1. An excess of zinc powder was added to 50.0 cm3 of 0.100 M AgNO3 in a polystyrene cup.

Initially, the
temperature was 21.10 o C and it rose to 25.40 oC.
Calculate the enthalpy change for the reaction

Zn(s) + 2Ag+(aq)

Zn2+ (aq) + 2Ag(s)

Assume that the density of the solution is 1.00 g cm-3 and its specific heat capacity is 4.18 kJ kg-1 K-1. Ignore the
heat capacity of the metals.

2.

Calculate the enthalpy of formation of carbon monoxide from the following information:

C (s) + O2 (g)

CO2 (g)

Hc = -393.5 kJ mol-1

CO (g) + O2 (g)

CO2 (g)

Hc = -283.0 kJ mol-1

3.Calculate the standard enthalpy of formation of ethanol from the following information.
Hc [C2H5OH] = -1367 kJ mol-1
Hf [CO2] = -393.5 kJ mol-1
Hf [H2O] = -285.8 kJ mol-1
4.Calculate the standard molar enthalpy of the hydrogenation of ethene.
C2H4 + H2

C2H6

5. Find the standard enthalpy of formation of ethyne given the following information;

C (s) + O2 (g)

H2 (g) + O2 (g)

CO2 (g)

H2O (l)

Hc = -394 kJ mol-1

Hc = -286 kJ mol-1

C2H2 (g) + 2 O2 (g)

2CO2 (g) + H2O (l)

Hc = -1300 kJ mol-1

6.Calculate the value of Ho/kJ for the following reaction using the listed thermochemical equations:2 F2(g) + 2
H2O(l)
4 HF(g) + O2(g)
H2(g) + F2(g)
2 H2(g) + O2(g)

2 HF(g)
2 H2O(l)

7.Given the following equations and

+ 1/2 O2(g)
NO2(g)
1/2 N2(g) + 1/2 O2(g)
NO(g)
1/2 N2(g) + O2(g)
NO2(g)

Ho/kJ = -542 kJ
H /kJ = -572 kJ
o

Ho values, determine the heat of reaction at 298 K for the reaction:NO(g)

Ho/kJ = +90.37
Ho/kJ = +33.85

8.The standard enthalpy of formation of methanol, CH3OH, is -238.6 kJ mole. Calculate the heat of combustion
of one mole of CH3OH. The heats of formation of CO2(g) and H2O(l) are -394 kJ/mole and -285.8
kJ/mole respectively.
9.The standard enthalpy of formation of cyclohexane, C6H12, is -156.4 kJ/mole. Calculate the heat of combustion
of one mole of C6H12. The heats of formation of CO2(g) and H2O(l) are -394 kJ/mole and -285.8
kJ/mole respectively.
10.The standard enthalpy of formation of propyne, C3H4, is +185.4 kJ/mole. Calculate the heat of combustion of
one mole of C3H4. The heats of formation of CO2(g) and H2O(l) are -394 kJ/mole and -285.8 kJ/mole
respectively.

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