Bi tp nguyn t Ganvani

Cu 1:
Nguyn t Ganvani c thit lp vi in cc Cu v Cd.
Cu2+/Cu = 0,337 V; Cd2+/Cd = 0,403 V;
Vit phng trnh biu din s ph thuc ca S E vo nng ca cc ion.
Cu 2:
Cho pin in vi s
(Phng trnh) H2 (p=1atm) | HCl (0,15M) | Hg2Cl2 ,Hg
25OC , Cl,Hg2Cl2 /Hg = 0,2681 V. Tnh S ca pin.
Cu 3:
298K th chun ca h Ce4+.Ce3+/Pt v Fe3+.Fe2+/Pt tng ng l 1,61 v 0,77 V.
Tnh hng s cn bng ca phn ng:
Ce4+ + Fe2+ Ce3+ + Fe3+
Cu 4:
Tm cc nguyn t Ganvani c cc phn ng xy ra khi nguyn t ny hot ng
c cc phn ng tng ng sau:
a) Zn + Cu2+ Cu + Zn2+
b) Ag+ + Cl AgCl
c) Zn + Cl2 ZnCl2
d) HgO(rn) + H2 Hg + O2
4+
2+
3+
3+
e) Ce + Fe Ce + Fe
f) Zn + H2S ZnS + H2
Cu 5:
Tnh S ca cc pin nng :
Ag | AgNO3 0,01 M || AgNO3 0,1 M | Ag.
Ag, AgCl | NaCl 0,1 M || NaCl 0,01 M | Ag.
Cu 6:
S ca mch in gm mt in cc calomen bo ha v in cc hiro nhng
vo dung dch nghin cu 25OC c gi tr bng 0,562 V. Bit th ca in cc
calomen bo ha 25OC l 0,2415 V. Xc nh pH ca dung dch nghin cu.
Cu 7:
S ca pin (Pt) H2 (1atm) | H+ , Cl (0,01 M) | AgCl, Ag
25OC l 0,4615 V. Th in cc chun ca in cc AgCl/Ag l 0,2225 V. Tnh
pH ca dung dch nghin cu.
Cu 8:
25OC , th chun ca in cc Ag+/Ag l 0,7991 V, ca in cc AgCl/Ag l
0,224 V. Tnh Ks AgCl .
Cu 9:
298K, S ca mch
(Pt) H2 (1 atm) | CH3COOH 0,01 M, CH3COONa 0,01 M, NaCl 0,01 M| AgCl,Ag
l 0,6220 V. Bit th in cc chun ca AgCl/Ag l 0,2225 V. Vit cc phng
trnh phn ng in cc v tnh hng s phn ly ca CH3COOH.
Cu 10:
CuNH32+ Cu2+ + NH3
K kb= 1,7.105
Cu2+ + 2e Cu
EO = 0,337 V
Hi th kh ca dung dch CuSO 4 0,1 M v NH3 0,1 M bng bao nhiu? (B qua
cc qu trnh to phc khc).
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Bi tp nguyn t Ganvani

Cu 11:
Cho phn ng ho hc xy ra trong nguyn t in ha nh sau:
Ag(NH3)2+ Ag+ + 2 NH3
Hy thit lp nguyn t Ganvani v xc nh hng s khng bn ca phc
Ag(NH3)2+ .
Bit EO Ag+/Ag = 0,7991 V; EO Ag(NH3)2+/Ag = 0,373 V.
Cu 12:
a) Nu iu kin kim loi phn ng c vi dung dch axit.
b) Tnh tan ca Cu trong dung dch HCl 1M; CH3COOH 1M.
c) Kim loi no phn ng c vi HI iu kin chun: Fe; Cu; Ag.
d) Ti sao Hg phn ng c vi H2S gii phng H2.
Cu 13:
Gii thch ti sao pin kh (pin con th) dng mt thi gian b yu i. Nu khng
dng na th pin li phc hi c mt phn.
Cu 14:
Vit phng trnh phn ng ca cc pin sau v tnh S iu kin chun:
Pt | Fe2+, H+,Fe3+ || HCl , Cl2 (Pt)
Pt | Fe2+, H+,Fe3+ || H+, MnO4, Mn2+ | Pt
Cho cc gi tr EO : Fe3+/Fe2+ 0,771. Cl2/2Cl 1,359; MnO4,H+/Mn2+ 1,507
Cu 15:
Cho gin
0,8
1,07
1,0 1,59 1,77 3,09 1,26
1,41
1,28

+
+
NO3 N2O4HNO2NO N2O N2 HN3 NH3OH N2H5 NH4+
Tnh th kh chun ca cc bn phn ng v cc phn ng:
NO3 + H+ + 1e N2O4 + H2O
N2O4 + 2H+ +2e 2 HNO2
2N2O N2 + 2NO
N2O4 + 2NO + H2O 4 HNO2

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