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L6 Finals P1 2010 PDF
L6 Finals P1 2010 PDF
L6 FINALS 2009
OKTOBER 2010
CHEMISTRY PAPER 1
1 HOURS
Instructions to candidate:
DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO.
There are fifty questions in this paper. For each question, four suggested answers are given.
Choose one correct answer and indicate it on the multiple-choice answer sheet provided.
Read the instructions an the multiple-choice answer sheet carefully. Answer all questions.
Marks will not be deducted for wrong answers.
Arahan kepada calon:
JANGAN BUKA KERTAS SOALAN INI SEHINGGA ANDA DIBENARKAN BERBUAT
DEMIKIAN.
Ada lima puluh soalan dalam kertas ini. Bagi setiap soalan, empat cadangan jawapan
diberikan. Pilih satu jawapan yang betul dan tandakan jawapan itu pada helaian jawapan aneka
pilihan yang dibekalkan.
Baca arahan pada helaian jawapan aneka pilihan itu dengan teliti. Jawab semua soalan.
Markah tidak akan ditolak bagi jawapan yang salah.
This question paper consists of 11 printed pages.
(Kertas soalan ini terdiri daripada 11 halaman bercetak)
Lau Kah Pew SMKBU 2010
Section A
Four suggested answers labelled A, B, C and D are given for each question. Choose one
correct answer.
1.
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
Which of the following gasses shows the greatest deviation from reality?
A) methane
B) ammonia
C) ethene
D) carbon dioxide
A)
B)
C)
D)
2 g of deuterium of volume V.
4 g of deuterium of volume V.
a mixture of 1 g of hydrogen and 2 g of deuterium of total volume V.
a mixture of 2 g of hydrogen and 1 g of deuterium of total volume 2V.
5. When heated, solid iodine readily forms iodine vapour. What does this information
suggest about the nature of the particles in these two physical states of iodine?
A)
B)
C)
D)
solid
ionic
ionic
molecular
molecular
vapour
atomic
molecular
atomic
molecular
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
7. Graphite can be used as a lubricant, diamond cannot. This is because graphite has
(A-lvl(s) D925 P4-18)
A)
B)
C)
D)
C)
B)
D)
9. What is the maximum number of spectral lines that could be produced by electrons going
from n = 5 to n = 2, by all possible routes?
A) 2
B) 3
C) 4
D) 5
10. Which of the following is the best reason why electrons are treated as standing waves in
the modern quantum theory of the atom?
A)
B)
C)
D)
11. The rule which states that no two electrons in an atom can have the same set of quantum
numbers is known as:
A) Hunds rule
B) Aufbau principle
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
12. A line in the Pfund series (nlow = 5) occurs at 3.74 x 10-6 m. What is nhigh for this
transition? The Rydberg constant equals 2.18 x 10-18 J.
A) 6
B) 7
C) 8
D) 9
13. Which of the following elements has the highest second ionization energy? (A-lvl(s) D87 P3-1)
A) O
B) Ne
C) Na
D) Mg
14. Which equation represents the ionisation energy of magnesium?
A) Mg(g) Mg+(g) + e
C) Mg(g) Mg2+(g) + 2e
B) Mg(s) Mg+(g) + e
D) Mg(s) Mg2+(g) + 2e
15. The first to fourth ionization energies of four elements are as follows:
Elements
Second
Third
Fourth
577
1 820
2 740
11 600
418
3 070
4 600
5 860
736
1 450
7 740
10 500
494
4 560
6 940
9 540
Ionic radius/nm
P+
Q2+
R
S
0.095
0.031
0.136
0.126
Which ionic compound has bonding with the greatest covalent character? (STPM 08 P1-5)
A) PR
B) PS
C) QR2
D) QS2
17. Rank the following molecules in order of decreasing ionic character of their bonds.
SiCl2 NaCl PF3
A) NaCl > PF3 > SiCl2
B) SiCl2 > PF3 > NaCl
STPM CHEMISTRY 962/1
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
18. Polyatomic molecules and ions have varied geometries. Which species and geometry
corresponds CORRECTLY? (STPM 09 P1-6)
Species
Geometry
A)
NH2
Linear
B)
H3O
C)
SiCl4
Square planar
D)
ICl3
T-shape
Trigonal planar
19. Based on the band theory, the conductivity of metal is due to delocalized electrons in the
conduction band. How many electrons are found in the conduction band of a 10.0 g
magnesium metal strip?
[Relative atomic mass of Mg is 24.0; Avogadro constant is 6.02 x 1023 mol-1] (STPM 09 P1-7)
A) 2.51 x 1023
B) 5.02 x 1023
C) 2.51 x 1024
D) 3.01 x 1024
bonds
1
bonds
1
B)
C)
D)
2
1
2
1
2
2
C)
D) NH4+
C3H6
angle P
H3C
angle Q
CH3
C
CH3
CH3
A)
angle P
90
angle Q
105
B)
C)
D)
90
109.5
109.5
180
105
180
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
25. Which of the following isomers is likely to have the highest boiling point?
A) CH3CHOHCH3
C) CH3CH2CH2CHO
B) CH3CH2CH2Cl
D) CH3CH2CH2CH2CH3
26. Which of the following statements explain why copper conducts electricity when a
potential difference is applied? (A-lvl(s) J91 P1-7)
A) electrons combine with the Cu2+ ion.
B) bonding electrons in the crystal lattice move.
C) Cu2+ ions move from the anode to the cathode.
D) electrons are excited from lower energy level to higher energy levels
27. Which type of bond is responsible for intermolecular forces in liquid nitrogen?
A) covalent bonding
C) induced dipole-induced dipole attractions
B) hydrogen bonding
D) permanent dipole- permanent dipole attractions
28. What is the bond angle around a triple bond?
A) 90
B) 109.5
C) 120
D) 180
H3C
A)
H3C
H3C
B)
C)
H3C
H3C
F
N
H3C
D)
H3 C
H3C
CH3
H 3C
F
N
F
F
F
H 3C
B
F
H3C
N
H3C
CH3
F
H3C
H3C
H3C
H3C
F
H3C
H3C
F
F
H 3C
H3C
H3C
H 3C
F
F
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
30. Which of the following molecular structures below will have the smallest overall dipole?
H3C
Cl
C
A)
H3C
Cl
C
C)
Cl
CH3
H3C
Cl
H3C
CH3
H3C
CH3
B)
C
Cl
D)
H3C
Cl
Cl
31. The graphs of initial rate versus concentration of reactants for the reaction; X + Y Z,
are shown below:
X
0
1
1
Y
1
0
2
D)
32. The following reaction is first order with respect to [P] and zero order with respect to [Q].
P + Q products
If the rate constant doubles for each 10C rise in temperature, which of the following sets
of conditions will give the greatest rate of reaction? (A-lvl(s) J88 P3-12)
A)
B)
C)
[P]/mol dm-3
0.1
0.1
0.3
[Q]/mol dm-3
0.2
0.3
0.1
Temperature/ C
40
30
30
D)
0.3
0.1
20
33. For a first order reaction, rate constant is 0.6932 hr-1. Determine the half-life for the
reaction.
A) 0.1 hr
B) 1 hr
C) 2 hrs
D) 10 hrs
STPM CHEMISTRY 962/1
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
34. For the reaction H2(g) + I2(g) 2HI(g), the rate of reaction is expressed as
[I2 ]
[H 2 ] 1 [HI]
t
t
2 t
A)
B)
[I2 ] [H 2 ] [HI]
t
t
2 t
C)
[H 2 ] 1 [I2 ]
[HI]
t
2 t
t
D) None of these
35. For the reaction; OCl (aq) + I(aq) OI(aq) + Cl(aq), the following data were
collected at constant temperature.
What is the rate law for this reaction?
Experiment
[OCl]
[I]
1.7 x 10-3
1.7 x 10-3
1.75 x 104
3.4 x 10-3
1.7 x 10-3
3.50 x 104
1.7 x 10-3
3.4 x 10-3
3.50 x 104
A) Rate = k [OCl]
B) Rate = k [OCl] [I]
36. The rate of a gaseous reaction is given by the expression k [A] [B]. If the volume of the
reaction vessel is suddenly reduced to th of the initial volume, the reaction rate relating
to original rate will be
A) 0.10
B)
C) 8
D) 16
37. The decomposition of hydrogen peroxide follows a first order kinetic. Which of the
following graphs correctly represent this reaction?
A)
C)
B)
D)
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
38. Which one of the following correctly represents the units of the rate constant, k, for a
second order reaction?
A) s-1
B) mol dm-3 s
C) mol dm-3 s-1
D) mol-1 dm3 s-1
39. Consider the reaction:
S2O82-(aq) + 2I(aq) 2SO42-(aq) + I2(aq)
The rate equation is: Rate = k [S2O82-] [I]; where k is the rate constant. Which of the
following conclusions can be drawn from this information?
A) the reaction goes to completion
B) the reaction is second order with respect to I
C) the reaction is first order with respect to S2O82D) the value of k depends on the concentrations of S2O82- and I
40. If a reaction involving a single reactant is first order with a rate constant of 4.50 x 10-2 s-1,
how much time is required for 75% of its initial concentration of reactant to be used up?
A) 16.7s
B) 25.3s
C) 23.1s
D) 30.8s
Section B
For each of the questions in this section, one or more of the three numbered statements 1 to 3
may be correct. The responses A to D should be selected on the basis of the following.
A
1 only
is correct
1 and 2 only
are correct
2 and 3 only
are correct
1, 2 and 3
are correct
41. Simple ionic crystals have good cleavage planes because the particles in the crystals are
(A-lvl(s) D90 P1-33)
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
1 only
is correct
1 and 2 only
are correct
2 and 3 only
are correct
1, 2 and 3
are correct
43. Which of the following is/are part of Bohrs interpretation of the hydrogen line spectrum?
1. different wavelengths of light correspond to electrons dropping between different
quantum levels
2. electrons release energy as light as they move to a higher energy level
3. the potential energy of an electron decreases as it moves further from the nucleus
44. Choose the statement(s) that are TRUE
1. Outer electrons can penetrate the electron cloud of inner electrons.
2. Outer electrons experience partial nuclear charge
3. The 2s and 2p electrons are of different energy levels except in hydrogen atoms.
45. The Group 2 metals have higher melting points than the Group 1 metals.
Which factors could contribute towards the higher melting points? (A-lvl(s) J97 P3-35)
1. There are smaller interatomic distances in the metallic lattices of Group 2 metals.
2. Two valency electrons are available from each Group 2 metal atom for bonding the
atoms into the metallic lattice.
3. Group 2 metals have higher first ionization energies.
46. The melting and boiling points of sulphur are higher than chlorine because
1. Sulphur form larger and heavier molecules.
2. Chlorine has a higher relative atomic mass.
3. Sulphur molecules are more polarized compared to chlorine molecules.
47. The bond lengths and bond angles in the molecules of methane, ammonia and water may
be represented as follows:
What causes this trend in the bond angles shown? (A-lvl(s) J92 P4-31)
1. Increasing repulsion between hydrogen atoms as the bond length decreases.
2. The number of non-bonding electron pairs in the molecule.
3. A non-bonding electron pair having a greater repulsive force than a bonding electron
pair.
10
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
1 only
is correct
1 and 2 only
are correct
2 and 3 only
are correct
1, 2 and 3
are correct
Prepared by,
Checked by,
Verified by,
11
CONFIDENTIAL*/SULIT*
L6 FINALS 2009
ideal gas
PV
Proportion of molecules
non-ideal gas
T2
T1
Molecular speed
12