S GIO DC V O TO H TNH

TRNG THPT C HUY CN

( thi gm 04 trang)

THI TH THPT QUC GIA

LN 1 NM 2015
Mn: HA HC
Thi gian lm bi: 90 pht, khng k thi gian pht
M thi 164

H, tn th sinh:.........................................................S bo danh: ..............................................................

Cho nguyn t khi ca cc nguyn t: H=1; He=4; Li=7; C=12; N=14; O=16; Na=23; Mg=24; Al=27;
Si=28; P=31; S=32; Cl=35,5; K=39; Ca=40; Fe=56; Cu=64; Zn= 65; Br=80; Ag=108; Ba=137
Cu 1: Hp th hon ton 4,48 lt kh CO2 (ktc) vo 750 ml dung dch Ba(OH)2 0,2M, thu c m gam
kt ta. Gi tr ca m l:
A. 39,40
B. 19,70.
C. 29,55.
D. 9,85.
Cu 2: Phn t no di y cha lin kt cng ha tr khng phn cc:
A. CO2.
B. NH3
C. Cl2
D. NaCl
+
2+
2+
2+
Cu 3: Cho dy cc ion kim loi: K , Ni , Fe , Sn . Ion kim loi c tnh oxi ha mnh nht trong dy l:
A. Ni2+ .
B. Sn2+.
C. Fe2+.
D. K+ .
Cu 4: Este X c CTPT C4H8O2. un nng 1,76 gam X vi 200 mL dung dch NaOH 0,15M. Sau khi
phn ng xy ra hon ton thu c dung dch Y. C cn cn thn dung dch Y thu c 2,32 gam cht
rn khan. Tn gi ca X l:
A. Mety propionat
B. Etyl axetat
C. Metyl axetat
D. Propyl fomat.
Cu 5: Cho dy cc kim loi: Be; Na, K, Ba, Fe. S kim loi tc dng mnh vi nc iu kin thng
l:
A. 3.
B. 2.
C. 4.
D. 5.
Cu 6: Cho dy cc cht: glyxin, phenol, etyl axetat, axit axetic, phenylamoni clorua. S cht trong dy
phn ng vi dung dch KOH un nng l:
A. 3.
B. 2.
C. 5.
D. 4.
Cu 7: Cho cc pht biu sau:
(1) Bn knh nguyn t ca clo ln hn bn knh nguyn t ca flo.
(2) m in ca brom ln hn m in ca iot.
(3) Tnh axit tng dn t tri sang phi trong dy: HF, HCl, HBr, HI.
(4) Tnh kh ca ion I- mnh hn tnh kh ca ion Cl(5) Trong hp cht, cc halogen (F, Cl, Br, I) u c s oxi ha: -1, +1, +3, +5 v +7.
S pht biu ng l:
A. 3
B. 2
C. 4
D. 5
Cu 8: Trn 200 mL dung dch HCl 1,25M vi 300 mL dung dch NaOH 1M thu c 500 mL dung dch
pH l:
A. 12,3
B. 0,7
C. 1,0
D. 13,0
Cu 9: Ha tan ht 5,22 gam bt Al trong dung dch cha HCl (d) v NaNO 3. Sau khi phn ng xy ra
hon ton thu c dung dch X v 2,24 lt ( ktc) hn hp kh Y gm 2 kh trong c mt kh ha nu
trong khng kh. Cho t khi ca Y so vi H2 l 9,4. Hi dung dch X cha bao nhiu gam mui?
A. 28,83 gam
B. 32,38 gam
C. 33,08 gam
D. 33,80 gam
Cu 10: Cht no di y trong dung dch lm qu tm ha ?
A. Phenol
B. Ancol etylic
C. Metylamin.
D. Axit axetic
Cu 11: t chy hon ton m gam hn hp ancol n chc l ng ng ca nhau bng oxi (va ) thu
c 13,44 lt ( ktc) kh CO2 v 17,1 gam H2O. Gi tr ca m l:
A. 16,8 gam
B. 12,3 gam
C. 15,4 gam
D. 14,7 gam
Cu 12: Nung hn hp gm 0,12 mol Al v 0,04 mol Fe 3O4 mt thi gian, thu c hn hp rn X. Ho
tan hon ton X trong dung dch H2SO4 (long, d), thu c 3,36 lt ( ktc) kh H2 v dung dch cha m
gam mui. Gi tr ca m l:
A. 38,92.
B. 39,72.
C. 35,96.
D. 41,20.
Cu 13: Cho cc cn bng ha hc sau:
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(a) H2 (k) + I2 (k)

(c) 3H2 (k) + N2 (k)

2HI (k).
2NH3 (k).

(b) N2O4 (k)

2NO2 (k).

(d) 2SO2 (k) + O2 (k)

2SO3 (k).

iu kin nhit khng i, khi tng p sut chung ca mi h cn bng, s cn bng ha hc

chuyn dch theo chiu thun l?
A. 3.
B. 2.
C. 1.
D. 0.
Cu 14: Cho 100 ml dung dch amino axit X nng 0,2M phn ng va vi 80 ml dung dch HCl
0,25M, thu c dung dch Y. Bit Y phn ng ti a vi 120 ml dung dch NaOH 0,5M, thu c dung
dch cha 4,99 gam hn hp mui. Cng thc ca X l:
A. H2NC3H5(COOH)2. B. H2NC2H3(COOH)2. C. H2NC2H4COOH.
D. H2NC3H6COOH.
+
2+
Cu 15: Dung dch X cha 0,1 mol Na ; 0,3 mol Mg ; 0,4 mol Cl v a mol SO42-. un dung dch X n
cn thu c mui khan c khi lng l:
A. 52,5 gam.
B. 38,1 gam.
C. 47,2 gam.
D. 36,8 gam.
Cu 16: Cho dung dch HCl ln lt vo cc dung dch sau: K2SO4, AgNO3, Ba(OH)2, NaHCO3, NaAlO2.
S trng hp c phn ng xy ra l:
A. 5.
B. 4.
C. 2.
D. 3.
Cu 17: Cho m gam hn hp gm Al v Ba vo nc d, sau khi cc phn ng xy ra hon ton, thu
c 8,96 lt kh H2 ( ktc) v 2,4 gam cht rn khng tan. Gi tr ca m l:
A. 22,4 gam.
B. 21,5 gam
C. 24,5 gam
D. 24,2 gam
Cu 18: Cho 9,26 gam hn hp gm Cu, Ag, Zn tc dng hon ton vi dung dch HNO 3 d, thu c
dung dch Y v 1,792 lt kh NO ( ktc, l sn phm kh duy nht). Khi lng mui trong Y l:
A. 20,40 gam.
B. 24,14 gam.
C. 14,22 gam.
D. 29,10 gam.
Cu 19: Cho phn ng: aFe(OH)2 + bHNO3 cFe(NO3)3 + dNO + eH2O
T l a : b l
A. 3 : 8
B. 1 : 3
C. 3 : 5
D. 3 : 10.
Cu 20: Ha tan ht 5,16 gam oleum c cng thc H2SO4.2SO3 vo nc d. Trung ha dung dch thu
c cn V ml dung dch NaOH 2M. Gi tr ca V l:
A. 40 mL.
B. 80 mL.
C. 20 mL.
D. 60 mL.
Cu 21: Cacbohirat no sau y thuc loi polisaccarit?
A. Fructoz.
B. Saccaroz.
C. Glucoz.
D. Xenluloz.
Cu 22: Tn thay th (theo IUPAC) ca (CH3)2C=CH-CH3 l:
A. 2-metylbut-2-en
B. 3-metylbut-2-in
C. 3-metylbut-2-en
D. 2-metylbut-2-in
Cu 23: Este no sau y khi tc dng hon ton vi dung dch NaOH (un nng) thu c sn phm l
mui v anehit?
A. Vinyl axetat
B. Phenyl axetat
C. Metyl acrylat.
D. Etyl fomat
Cu 24: Nguyn t ca nguyn t R c cu hnh electron lp ngoi cng l ns 2np2. Phn trm khi lng
ca R trong oxit cao nht l 46,67%. Pht biu no sau y l ng?
A. Nguyn t R ( trng thi c bn) c 4 electron c thn.
B. Trong bng tun hon cc nguyn t ha hc, R thuc chu k 2.
C. Oxit cao nht ca R tc dng c vi dung dch kim long iu kin thng.
D. Oxit cao nht ca R iu kin thng l cht rn.
Cu 25: Cht no di y c th lm mt mu dung dch KMnO4 ( iu kin thng) l:
A. Benzen
B. Xiclopropan
C. Stiren
D. Cumen
Cu 26: Phn ng no sau y c phng trnh ion thu gn dng: 2H+ + CO32- CO2 + H2O
A. K2CO3 + 2HNO3 2KNO3 + CO2 + H2O
B. CaCO3 + 2HCl CaCl2 + CO2 + H2O
C. Na2CO3 + CH3COOH 2CH3COONa + CO2 + H2O
D. 2NaHCO3 + H2SO4 (long) Na2SO4 + 2CO2 + 2H2O
Cu 27: t chy 7,8 gam hn hp gm Mg, Al trong kh O2 d. Sau khi cc phn ng xy ra hon ton,
thu c 14,2 gam hn hp oxit. Th tch kh O2 (ktc) phn ng l:
A. 8,96 lt.
B. 2,24 lt.
C. 4,48 lt.
D. 6,72 lt.
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Cu 28: Phenol khng c phn ng vi cht no di y?

A. Na
B. KOH
C. NaCl
D. Br2
Cu 29: Cho dung dch A cha 0,2 mol Na2CO3 v 0,3 mol NaHCO3. Dung dch B cha 0,5 mol HCl.
Tnh th tch kh CO2 (ktc) thu c khi cho t t n ht dung dch B vo dung dch A? Gi s cc
phn ng l hon ton.
A. 5,60 lt
B. 8,96 lt
C. 4,48 lt
D. 6,72 lt
Cu 30: Nguyn t X to anion X c cu hnh electron phn lp ngoi cng trng thi c bn l 3p 6. S
ht mang in ca nguyn t nguyn t X l:
A. 17
B. 35
C. 34
D. 18
Cu 31: S ng phn ancol bc I ng vi cng thc phn t C5H12O l:
A. 8
B. 6
C. 4
D. 3
Cu 32: Cho cc cht sau: NH4NO3, NaHSO4, NH4HCO3, Al2(SO4)3. S cht khi tc dng hon ton vi
dung dch Ba(OH)2 d thu c kt ta l:
A. 1
B. 4
C. 2
D. 3
Cu 33: Trung ho 3,05 gam hn hp X gm hai axit cacboxylic no, n chc, mch h bng dung dch
KOH, c cn ton b dung dch sau phn ng thu c 4,76 gam hn hp mui khan. Nu t chy hon
ton 6,10 gam hn hp X th th tch oxi (ktc) ti thiu cn dng l:
A. 5,712 lt.
B. 2,856 lt.
C. 5,040 lt.
D. 2,520 lt.
Cu 34: T nitron dai, bn vi nhit, gi nhit tt, thng c dng dt vi v may qun o m.
Monome dng sn xut t nitron l:
A. H2N-[CH2]5-COOH B. CH2=CH-Cl
C. CH2=CH-CN
D. CH2=CH2
Cu 35: Phn ng no di y thuc loi phn ng oxi ha - kh?
A. Cl2 + 2NaOH NaCl + NaClO + H2O.
B. SO2 + CaO CaSO3.
to
C. NH4HCO3
NH3 + CO2 + H2O.
D. NaHCO3 + HCl NaCl + CO2 + H2O.
Cu 36: un nng 0,025 mol triolein trong dung dch KOH (va ), sau khi phn ng hon ton thu
c m gam mui. Gi tr ca m l:
A. 24,00 gam
B. 22,95 gam
C. 22,80 gam
D. 24,15 gam.
Cu 37: t chy hon ton 27,2 gam hn hp gm mt axit cacboxylic no, n chc, mch h (X) v
mt ancol n chc (Y) bit MX > MY, thu c 24,64 lt CO2 ( ktc) v 25,2 gam H2O. Thc hin phn
ng este ha 27,2 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l
A. 16,32 gam.
B. 15,12 gam.
C. 17,60 gam.
D. 18,24 gam.
Cu 38: Trong cng nghip, ancol etylic c th c sn xut bng phng php ln men xenluloz
(trong mn ca, v bo). Thc hin ln men m tn mn ca (cha 50% xenluloz, cn li l cc tp cht
tr) sn xut 460 lt ancol etylic 90 o (cn 90o). Bit rng hiu sut c qu trnh ln men l 90%, khi
lng ring ca ancol etylic nguyn cht l 0,8 gam/mL. Gi tr ca m l:
A. 1,296 tn
B. 1,166 tn
C. 1,458 tn
D. 1,620 tn
Cu 39: Bt ngt (m chnh) l mui mononatri ca axit no sau y?
A. Axit stearic
B. Axit aipic
C. Axit glutamic
D. Axit axetic
Cu 40: Mt on t nilon-6,6 c khi lng 45652 vC. S mt xch trong on polime trn l:
A. 202
B. 452
C. 252
D. 262.
Cu 41: Trong phng th nghim, iu ch axit H3PO4 ngi ta lm cch no sau y?
A. Cho dung dch axit H2SO4 c, nng tc dng vi qung apatit.
B. Cho dung dch axit H2SO4 c, nng tc dng vi qung photphorit.
C. Cho photpho tc dng vi dung dch HNO3 c, nng.
D. t chy photpho trong oxi d, cho sn phm tc dng vi nc.
Cu 42: Cho 2,42 gam hn hp X gm cc amin no, n chc, mch h tc dng va vi dung dch
HCl thu c 4,61 gam mui. Mt khc, t chy hon ton 2,42 gam hn hp X bng lng khng kh
va . Ton b sn phm thu c sau phn ng em dn qua bnh cha H 2SO4 c, d. Kh ra khi
bnh o c th tch V lt ktc. Gi s cc qu trnh xy ra hon ton v cho bit khng kh l hn hp
gm 80% N2 v 20% O2 theo th tch. Tnh gi tr ca V?
A. 28,896 lt
B. 2,912 lt
C. 20,384 lt
D. 19,488 lt.

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Cu 43: t chy hon ton 1,12 lt ( ktc) hn hp X gm mt ankan v mt anken thu c 7,04 gam
CO2 v 3,42 gam H2O. Mt khc, cho 1,12 lt hn hp X phn ng ti a vi m gam Br 2 trong dung dch.
Gi tr ca m l:
A. 4,8 gam
B. 4,0 gam.
C. 8,0 gam
D. 3,2 gam
Cu 44: Hn hp M gm axit stearic, axit oleic v axit linoleic. Trung ha m gam hn hp M cn dng
va 50 ml dung dch NaOH 1M. t chy hon ton m gam hn hp M, hp th ton b sn phm
chy vo bnh ng nc vi trong d, thu c dung dch c khi lng gim 35,28 gam so vi khi
lng nc vi ban u. Gi tr ca m l
A. 14,08 gam..
B. 14,16 gam.
C. 14,10 gam.
D. 14,12 gam.
Cu 45: t chy hon ton 0,02 mol mt triglixerit X bng lng oxi (va ) thu c 1,14 mol CO 2.
Mt khc, hiro ha hon ton 0,02 mol X cn va 0,08 mol H 2 (xc tc Ni, un nng). Th tch kh
O2 ( ktc) dng l:
A. 36,288 lt.
B. 36,064 lt.
C. 22,848 lt.
D. 35,616 lt.
Cu 46: Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO 3
(d) th thu c 15,68 lt CO 2. Mt khc, t chy hon ton m gam X cn 8,96 lt kh O 2, thu c 10,8
gam H2O. Gi tr ca m l:
A. 20,0 gam.
B. 33,2 gam.
C. 37,6 gam.
D. 26,8 gam.
Cu 47: Cho cc cht: anehit axetic, etanol, glucoz, saccaroz, axit fomic. S cht c kh nng tham
gia phn ng trng bc l:
A. 2
B. 3
C. 4
D. 1
Cu 48: Dung dch X cha a mol HCl v b mol AlCl 3. Thm t t dung dch NaOH 1M vo dung dch X,
n khi ht 200 mL th bt u xut hin kt ta, cn khi ht 800 mL hoc 1200 mL th u thu c 15,6
gam kt ta.
T l a : b l:
A. 4 : 3
B. 2 : 3
C. 1 : 1
D. 1 : 2
Cu 49: Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt c dng rc ln
thu ngn ri gom li l:
A. lu hunh.
B. vi sng.
C. than.
D. mui n.
Cu 50: Cho cc cht sau: (1) ancol etylic, (2) axit propionic, (3) imetyl ete, (4) axit axetic. Th t tng
dn nhit si cc cht (t tri sang phi) l:
A. (1), (2), (3), (4)
B. (3), (1), (4), (2)
C. (3), (1), (2), (4)
D. (1), (3), (4), (2)
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