 50,4.
V d 10. (B8) Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm
0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO)
A. 0,8 lt.
B. 1,0 lt.
C. 0,6 lt.
D. 1,2 lt.
V d 11. Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M. Sau
khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A. 0,672
B. 0,448
C. 0,746
D. 1,792
V d 12. (A11) Cho 7,68 gam Cu vo 200ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi cc phn
ng xy ra hon ton (sn phm kh duy nht l NO), c cn cn thn ton b dung dch sau phn ng th khi
lng mui khan thu c l:
A. 19,76 gam.
B. 20,16 gam.
C. 19,20 gam.
D. 22,56 gam.
V d 13. (A9) Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4
0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh
duy nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti
thiu ca V l
A. 240.
B. 120.
C. 360.
D. 400.

M046. KIM LOI TC DNG VI HNO3, H2SO4 c

V d 1. Khi cho 9,6 gam Mg tc dng ht vi dung dch H2SO4 thy c 0,5 mol H2SO4 tham gia phn ng thu
c dung dch X v sn phm kh Y. Cht Y l
A. SO2
B. S
C. H2S
D. H2.
V d 2. Cho 1,26 gam hn hp Mg v Al (trn theo t l mol 3 : 2) tc dng vi H2SO4 c, nng va , thu
c 0,02 mol sn phm X (sn phm kh duy nht). X l cht no di y ?
A. SO2
B. S
C. H2S
D. H2
V d 3. Cho 0,04 mol Zn tan ht trong dung dch HNO3 thy thot ra 0,01 mol kh X l sn phm kh duy
nht (ktc). X l
A. NH3
B. N2
C. NO
D. N2O
V d 4. Ho tan 5,95 gam hn hp Al, Zn c t l mol 2:1 bng HNO3 long d thu c 0,896 lt kh X l
sn phm kh duy nht. Xc nh X.
A. N2.
B. N2O.
C. NO.
D. NO2.
V d 5. Hn hp M gm 0,04 mol Al v 0,06 mol Mg. Nu em hn hp ny ha tan hon ton trong HNO3
d c 0,03 mol sn phm kh duy nht X. Nu em ha tan hn hp trong H2SO4 c, nng d cng thu
c 0,03 mol sn phm kh duy nht Y. X v Y ln lt l
A. NO2 v H2S
B. NO2 v SO2
C. NO v SO2
D. NH4NO3 v H2S.
V d 6. Ha tan hon ton 10,8 gam Al trong dung dch HNO3 d, khng thy kh thot ra, thu c dung
dch X. C cn cn thn dung dch X thu c khi lng mui khan l
A. 85,2 gam.
B. 97,2 gam.
C. 87,9 gam.
D. 117,2 gam.
V d 7. (C11) Ha tan hon ton 13,00 gam Zn trong dung dch HNO3 long, d thu c dung dch X v
0,448 lt kh N2 (ktc). Khi lng mui trong dung dch X l
A. 18,90 gam
B. 37,80 gam
C. 39,80 gam
D. 28,35 gam.
V d 8. (C10) Cho hn hp gm 6,72 gam Mg v 0,8 gam MgO tc dng ht vi lng d dung dch HNO3.
Sau khi cc phn ng xy ra hon ton, thu c 0,896 lt mt kh X (ktc) v dung dch Y. Lm bay hi dung
dch Y thu c 46 gam mui khan. Kh X l
A. NO2.
B. NO.
C. N2O.
D. N2.
V d 9. (C12) Ha tan hon ton 8,9 gam hn hp gm Mg v Zn bng lng va 500 ml dung dch
HNO3 1M. Sau khi cc phn ng kt thc, thu c 1,008 lt kh N2O (ktc) duy nht v dung dch X cha m
gam mui. Gi tr ca m l
A. 34,10.
B. 31,32.
C. 34,32.
D. 33,70.

M047. KIM LOI TC DNG VI PHI KIM

(T liu hc bi)
Dng 1. Kim loi tc dng vi oxi

V d 1. (C11) t chy hon ton 17,4 gam hn hp Mg v Al trong kh oxi (d) thu c 30,2 gam hn hp
oxit. Th tch kh oxi (ktc) tham gia phn ng l:
A. 17,92 lt
B. 4,48 lt
C. 11,20 lt
D. 8,96 lt
V d 2. (A8) Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi oxi
thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va phn ng ht
vi Y l
A. 50 ml.
B. 57 ml.
C. 75 ml.
D. 90 ml.
V d 3. Cho 40 gam hn hp X gm Au, Ag, Fe, Zn tc dng vi oxi d nung nng thu c 46,4 gam cht
rn Y. Th tch dung dch H2SO4 20% (d = 1,14 g/ml) c kh nng phn ng vi cht rn Y l
A. 257,95 ml
B. 85,96 ml
C. 334,86 ml
D. 171,93 ml
V d 4. Cho 2,13 gam hn hp X gm Mg, Al, Cu, Fe dng bt tc dng hon ton vi oxi thu c hn
hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch hn hp HCl 1M v H2SO4 2M va phn
ng ht vi Y l
A. 15 ml
B. 30 ml
C. 45 ml
D. 50 ml
V d 5. Oxi ha hon ton 14,30 gam hn hp bt cc kim loi Mg, Al, Zn bng oxi d thu c 22,3 gam
hn hp oxit. Cho lng oxit ny tc dng ht vi dung dch HCl th lng mui to ra l:
A. 41,80 gam.
B. 36,60 gam.
C. 32,050 gam.
D. 49,80 gam.
V d 6. Cho m gam hn hp X gm Mg, Fe, Zn dng bt tc dng hon ton vi oxi thu c 2,81 gam
hn hp Y gm cc oxit. Ha tan hon ton lng Y trn vo axit H2SO4 long (va ). Sau phn ng, c
cn dd thu c 6,81 gam hn hp mui sunfat khan. Gi tr ca m l
A. 1,21
B. 1,81
C. 2,01
D. 6,03
Dng 2. Kim loi tc dng vi clo

V d 7. Cho dung dch HCl c, d tc dng vi 6,96 gam MnO2. Lng kh clo sinh ra oxi ha hon ton kim
loi M, to ra 7,6 gam mui. Kim loi M l
A. Mg
B. Fe
C. Al
D. Cu
V d 8. Hn hp kh X gm clo v oxi. X phn ng va ht vi mt hn hp gm 4,8 gam Mg v 8,1 gam Al

to ra 37,05 gam hn hp cc mui v oxit ca hai kim loi. T l v th tch gia kh clo v oxi trong X tng
ng l
A. 1:1
B. 4:5
C. 3:5
D. 5:4
V d 9. Cho hn hp X gm Al v Mg tc dng va vi 1,344 lt ( ktc) hn hp kh Y gm O2 v Cl2,
d Y/H2 = 27,375 . Sau phn ng thu c 5,055 gam cht rn. Khi lng ca Al v Mg trong hn hp ban u
ln lt l
A. 0,81; 0,72
B. 0,27; 0,24
C. 0,81; 0,24
D. 0,81; 0,96.
V d 10. (C9) t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn hp
kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hn hp kh phn ng l 5,6 lt ( ktc).
Kim loi M l
A. Mg.
B. Ca.
C. Be.
D. Cu.
Dng 3. Kim loi tc dng vi lu hunh
V d 11. (C8) Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng
kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn
li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (ktc). Gi tr ca V l
A. 2,80.
B. 3,36.
C. 3,08.
D. 4,48.
V d 12. Trn bt lu hunh vi bt mt kim loi M (ha tr 2) c 25,9 gam hn hp X. Cho X vo bnh kn
khng cha khng kh, nung nng thu c cht rn Y. Bit Y tan hon ton trong dung dch HCl d cho 0,3
mol kh Z c d Z/H2 = 11, 67 . Kim loi M l
A. Fe
B. Zn
C. Pb
D. Mg
V d 13. Nung m gam hn hp bt Fe v S trong bnh kn khng c khng kh. Sau phn ng em phn rn thu
c ha tan vo lng d dung dch HCl c 3,8 gam cht rn X khng tan, dung dch Y v 0,2 mol kh Z.
Dn Z qua dung dch Cu(NO3)2 d, thu c 9,6 gam kt ta en. Gi tr ca m l
A. 11,2
B. 15,6
C. 18,2
D. 18,4
V d 14. Nung nng hn hp 5,6 gam bt Fe vi 4 gam bt S trong bnh kn (khng c khng kh) mt thi
gian thu c hn hp X gm FeS, FeS2, Fe v S d. Cho X tan ht trong axit H2SO4 c nng d c V lt
kh SO2. Gi tr ca V l
A. 3,36.
B. 8,96.
C. 11,65.
D. 11,76.
V d 15. (B12) Ha tan hon ton 0,1 mol FeS2 trong 200 ml dung dch HNO3 4M, sn phm thu c gm
dung dch X v mt cht kh thot ra. Dung dch X c th ha tan ti a m gam Cu. Bit trong cc qu trnh
trn, sn phm kh duy nht ca N+5 u l NO. Gi tr ca m l
A. 12,8
B. 6,4
C. 9,6
D. 3,2.
M048. KIM LOI TC DNG VI MUI

(T liu hc bi)
V d 1. (C9) Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi lng 50 gam vo 200 ml
dung dch AgNO3 1M cho n khi phn ng xy ra hon ton. Lc dung dch, em c cn thu c 18,8 gam
mui khan. Kim loi M l
A. Fe.
B. Cu.
C. Mg.
D. Zn.
V d 2. (B8) Tin hnh hai th nghim sau:
- Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M;
- Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M.
Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr
ca V1 so vi V2 l
A. V1 = 10V2.
B. V1 = 5V2.
C. V1 = 2V2.
D. V1 = V2.
V d 3. (B11) Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn ng xy ra hon
ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l
A. 32,50
B. 20,80
C. 29,25
D. 48,75.
V d 4. (A10) Cho 19,3 gam hn hp bt gm Zn v Cu c t l mol tng ng l 1 : 2 vo dung dch cha
0,2 mol Fe2(SO4)3. Sau khi cc phn ng xy ra hon ton, thu c m gam kim loi. Gi tr ca m l
A. 12,80.
B. 12,00.
C. 6,40.
D. 16,53.
V d 5. (A12) Cho 2,8 gam bt st vo 200 ml dung dch gm AgNO3 0,1M v Cu(NO3)2 0,5M; khi cc phn
ng xy ra hon ton thu c m gam cht rn X. Gi tr ca m l
A. 4,72.
B. 4,08.
C. 4,48.
D. 3,20.
V d 6. (A8) Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi cc
phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l
A. 32,4.
B. 64,8.
C. 59,4.
D. 54,0.
V d 7. (B7) Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn
ng, lc b phn dung dch thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hn
hp bt ban u l
A. 90,27%.
B. 12,67%.
C. 85,30%.
D. 82,20%.
V d 8. (B12) Cho 0,42 gam hn hp bt Fe v Al vo 250 ml dung dch AgNO3 0,12M. Sau khi cc phn
ng xy ra hon ton, thu c dung dch X v 3,333 gam cht rn. Khi lng Fe trong hn hp ban u l
A. 0,168 gam
B. 0,123 gam
C. 0,177 gam
D. 0,150 gam
V d 9. (B9) Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v
AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim
loi to thnh u bm ht vo thanh st). Khi lng st phn ng l
A. 1,40 gam.
B. 2,16 gam.
C. 0,84 gam.
D. 1,72 gam.
V d 10. (C8) Cho hn hp bt Al, Fe vo dung dch cha Cu(NO3)2 v AgNO3. Sau khi cc phn ng xy ra
hon ton, thu c hn hp rn gm ba kim loi l:
A. Fe, Cu, Ag.
B. Al, Cu, Ag.
C. Al, Fe, Cu.
D. Al, Fe, Ag.
V d 11. (A9) Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu
c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l
A. Fe(NO3)3 v Zn(NO3)2.
B. Zn(NO3)2 v Fe(NO3)2.
C. AgNO3 v Zn(NO3)2.
D. Fe(NO3)2 v AgNO3.
V d 12. (A12) Cho hn hp gm Fe v Mg vo dung dch AgNO3, khi cc phn ng xy ra hon ton thu
c dung dch X (gm hai mui) v cht rn Y (gm hai kim loi). Hai mui trong X l:
A. Mg(NO3)2 v Fe(NO3)2
B. Fe(NO3)2 v AgNO3
C. Fe(NO3)3 v Mg(NO3)2
D. AgNO3 v Mg(NO3)2.
V d 13. (A9) Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 1 mol Ag+ n
khi cc phn ng xy ra hon ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi
tr no ca x tho mn trng hp trn ?
A. 1,8.
B. 1,5.
C. 1,2.
D. 2,0.
V d 14. Cho 1,93 gam hn hp gm Fe v Al tc dng vi dung dch cha Cu2+ v 0,03 mol Ag+. Sau phn
ng thu c 6,44 gam hn hp c 2 kim loi. Phn trm khi lng Fe trong hn hp u bng
A. 58,03%
B. 44,04%
C. 72,02%
D. 29,01%.
V d 15. Ha tan hn hp cha 0,1 mol Mg v 0,1 mol Al vo dung dch hn hp cha 0,1 mol Cu(NO3)2 v
0,35 mol AgNO3. Khi lng cht rn thu c khi phn ng xy ra hon ton l
A. 21,6 gam
B. 37,8 gam
C. 42,6 gam
D. 44,2 gam.

M048. KIM LOI TC DNG VI MUI

(T liu hc bi)
V d 1. (C9) Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi lng 50 gam vo 200 ml
dung dch AgNO3 1M cho n khi phn ng xy ra hon ton. Lc dung dch, em c cn thu c 18,8 gam
mui khan. Kim loi M l
A. Fe.
B. Cu.
C. Mg.
D. Zn.
V d 2. (B8) Tin hnh hai th nghim sau:
- Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M;
- Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M.
Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr
ca V1 so vi V2 l
A. V1 = 10V2.
B. V1 = 5V2.
C. V1 = 2V2.
D. V1 = V2.
V d 3. (B11) Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn ng xy ra hon
ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l
A. 32,50
B. 20,80
C. 29,25
D. 48,75.
V d 4. (A10) Cho 19,3 gam hn hp bt gm Zn v Cu c t l mol tng ng l 1 : 2 vo dung dch cha
0,2 mol Fe2(SO4)3. Sau khi cc phn ng xy ra hon ton, thu c m gam kim loi. Gi tr ca m l
A. 12,80.
B. 12,00.
C. 6,40.
D. 16,53.
V d 5. (A12) Cho 2,8 gam bt st vo 200 ml dung dch gm AgNO3 0,1M v Cu(NO3)2 0,5M; khi cc phn
ng xy ra hon ton thu c m gam cht rn X. Gi tr ca m l
A. 4,72.
B. 4,08.
C. 4,48.
D. 3,20.
V d 6. (A8) Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi cc
phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l
A. 32,4.
B. 64,8.
C. 59,4.
D. 54,0.
V d 7. (B7) Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn
ng, lc b phn dung dch thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hn
hp bt ban u l
A. 90,27%.
B. 12,67%.
C. 85,30%.
D. 82,20%.
V d 8. (B12) Cho 0,42 gam hn hp bt Fe v Al vo 250 ml dung dch AgNO3 0,12M. Sau khi cc phn
ng xy ra hon ton, thu c dung dch X v 3,333 gam cht rn. Khi lng Fe trong hn hp ban u l
A. 0,168 gam
B. 0,123 gam
C. 0,177 gam
D. 0,150 gam
V d 9. (B9) Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v
AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim
loi to thnh u bm ht vo thanh st). Khi lng st phn ng l
A. 1,40 gam.
B. 2,16 gam.
C. 0,84 gam.
D. 1,72 gam.
V d 10. (C8) Cho hn hp bt Al, Fe vo dung dch cha Cu(NO3)2 v AgNO3. Sau khi cc phn ng xy ra
hon ton, thu c hn hp rn gm ba kim loi l:
A. Fe, Cu, Ag.
B. Al, Cu, Ag.
C. Al, Fe, Cu.
D. Al, Fe, Ag.
V d 11. (A9) Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu
c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l
A. Fe(NO3)3 v Zn(NO3)2.
B. Zn(NO3)2 v Fe(NO3)2.
C. AgNO3 v Zn(NO3)2.
D. Fe(NO3)2 v AgNO3.
V d 12. (A12) Cho hn hp gm Fe v Mg vo dung dch AgNO3, khi cc phn ng xy ra hon ton thu
c dung dch X (gm hai mui) v cht rn Y (gm hai kim loi). Hai mui trong X l:
A. Mg(NO3)2 v Fe(NO3)2
B. Fe(NO3)2 v AgNO3
C. Fe(NO3)3 v Mg(NO3)2
D. AgNO3 v Mg(NO3)2.
V d 13. (A9) Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 1 mol Ag+ n
khi cc phn ng xy ra hon ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi
tr no ca x tho mn trng hp trn ?
A. 1,8.
B. 1,5.
C. 1,2.
D. 2,0.
V d 14. Cho 1,93 gam hn hp gm Fe v Al tc dng vi dung dch cha Cu2+ v 0,03 mol Ag+. Sau phn
ng thu c 6,44 gam hn hp c 2 kim loi. Phn trm khi lng Fe trong hn hp u bng
A. 58,03%
B. 44,04%
C. 72,02%
D. 29,01%.
V d 15. Ha tan hn hp cha 0,1 mol Mg v 0,1 mol Al vo dung dch hn hp cha 0,1 mol Cu(NO3)2 v
0,35 mol AgNO3. Khi lng cht rn thu c khi phn ng xy ra hon ton l
A. 21,6 gam
B. 37,8 gam
C. 42,6 gam
D. 44,2 gam.

M050. PHNG PHP GII BI TON IN PHN

(T liu hc bi Phn I)
Phn I. L thuyt v s in phn
V d 1. Pht biu no di y khng ng v bn cht qu trnh ha hc in cc trong qu trnh in
phn ?
B. Xy ra s nhn electron catot.
A. Xy ra s nhng electron anot.
C. S oxi ha xy ra catot.
D. S oxi ha xy ra anot.
V d 2. (A10) Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n mn in ho xy ra
khi nhng hp kim Zn-Cu vo dung dch HCl c c im l:
A. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi.
B. Phn ng cc dng u l s oxi ho Cl.
C. u sinh ra Cu cc m.
D. Phn ng xy ra lun km theo s pht sinh dng in.
V d 3. (A7) Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp cht
nng chy ca chng, l:
A. Na, Ca, Al.
B. Na, Ca, Zn.
C. Na, Cu, Al.
D. Fe, Ca, Al.
V d 4. (A8) Khi in phn NaCl nng chy (in cc tr), ti catot xy ra
A. s oxi ho ion Cl.
B. s oxi ho ion Na+.
C. s kh ion Cl.
D. s kh ion Na+.
V d 5. (A12) Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui (vi
in cc tr) l:
A. Ni, Cu, Ag.
B. Li, Ag, Sn.
C. Ca, Zn, Cu.
D. Al, Fe, Cr.
V d 6. in phn dung dch hn hp HCl, NaCl, FeCl3, CuCl2. Trnh t in phn catot l
A. Cu2+ > Fe3+ > H+ (axit) > Na+ > H+ (H2O).
B. Fe3+ > Cu2+ > H+ (axit) > Fe2+ > H+ (H2O).
3+
2+
+
+
C. Fe > Cu > H (axit) > H (H2O).
D. Cu2+ > Fe3+ > Fe2+ > H+ (axit) > H+ (H2O).
V d 7. Dung dch X cha hn hp cc mui: NaCl, CuCl2, FeCl3 v ZnCl2. Kim loi cui cng thot ra
catot khi in phn dung dch X l
A. Na.
B. Zn.
C. Fe.
D. Cu.
V d 8. (C10) in phn dung dch CuSO4 vi anot bng ng (anot tan) v in phn dung dch CuSO4 vi
anot bng graphit (in cc tr) u c c im chung l
A. catot xy ra s oxi ha: 2H2O + 2e 2OH + H2.
B. anot xy ra s kh: 2H2O O2 + 4H+ + 4e.
C. anot xy ra s oxi ha: Cu Cu2+ + 2e.
D. catot xy ra s kh: Cu2+ + 2e Cu.
V d 9. in phn dung dch CuSO4 vi anot bng Cu. Nhn nh no sau y ng ?
A. Phng trnh in phn: 2CuSO 4 + 2H 2 O
2Cu + O 2 + 2H 2SO 4 .
B. Catot b ha tan.
C. C kh khng mu bay ra anot.
D. Dung dch khng i mu.
V d 10. Khi in phn dung dch CuSO4 ngi ta thy khi lng catot tng ng bng khi lng anot gim,
iu chng t
A. anot tr.
B. anot bng Zn.
C. anot bng Cu.
D. catot tr.
V d 11. Trong qu trnh m Ni ln mt vt bng Fe, thng tin no di y khng ng ?
A. anot l Ni.
B. cc m l Fe.
C. dung dch in phn c th l NiSO4.
D. catot l vt liu tr.

Phn II. Phng php gii bi ton in phn

V d 1. in phn bng in cc tr dung dch mui sunfat ca kim loi ho tr II vi dng in cng
6A. Sau 29 pht in phn thy khi lng catot tng 3,45 gam. Kim loi l:
A. Zn.
B. Cu.
C. Ni.
D. Sn.
V d 2. (A10NC) in phn (in cc tr) dung dch X cha 0,2 mol CuSO4 v 0,12 mol NaCl bng dng
in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l
A. 1,344 lt.
B. 2,240 lt.
C. 1,792 lt.
D. 2,912 lt.
V d 3. (B9) in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M (in
cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in
phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l
A. 4,05.
B. 2,70.
C. 1,35.
D. 5,40.
V d 4. (B12) Ngi ta iu ch H2 v O2 bng phng php in phn dung dch NaOH vi in cc tr,
cng dng in 0,67A trong thi gian 40 gi. Dung dch thu c sau in phn c khi lng 100 gam v
nng NaOH l 6%. Nng dung dch NaOH trc in phn l (gi thit lng nc bay hi khng ng
k)
A. 5,08%
B. 6,00%
C. 5,50%
D. 3,16%
V d 5. (C11) in phn 500 ml dung dch CuSO4 0,2M (in cc tr) cho n khi catot thu c 3,2 gam
kim loi th th tch kh (ktc) thu c anot l:
A. 3,36 lt
B. 1,12 lt
C. 0,56 lt
D. 2,24 lt
V d 6. (A7) in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catot v
mt lng kh X anot. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng).
Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u
ca dung dch NaOH l
A. 0,15M.
B. 0,2M.
C. 0,1M.
D. 0,05M.
V d 7. (A10) in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi
catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l
A. kh Cl2 v H2.
B. kh Cl2 v O2.
C. ch c Cl2.
D. kh H2 v O2.
V d 8. (B12) in phn dung dch hn hp gm 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc
tr). Khi catot bt u thot kh th anot thu c V lt kh (ktc). Bit hiu sut ca qu trnh in phn l
100%. Gi tr ca V l:
A. 5,60.
B. 11,20.
C. 22,40.
D. 4,48.
V d 9. (C12) Tin hnh in phn (vi in cc tr) V lt dung dch CuCl2 0,5M. Khi dng in phn thu
c dung dch X v 1,68 lt kh Cl2 (ktc) duy nht anot. Ton b dung dch X tc dng va vi 12,6 gam
Fe. Gi tr ca V l
A. 0,60.
B. 0,15.
C. 0,45.
D. 0,80.
V d 10. (A11) Ha tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi in cc tr,
cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy nht catot v 0,035 mol kh
anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi
tr ca y l
A. 4,788.
B. 1,680.
C. 4,480.
D. 3,920.
V d 11. (B7) in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn). iu
kin dung dch sau in phn lm phenolphtalein chuyn sang mu hng l
A. b < 2a.
B. b = 2a.
C. b > 2a.
D. 2b = a.
V d 12. in phn dung dch cha m gam hn hp CuSO4 v NaCl. Khi thy c 2 in cc tr u xut
hin bt kh th ngng in phn. Kt qu Anot c 0,02 mol kh thot ra, cn dung dch sau in phn c th
ha tan ti a 0,005 mol Fe3O4. Gi tr ca m l
A. 5,64.
B. 7,98.
C. 5,97.
D. 6,81.
V d 13. (B10) in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu
c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8 gam bt
Fe vo Y, sau khi cc phn ng xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x l
A. 2,25.
B. 1,5.
C. 1,25.
D. 3,25.
V d 14. (A11) in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2 (in cc tr, mng ngn xp)
n khi khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit lng nc bay hi khng ng
k). Tt c cc cht tan trong dung dch sau in phn l:
A. KNO3 v KOH.
B. KNO3, HNO3 v Cu(NO3)2.
C. KNO3, KCl v KOH.
D. KNO3 v Cu(NO3)2.
V d 15. (A12) in phn 150 ml dung dch AgNO3 1M vi in cc tr trong t gi, cng dng in
khng i 2,68A (hiu sut qu trnh in phn l 100%), thu c cht rn X, dung dch Y v kh Z. Cho 12,6
gam Fe vo Y, sau khi cc phn ng kt thc thu c 14,5 gam hn hp kim loi v kh NO (sn phm kh
duy nht ca N+5). Gi tr ca t l
A. 0.8.
B. 0,3.
C. 1,0.
D. 1,2.


Phn II. Phng php gii bi ton in phn

V d 1. in phn bng in cc tr dung dch mui sunfat ca kim loi ho tr II vi dng in cng
6A. Sau 29 pht in phn thy khi lng catot tng 3,45 gam. Kim loi l:
A. Zn.
B. Cu.
C. Ni.
D. Sn.
V d 2. (A10NC) in phn (in cc tr) dung dch X cha 0,2 mol CuSO4 v 0,12 mol NaCl bng dng
in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l
A. 1,344 lt.
B. 2,240 lt.
C. 1,792 lt.
D. 2,912 lt.
V d 3. (B9) in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M (in
cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in
phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l
A. 4,05.
B. 2,70.
C. 1,35.
D. 5,40.
V d 4. (B12) Ngi ta iu ch H2 v O2 bng phng php in phn dung dch NaOH vi in cc tr,
cng dng in 0,67A trong thi gian 40 gi. Dung dch thu c sau in phn c khi lng 100 gam v
nng NaOH l 6%. Nng dung dch NaOH trc in phn l (gi thit lng nc bay hi khng ng
k)
A. 5,08%
B. 6,00%
C. 5,50%
D. 3,16%
V d 5. (C11) in phn 500 ml dung dch CuSO4 0,2M (in cc tr) cho n khi catot thu c 3,2 gam
kim loi th th tch kh (ktc) thu c anot l:
A. 3,36 lt
B. 1,12 lt
C. 0,56 lt
D. 2,24 lt
V d 6. (A7) in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catot v
mt lng kh X anot. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng).
Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u
ca dung dch NaOH l
A. 0,15M.
B. 0,2M.
C. 0,1M.
D. 0,05M.
V d 7. (A10) in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi
catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l
A. kh Cl2 v H2.
B. kh Cl2 v O2.
C. ch c Cl2.
D. kh H2 v O2.
V d 8. (B12) in phn dung dch hn hp gm 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc
tr). Khi catot bt u thot kh th anot thu c V lt kh (ktc). Bit hiu sut ca qu trnh in phn l
100%. Gi tr ca V l:
A. 5,60.
B. 11,20.
C. 22,40.
D. 4,48.
V d 9. (C12) Tin hnh in phn (vi in cc tr) V lt dung dch CuCl2 0,5M. Khi dng in phn thu
c dung dch X v 1,68 lt kh Cl2 (ktc) duy nht anot. Ton b dung dch X tc dng va vi 12,6 gam
Fe. Gi tr ca V l
A. 0,60.
B. 0,15.
C. 0,45.
D. 0,80.
V d 10. (A11) Ha tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi in cc tr,
cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy nht catot v 0,035 mol kh
anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi
tr ca y l
A. 4,788.
B. 1,680.
C. 4,480.
D. 3,920.
V d 11. (B7) in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn). iu
kin dung dch sau in phn lm phenolphtalein chuyn sang mu hng l
A. b < 2a.
B. b = 2a.
C. b > 2a.
D. 2b = a.
V d 12. in phn dung dch cha m gam hn hp CuSO4 v NaCl. Khi thy c 2 in cc tr u xut
hin bt kh th ngng in phn. Kt qu Anot c 0,02 mol kh thot ra, cn dung dch sau in phn c th
ha tan ti a 0,005 mol Fe3O4. Gi tr ca m l
A. 5,64.
B. 7,98.
C. 5,97.
D. 6,81.
V d 13. (B10) in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu
c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8 gam bt
Fe vo Y, sau khi cc phn ng xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x l
A. 2,25.
B. 1,5.
C. 1,25.
D. 3,25.
V d 14. (A11) in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2 (in cc tr, mng ngn xp)
n khi khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit lng nc bay hi khng ng
k). Tt c cc cht tan trong dung dch sau in phn l:
A. KNO3 v KOH.
B. KNO3, HNO3 v Cu(NO3)2.
C. KNO3, KCl v KOH.
D. KNO3 v Cu(NO3)2.
V d 15. (A12) in phn 150 ml dung dch AgNO3 1M vi in cc tr trong t gi, cng dng in
khng i 2,68A (hiu sut qu trnh in phn l 100%), thu c cht rn X, dung dch Y v kh Z. Cho 12,6
gam Fe vo Y, sau khi cc phn ng kt thc thu c 14,5 gam hn hp kim loi v kh NO (sn phm kh
duy nht ca N+5). Gi tr ca t l
A. 0.8.
B. 0,3.
C. 1,0.
D. 1,2.

M051. IU CH TINH CH KIM LOI

(T liu hc bi)
V d 1. (C9) Nguyn tc chung c dng iu ch kim loi l

A. cho hp cht cha ion kim loi tc dng vi cht kh.
B. oxi ho ion kim loi trong hp cht thnh nguyn t kim loi.
C. kh ion kim loi trong hp cht thnh nguyn t kim loi.
D. cho hp cht cha ion kim loi tc dng vi cht oxi ho.
V d 2. Khi iu ch kim loi, cc ion kim loi ng vai tr l cht
A. b kh.
B. nhn proton.
C. b oxi ho.
D. cho proton.
V d 3. Dy cc ion kim loi no sau y u b Zn kh thnh kim loi ?

A. Cu2+, Mg2+, Pb2+.
B. Cu2+, Ag+, Na+.
C. Sn2+, Pb2+, Cu2+.
D. Pb2+, Ag+, Al3+.
V d 4. Dy gm 2 kim loi u c th iu ch bng phng php thu luyn l

A. Fe v Ca.
B. Mg v Na.
C. Ag v Cu.
D. Fe v Ba.
V d 5. Cht khng kh c st oxit ( nhit cao) l

A. Cu.
B. Al.
C. CO.
D. H2.
V d 6. Dy gm cc kim loi iu ch c bng phng php nhit luyn l:

A. Mg, Al, Cu, Fe.
B. Al, Zn, Cu, Ag.
C. Na, Ca, Al, Mg.
D. Zn, Fe, Pb, Cr.
V d 7. Cho kh CO d i qua hn hp gm CuO, Al2O3, MgO (nung nng). Khi phn ng xy ra hon ton
thu c cht rn gm
A. Cu, Al, Mg.
B. Cu, Al, MgO.
C. Cu, Al2O3, Mg.
D. Cu, Al2O3, MgO.
V d 8. Hiro c th kh cc oxit kim loi trong dy no sau y thnh kim loi ?

A. CaO, CuO, Fe2O3, MnO2.
B. CuO, Fe2O3, Fe3O4, ZnO.
C. CuO, Fe2O3, Fe3O4, MgO.
D. HgO, Al2O3, Fe3O4, CuO.
V d 9. (A7) Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp cht
nng chy ca chng, l:
A. Na, Ca, Al.
B. Na, Ca, Zn.
C. Na, Cu, Al.
D. Fe, Ca, Al.
V d 10. (A12) Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui (vi
in cc tr) l:
A. Ni, Cu, Ag.
B. Li, Ag, Sn.
C. Ca, Zn, Cu.
D. Al, Fe, Cr.
V d 11. (C12) Tin hnh cc th nghim sau

(1) Cho Zn vo dung dch AgNO3;
(2) Cho Fe Vo dung dch Fe2(SO4)3;
(3) Cho Na vo dung dch CuSO4;
(4) Dn kh CO (d) qua bt CuO nng.
Cc th nghim c to thnh kim loi l

A. (3) v (4).
B. (1) v (2).
C. (2) v (3).
D. (1) v (4).
V d 12. Cho cc trng hp sau :

(1). in phn nng chy MgCl2.
(2). in phn dung dch ZnSO4
(3). in phn dung dch CuSO4
(4). in phn dung dch NaCl.
S trng hp ion kim loi b kh thnh kim loi l:

A. 1.
B. 2.
C. 3
D. 4.
V d 13. Phng trnh ha hc no sau y biu din cch iu ch Ag t AgNO3 theo phng php thu
luyn ?
A. 2AgNO3 + Zn 2Ag + Zn(NO3)2
B. 2AgNO3 2Ag + 2NO2 + O2
C. 4AgNO3 + 2H2O 4Ag + 4HNO3 + O2
D. Ag2O + CO 2Ag + CO2.
V d 14. Phn ng iu ch kim loi no di y thuc phng php nhit luyn ?

A. C + ZnO Zn + CO.
B. 2Al2O3 4Al + 3O2.
C. MgCl2 Mg + Cl2.
D. Zn + 2 [Ag(CN)2 ] [Zn(CN)4 ]2 + 2Ag.
V d 15. Phn ng ha hc no sau y ch thc hin c bng phng php in phn ?

A. Fe + CuSO4 FeSO4 + Cu.
B. 2CuSO4 + 2H2O 2Cu + O2 + 2H2SO4.
C. CuSO4 + 2NaOH Cu(OH)2 + Na2SO4.
D. Cu + 2AgNO3 2Ag + Cu(NO3)2.
V d 16. Phng trnh ho hc no sau y th hin cch iu ch Cu theo phng php thu luyn ?
A. Zn + CuSO4 Cu + ZnSO4
B. H2 + CuO Cu + H2O
C. CuCl2 Cu + Cl2
D. 2CuSO4 + 2H2O 2Cu + 2H2SO4 + O2
V d 17. C th iu ch c Ag nguyn cht t dung dch AgNO3 vi dung dch no sau y ?

A. Fe(NO3)3.
B. Fe(NO3)2.
C. Al(NO3)3.
D. Mg(NO3)2.
V d 18. loi b kim loi Cu ra khi hn hp bt gm Ag v Cu, ngi ta ngm hn hp kim loi trn vo
lng d dung dch
A. AgNO3.
B. HNO3.
C. Cu(NO3)2.
D. Fe(NO3)2.
V d 19. Mt tm kim loi bng vng b bm mt lp kim loi st b mt, ta c th dng dung dch no sau
y loi ht tp cht v thu c tm kim loi vng sch ?
A. dd Al2(SO4)3 d.
B. dd Zn(NO3)2 d.
C. dd Fe2(SO4)3 d.
D. dd AgNO3 d.
V d 20. Dung dch FeSO4 c ln tp cht CuSO4. Phng php ho hc n gin loi c tp cht l
A. in phn dung dch vi in cc tr n khi ht mu xanh.
B. Chuyn hai mui thnh hiroxit; nhit phn thnh oxit kim loi; kh bng CO d; ri cho cht rn vo dung
dch H2SO4 long d.
C. Cho Mg vo dung dch cho n khi ht mu xanh.
D. Cho Fe d vo dung dch, sau khi phn ng xong lc b cht rn.

M052. L THUYT TRNG TM V KIM LOI KIM

(T liu hc bi)
V d 1. Pht biu no di y l ng ?
A. Kim loi kim c nhit nng chy v nhit si thp do lin kt kim loi trong mng tinh th kim loi
kim bn vng.
B. Kim loi kim c khi lng ring nh do nguyn t kim loi kim c bn knh ln v cu trc tinh th km
c kht.
C. Kim loi kim c cng cao do lin kt kim loi trong mng tinh th kim loi kim bn vng.
D. Kim loi kim c t khi ln v thuc loi kim loi nng.
V d 2. Cho cc m t: (1) Kim loi mm v nh; (2) Ch c 1 electron ha tr; (3) Bn knh nguyn t ln
nht chu k; (4) Mng tinh th lp phng tm khi; (5) Nhit nng chy v nhit si thp.
S tnh cht chung ca cc kim loi kim l:
A. 2.
B. 3.
C. 4.
D. 5.
V d 3. Pht biu no di y l ng i vi kim loi kim ?
A. Kim loi kim nh nht l Li.
B. Kim loi kim mm nht l Li.
C. Kim loi kim c nhit si thp nht l Li.
D. Kim loi kim c nhit nng chy thp nht l Li.
V d 4. Chn pht biu khng ng:
i vi kim loi kim, theo chiu t Li n Cs th
A. nng lng ion ha gim dn.
B. gi tr th in cc chun tng dn.
C. gi tr m in gim dn.
D. tnh kim loi tng dn.
V d 5. Cho 0,2 mol Na chy ht trong O2 d c m gam sn phm rn X. Ha tan ht X trong nc thu
c 0,025 mol O2. Gi tr ca m l
A. 3,9.
B. 5,4.
C. 7,0.
D. 7,8.
V d 6. nhit thng, kim loi kim phn ng vi N2 mnh nht l

A. Li.
B. Na.
C. K.
D. Cs.
V d 7. Cho hn hp cc kim loi kim Na, K ho tan ht vo nc c dung dch X v 0,672 lt H2 ktc.
Th tch dung dch HCl 0,1M cn trung ho ht 1/3 dung dch X l
A. 100 ml
B. 200 ml
C. 300 ml
D. 600 ml
(ktc). C cn dung dch sau phn ng khi lng cht rn thu c l:
A. 18,55 gam.
B. 17,55 gam.
C. 20,95 gam.
D. 12,95 gam.
V d 9. Hin tng no xy ra khi cho Na kim loi vo dung dch CuSO4 ?

A. Si bt kh khng mu v c kt ta mu xanh.
B. B mt kim loi c mu , dung dch nht mu.
C. Si bt kh khng mu v c kt ta mu .
D. B mt kim loi c mu v c kt ta mu xanh.
(1) Ch to hp kim c nhit nng chy thp dng trong thit b bo chy.
(2) Kim loi K, Na dng lm cht trao i nhit trong l phn ng ht nhn.
(3) Cs dng ch to t bo quang in.
(4) iu ch mt s kim loi him bng phng php nhit luyn.
(5) Cht xc tc trong tng hp hu c.
S ng dng ng ca kim loi kim l:
A. 2.
B. 3.
C. 4.
D. 5.
V d 11. C cc th nghim sau:
(1) pnc NaCl
(2) pdd NaCl c mng ngn xp
(3) pnc NaOH
(4) Kh Na2O nhit cao bng H2
S th nghim c th dng iu ch Na l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 12. bo qun cc kim loi kim cn
A. Ngm chng vo nc.
B. Gi chng trong l c y np kn.
C. Ngm chng trong ru nguyn cht.
D. Ngm chng trong du ho.
V d 13. Xoa (Na2CO3.nH2O) cha 72,72% oxi. Vy n c gi tr l
A. 6
B. 8
C. 10
D. 12.
V d 14. Cho cc ha cht: (1) BaCl2 ; (2) dung dch Ca(HCO3)2 ; (3) dung dch HCl ; (4) dung dch Ca(OH)2 ;
(5) dung dch NaOH ; (6) dung dch Na3PO4. S ha cht c th dng phn bit 2 dung dch ring bit,
khng mu, mt nhn cha NaHCO3 v Na2CO3 l (ch cho trc tip ha cht vo 2 dung dch trn v quan st
hin tng m khng c tin hnh bt c thao tc no khc)
A. 2.
B. 3.
C. 4.
D. 5.
V d 15. Trong qu trnh in phn dung dch NaCl, cc m xy ra
A. S kh ion Na+
B. S kh H2O.
C. S oxi ho ion Na+.
D. S oxi ho H2O.
V d 16. in phn c mng ngn xp 500 ml dung dch NaCl 4M (d = 1,2 g/ml). Sau khi anot thot ra
17,92 lt Cl2 (ktc) th ngng in phn. Hy chn gi tr ng ca nng C% ca NaOH trong dung dch sau
in phn (nc bay hi khng ng k)
A. 8,26%.
B. 11,82%.
C. 12,14%.
D. 15,06%

M053. L THUYT TRNG TM V KIM LOI KIM TH V HP CHT

(T liu hc bi)
V d 1. Cho cc m t:
(1) Kim loi mm v nh;
(2) Ch c 2 electron ha tr;
(3) Bn knh nguyn t ln nht chu k;
(4) Mng tinh th lp phng tm khi;
(5) Nhit nng chy v nhit si tng i thp.
S tnh cht chung ca cc kim loi kim th l:
A. 2.
B. 3.
C. 4.
D. 5.
V d 2. Cho cc so snh gia kim loi kim th vi kim loi kim trong cng chu k:
(1) Bn knh nguyn t ln hn;
(2) Khi lng ring ln hn;
(3) cng ln hn;
(4) Nhit nng chy, nhit si cao hn;
S so snh ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 3. Cho cc m t cho cc kim loi nhm IIA:

(1) Bn knh nguyn t tng dn;
(2) S electron ha tr tng dn;
(3) Khi lng ring tng dn;

(5) Nhit nng chy tng dn;
(4) cng tng dn;

(6) Nhit si tng dn;
(7) Th in cc chun tng dn;

(8) Nng lng ion ha (I2) tng dn;
S tnh cht bin i tun t theo chiu t Be n Ba l:
A. 1.
B. 2.
V d 4. Nhn xt no sau y khng ng ?
C. 3.
D. 4.
A. Cc kim loi kim th c tnh kh mnh.

B. Tnh kh ca cc kim loi kim th tng dn t Be n Ba.
C. Tnh kh ca cc kim loi kim th yu hn kim loi kim trong cng chu k.
D. Be, Mg, Ca, Sr, Ba u phn ng vi nc nhit thng nn gi l kim loi kim th.
V d 5. Ha tan 27,4 gam Ba vo 100ml dung dch hn hp HCl 2M v CuSO4 3M c m gam kt ta. Gi
tr ca m l
A. 33,1.
B. 56,4.
C. 12,8.
D. 46,6.
V d 6. Cho cc cht: (1) dung dch NaOH (to); (2) CO2 (to); (3) SiO2 (to); (4) HNO3 c ngui; (5) dung dch
AlCl3. S cht m Mg c th phn ng l:
A. 2.
B. 3.
C. 4.
D. 5.
V d 7. Dung dch X cha cc ion Mg2+, SO 24 , NH +4 , Cl. Chia dung dch X thnh 2 phn bng nhau:
- Phn 1 tc dng vi dung dch NaOH d, un nng, c 0,58 gam kt ta v 0,672 lt kh (ktc).
- Phn 2 tc dng vi dung dch BaCl2 d c 4,66 gam kt ta.
Tng khi lng cc cht tan trong dung dch X l:
A. 6,110 gam.
B. 3,055 gam.
C. 5,350 gam.
D. 9,165 gam.
V d 8. (A8) T hai mui X v Y thc hin cc phn ng sau:

t
X1 + CO2
X2 + Y X + Y1 + H2O
o
X1 + H2O X2
X2 + 2Y X + Y2 + 2H2O
Hai mui X, Y tng ng l

A. BaCO3, Na2CO3.
B. CaCO3, NaHSO4.
C. MgCO3, NaHCO3.
D. CaCO3, NaHCO3.
V d 9. Ho tan hon ton mui MCO3 bng lng va dung dch H2SO4 12,25% thu c dung dch
MSO4 15,89%. Kim loi M l:
A. Mg.
B. Ca.
C. Sr.
D. Ba
V d 10. Cho cc m t sau:

(1) Phng php c bn iu ch kim loi kim th l pnc mui clorua.
(2) Hp kim ca Mg c c tnh cng, nh, bn nn c dng ch to my bay, tn la, t,...
(3) Ca(OH)2 dng trn va xy nh; kh chua t trng trt; sn xut Clorua vi v Gia-ven.
(4) CaCO3 dng sn xut thy tinh, xi mng, gang, thp, vi,
(5) Thch cao nung dng c tng, trang tr ni tht, lm phn vit bng, sn xut xi mng,
S m t ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 11. ng dng no sau y khng phi ca CaCO3 ?
A. Lm bt nh pha sn.
B. Lm cht n trong cng nghip.
C. Lm vi qut tng.
D. Sn xut xi mng.
V d 12. Vt liu thng c dng c tng, b bt khi b gy xng l
A. CaSO4.3H2O.
B. CaSO4.2H2O.
C. CaSO4.H2O.
D. CaSO4.
M054. L THUYT TRNG TM V NHM V HP CHT

(T liu hc bi)
Dng 1. V tr Cu to Tnh cht vt l

(1) s oxi ha bn l +3.
(3) bn knh nguyn t nh hn Mg.
(5) mng lp phng tm din.
S m t ng vi nhm l:
A. 3.
B. 4.
V d 2. Cho cc tnh cht vt l sau:
(1) mu trng bc.
(3) d ko si v dt mng.
(5) nhit nng chy thp, 660oC.
S tnh cht ng vi nhm l:
A. 3.
B. 4.
(2) c 3 electron ha tr.

(4) l nguyn t p.
(6) c 3 lp electron.
C. 5.
D. 6.
(2) mm.
(4) kim loi nh.
(6) dn in v dn nhit tt.
C. 5.
D. 6.
Dng 2. Tnh cht ha hc

V d 3. Tnh kh ca cc nguyn t Na, K, Al, Mg c xp theo th t tng dn l
A. K, Na, Mg, Al.
B. Al, Mg, Na, K.
C. Mg, Al, Na, K.
D. Al, Mg, K, Na
V d 4. Khi trong khng kh nhm kh b n mn hn st l do
A. nhm c tnh kh mnh hn st.
B. trn b mt nhm c lp Al2O3 bo v
C. nhm c tnh kh yu hn st.
D. trn b mt nhm c lp Al(OH)3 bo v.
V d 5. Cho 0,28 mol Al vo dung dch HNO3 d, thu c kh NO v dung dch cha 62,04
gam mui. S mol NO thu c l
A. 0,1.
B. 0,14.
C. 0,2.
D. 0,28.
V d 6. Cho 16,2 gam kim loi M tc dng vi 0,15 mol oxi, cht rn thu c tc dng ht
vi dung dch HCl to ra 0,6 mol H2. Kim loi M l
A. Fe
B. Al
C. Ca
D. Mg
V d 7. (C7) Phn ng ho hc xy ra trong trng hp no di y khng thuc loi phn

ng nhit nhm?
A. Al tc dng vi Fe3O4 nung nng.
B. Al tc dng vi axit H2SO4 c, nng.
C. Al tc dng vi CuO nung nng.
D. Al tc dng vi Fe2O3 nung nng.
V d 8. Ln lt cho mt l nhm mng vo cc ng nghim cha lng d cc ha cht sau:

(1) dung dch HCl c ngui.
(2) dung dch H2SO4 c ngui.
(3) dung dch HNO3 c ngui.
(4) dung dch NaOH c ngui.
(5) dung dch NH3 c ngui.
(6) nc un nng.
Sau khi cc phn ng xy ra hon ton, s ng nghim m l nhm b ha tan ht l:

A. 2.
B. 3.
C. 4.
D. 5.
Dng 3. ng dng v sn xut

V d 9. Cho cc ng dng sau:
(1) ch to my bay, t, tn la, tu v tr.
(2) lm khung ca v trang tr ni tht.
(3) lm dy cp dn in.
(4) lm dng c un nu.
(5) ch to thit b trao i nhit.
(6) to hn hp tecmit (Al v Fe3O4) hn
ng ray.
S ng dng ca nhm l:
A. 3.
B. 4.
C. 5.
D. 6.
V d 10. Gii thch ti sao iu ch Al ngi ta in phn Al2O3 nng chy m khng in
phn AlCl3 nng chy l:
A. AlCl3 nng chy nhit cao hn Al2O3.
B. AlCl3 l hp cht khng nng chy m thng hoa
C. in phn AlCl3 to ra Cl2 rt c.
D. in phn Al2O3 cho ra Al tinh khit hn.
V d 11. (B7) thu c Al2O3 t hn hp Al2O3 v Fe2O3, ngi ta ln lt:
A. dng dung dch NaOH (d), kh CO2 (d), ri nung nng.
B. dng kh H2 nhit cao, dung dch NaOH (d).
C. dng kh CO nhit cao, dung dch HCl (d).
D. dng dung dch NaOH (d), dung dch HCl (d), ri nung nng.
V d 12. Trong qu trnh sn xut nhm trong cng nghip khong cht criolit (Na3AlF6) c
s dng vi mc ch chnh l
A. to thnh hn hp c kh nng dn in tt hn so vi ban u.
B. to ra lp bo v nhm nng chy khi s oxi ho ca oxi khng kh.
C. to thnh hn hp c nhit nng chy thp hn so vi ban u.
D. to ra lp bo v in cc khi b n mn.
V d 13. (B9) in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu
c m kg Al catot v 67,2 m3 ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly
2,24 lt ( ktc) hn hp kh X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta.
Gi tr ca m l
A. 108,0.
B. 75,6.
C. 54,0.
D. 67,5.
Dng 4. Hp cht quan trng ca nhm

V d 14. Dy cc hp cht va tc dng c vi dung dch HCl, va tc c vi dung dch
NaOH l
A. AlCl3, Al2O3, Al(OH)3
B. Al2O3, ZnO, NaHCO3
C. Zn(OH)2, Al2O3, Na2CO3
D. ZnO, Zn(OH)2, NH4Cl
V d 15. Dy gm cc cht u tc dng vi dung dch Al2(SO4)3 l:
A. CO2, NaOH, NH3
B. BaCl2, HCl, NaOH
C. Na2CO3, NH3, NaOH
D. NH3, NaOH, Fe
V d 16. (A7) Nh t t cho n d dung dch NaOH vo dung dch AlCl3. Hin tng xy ra
l
A. c kt ta keo trng, sau kt ta tan.
B. ch c kt ta keo trng.
D. khng c kt ta, c kh bay ln.
C. c kt ta keo trng v c kh bay ln.
V d 17. Khi cho phn chua vo nc ging khoan, nc sng, nc h, th phn chua c tc
dng ch yu no sau y ?
A. Kh mi.
B. Dit khun.
C. Lm trong nc.
D. Phn hy cc tp cht c trong nc.
V d 18. Mt loi phn c cng thc MAl(SO4)2.nH2O, trong M l kim loi kim. Ly 7,11
gam phn nung ti khi lng khng i thu 3,87 gam phn khan. Mt khc ly 7,11 gam phn
ha vo nc ri cho tc dng BaCl2 d thu c 6,99 gam kt ta. Cng thc ca phn l:
A. NaAl(SO4)2.12H2O.
B. KAl(SO4)2.12H2O.
C. NaAl(SO4)2.24H2O.
D. KAl(SO4)2.24H2O.

M055. PHNG PHP GII BI TON KIM LOI TC DNG VI DUNG DCH CHT IN LI
(T liu hc bi)
V d 1. (C7) Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X v 3,36 lt H2
(ktc). Th tch dung dch axit H2SO4 2M cn dng trung ho dung dch X l
A. 60ml.
B. 150ml.
C. 30ml.
D. 75ml.
V d 2. (A10) Ho tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v
2,688 lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4, t l mol tng ng l 4 : 1. Trung ho dung dch X
bi dung dch Y, tng khi lng cc mui c to ra l
A. 13,70 gam.
B. 12,78 gam.
C. 18,46 gam.
D. 14,62 gam.
V d 3. Ha tan hon ton hn hp Na, K, Ba vo nc c 100ml dung dch X v 0,56 lt kh H2 (ktc). Cho
100ml dung dch hn hp H2SO4 0,2M v HCl 0,3M vo 100ml dd X c dung dch Y. Gi tr pH ca Y l
A. 1,0.
B. 7,0.
C. 4,0.
D. 9,0.
(ktc). C cn dung dch sau phn ng khi lng cht rn thu c l:
A. 18,55 gam.
B. 17,55 gam.
C. 20,95 gam.
D. 12,95 gam.
V d 5. Cho 0,1 mol Ba vo dung dch X cha hn hp 0,2 mol CuSO4 v 0,12 mol HCl. Kt thc phn ng
thu c kt ta, nung nng nhit cao n khi lng khng i thu c bao nhiu gam cht rn ?
A. 13,98 gam.
B. 23,3 gam.
C. 26,5 gam.
D. 29,7 gam.
V d 6. Cho hn hp (Na, Al) ly d vo 91,6 gam dd H2SO4 21,4% th c V lt H2 (ktc). Gi tr ca V l
A. 4,48.
B. 49,28.
C. 94,08.
D. 47,04.
V d 7. (B7) Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th thot ra V lt kh. Nu cng
cho m gam X vo dung dch NaOH (d) th c 1,75V lt kh. Thnh phn phn trm theo khi lng ca Na
trong X l (bit cc th tch kh o trong cng iu kin)
A. 77,31%.
B. 39,87%.
C. 49,87%.
D. 29,87%.
V d 8. Cho m gam hn hp X gm Ba v Al vo lng nc d thy thot ra 8,96 lt kh H2 (ktc). Cng
cho m gam hn hp ny vo dung dch NaOH d th thu c 12,32 lt kh H2 (ktc). Gi tr ca m l
A. 13,70.
B. 21,80.
C. 57,50.
D. 58,85.
V d 9. Cho 10,5 gam hn hp bt Al v mt kim loi kim M vo nc. Sau phn ng c dung dch X
cha 2 cht tan v 5,6 lt kh (ktc). Cho t t dung dch HCl vo dung dch X lng kt ta thu c l ln
nht. Lc kt ta, sy kh, cn c 7,8 gam. Kim loi M l
A. Li.
B. Na.
C. K.
D. Rb.
V d 10. (C12) Hn hp X gm Na, Al v Fe (vi t l s mol gia Na v Al tng ng l 2 : 1). Cho X tc
dng vi H2O (d) thu c cht rn Y v V lt kh. Cho ton b Y tc dng vi dung dch H2SO4 long (d)
thu c 0,25V lt kh. Bit cc kh o cng iu kin, cc phn ng u xy ra hon ton. T l s mol ca Fe
v Al trong X tng ng l
A. 1 : 2.
B. 5 : 8.
C. 5 : 16.
D. 16 : 5.
V d 11. (A11) Chia hn hp X gm K, Al v Fe thnh hai phn bng nhau.
- Cho phn mt vo dung dch KOH (d) thu c 0,784 lt kh H2 (ktc).
- Cho phn hai vo mt lng d H2O, thu c 0,448 lt kh H2 (ktc) v m gam hn hp kim loi Y. Ha tan
hon ton Y vo dung dch HCl (d) thu c 0,56 lt kh H2 (ktc).
Khi lng (tnh theo gam) ca K, Al, Fe tnh trong mi phn hn hp X ln lt l :
A. 0,39 ; 0,54 ; 1,40.
B. 0,78; 0,54; 1,12.
C. 0,39; 0,54; 0,56.
D. 0,78; 1,08; 0,56.
V d 12. (A8) Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol
hn hp kh v dung dch X. Sc kh CO2 (d) vo X, lng kt ta thu c l 46,8 gam. Gi tr ca a l
A. 0,55.
B. 0,60.
C. 0,45.
D. 0,40.
M056. CHUYN NC CNG

(T liu hc bi)
V d 1. Cu no sau y l ng ?
A. Nc cng l nc c cha nhiu Ca2+, Mg2+.
B. Nc c cha anion HCO3 l nc cng tm thi.
C. Nc c cha 1 trong 2 ion Cl v SO 24 hoc c 2 l nc cng vnh cu.
D. Nc c cha ng thi anion HCO3 v SO 24 hoc Cl l nc cng ton phn.
V d 2. Trong 1 cc nc cha 0,01 mol Na+ ; 0,02 mol Ca2+ ; 0,01 mol Mg2+ ; 0,05 mol HCO3 ; 0,02 mol
Cl. Nc trong cc thuc loi
B. nc cng vnh cu.
C. nc mm.
D. nc cng ton phn.
A. nc cng tm thi.
+
2+
V d 3. (C11) Mt cc nc c cha cc ion : Na (0,02 mol), Mg (0,02 mol), Ca2+ (0,04 mol), Cl (0,02
mol), HCO3 (0,10 mol) v SO 24 (0,01 mol). un si cc nc trn cho n khi phn ng xy ra hon ton th
nc cn li trong cc
A. c tnh cng ton phn
B. c tnh cng vnh cu
C. l nc mm
D. c tnh cng tm thi
V d 4. C 4 cc mt nhn ng ring bit cc dung dch sau: nc nguyn cht; nc cng tm thi; nc
cng vnh cu; nc cng ton phn. Ch dng thm 01 ha cht no di y phn bit cc cc trn ?
A. NaHCO3.
B. MgCO3.
C. Na2CO3.
D. Ca(OH)2.
V d 5. Cho cc m t:
(1) lm tiu tn bt git;
(2) lm qun o nhanh hng;
(3) gy nhim c ngun nc;
(4) lm thc n lu chn v gim mi v;
(5) gy tiu tn nhin liu;
(6) lm tng nguy c mc bnh si thn ;
(7) gy nguy c n ni hi;
S m t ng vi tc hi ca nc cng l:
A. 4.
B. 5.
C. 6.
D. 7.
V d 6. C th dng nc cng tm thi vo vic no di y ?
A. un si lm nc ung.
B. Git qun o bng x phng.
C. Pha ch cc dung dch.
D. Dng cho cc bnh nng lnh.
V d 7. (A11) Dy gm cc cht u c th lm mt tnh cng tm thi ca nc l:
A. NaOH, Na3PO4, Na2CO3.
B. HCl, NaOH, Na2CO3.
C. KCl, Ca(OH)2, Na2CO3.
D. HCl, Ca(OH)2, Na2CO3.
V d 8. Cho cc phn ng m t cc phng php khc nhau lm mm nc cng (dng M2+ thay cho
Ca2+ v Mg2+) ?
MCO3 + CO2 + H2O

MCO3
(1) M2+ + 2 HCO3
(2) M2+ + HCO3 + OH
(3) M2+ + CO 32
(4) 3M2+ + 2 PO 34
S phng php c th p dng vi nc c cng tm thi l:

A. 1.
B. 2.
C. 3.
MCO3 + H2O
M3(PO4)2
D. 4.
V d 9. Cho cc cht sau: NaCl, Ca(OH)2, Na2CO3, HCl, NaHSO4. S cht c th lm mm nc cng tm
thi l
A. 1.
B. 2.
C. 3.
D. 4.
V d 10. (C8) Hai cht c dng lm mm nc cng vnh cu l
C. Na2CO3 v Ca(OH)2.
D. NaCl v Ca(OH)2.
A. Na2CO3 v HCl.
B. Na2CO3 v Na3PO4.
V d 11. Cho cc cht: Ca(OH)2 (1); Na2CO3 (2); Na2SO4 (3); NaOH (4); Na3PO4 (5). S ho cht c th dng
loi b cng ton phn l:
A. 1.
B. 3.
C. 2.
D. 4.
V d 12. Trong 1 cc nc cha 0,01 mol Na+ ; 0,02 mol Ca2+ ; 0,01 mol Mg2+ ; 0,05 mol HCO3 ; 0,02 mol
Cl. Cc cht c th dng lm mm nc trong cc l
A. HCl, Na2CO3, Na2SO4
B. Na2CO3, Na3PO4
C. Ca(OH)2, HCl, Na2SO4
D. Ca(OH)2, Na2CO3
+
V d 13. Mt loi nc cng c nng cc ion K : 0,04 mol/l, Mg2+: 0,04 mol/l, Ca2+: 0,04 mol/l, Cl : 0,04
2
mol/l, S O 4 : 0,04 mol/l, HCO3 : 0,08 mol/l. C th lm mm nc cng bng cch no trong cc cch sau ?
A. un nng nc
B. dng dung dch Na2CO3
C. dng dung dch HCl
D. un nng hoc dng dung dch Na2CO3
+
2+
V d 14. Cho dung dch cha cc ion sau (Na , Ca , Mg2+, Ba2+, H+, Cl). Mun tch c nhiu cation ra
khi dung dch m khng a ion l vo dung dch, ta c th cho dung dch tc dng vi cht no trong cc cht
sau:
A. Dung dch K2CO3 va
B. Dung dch Na2SO4 va
C. Dung ch NaOH va
D. Dung dch Na2CO3 va
V d 15. (A10) Cho dung dch X gm: 0,007 mol Na+; 0,003 mol Ca2+; 0,006 mol Cl; 0,006 mol HCO3 v
0,001 mol NO3 . loi b ht Ca2+ trong X cn mt lng va dung dch cha a gam Ca(OH)2. Gi tr ca
a l
A. 0,180.
B. 0,120.
C. 0,444.
2+
2+
D. 0,222.
V d 16. (C12) Dung dch E gm x mol Ca , y mol Ba , z mol HCO . Cho t t dung dch Ca(OH)2 nng
a mol/l vo dung dch E n khi thu c lng kt ta ln nht th va ht V lt dung dch Ca(OH)2. Biu
thc lin h gia cc gi tr V, a, x, y l
x + 2y
x+y
A. V =
B. V =
C. V = 2a(x + y)
D. V = a(2x + y)
a
a
V d 17. Dung dch X gm a mol Na+, b mol HCO3 , c mol CO 32 , d mol SO 24 . Cn dng 100 ml dung dch
Ba(OH)2 c nng l xM cho vo dung dch X th c lng kt ta ln nht. Biu thc lin h gia x vi
a, b l:
A. x = (3a + 2b)/0,2.
B. x = (2a + b)/0,2.
C. x = (a b)/0,2.
D. x = (a + b)/0,2.
V d 18. Cho dung dch X gm: 0,001 mol NO 3 ; 0,002 mol Mg2+; 0,003 mol Ca2+; 0,004 mol Cl v 0,005
mol HCO3 . Dn t t dung dch X qua nha trao i ion (nha cationit) thu c dung dch Y m thnh phn
cation ch c x mol Na+ (xem nh thnh phn anion khng thay i). Gi tr ca x l
A. 0,005.
B. 0,010.
C. 0,015.
D. 0,020.

M057. PHNG PHP GII BI TON CO2 (SO2)

TC DNG VI DUNG DCH KIM
(T liu hc bi)
V d 1. Thi t t n d kh CO2 vo dung dch NaOH, mui to thnh trong dung dch l
A. ch c Na2CO3.
B. ch c NaHCO3.
C. u tin to NaHCO3 ; sau to Na2CO3. D. u tin to Na2CO3 ; sau to NaHCO3.
V d 2. Thi kh CO2 t t n d vo bnh cha dung dch Ca(OH)2. Cht c trong bnh sau
khi cc phn ng kt thc l:
B. CaCO3.
A. Ca(HCO3)2.
C. Ca(HCO3)2 v CaCO3.
D. CaCO3 v Ca(OH)2.
V d 3. Hin tng xy ra khi sc t t n d kh CO2 vo dung dch cha hn hp NaOH
v Ba(OH)2 l:
A. Ban u khng c hin tng g sau xut hin kt ta v tan ngay.
B. Dung dch vn c, c tng dn n cc i sau gim dn n trong sut.
C. Dung dch vn c, c tng dn n cc i v khng i mt thi gian sau gim dn
n trong sut.
D. Ban u khng c hin tng g n mt lc no dung dch vn c, c tng dn n
cc i sau gim dn n trong sut.
V d 4. Hp th hon ton 2,24 lt CO2 (kc) vo bnh cha dung dch ha tan 0,15 mol
Ba(OH)2. Cht c trong bnh sau khi cc phn ng kt thc l:
A. Ch c BaCO3.
B. Ch c Ba(HCO3)2.
C. C BaCO3 v Ba(HCO3)2.
D. C BaCO3 v Ba(OH)2.
V d 5. Hp th hon ton 2,24 lt CO2 (ktc) vo dung dch nc vi trong c cha 0,075
mol Ca(OH)2. Cht thu c sau phn ng l:
A. Ch c CaCO3.
B. Ch c Ca(HCO3)2.
C. CaCO3 v Ca(HCO3)2.
D. Ca(HCO3)2 v Ca(OH)2.
V d 6. Hp th hon ton a mol kh CO2 vo dung dch cha b mol Ba(OH)2 th thu c
hn hp 2 mui BaCO3 v Ba(HCO3)2. Quan h gia a v b l:
A. a > b.
B. a < b.
C. b < a < 2b.
D. a = b.
V d 7. (C12) Hp th hon ton 0,336 lt kh CO2 (ktc) vo 200 ml dung dch gm NaOH
0,1M v KOH 0,1M thu c dung dch X. C cn ton b dung dch X thu c bao nhiu
gam cht rn khan ?
A. 2,44 gam.
B. 2,22 gam.
C. 2,31 gam.
D. 2,58 gam.
V d 8. (C10) Hp th hon ton 3,36 lt kh CO2 (ktc) vo 125 ml dung dch Ba(OH)2 1M,
thu c dung dch X. Coi th tch dung dch khng thay i, nng mol ca cht tan trong
dung dch X l
A. 0,4M.
B. 0,2M.
C. 0,6M.
D. 0,1M.
V d 9. (A7) Hp th hon ton 2,688 lt kh CO2 (ktc) vo 2,5 lt dung dch Ba(OH)2 nng
a mol/l, thu c 15,76 gam kt ta. Gi tr ca a l
A. 0,032.
B. 0,048.
C. 0,06.
D. 0,04.
V d 10. (A11) Hp th hon ton 0,672 lt kh CO2 (ktc) vo mt lt dung dch gm NaOH
0,025M v Ca(OH)2 0,0125M, thu c x gam kt ta. Gi tr ca x l
A. 2,00.
B. 0,75.
C. 1,25.
D. 1,00.
V d 11. (B12) Sc 4,48 lt kh CO2 (ktc) vo 1 lt dung dch hn hp Ba(OH)2 0,12M v
NaOH 0,06M. Sau khi cc phn ng xy ra hon ton thu c m gam kt ta. Gi tr ca m l
A. 19,70.
B. 23,64.
C. 7,88.
D. 13,79.
V d 12. (B10) t chy hon ton m gam FeS2 bng mt lng O2 va , thu c kh X.
Hp th ht X vo 1 lt dung dch cha Ba(OH)2 0,15M v KOH 0,1M, thu c dung dch Y
v 21,7 gam kt ta. Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l
A. 23,2.
B. 12,6.
C. 18,0.
D. 24,0.
V d 13. Hp th ton b 0,3 mol CO2 vo dung dch cha 0,25 mol Ca(OH)2. Khi lng
dung dch sau phn ng tng hay gim bao nhiu gam ?
A. Tng 13,2 gam.
B. Tng 20 gam.
C. Gim 16,8 gam.
D. Gim 6,8 gam.
V d 14. Hp th hon ton 0,16 mol CO2 vo 2 lt dung dch Ca(OH)2 0,05M c kt ta X
v dung dch Y. Khi khi lng dung dch Y so vi khi lng dung dch Ca(OH)2 ban u
s
A. tng 3,04 gam.
B. gim 3,04 gam.
C. tng 7,04 gam.
D. gim 7,04 gam.
V d 15. (A12) t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng)
ri em ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn
ng thu c 39,4 gam kt ta v khi lng phn dung dch gim bt 19,912 gam. Cng thc
phn t ca X l
A. C3H4.
B. CH4.
C. C2H4.
D. C4H10.
V d 16. (A11) t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl
acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn
ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch
Ca(OH)2 ban u thay i nh th no?
A. Tng 2,70 gam.
B. Gim 7,74 gam.
C. Tng 7,92 gam.
D. Gim 7,38 gam.

M058. PHNG PHP GII BI TON V MUI CACBONAT

(T liu hc bi)
V d 1. C cc nhn nh sau (xt trong iu kin thng thng):

(1) Tt c cc mui cacbonat u b nhit phn.
(2) Tt c cc mui hirocacbonat u b nhit phn.
(3) Tt c cc mui cacbonat u khng tan trong nc.
(4) Tt c cc mui hirocacbonat u tan tt trong nc.
S nhn nh ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 2. Trn ln cc cp dung dch sau:
(1) Na2CO3 v AlCl3.
(2) NaHSO4 v NaHCO3.
(3) KHCO3 v NH4Cl.
(4) HClO v KHCO3.
S th nghim c kh thot ra l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 3. (A8) T hai mui X v Y thc hin cc phn ng sau:
X1 + CO2
X
X1 + H2O X2
X2 + Y X + Y1 + H2O
X2 + 2Y X + Y2 + 2H2O
Hai mui X, Y tng ng l
A. BaCO3, Na2CO3.
B. CaCO3, NaHSO4. C. MgCO3, NaHCO3. D. CaCO3, NaHCO3.
V d 4. C 3 dung dch hn hp :
(2) NaHCO3 + Na2SO4
(3) Na2CO3 + Na2SO4
(1) NaHCO3 + Na2CO3
Ch dng thm mt cp cht no trong s cc cp cht cho di y c th phn bit c
cc dung dch hn hp trn ?
A. Dung dch HNO3 v dung dch KNO3.
B. Dung dch HCl v dung dch KNO3.
C. Dung dch HNO3 v dung dch Ba(NO3)2. D. Dung dch Ba(OH)2 d.
V d 5. Nung nng 100 gam hn hp gm Na2CO3 v NaHCO3 cho n khi lng khng
i cn li 69 gam cht rn. % khi lng mi cht trong hn hp u l
A. 63% v 37%
B. 42% v 58%
C. 16% v 84%
D. 84% v 16%.
V d 6. Nung 49,2 gam hn hp Ca(HCO3)2 v NaHCO3 n khi lng khng i, c 5,4
gam H2O. Khi lng cht rn thu c l
A. 43,8 gam.
B. 30,6 gam.
C. 21,8 gam.
D. 17,4 gam.
V d 7. (A10) Cho m gam NaOH vo 2 lt dung dch NaHCO3 nng a mol/l, thu c 2 lt
dung dch X. Ly 1 lt dung dch X tc dng vi dung dch BaCl2 (d) thu c 11,82 gam kt
ta. Mt khc, cho 1 lt dung dch X vo dung dch CaCl2 (d) ri un nng, sau khi kt thc
cc phn ng thu c 7,0 gam kt ta. Gi tr ca a, m tng ng l
A. 0,08 v 4,8.
B. 0,04 v 4,8.
C. 0,14 v 2,4.
D. 0,07 v 3,2.
to
V d 8. Cho 7,0 gam hn hp hai mui cacbonat ca kim loi ha tr II tc dng ht vi dung
dch HCl thy thot ra V lt kh iu kin tiu chun. C cn dung dch sau phn ng thu c
9,2 gam mui khan. Gi tr ca V l
A. 1,12 lt.
B. 2,24 lt.
C. 3,36 lt.
D. 4,48 lt.
V d 9. Ha tan hon ton 4 gam hn hp MCO3 v RCO3 bng dung dch HCl d thy thot
ra V lt kh (ktc). Dung dch thu c em c cn c 5,1 gam mui khan. Gi tr ca V l
A. 1,12 lt.
B. 1,68 lt.
C. 2,24 lt.
D. 3,36 lt.
V d 10. (B8) Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc
dng ht vi dung dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l
A. Na.
B. Li.
C. K.
D. Rb.
V d 11. (C10) Cho 9,125 gam mui hirocacbonat phn ng ht vi dung dch H2SO4 (d),
thu c dung dch cha 7,5 gam mui sunfat trung ho. Cng thc ca mui hirocacbonat l
B. Mg(HCO3)2.
C. Ba(HCO3)2.
D. Ca(HCO3)2.
A. NaHCO3.
V d 12. (A7) Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng
thi khuy u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung
dch X thy c xut hin kt ta. Biu thc lin h gia V vi a, b l:
A. V = 22,4(a b).
B. V = 11,2(a b).
C. V = 11,2(a + b).
D. V = 22,4(a + b).
V d 13. (A12) Cho hn hp K2CO3 v NaHCO3 (t l mol 1 : 1) vo bnh dung dch
Ba(HCO3)2 thu c kt ta X v dung dch Y. Thm t t dung dch HCl 0,5M vo bnh n
khi khng cn kh thot ra th ht 560 ml. Bit ton b Y phn ng va vi 200 ml dung dch
NaOH 1M. Khi lng kt ta X l
A. 3,94 gam.
B. 7,88 gam.
C. 11,28 gam.
D. 9,85 gam.
V d 14. Trn 100ml dung dch cha KHCO3 1M v K2CO3 1M vi 100ml dung dch cha
NaHCO3 1M v Na2CO3 1M c 200ml dung dch X. Nh t t 100ml dung dch Y cha
H2SO4 1M v HCl 1M vo dung dch X c V lt CO2 (ktc) v dung dch Z. Cho Ba(OH)2 d
vo Z th thu c m gam kt ta. Gi tr ca V v m ln lt l
A. 5,6 v 59,1.
B. 1,12 v 82,4.
C. 2,24 v 59,1.
D. 2,24 v 82,4.
V d 15. Cho t t dung dch cha 0,015 mol HCl vo dung dch cha a mol K2CO3 thu c
dung dch X (khng cha HCl) v 0,005 mol CO2. Nu th nghim trn c tin hnh ngc
li (cho t t K2CO3 vo dung dch HCl) th s mol CO2 thu c l
A. 0,005.
B. 0,0075.
C. 0,01.
D. 0,015.
V d 16. C 2 cc ring bit: cc 1 ng dung dch cha 0,2 mol Na2CO3 v 0,3 mol NaHCO3
; cc 2 ng dung dch cha 0,5 mol HCl. Khi nh t t cc 1 vo cc 2 thy thot ra V lt kh
CO2 (ktc). Gi tr ca V l
A. 6,72.
B. 7,84.
C. 8,00.
D. 8,96.
M059. PHNG PHP GII BI TON V HIROXIT LNG TNH

(T liu hc bi)
V d 1. (A7) Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt ta th cn
c t l
A. a : b = 1 : 4.
B. a : b < 1 : 4.
C. a : b = 1 : 5.
D. a : b > 1 : 4.
V d 2. (C9) Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl3; 0,016 mol
Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l
A. 2,568.
B. 1,560.
C. 4,128.
D. 5,064.
V d 3. (A8) Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol H2SO4 n khi
phn ng hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l
A. 0,35.
B. 0,45.
C. 0,25.
D. 0,05.
V d 4. (B10) Cho 150 ml dung dch KOH 1,2M tc dng vi 100 ml dung dch AlCl3 nng x mol/l, thu
c dung dch Y v 4,68 gam kt ta. Loi b kt ta, thm tip 175 ml dung dch KOH 1,2M vo Y, thu c
2,34 gam kt ta. Gi tr ca x l
A. 1,2.
B. 0,8.
C. 0,9.
D. 1,0.
V d 5. (A9) Ho tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110 ml dung dch KOH 2M vo X,
thu c a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta.
Gi tr ca m l
A. 20,125.
B. 22,540.
C. 12,375.
D. 17,710.
V d 6. (A10) Ho tan hon ton m gam ZnSO4 vo nc c dung dch X. Nu cho 110 ml dung dch
KOH 2M vo X th thu c 3a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th thu c
2a gam kt ta. Gi tr ca m l
A. 17,17.
B. 16,10.
C. 14,49.
D. 24,15.
V d 7. (C7) Thm m gam kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch
X. Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta
Y ln nht th gi tr ca m l
A. 1,59.
B. 1,17.
C. 1,95.
D. 1,71.
V d 8. (B11) Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung
dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc
dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. T l x : y l
A. 4 : 3
B. 3 : 4
C. 7 : 4
D. 3 : 2
V d 9. (A12) Cho 500ml dung dch Ba(OH)2 0,1M vo V ml dung dch Al2(SO4)3 0,1M; sau khi cc phn
ng kt thc thu c 12,045 gam kt ta. Gi tr ca V l
A. 75.
B. 150.
C. 300.
D. 200.
V d 10. (C9) Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch
Y ch cha cht tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta. Gi tr ca m
v a ln lt l
A. 8,3 v 7,2.
B. 11,3 v 7,8.
C. 13,3 v 3,9.
D. 8,2 v 7,8.
V d 11. Cho dung dch X cha 0,05 mol Na[Al(OH)4] v 0,1 mol NaOH tc dng vi dung dch HCl 2M. Th
tch dung dch HCl 2M ln nht cn cho vo dung dch X xut hin 1,56 gam kt ta l
A. 0,06 lt .
B. 0,08 lt.
C. 0,12 lt.
D. 0,18 lt.
V d 12. (A12) Ha tan hon ton m gam hn hp gm Na2O v Al2O3 vo nc thu c dung dch X trong
sut. Thm t t dung dch HCl 1M vo X, khi ht 100 ml th bt u xut hin kt ta; khi ht 300 ml hoc 700
ml th u thu c a gam kt ta. Gi tr ca a v m ln lt l
A. 23,4 v 56,3.
B. 23,4 v 35,9.
C. 15,6 v 27,7.
D. 15,6 v 55,4.
M060. PHNG PHP GII BI TON NHIT NHM

(T liu hc bi)
V d 1. (C11) Dy gm cc oxit u b Al kh nhit cao l:

A. FeO, CuO, Cr2O3 B. PbO, K2O, SnO
C. FeO, MgO, CuO
D. Fe3O4, SnO, BaO.
V d 2. t nng mt hn hp Al v Fe3O4 trong mi trng khng c khng kh. Sau khi
phn ng xy ra hon ton thu c hn hp X. Cho X tc dng vi dung dch NaOH d thu
c kh H2 bay ra. Cc cht c trong hn hp X l
B. Al, Fe, Fe2O3, Al2O3.
A. Al, Fe, Al2O3.
C. Al, Fe, Fe3O4, Al2O3.
D. Al, Fe, FeO, Al2O3.
V d 3. (A12) Hn hp X gm Fe3O4 v Al c t l mol tng ng 1 : 3. Thc hin phn ng
nhit nhm X (khng c khng kh) n khi phn ng xy ra hon ton thu c hn hp gm
A. Al2O3 v Fe.
B. Al, Fe v Al2O3.
C. Al, Fe, Fe3O4 v Al2O3.
D. Al2O3, Fe v Fe3O4.
V d 4. (C7) Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung
dch NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton
41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo
khi lng ca Cr2O3 trong hn hp X l
A. 20,33%.
B. 50,67%.
C. 36,71%.
D. 66,67%.
V d 5. (C8) t nng mt hn hp gm Al v 16 gam Fe2O3 (trong iu kin khng c
khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng va
vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 (ktc). Gi tr ca V l
A. 150.
B. 100.
C. 200.
D. 300.
V d 6. (C12) Nung hn hp bt gm Al v Fe2O3 (trong iu kin khng c oxi), thu c
hn hp cht rn X. Chia X thnh 2 phn bng nhau:
- Cho phn 1 vo dung dch HCl (d) thu c 7,84 lt kh H2 (ktc);
- Cho phn 2 vo dung dch NaOH (d) thu c 3,36 lt kh H2 (ktc).
Bit rng cc phn ng u xy ra hon ton. Phn trm khi lng ca Fe trong X l
A. 42,32%.
B. 46,47%.
C. 66,39%.
D. 33,61%.
V d 7. (B9) Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng
kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch
NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo
dung dch Y, thu c 39 gam kt ta. Gi tr ca m l
A. 45,6.
B. 48,3.
C. 36,7.
D. 46,7.
V d 8. (C9) iu ch c 78 gam Cr t Cr2O3 (d) bng phng php nhit nhm vi

hiu sut ca phn ng l 90% th khi lng bt nhm cn dng ti thiu l
A. 81,0 gam.
B. 54,0 gam.
C. 40,5 gam.
D. 45,0 gam.
V d 9. (B10) Trn 10,8 gam bt Al vi 34,8 gam bt Fe3O4 ri tin hnh phn ng nhit
nhm trong iu kin khng c khng kh. Ho tan hon ton hn hp rn sau phn ng bng
dung dch H2SO4 long (d) thu c 10,752 lt kh H2 (ktc). Hiu sut ca phn ng nhit
nhm l
A. 80%.
B. 90%.
C. 70%.
D. 60%.
V d 10. Hn hp X gm Al v Fe3O4. Nung hn hp X nhit cao thu c hn hp Y.
Chia Y lm 2 phn bng nhau:
Phn 1 cho vo dung dch NaOH ly d, sau phn ng thu c 1,344 lt kh (ktc).
Phn 2 ha tan ht trong 310 ml dung dch H2SO4 1M (long) thu c 3,36 lt kh (ktc).
Hiu sut ca phn ng nhit nhm l
A. 60%.
B. 66,67%.
C. 75%.
D. 80%.
V d 11. Hn hp X gm Al, FexOy. Tin hnh phn ng nhit nhm hon ton m gam hn
hp X trong iu kin khng c khng kh thu c hn hp Y. Chia Y thnh 2 phn.
Phn 1 cho tc dng vi dung dch NaOH d thu c 1,008 lt H2 (ktc) v cn li 5,04 gam
cht rn khng tan.
Phn 2 c khi lng 29,79 gam, cho tc dng vi dung dch HNO3 long d thu c 8,064
lt NO (ktc, l sn phm kh duy nht).
Gi tr ca m v cng thc ca oxit st l:
A. 39,72 gam v FeO
B. 39,72 gam v Fe3O4
C. 38,91 gam v FeO
D. 36,48 gam v Fe3O4
V d 12. (B02) Cho hn hp X c khi lng m gam gm bt Al v st oxit FexOy. Tin hnh
phn ng nhit nhm trong iu kin khng c khng kh, thu c hn hp Y. Nghin nh,
trn u Y ri chia thnh hai phn. Phn mt c khi lng 14,49 gam c ho tan ht trong
dung dch HNO3 un nng, thu c dung dch Z v 3,696 lt kh NO duy nht ktc. Cho
phn hai tc dng vi lng d dung dch NaOH un nng thy gii phng 0,336 lt kh H2
ktc v cn li 2,52 gam cht rn. Cc phn ng xy ra hon ton. Cng thc oxit v gi tr ca
m ln lt l
A. Fe3O4 ; 18,72.
B. Fe2O3 ; 18,72.
C. Fe3O4 ; 19,32.
D. Fe2O3 ; 19,32.
M061. L THUYT TRNG TM V CROM V HP CHT

(T liu hc bi)
V d 1. C cc m t sau v cu to v v tr ca Crom:
(1) Kim loi h d.
(3) Mng lp phng tm khi.
(5) C 2 electron lp ngoi cng.
S m t ng l:
A. 2.
B. 3.
V d 2. C cc m t sau v tnh cht ca Crom:
(1) Mu lc.
(2) Kim loi cng nht.
(4) D nng chy.
(5) Kim loi nng.
S m t ng l:
A. 2.
B. 3.
V d 3. Cho cc phn ng ca Crom vi phi kim:
(2) C 6 electron c thn.

(4) Thuc chu k 4, nhm VIA.
(6) S oxi ha quan trng: +2, +4, +6.
C. 4.
D. 5.
(3) Rch c thy tinh.
(6) C nhiu trng thi oxi ha trong hp cht.
C. 4.
(1) 3Cr + 2O2
D. 5.
t
o
Cr3O4.
(2) 2Cr + 3Cl2
2CrCl3
CrS.
2CrN
(3) Cr + S
(4) 2Cr + N2
S phn ng vit ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 4. Cho cc so snh sau v tnh cht ha hc ca nhm v crom:
(1) Nhm v crm u b th ng ha trong dung dch HNO3 c ngui.
(2) Nhm v crm u phn ng vi dung dch HCl theo cng t l v s mol.
(3) Nhm c tnh kh mnh hn crom.
(4) Nhm v crm u bn trong khng kh v trong nc.
S so snh ng l:
A. 1.
B. 2.
C. 3.
D. 4.
(1) L kim loi nhm VIB.
(2) C nhiu s oxi ha.
(3) Khng tan trong H2SO4 c ngui, do c mng oxit bn bo v.
(4) Tc dng vi HCl (hoc H2SO4 long) cho hp cht vi s oxi ha +2.
(5) Tc dng vi Cl2 cho mui MCl3.
S m t ng cho c Cr v Fe l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 6. (C10) Cho m gam bt crom phn ng hon ton vi dung dch HCl (d) thu c V lt kh H2 (ktc). Mt khc
cng m gam bt crom trn phn ng hon ton vi kh O2 (d) thu c 15,2 gam oxit duy nht. Gi tr ca V l
A. 2,24.
B. 4,48.
C. 3,36.
D. 6,72.
V d 7. Cho cc m t sau v ng dng ca crom:
(1) Crom l kim loi rt cng c th dng ct thy tinh.
(2) Crom lm hp kim cng v chu nhit hn, nn dng to thp cng, khng g, chu nhit.
(3) Crom l kim loi nh, nn c s dng to cc hp kim dng trong ngnh hng khng.
(4) Crom to c lp mng oxit mn, bn chc nn c dng m bo v thp.
S m t ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 8. Hin nay, t qung cromit (FeO.Cr2O3) ngi ta iu ch Cr bng phng php no sau y ?
A. tch qung ri thc hin in phn nng chy Cr2O3.
B. tch qung ri thc hin phn ng nhit nhm Cr2O3.
C. tch qung ri thc hin phn ng kh Cr2O3 bi CO.
D. ha tan qung bng HCl ri in phn dung dch CrCl3.
t
V d 9. Trong cng nghip, hin nay crm c iu ch theo s sau:

H = 90%
H = 85%
H =80%
H = 75%
FeCr2 O 4
Na 2 CrO 4
Na 2 Cr2 O 7
Cr2 O 3
Cr
(1)
(2)
(3)
(4)
iu ch c 65,0 kg Cr cn dng lng ti thiu FeCr2O4 l:

A. 128,5 kg.
B. 140,0 kg.
C. 280,0 kg.
D. 305,0 kg.
V d 10. (B12) Nung nng 46,6 gam hn hp gm Al v Cr2O3 (trong iu kin khng c khng kh) n khi phn ng
xy ra hon ton. Chia hn hp thu c sau phn ng thnh hai phn bng nhau. Phn mt phn ng va vi 300 ml
dung dch NaOH 1M (long). ha tan ht phn hai cn va dung dch cha a mol HCl. Gi tr ca a l
A. 0,9
B. 1,3
C. 0,5
D. 1,5
V d 11. Cho bng mu ca cc cht rn sau:
CrO
Cr(OH)2
Cr2O3
Cr(OH)3
CrO3
BaCrO4
K2Cr2O7
K2SO4.Cr2(SO4)3.24H2O
en
vng
lc thm
lc xm
thm
vng
da cam
xanh tm
S m t ng l:
A. 5.
B. 6.
C. 7.
D. 8.
(1) Crom (VI) oxit l oxit baz.
(2) Ancol etylic bc chy khi tip xc vi CrO3.
(3) Khi phn ng vi dung dch HCl, kim loi Cr b oxi ho thnh ion Cr2+.
(4) Cc hp cht Cr2O3, Cr(OH)3, CrO, Cr(OH)2 u c tnh cht lng tnh.
(5) Hp cht Cr(II) c tnh kh c trng cn hp cht Cr(VI) c tnh oxi ho mnh.
(6) Cc hp cht CrO, Cr(OH)2 tc dng c vi dung dch HCl cn CrO3 tc dng c vi dung dch NaOH.
S pht biu ng l:
A. 1.
B. 2.
C. 3.
D. 4.
(1) SO3 v CrO3 u l oxit axit.
(2) Cr(OH)3 tan trong dung dch NaOH.
(3) Photpho bc chy khi tip xc vi CrO3.
(4) Trong mi trng axit, Zn kh Cr3+ thnh Cr.
(5) Fe(OH)2 v Cr(OH)2 u l baz v c tnh kh.
(6) BaSO4 v BaCrO4 hu nh khng tan trong nc.
2
(7) Trong mi trng kim, Br2 oxi ha C rO 2 thnh CrO 4 .
(8) Al(OH)3 v Cr(OH)3 u l hiroxit lng tnh v c tnh kh.
S pht biu ng l:
A. 4.
B. 5.
C. 6.
D. 7.
2CrO 24 + 2H + . Trong cc trng hp sau: (1) thm

V d 14. Cho cn bng ha hc sau: Cr2 O72 + H 2 O
OH vo h; (2) pha long; (3) thm BaCl2; (4) thm Na2CO3; (5) thm NH4Cl; (6) thm vi tinh th NaCl. S trng hp
khi tc ng vo h lm cho dung dch chuyn sang mu vng l:
A. 4
B. 5
C. 3
D. 6.
+ Cl d, t
+ KOH (c, d) + Cl 2
Y
V d 15. (C12) Cho s phn ng: Cr 2 X
o
Bit Y l hp cht ca crom. Hai cht X v Y ln lt l

B. CrCl3 v K2Cr2O7
C. CrCl3 v K2CrO4
A. CrCl2 v K2CrO4.
V d 16. (B9) Cho s chuyn ho gia cc hp cht ca crom:
D. CrCl2 v Cr(OH)3
+ (Cl2 + KOH)
+ H 2SO 4
+ FeSO4 + H 2SO4
+ KOH
Cr(OH)3
X
Y
Z
T
Cc cht X, Y, Z, T theo th t ln lt l:
A. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3
B. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3
C. KCrO2; K2Cr2O7; K2CrO4; CrSO4
D. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3
V d 17. (A8) oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt KOH, lng ti thiu Cl2 v
KOH tng ng l
A. 0,03 mol v 0,08 mol.
B. 0,015 mol v 0,08 mol.
C. 0,015 mol v 0,04 mol.
D. 0,03 mol v 0,04 mol.
V d 18. (A10) Trong phn ng: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O
S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr ca k l
A. 3/14.
B. 4/7.
C. 1/7.
D. 3/7.

M062. L THUYT TRNG TM V ST V HP CHT

(T liu hc bi)
V d 1. C cc m t sau v cu to v v tr ca St:
(1) Kim loi h d.
(4) Thuc chu k 4, nhm VIIIB.
(5) C 2 electron ha tr.
S m t ng l:
A. 2.
B. 3.
C. 4.
V d 2. C cc m t sau v tnh cht ca St:
(2) Dn in, dn nhit tt.
(1) Mu trng xm.
(4) D nng chy.
(5) C kh nng nhim t.
S m t ng l:
A. 2.
B. 3.
C. 4.
V d 3. Cho cc phn ng ca St vi phi kim:

(6) S oxi ha quan trng: +2, +3.
D. 5.
(3) Kim loi nng.
(6) C kh nng xc tc.
D. 5.
(1) 3Fe + 2O2
Fe3O4.
(2) 2Fe + 3Cl2
2FeCl3.
FeS.
FeI2.
(3) Fe + S
(4) Fe + I2
S phn ng vit ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 4. Cho cc so snh sau v tnh cht ha hc ca st v nhm:
(1) Nhm c tnh kh mnh hn st.
(2) Trong khng kh v nc, nhm bn hn st.
(3) Nhm v st u b th ng ha trong dung dch HNO3 c ngui.
(4) Nhm v st u phn ng vi dung dch H2SO4 long theo cng t l v s mol.
S so snh ng l:
A. 1.
B. 2.
C. 3.
D. 4.
(1) L kim loi nhm B.
(2) Khng tan trong dung dch NaOH long.
(3) Khng tan trong HNO3 c ngui, nhng tan trong HNO3 long.
A. 1.
B. 2.
C. 3.
D. 4.
V d 6. (A11) Thc hin cc th nghim sau:
(1) t dy st trong kh clo.
(2) t nng hn hp bt Fe v S (trong iu kin khng c oxi)
(3) Cho FeO vo dung dch HNO3 (long, d)
(4) Cho Fe vo dung dch Fe2(SO4)3
(5) Cho Fe vo dung dch H2SO4 (long, d)
C bao nhiu th nghim to ra mui st(II) ?
A. 3.
B. 2.
C. 1.
D. 4.
t
V d 7. Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long d thu
c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. Dung dch X c th ha tan ti a 12,88
gam Fe. S mol HNO3 c trong dung dch u l
A. 0,94 mol
B. 0,88 mol
C. 0,64 mol
D. 0,77 mol
V d 8. (C9) Cho 100 ml dung dch FeCl2 1,2M tc dng vi 200 ml dung dch AgNO3 2,0M, thu c m
gam kt ta. Gi tr ca m l
A. 34,44.
B. 47,4.
C. 30,18.
D. 12,96.
V d 9. Cho cc loi qung st sau: (1) pirit st;
(2) xierit;
(3) hematit ;
(4) manhetit;
Dy sp xp theo chiu tng dn hm lng Fe trong cc qung trn l:
A. (1) < (2) < (3) < (4).
B. (3) < (1) < (2) < (4).
C. (4) < (3) < (2) < (1).
D. (1) < (2) < (4) < (3).
V d 10. (A7) Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4,
Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho kh l
A. 8.
B. 5.
C. 7.
D. 6.
V d 11. (A7) Khi nung hn hp cc cht Fe(NO3)2, Fe(OH)3 v FeCO3 trong khng kh n khi lng khng
i, thu c mt cht rn l
A. Fe3O4.
B. FeO.
C. Fe.
D. Fe2O3.
V d 12. (C8) Ha tan hon ton Fe3O4 trong dung dch H2SO4 long (d) c dung dch X1. Cho lng d
bt Fe vo dung dch X1 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c
dung dch X2 cha cht tan l
A. Fe2(SO4)3 v H2SO4.
B. FeSO4.
C. Fe2(SO4)3.
D. FeSO4 v H2SO4.
V d 13. (B12) Cho cc cht sau: FeCO3, Fe3O4, FeS, Fe(OH)2. Nu ha tan cng s mol mi cht vo dung
dch H2SO4 c, nng (d) th cht to ra s mol kh ln nht l
A. Fe3O4
B. Fe(OH)2
C. FeS
D. FeCO3
V d 14. (B8) Nung mt hn hp rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh (d).
Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe2O3 v
hn hp kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia a v b l (bit sau
cc phn ng, lu hunh mc oxi ho +4)
A. a = 4b.
B. a = 2b.
C. a = b.
D. a = 0,5b.
V d 15. (A11) Nung m gam hn hp X gm FeS v FeS2, trong mt bnh kn cha khng kh (gm 20 % th
tch O2 v 80% th tch N2) n khi cc phn ng ny xy ra hon ton, thu c mt cht rn duy nht v hn
hp kh Y c thnh phn th tch: 84,8% N2, 14% SO2, cn li l O2. % khi lng ca FeS trong hn hp X l:
A. 59,46%
B. 19,64%
C. 42,31%
D. 26,83%
V d 16. (B11) Ha tan 25 gam hn hp X gm FeSO4 v Fe2(SO4)3 vo nc, thu c 150 ml dung dch Y.
Thm H2SO4 (d) vo 20ml dung dch Y ri chun ton b dung dch ny bng dung dch KMnO4 0,1M th
dng ht 30 ml dung dch chun. Phn trm khi lng FeSO4 trong hn hp X l
A. 13,68%
B. 68,4%
C. 9,12%
D. 31,6%
V d 17. (B8) Nguyn tc luyn thp l:
A. Dng O2 oxi ho cc tp cht Si, P, S, Mn, ... trong gang thu c thp.
B. Dng cht kh CO kh oxit st thnh st nhit cao.
C. Dng CaO hoc CaCO3 kh tp cht Si, P, S, Mn, ... trong gang thu c thp.
D. Tng thm hm lng cacbon trong gang thu c thp.
V d 18. (B11) luyn c 800 tn gang c hm lng st 95%, cn dng m tn qung manhetit cha 80%
Fe3O4 (cn li l tp cht khng cha st). Bit rng lng st b hao ht trong qu trnh sn xut l 1%. Gi tr
ca m l:
A. 959,59.
B. 1311,90.
C. 1394,90.
D. 1325,16.
M062. L THUYT TRNG TM V ST V HP CHT

(T liu hc bi)
V d 1. C cc m t sau v cu to v v tr ca St:
(1) Kim loi h d.
(4) Thuc chu k 4, nhm VIIIB.
(5) C 2 electron ha tr.
S m t ng l:
A. 2.
B. 3.
C. 4.
V d 2. C cc m t sau v tnh cht ca St:
(2) Dn in, dn nhit tt.
(1) Mu trng xm.
(4) D nng chy.
(5) C kh nng nhim t.
S m t ng l:
A. 2.
B. 3.
C. 4.
V d 3. Cho cc phn ng ca St vi phi kim:

(6) S oxi ha quan trng: +2, +3.
D. 5.
(3) Kim loi nng.
(6) C kh nng xc tc.
D. 5.
(1) 3Fe + 2O2
Fe3O4.
(2) 2Fe + 3Cl2
2FeCl3.
FeS.
FeI2.
(3) Fe + S
(4) Fe + I2
S phn ng vit ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 4. Cho cc so snh sau v tnh cht ha hc ca st v nhm:
(1) Nhm c tnh kh mnh hn st.
(2) Trong khng kh v nc, nhm bn hn st.
(3) Nhm v st u b th ng ha trong dung dch HNO3 c ngui.
(4) Nhm v st u phn ng vi dung dch H2SO4 long theo cng t l v s mol.
S so snh ng l:
A. 1.
B. 2.
C. 3.
D. 4.
(1) L kim loi nhm B.
(2) Khng tan trong dung dch NaOH long.
(3) Khng tan trong HNO3 c ngui, nhng tan trong HNO3 long.
A. 1.
B. 2.
C. 3.
D. 4.
V d 6. (A11) Thc hin cc th nghim sau:
(1) t dy st trong kh clo.
(2) t nng hn hp bt Fe v S (trong iu kin khng c oxi)
(3) Cho FeO vo dung dch HNO3 (long, d)
(4) Cho Fe vo dung dch Fe2(SO4)3
(5) Cho Fe vo dung dch H2SO4 (long, d)
C bao nhiu th nghim to ra mui st(II) ?
A. 3.
B. 2.
C. 1.
D. 4.
t
V d 7. Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long d thu
c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. Dung dch X c th ha tan ti a 12,88
gam Fe. S mol HNO3 c trong dung dch u l
A. 0,94 mol
B. 0,88 mol
C. 0,64 mol
D. 0,77 mol
V d 8. (C9) Cho 100 ml dung dch FeCl2 1,2M tc dng vi 200 ml dung dch AgNO3 2,0M, thu c m
gam kt ta. Gi tr ca m l
A. 34,44.
B. 47,4.
C. 30,18.
D. 12,96.
V d 9. Cho cc loi qung st sau: (1) pirit st;
(2) xierit;
(3) hematit ;
(4) manhetit;
Dy sp xp theo chiu tng dn hm lng Fe trong cc qung trn l:
A. (1) < (2) < (3) < (4).
B. (3) < (1) < (2) < (4).
C. (4) < (3) < (2) < (1).
D. (1) < (2) < (4) < (3).
V d 10. (A7) Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4,
Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho kh l
A. 8.
B. 5.
C. 7.
D. 6.
V d 11. (A7) Khi nung hn hp cc cht Fe(NO3)2, Fe(OH)3 v FeCO3 trong khng kh n khi lng khng
i, thu c mt cht rn l
A. Fe3O4.
B. FeO.
C. Fe.
D. Fe2O3.
V d 12. (C8) Ha tan hon ton Fe3O4 trong dung dch H2SO4 long (d) c dung dch X1. Cho lng d
bt Fe vo dung dch X1 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c
dung dch X2 cha cht tan l
A. Fe2(SO4)3 v H2SO4.
B. FeSO4.
C. Fe2(SO4)3.
D. FeSO4 v H2SO4.
V d 13. (B12) Cho cc cht sau: FeCO3, Fe3O4, FeS, Fe(OH)2. Nu ha tan cng s mol mi cht vo dung
dch H2SO4 c, nng (d) th cht to ra s mol kh ln nht l
A. Fe3O4
B. Fe(OH)2
C. FeS
D. FeCO3
V d 14. (B8) Nung mt hn hp rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh (d).
Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe2O3 v
hn hp kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia a v b l (bit sau
cc phn ng, lu hunh mc oxi ho +4)
A. a = 4b.
B. a = 2b.
C. a = b.
D. a = 0,5b.
V d 15. (A11) Nung m gam hn hp X gm FeS v FeS2, trong mt bnh kn cha khng kh (gm 20 % th
tch O2 v 80% th tch N2) n khi cc phn ng ny xy ra hon ton, thu c mt cht rn duy nht v hn
hp kh Y c thnh phn th tch: 84,8% N2, 14% SO2, cn li l O2. % khi lng ca FeS trong hn hp X l:
A. 59,46%
B. 19,64%
C. 42,31%
D. 26,83%
V d 16. (B11) Ha tan 25 gam hn hp X gm FeSO4 v Fe2(SO4)3 vo nc, thu c 150 ml dung dch Y.
Thm H2SO4 (d) vo 20ml dung dch Y ri chun ton b dung dch ny bng dung dch KMnO4 0,1M th
dng ht 30 ml dung dch chun. Phn trm khi lng FeSO4 trong hn hp X l
A. 13,68%
B. 68,4%
C. 9,12%
D. 31,6%
V d 17. (B8) Nguyn tc luyn thp l:
A. Dng O2 oxi ho cc tp cht Si, P, S, Mn, ... trong gang thu c thp.
B. Dng cht kh CO kh oxit st thnh st nhit cao.
C. Dng CaO hoc CaCO3 kh tp cht Si, P, S, Mn, ... trong gang thu c thp.
D. Tng thm hm lng cacbon trong gang thu c thp.
V d 18. (B11) luyn c 800 tn gang c hm lng st 95%, cn dng m tn qung manhetit cha 80%
Fe3O4 (cn li l tp cht khng cha st). Bit rng lng st b hao ht trong qu trnh sn xut l 1%. Gi tr
ca m l:
A. 959,59.
B. 1311,90.
C. 1394,90.
D. 1325,16.
M063. L THUYT TRNG TM V NG V HP CHT

(T liu hc bi)
V d 1. C cc m t sau v cu to v v tr ca ng:
(1) Kim loi h d.
(4) Thuc chu k 4, nhm IB.
(5) C 2 electron lp ngoi cng.
S m t ng l:
A. 3.
B. 4.
C. 5.
V d 2. C cc m t sau v tnh cht ca ng:
(1) Mu .
(2) Dn in, dn nhit tt hn vng.
(5) cng xp x nhm.
(4) Nhit nng chy thp.
S m t ng l:
A. 3.
B. 4.
C. 5.
V d 3. Cho cc phn ng sau:
(3) Mng lp phng tm din.

(6) S oxi ha ph bin: +1, +2.
D. 6.
(3) Kim loi nng.
(6) D ko si v dt mng.
D. 6.
Cu2O.
(1) CuO + Cu
(2) 2Cu + 2H2SO4(long) + O2 2CuSO4 + 2H2O.
(3) Cu + 2FeCl3 CuCl2 + 2FeCl2.
(4) Cu + 4HNO3(long) Cu(NO3)2 + 2NO2 + 2H2O.
S phn ng vit ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 4. Cho cc so snh sau v tnh cht ha hc ca ng:
(1) Tng t nhm, trong khng kh kh ng bn do c mng oxit bo v.
(2) Tng t bc, ng khng tan trong dd HCl long, do c tnh kh yu hn H+.
(3) Tng t nhm v st, ng b th ng ha trong dung dch HNO3 c ngui.
(4) Trong khng kh m, ng b bao ph bi lp r ng mu xanh ca CuCO3.Cu(OH)2.
(5) Tng t crom, ng khng tan trong dd H2SO4 long lnh, do c mng oxit bn bo v.
S so snh ng l:
A. 2.
B. 3.
C. 4.
D. 5.
V d 5. (B10) Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi
cc phn ng xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A. 6,72.
B. 8,96.
C. 4,48.
D. 10,08.
V d 6. (A11) Cho 7,68 gam Cu vo 200 ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi cc phn
ng xy ra hon ton (sn phm kh duy nht l NO), c cn cn thn ton b dung dch sau phn ng th khi
lng mui khan thu c l:
A. 19,76 gam.
B. 20,16 gam.
C. 19,20 gam.
D. 22,56 gam.
V d 7. (A11) un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung
dch HNO3. Khi cc phn ng kt thc, thu dc 0,75m gam cht rn, dung dch X v 5,6 lt hn hp kh (ktc)
gm NO v NO2 (khng c sn phm kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca
m l
A. 44,8.
B. 33,6.
C. 40,5.
D. 50,4.
to
V d 8. (B9) Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v
khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht,
ktc), dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca
m l
A. 151,5.
B. 137,1.
C. 97,5.
D. 108,9.
V d 9. C cc hp kim ca ng:
(1) Hp kim Cu-Au cn c gi l vng 9 cara.
(2) ng bch (Cu-Ni) dng ch to chn vt tu bin.
(3) ng thanh c thnh phn chnh l hp kim Cu-Sn.
(4) ng thau (Cu-Zn) dng ch to chi tit my, cng nghip ng tu bin.
S m t ng l:
A. 1
B. 2
C. 3
D. 4
t
o
(1) Cu2O + Cu2S
t
o
(2) Cu(NO3)2
(3) CuO + CO
(4) CuO + NH3
S phn ng to ra kim loi Cu l:
A. 1
B. 2
C. 3
V d 11. (A8) Cho s chuyn ha qung ng thnh ng :
to
t
o
D. 4
+O 2 , t
+O 2 , t
+X, t
CuFeS2
X
Y
Cu
o
Hai cht X, Y ln lt l
B. CuS, CuO.
C. Cu2S, CuO.
D. Cu2S, Cu2O.
A. Cu2O, CuO.
V d 12. (A10) Cho 0,448 lt kh NH3 (ktc) i qua ng s ng 16 gam CuO nung nng, thu c cht rn X
(gi s phn ng xy ra hon ton). Phn trm khi lng ca Cu trong X l
A. 85,88%.
B. 14,12%.
C. 87,63%.
D. 12,37%.
V d 13. (C10) Cht rn X phn ng vi dung dch HCl c dung dch Y. Cho t t dung dch NH3 n d
vo dung dch Y, ban u xut hin kt ta xanh, sau kt ta tan, thu c dung dch mu xanh thm. Cht X
l
A. FeO.
B. Fe.
C. CuO.
D. Cu.
V d 14. (B8) Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2 l
A. 2.
B. 1.
C. 3.
D. 4.
V d 15. (B9) Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu
c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung
dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong
hn hp X v gi tr ca m ln lt l
A. 21,95% v 2,25.
B. 78,05% v 2,25.
C. 21,95% v 0,78.
D. 78,05% v 0,78.
M064. L THUYT TRNG TM V Ag Au Ni Zn Sn Pb

(T liu hc bi)
V d 1. C cc m t sau v kim loi Ag:
(1) Ion Ag+ c tnh oxi ha mnh.
(2) Ag c cc s oxi ha: +1, +2 v +3.
(3) Ag c tnh dn in, dn nhit tt hn Au.
(4) B xn en trong khng kh do c phn ng vi O2.
(5) Trong cc mui AgCl, AgBr, AgI, ch c AgCl tan trong dung dch NH3 long.
(6) Ag khng tan trong dung dch H2SO4 long, nhng tan trong dung dch HNO3.
S m t ng l:
A. 3.
B. 4.
C. 5.
D. 6.
V d 2. Thc hin cc th nghim vi hn hp gm Ag v Cu (hn hp X):
(a) Cho X vo bnh cha mt lng d kh O3 ( iu kin thng).
(b) Cho X vo mt lng d dung dch HNO3 (c ngui).
(c) Cho X vo mt lng d dung dch HCl (khng c mt O2).
(d) Cho X vo mt lng d dung dch FeCl3.
S th nghim m Cu b oxi ha cn Ag khng b oxi ha l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 3. (A7) thu ly Ag tinh khit t hn hp X (gm a mol Al2O3, b mol CuO, c mol Ag2O) ngi ta ha tan
X bi dd cha (6a + 2b + 2c) mol HNO3 c dd Y. Sau thm (gi thit hiu sut cc phn ng u t 100%)
B. c mol bt Cu vo Y.
C. 2c mol bt Al vo Y.
D. 2c mol bt Cu vo Y.
A. c mol bt Al vo y.
V d 4. (A12) Cho 100 ml dung dch AgNO3 2a mol/l vo 100 ml dung dch Fe(NO3)2 a mol/l. Sau khi phn ng
kt thc thu c 8,64 gam cht rn v dung dch X. Cho dd HCl d vo X thu c m gam kt ta. Gi tr ca m l
A. 11,48
B. 14,35
C. 17,22
D. 22,96
(1) Au c cc s oxi ha: +1 v +3.
(2) Chiu tng dn tnh do: Fe < Cu < Au.
(3) Thuc cng nhm nguyn t vi Cu, Ag.
(4) Khng tc dng vi O2, H2SO4 c nng.
(5) Kh nng dn in, dn nhit ca Au ch km Ag.
(6) Au khng tan trong dung dch HNO3, nhng tan trong dung dch NaCN.
S m t ng l:
A. 3.
B. 4.
C. 5.
D. 6.
V d 6. Cho cc cht v dung dch: (1) Thu ngn; (2) dung dch NaCN; (3) dung dch HNO3 c nng; (4) nc
cng toan; (5) dung dch H2SO4 c nng. Tng s (cht v dung dch) ho tan c vng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 7. (B12) Ha tan Au bng nc cng toan th sn phm kh l NO; ha tan Ag trong dung dch HNO3 c
th sn phm kh l NO2. s mol NO2 bng s mol NO th t l s mol Ag v Au tng ng l
A. 1 : 2
B. 3 : 1
C. 1 : 1
D. 1 : 3
(1) Tng t Zn(OH)2, Ni(OH)2 c tnh lng tnh.
(2) Tng t st, niken c cc s oxi ha: +2 v +3.
(3) Tng t Pt, Ni cng c dng lm cht xc tc.
(4) Tng t crom, niken l kim loi nng, c mu trng bc, rt cng.
(5) Tng t nhm, niken bn trong khng kh v nc do c mng oxit bo v.
(6) Tng t Cu(OH)2, Ni(OH)2 tan trong dung dch NH3 long do to phc [M(NH3)4](OH)2.
S m t ng l:
A. 3.
B. 4.
C. 5.
D. 6.
V d 9. Cho m gam bt niken phn ng hon ton vi dung dch HCl (d) thu c V lt kh H2 (ktc). Mt khc
cng m gam bt niken trn phn ng hon ton vi kh O2 (d) thu c 12,45 gam oxit duy nht. Gi tr ca V l
A. 1,68.
B. 3,36.
C. 3,72.
D. 5,04.
V d 10. Cho ng bch l hp kim ca Ni-Zn-Cu c t l khi lng l 3 : 4 : 13. Cho 29,913 gam ng bch vo
dung dch HNO3 long d, thu c dung dch X v V lt kh NO duy nht (ktc). C cn dung dch X thu c
89,481 gam mui khan. Gi tr ca V l
A. 4,874.
B. 6,272.
C. 7,049.
D. 7,174.
(1) Oxit lng tnh.
(2) C mng oxit bn bo v.
(3) Hiroxit tan trong dung dch NH3 d.
(4) Ch c 1 s oxi ha trong mi hp cht.
(5) Khng tan trong H2O, nhng tan trong dung dch NaOH.
(6) Khng tan trong dung dch HNO3 c ngui, do hin tng th ng.
S m t ng cho c Zn v Al l:
A. 3.
B. 4.
C. 5.
D. 6.
V d 12. Hn hp X gm Al, Zn, Ni, Cu. Ho tan ht X trong dung dch H2SO4 c nng c dung dch Y. Cho Y
tc dng vi dung dch Ba(OH)2 long d thu c kt ta Z. Nung Z ti khi lng khng i c cht rn T. Dn
kh H2 d qua T un nng n phn ng hon ton thu c hn hp rn G. C cc m t sau (cc phn ng u xy
ra hon ton):
(1) dung dch Y c th cha ti a 5 cht tan;
(2) Kt ta Z gm 3 cht.
(3) Rn T c cha 2 oxit.
(4) Rn G ch tan mt phn trong dd HNO3.
S m t ng l:
A. 1.
B. 2.
C. 3.
D. 4.
V d 13. Hn hp X gm 2,4 gam Mg; 1,08 gam Al; 9,75 gam Zn. Ha tan hon ton X bng dung dch HNO3, thy
khi lng dung dch tng 13,23 gam. S mol HNO3 tham gia phn ng l
A. 0,62 mol.
B. 1,24 mol.
C. 0,6975 mol.
D. 0,775 mol.
(1) Sn b ha tan trong dung dch NaOH c.
(2) St ty c thnh phn chnh l Fe v Sn.
(3) C th cn Sn thnh l mng gi l giy thic.
(4) Do c mng oxit bn bo v nn Sn b n mn chm.
(5) Sn tc dng O2, H2SO4 c, HNO3 c to hp cht Sn+4.
(6) Sn tc dng HCl, H2SO4 long, HNO3 long to hp cht Sn+2.
S m t ng cho Sn l:
A. 3.
B. 4.
C. 5.
D. 6.
V d 15. (A10) Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng
d dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 8,98 gam mui khan.
Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3 oxit th th tch kh O2 (ktc) phn ng
l
A. 2,016 lt.
B. 1,008 lt.
C. 0,672 lt.
D. 1,344 lt.
(1) Kim loi nhm IVA.
(2) S oxi ha: +2; +4.
(3) C mng oxit bn.
(4) Tan trong dd HCl long.
(5) Tan trong dd NaOH c.
(6) un nng trong khng kh to MO2.
S m t ng cho c Pb v Sn l:
A. 3.
B. 4.
C. 5.
D. 6.
V d 17. Ln lt cho Pb tc dng vi cc cht:
(1) HNO3 long;
(2) O2 (nung nng).
(3) HNO3 c nng. (4) KOH c nng.
(5) H2SO4 c nng.
S phn ng to thnh hp cht Pb+2 l:
A. 2.
B. 3.
C. 4.
D. 5.
V d 18. (A9) Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn hp rn (c cha mt oxit)
nng 0,95m gam. Phn trm khi lng PbS b t chy l
A. 95,00%.
B. 25,31%.
C. 74,69%.
D. 64,68%.
M085. PHNG PHP QUY I

(T liu hc bi)
V d 1. Ha tan hon ton 14,52 gam hn hp X gm NaHCO3, KHCO3 v MgCO3 trong dung dch HCl d,
thu c 3,36 lt kh CO2 (ktc). Khi lng mui KCl to thnh trong dung dch sau phn ng l
A. 8,94 gam.
B. 16,17 gam.
C. 7,92 gam.
D. 12,0 gam.
V d 2. Hn hp X gm ba cht rn Fe3O4, FeO v Cu2O. Cho 52,20 gam X tc dng vi dung dch HNO3
long d thu c 3,92 lt kh NO (sn phm kh duy nht, o ktc). Khi lng ca Fe3O4 trong X l
A. 31,32 gam.
B. 15,66 gam.
C. 26,10 gam.
D. 20,88 gam.
V d 3. (A8) ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO bng s
mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l
A. 0,16.
B. 0,18.
C. 0,23.
D. 0,08.
V d 4. Cho 2,32 gam hn hp bt X gm FeO, Fe2O3, Fe3O4 (trong t l khi lng FeO v Fe2O3 l
m FeO
9
=
) trong 200 ml dung dch HCl 1M thu c dung dch Y. Dung dch Y c th ha tan ti a bao
m Fe2O3 20
nhiu gam Fe ?
A. 0,56 gam.
B. 3,36 gam.
C. 3,92 gam.
D. 4,48 gam.
V d 5. (B8) Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc
phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca
m l
A. 8,75.
B. 9,75.
C. 6,50.
D. 7,80.
V d 6. (B7) Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X trong
dung dch HNO3 (d), thot ra 0,56 lt (ktc) NO (l sn phm kh duy nht). Gi tr ca m l
A. 2,52.
B. 2,22.
C. 2,32.
D. 2,62.
V d 7. (A8) Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long
(d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c
m gam mui khan. Gi tr ca m l
A. 35,50.
B. 34,36.
C. 49,09.
D. 38,72.
V d 8. (B9) Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch
X v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat
khan. Gi tr ca m l
A. 52,2.
B. 54,0.
C. 58,0.
D. 48,4.
V d 9. Nung m gam bt Cu trong oxi thu c 24,8 gam hn hp cht rn X gm Cu, CuO v Cu2O. Ha tan
hon ton X trong H2SO4 c nng thot ra 4,48 lt kh SO2 duy nht (ktc). Gi tr ca m l
A. 9,6.
B. 14,72.
C. 21,12.
D. 22,4.
V d 10. Cho 18,5 gam hn hp X gm Fe v Fe3O4 tc dng vi 200 ml dung dch HNO3 long un nng v
khuy u. Sau khi phn ng xy ra hon ton thu c 2,24 lt kh NO duy nht (ktc), dung dch Y v cn li
1,46 gam kim loi. Nng mol ca dung dch HNO3 v khi lng mui c trong dung dch Y ln lt l
A. 1,6M v 24,3 gam.
B. 3,2M v 48,6 gam.
C. 3,2M v 54 gam.
D. 1,8M v 36,45 gam.
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TRUNG TM LUYN THI I HC

S 11 Ngch 98 Ng 72 Tn Tht Tng ng a HN

KHAI THC TRIT PHNG PHP BO TON NGUYN T

Bin son: Thy L Phm Thnh (0976.053.496)

PP 04. PHNG PHP BO TON IN TCH

Bin son: Thy L PHM THNH (https://www.facebook.com/thanh.lepham)

PP 05. KT HP BO TON IN TCH

Bin son: Thy L PHM THNH (https://www.facebook.com/thanh.lepham)

PP 07. PHNG PHP S DNG PHNG TRNH ION THU GN

Bin son: Thy L PHM THNH (https://www.facebook.com/thanh.lepham)

PP 08. PHNG PHP S DNG PHNG TRNH ION ELECTRON

Bin son: Thy L PHM THNH (https://www.facebook.com/thanh.lepham)

Phm Thnh (0976.053.496)

V d 1. (C9) Mt nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52 v c s khi l 35.

Phm Thnh (0976.053.496)

Phm Thnh (0976.053.496)

C s I: Ng 72 - Tn Tht Tng (gn H Y H Ni) C s II: S 27 - T Hiu - H ng (gn Cu en)

Phm Thnh (0976.053.496)

V d 34. Hiro c 3 ng v H, H, H. Oxi c 3 ng v l

O. S loi phn t nc khc nhau

V d 35. (C7) Trong t nhin, nguyn t ng c hai ng v l

ng l 63,54. Thnh phn phn trm tng s nguyn t ca ng v

Cu . Nguyn t khi trung bnh ca

chim 54,5% s nguyn t. Nguyn t khi ca ng v cn li l

V d 38. Nguyn t khi trung bnh ca Ne l 20,19. Bit Ne c ba ng v trong ng v

90,48% v ng v Ne chim 0,27% s nguyn t. Nguyn t khi ca ng v cn li l

V d 40. Trong t nhin st gm 4 ng v

chim 0,28%. Brom l hn hp hai ng v

Br chim 49,31%. Thnh phn % khi

lng ca 56Fe trong FeBr3 l

V d 41. (B11) Trong t nhin clo c hai ng v bn:

Cl chim 24,23% tng s nguyn t, cn li l

Cl trong HClO4 l (Cho: H = 1, O = 16):

Bin son: Thy L PHM THNH

Phm Thnh (0976.053.496)

M002. NH LUT TUN HON

Phm Thnh (0976.053.496)

Phm Thnh (0976.053.496)

M002. NH LUT TUN HON

Phm Thnh (0976.053.496)

Phm Thnh (0976.053.496)

M004. GII TON BNG PHNG PHP BO TON ELECTRON

Phm Thnh (0976.053.496)

Bin son: Thy L PHM THNH

M013. PHNG PHP LP CTPT HP CHT HU C

V d 1. Thnh phn cc nguyn t trong hp cht hu c c c im l

V d 10. (A9) Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp

V d 11. Cho 5 ml hirocacbon X th kh vi 30 ml O2 (ly d) vo kh k ri bt tia la in t sau lm

Bin son: Thy L PHM THNH

M014. HIN TNG NG NG NG PHN

Dng 1. Lin kt trong phn t hp cht hu c

Trng thi lai ha ca cc nguyn t C (theo th t t tri qua phi) l

D. sp, sp2, sp, sp2.

V d 9. Xt hai phn t cht hu c X v Y :

D. anken hoc xicloankan.

V d 16. S ng phn ng vi c cng thc phn t C4H11N l:

V d 18. (C10NC) Cht no sau y c ng phn hnh hc ?

CH3-CH=CH-CH=CH2; CH3-CH=CH-COOH. S cht c ng phn hnh hc l

V d 20. S hirocacbon c cng thc phn t C4H8 l:

Bin son: Thy L PHM THNH

M015. PHNG PHP GII BI TP V PHN NG TH CA HIROCACBON

V d 6. Ankin C6H10 c bao nhiu ng phn phn ng vi dung dch AgNO3/NH3 ?

Bin son: Thy L PHM THNH