31

2 0 1 0

TRAN SA CT ION S O FM ATER IALS AND HEAT TR EATM ENT

V o l. 3 1

N o. 2

F ebrua ry

2010

P92

1, 2

( 11 , 430072; 21 ( ) ,
643001; 31, 430080)

: 650 e , 100 M P a 15461 5 h P92 ,

, M 23 C6 , , M 23 C6 ,
L aves, 320 nm, 216%
, Laves L aves , ,
, P92 Laves

: P 92;

: TG132. 3; TG 11118

: A

: 1009-6264( 2010) 02-0065-05

Analysis of creep damage at elevated temperature in a P92 steel

1, 2

WANG Xue ,

PAN Q ian-gang ,

CH EN Fang-yu ,

TAO Y ong-shun ,

PENG F ang- fang

( 11Schoo l o f Pow er and M echanics, W uhan University, W uhan 430072, Ch in a;

21Dong fang Bo iler G roup Co L td, Z ig ong 643001, Ch in a;
31T echno lo gy C entre, W uhan Iron and Steel Corporat io n, W uhan 430080, Ch in a)
Abstrac t: The therm a lly and stra in induced damage o f P92 ( 9Cr-015M o-118W-VNb ) stee l w ere investiga ted after creep test conducted
under an app lied stress of 100M Pa for 154615 h at 650 e , and the m echan ism o f creep dam ag e was exam ined. T he resu lts show tha tM 23
C6 carb ide located on subg ra in boundar ies m aintains w ith fine and h igh densitiy distr ibution during the c reep, butm ost o f the re lative larg e
M 23 C6 pa rtic les located on grain boundaries disappears, wh ich resu lts in the cons iderable reduc tion in vo lum e fraction o fM 23 C6 1 The Laves
phase w ith the mean d iame ter o f abou t 320 nm and the vo lum e fraction of 216 % is precip itated a long g rain bounda ries after creep test. A
few sparse ly d istr ibu ted vo ids nucleated at the L aves phase form a long g ra in boundar ies. T he L aves phase distr ibuted along gra in
boundar ies can no t contribute to the prec ip itation hardening, but leads to the decrease of the creep rupture strength due to providing cav ity
nuc lea tion sites. The creep properties o f P92 stee l can be im proved by retard ing and avo id ing the fo rm ation o f Laves phase along gra in
boundar ies.
K ey word s: P92 stee;l heat- res istan t stee;l creep; dam age

P92 9Cr-015M o-118W ,

NbV, B N

, P91,

650 e , 100 M Pa 154615 h P 92

,
[ 1]
,

,
, P92

600 MW 1000 MW
P92 ,

1
V&M P92,

2008-12-03;

2009-11-03

< 325 mm @ 71 mm, 1040~ 1080

e + 750 ~ 780 e , 1

, 20 , : 027-62006356, E-m ai:l wxue2003@ tom.

599 M Pa,

com

751M P a

( 1971) ) , , , ,

66

31

1 P92 ( w t% )
Tab le 1

Ch em ical composition of experimen tal stee l( w t% )

Mn

Si

Cr

Mo

Nb

Ni

Fe

01 12

01 43

01 014

01 004

01 21

81 84

1167

0150

01 21

01 067

01 042

01 0033

01 16

Ba.l

, < 10 mm
, 650 e , 100 M Pa,
RD2-3
154615 h ,
,
,
, EDS
EDS
,
, : 5
,

2
211
1 1,
,

2 3 2,
,
, ,

1 P92
( a); ( b)
F ig11 O ptica lm ic rograghs o f P 92 steel
( a) as- rece ived; ( b) afte r c reep test

, EDS
C r, ,

M 23 C6 2( a) 3( a) ,
, , 3( b) ,

3 Lm

M 23 C6 ,

, Laves

M 23 C6 , EDS

[ 2]

W, L aves

[ 3]

, , , Laves,

, , , M 23 C6

( a) 3( a) , M 23 C6

EDS,

, , ,

5,
W , L aves

,
M 23 C6 ,

, C r M 23 C6

6184% 4122% , 40%

L aves 320 nm, M 23 C 6
2, L aves 216%
212
SEM ,
4 4, 154615 h,

3
311
M 23 C6 ,
Ostw a ld
, ,

[ 4]

: P92

2 P 92 SEM

67

P92 SEM

( a); ( b)

( a); ( b)

F ig1 2 SEM m icrograghs o f prec ip itates

F ig1 3 SEM m icrograghs o f prec ip itates

in the as-rece ived P92 stee l

in P92 stee l after creep test

( a) SE im age; ( b) BSE im age

( a) SE im age; ( b) BSE im age

, M 23 C6 ,
, M 23 C 6

, Laves,
320 nm, - ,

[ 5]

, Laves

P92 W

M 23 C6 L aves
Saw ada GX12 ( G-X12C rM oWVNbN10-1-1)

[ 6]

, L aves M 23 C6 ,

WM o ,
L aves,
Yutaka

[ 8]

, W 9%

M 23 C6 , Laves

, 50% Laves

, M 23 C 6
Laves 1( b)

, ,
L aves,

P92,

M 23 C6
, ,

4, Laves

MX, 50 nm ,
,

L aves ( F eCr) 2 ( WM o )

, 650 e ,

[ 7]

, Cr Laves
750 e , P92,

[ 9]

312

Laves,

P 92 650 e , 154615 h ,

, L aves, P92

L aves 216% [ 7]
, 650 e , P 92 L aves 2000 h

L aves,

, ,

68

[ 10]

31

, ,

,
[ 11]

,
650 e 100 MP a 154615 h,
P92
L aves, ,
L aves,
, P92

, L aves
, L aves ,
P92, ,
Laves
313 P92

C r-M o C r-M o-V , M 6 C

4
( a); ( b)
F ig1 4 BSE m icrograghs of creep cav ities
( a) d istribution of cav ities; ( b) precip itates in cav ities

,
[ 12 ]

, P 92, L aves
, Laves
, ,
P92, L aves
,
L aves
1000 MW
605 e , -
LM P= T (C + lgtr ) ( T ) , K; tr ) , h; C)
, P92 36) , ,
605 e 157743 h ,
,
, 16 @ 10 h
4

, , ,

4
1) P92 M 23 C 6
, , M 23 C6
, ;
5
F ig15

SA D spec trum o f prec ip itates in cav ities

,
,

2) L aves,
320 nm, 216% ;
3) ,
L aves
;

: P92

4) L aves,

69

, ,

5) - , 1000

,
Laves

MW P92 605 e 157743 h

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