Professional Documents
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1.0
INTRODUCTION
The innovation of solar chargers for mobile phones as a product of research and
development has been prompted by the challenge to uncover other possible means of charging
mobile phones especially where and when power supply becomes erratic or totally inaccessible.
This challenge has made solar charging which is one of the expedient alternative methods for
charging mobile devices a necessity. Although this charging idea at present has not been widely
known and accepted in this part of the world: specifically in Nigeria, it is the solution to the
erratic and incessant interruption of power supply to technological equipments mobile phones
being our focus. This fact is further substantiated by the simple fact that Nigeria is located in the
tropics, which are areas that are typically known to have an abundant supply of sunlight all year
round. The solar phone charger is inevitable in Nigeria as a case study, considering the facts that
Nigeria is located in the tropics and at present, many parts of the country are suffering from an
unstable, unreliable, erratic and severely unavailability electric power supply which poses a great
deal of danger to electronic and electrical appliances and consequently shortens their life span, or
incapacitates them at the most critical moments when they are needed to perform the functions
why they were invented or manufactured in the first place.
An electric phone charger (referred to as from now onwards as a regular charger) is a
device used to force current into the battery of a mobile phone by converting pulsating ac
(alternating current) from an ac supply outlet, to dc (direct current) which is the type of current
required by a mobile phone. In a solar mobile phone charger, the ac supply outlet is eliminated,
since the required current and voltage is supplied by a dc cell known as a solar cell, which
converts solar energy into electricity. A solar cell or photovoltaic cell is a large area electronic device
that converts solar energy into electricity by the photovoltaic effect. A solar charger provides an
alternative source for charging mobile phones and furthermore harnesses the use of the abundant solar
energy available for human use. There are many variations in the circuit design of regular electric
chargers and the circuit design of solar chargers. For example, because a solar cell produces dc,
which is what mobile phones generally require, if the solar cell ratings, as much as possible,
closely matches the power requirements of the mobile phone, a transformer is not required,
1
whereas a transformer is needed for a regular charger, since neither of the regular 220V or 110V
can be supplied to a mobile phone even if it is dc. Furthermore, regular chargers have an ac input
and a dc output which means, they definitely must have rectifier circuits and some sort of filter
components to remove ripples, these requirements are somewhat eliminated in the design of solar
chargers. These are some major differences in the design of regular electric phone chargers and
solar chargers, but generally, their mode of operation is the same. It is worth noting that while
regular chargers generally differ from solar chargers, regular chargers also differ one from
another and solar chargers themselves have differences in construction and circuit requirements.
These variations in their individual designs majorly depend on the level of efficiency required. A
solar charger could be designed by simply using a 6V solar cell, connected in series with a
suitable resistor at the positive side of the cell and practically charge a mobile phone, but for
efficiency, it is better to use the solar cell to charge a battery pack which serves as a charge
storage medium, which in turn is used to charge the mobile phone anytime. Another major
advantage of a solar charger is that, it is mobile and could be used anywhere, anytime as long as
theres enough sunlight to make the solar cell produce the power requirements of the phone
being charged and this means that on the move charging is made possible by a solar charger,
since it does not require a regular ac outlet electricity source. The major disadvantage of a mobile
charger, which has been innovatively eliminated in this project is that, a solar charger cannot be
used anywhere or anytime theres no available or sufficient sunlight, because, the solar cell
requires sunlight to produce a considerable amount of current flow. This disadvantage can be
innovatively minimized by placing the solar cell under strong lights when solar energy is
insufficient or unavailable. A better solution to this problem is to add a rechargeable battery to
the circuit, which further makes our design complex. The solar cell is however used to charge
this battery, while the battery in turn charges our mobile phone. In practice, solar cells only
require a small amount of incident light to produce an output power, making it possible to charge
round the clock with or without sunlight using a rechargeable battery.
1.1
A solar cell or photovoltaic cell is a large area electronic device that converts solar energy into
electricity by the photovoltaic effect. Assemblies of cells are used to make solar modules, or
2
photovoltaic arrays which are used to supply either higher current or voltage which cannot be
practically realizable from single cells to loads requiring higher power. Solar cells have many
applications. Cells are used for powering small devices such as electronic calculators, laptops,
mp3 players etc. Photovoltaic arrays generate a form of renewable electricity, particularly useful
in situations where electrical power from the grid is unavailable such as in remote area power
systems. Silicon has some special chemical properties, especially in its crystalline form.
An atom of silicon has 14 electrons, arranged in three different shells. The first two shells, those
closest to the center, are completely full. The outer shell, however, is only half full, having only
four electrons. A silicon atom will always look for ways to fill up its last shell (which would like
to have eight electrons). To do this, it will share electrons with four of its neighbor silicon atoms.
It's like every atom holds hands with its neighbors, except that in this case, each atom has four
hands joined to four neighbors. That's what forms the crystalline structure, and that structure
turns out to be important to this type of PV cell.
We've now described pure, crystalline silicon. Pure silicon is a poor conductor of electricity
because none of its electrons are free to move about, as electrons are in good conductors such as
copper. Instead, the electrons are all locked in the crystalline structure. The silicon in a solar cell
is modified slightly so that it will work as a solar cell.
A solar cell has silicon with impurities -- other atoms mixed in with the silicon atoms, changing
the way things work a bit. We usually think of impurities as something undesirable, but in our
case, our cell wouldn't work without them. These impurities are actually put there on purpose.
Consider silicon with an atom of phosphorous here and there, maybe one for every million
silicon atoms. Phosphorous has five electrons in its outer shell, not four. It still bonds with its
silicon neighbor atoms, but in a sense, the phosphorous has one electron that doesn't have anyone
to hold hands with. It doesn't form part of a bond, but there is a positive proton in the
phosphorous nucleus holding it in place.
When energy is added to pure silicon, for example in the form of heat, it can cause a few
electrons to break free of their bonds and leave their atoms. A hole is left behind in each case.
These electrons then wander randomly around the crystalline lattice looking for another hole to
fall into. These electrons are called free carriers, and can carry electrical current. There are so
few of them in pure silicon, however, that they aren't very useful. Our impure silicon with
phosphorous atoms mixed in is a different story. It turns out that it takes a lot less energy to
knock loose one of our "extra" phosphorous electrons because they aren't tied up in a bond -their neighbors aren't holding them back. As a result, most of these electrons do break free, and
we have a lot more free carriers than we would have in pure silicon. The process of adding
impurities on purpose is called doping, and when doped with phosphorous, the resulting silicon
is called N-type ("n" for negative) because of the prevalence of free electrons. N-type doped
silicon is a much better conductor than pure silicon is.
Actually, only part of our solar cell is N-type. The other part is doped with boron, which has only
three electrons in its outer shell instead of four, to become P-type silicon. Instead of having free
electrons, P-type silicon ("p" for positive) has free holes. Holes really are just the absence of
electrons, so they carry the opposite (positive) charge. They move around just like electrons do.
The interesting part starts when you put N-type silicon together with P-type silicon. Remember
that every PV cell has at least one electric field. Without an electric field, the cell wouldn't work,
and this field forms when the N-type and P-type silicon are in contact. Suddenly, the free
electrons in the N side, which have been looking all over for holes to fall into, see all the free
holes on the P side, and there's a mad rush to fill them in.
There are high efficiency cells which are a class of solar cells that can generate electricity at
higher efficiencies than conventional solar cells.
Solar cells are often electrically connected and encapsulated as a module. PV modules often have
a sheet of glass on the front (sun up) side, allowing light to pass while protecting the
semiconductor wafers from the elements (rain, hail, etc.). Solar cells are also usually connected
in series in modules, creating an additive voltage. Connecting cells in parallel will yield a higher
current. Modules are then interconnected, in series or parallel, or both, to create an array with the
desired peak DC voltage and current.
The power output of a solar array is measured in watts or kilowatts. In order to calculate the
typical energy needs of the application, a measurement in watt-hours, kilowatt-hours or kilowatthours per day is often used. A common rule of thumb is that average power is equal to 20% of
peak power, so that each peak kilowatt of solar array output power corresponds to energy
production of 4.8 kWh per day.
To make practical use of the solar-generated energy, the electricity is most often fed into the
electricity grid using inverters (grid-connected PV systems); in stand-alone systems, batteries are
used to store the energy that is not needed immediately.
1.2
Simple Explanation
1. Photons in sunlight hit the solar panel and are absorbed by semiconducting materials,
such as silicon.
2. Electrons (negatively charged) are knocked loose from their atoms, allowing them to flow
through the material to produce electricity. Due to the special composition of solar cells,
the electrons are only allowed to move in a single direction. The complementary positive
charges that are also created (like bubbles) are called holes and flow in the direction
opposite of the electrons in a silicon solar panel.
3. An array of solar cells converts solar energy into a usable amount of direct current (DC)
electricity.
Because solar cells are semiconductor devices, they share many of the same processing and
manufacturing techniques as other semiconductor devices such as computer and memory chips.
However, the stringent requirements for cleanliness and quality control of semiconductor
fabrication are a little more relaxed for solar cells. Most large-scale commercial solar cell
factories today make screen printed poly-crystalline silicon solar cells. Single crystalline wafers
which are used in the semiconductor industry can be made into excellent high efficiency solar
cells, but they are generally considered to be too expensive for large-scale mass production.
Poly-crystalline silicon wafers are made by wire-sawing block-cast silicon ingots into very thin
(180 to 350 micrometer) slices or wafers. The wafers are usually lightly p-type doped. To make a
solar cell from the wafer, a surface diffusion of n-type dopants is performed on the front side of
the wafer. This forms a p-n junction a few hundred nanometers below the surface.
Antireflection coatings, which increase the amount of light coupled into the solar cell, are
typically next applied. Over the past decade, silicon nitride has gradually replaced titanium
5
dioxide as the antireflection coating of choice because of its excellent surface passivation
qualities (i.e., it prevents carrier recombination at the surface of the solar cell). It is typically
applied in a layer several hundred nanometers thick using plasma-enhanced chemical vapor
deposition (PECVD). Some solar cells have textured front surfaces that, like antireflection
coatings, serve to increase the amount of light coupled into the cell. Such surfaces can usually
only be formed on single-crystal silicon, though in recent years methods of forming them on
multicrystalline silicon have been developed.
The wafer then has a full area metal contact made on the back surface, and a grid-like metal
contact made up of fine "fingers" and larger "busbars" are screen-printed onto the front surface
using a silver paste. The rear contact is also formed by screen-printing a metal paste, typically
aluminium. Usually this contact covers the entire rear side of the cell, though in some cell
designs it is printed in a grid pattern. The paste is then fired at several hundred degrees Celsius to
form metal electrodes in ohmic contact with the silicon. After the metal contacts are made, the
solar cells are interconnected in series (and/or parallel) by flat wires or metal ribbons, and
assembled into modules or "solar panels". Solar panels have a sheet of tempered glass on the
front, and a polymer encapsulation on the back. Tempered glass cannot be used with amorphous
silicon cells because of the high temperatures during the deposition process.
1.3
CHARGERS AT A GLANCE
A battery charger is a device used to put energy into a secondary cell or (rechargeable) battery
by forcing an electric current through it. The charge current depends upon the technology and
capacity of the battery being charged. Battery chargers come in different physical shapes, sizes
and various capacities. According to technological designs, chargers can be broadly classified
into any of the following categories, although, some chargers may fall into more than one
category. They are: Simple Chargers, Trickle Chargers, Timer based Chargers, Intelligent
Chargers, Fast Chargers, Inductive Chargers, Pulse Chargers, Solar Chargers, USB Chargers etc.
Most mobile phone chargers are not really chargers, only adapters that provide a power source
for the charging circuitry which is almost always contained within the mobile phone. Mobile
phones can usually accept a relatively wide range of voltages, as long as it is sufficiently above
the phone battery's voltage. However, if the voltage is too high, it can damage the phone while a
too low voltage generally will not charge the battery. Battery chargers for mobile phones and
other devices are notable in that they come in a wide variety of DC connector-styles and
voltages, most of which are not compatible with other manufacturers' phones or even different
models of phones from a single manufacturer.
CHAPTER TWO
2.0 LITERATURE REVIEW
2.1
SOLAR CELLS: A solar cell or photovoltaic cell is a large area electronic device that
converts solar energy into electricity by the photovoltaic effect. Photovoltaics is the field of
technology and research related to the application of solar cells for solar energy. Sometimes the
term solar cell is reserved for devices intended specifically to capture energy from sunlight,
while the term photovoltaic cell is used when the source is unspecified. Assemblies of cells are
used to make solar modules, or photovoltaic arrays. Solar cells have many applications. Cells are
used for powering small devices such as electronic calculators. Photovoltaic arrays generate a
form of renewable electricity, particularly useful in situations where electrical power from the
grid is unavailable such as in remote area power systems, Earth-orbiting satellites and space
probes, remote radiotelephones and water pumping applications. Photovoltaic electricity is also
increasingly deployed in grid-tied electrical systems. Similar devices intended to capture energy
from other sources include thermo-photovoltaic cells, betavoltaics cells, and optoelectric nuclear
batteries.
Current research is targeting conversion efficiencies of 30-60% while retaining low cost
materials and manufacturing techniques. They can exceed the theoretical solar conversion
efficiency limit for a single energy threshold material, that was calculated in 1961 by Shockley
and Queisser as 31% under 1 sun illumination and 40.8% under maximal concentration of
sunlight (46,200 suns, which makes the latter limit more difficult to approach than the former).
Solar cells are often electrically connected and encapsulated as a module. PV modules often
have a sheet of glass on the front (sun up) side, allowing light to pass while protecting the
semiconductor wafers from the elements (rain, hail, etc.). Solar cells are also usually connected
in series in modules, creating an additive voltage. Connecting cells in parallel will yield a higher
current. Modules are then interconnected, in series or parallel, or both, to create an array with
the desired peak DC voltage and current.
The power output of a solar array is measured in watts or kilowatts. In order to calculate the
typical energy needs of the application, a measurement in watt-hours, kilowatt-hours or kilowatt8
hours per day is often used. A common rule of thumb is that average power is equal to 20% of
peak power, so that each peak kilowatt of solar array output power corresponds to energy
production of 4.8 kWh per day.
To make practical use of the solar-generated energy, the electricity is most often fed into the
electricity grid using inverters (grid-connected PV systems); in stand alone systems, batteries are
used to store the energy that is not needed immediately.
There are a few approaches to achieving these high efficiencies:
Technologies include:
Silicon nanostructures
Up/Down converters
Hot-carrier cells
Thermoelectric cells
systems while reducing their size, weight and mechanical complexity. The new 3D solar cells
capture photons from sunlight using an array of miniature tower structures that resemble highrise buildings in a city street grid . To increase efficiency of solar cells a system has been
developed, known as concentrating photovoltaic systems which in practice are not cells but
rather are methods that use a large area of lenses or mirrors to focus sunlight on a small area of
photovoltaic cells. If these systems use single or dual-axis tracking to improve performance, they
may be referred to as Heliostat Concentrator Photovoltaics (HCPV). The primary attraction of
CPV systems is their reduced usage of semiconducting material which is expensive and currently
in short supply. Additionally, increasing the concentration ratio improves the performance of
general photovoltaic materials. Despite the advantages of CPV technologies their application has
been limited by the costs of focusing, tracking and cooling equipment
10
depletion region because it no longer contains any mobile charge carriers. It is also known as the
"space charge region".
To understand the electronic behaviour of a solar cell, it is useful to create a model which is
electrically equivalent, and is based on discrete electrical components whose behaviour is well
known. An ideal solar cell may be modelled by a current source in parallel with a diode; in
practice no solar cell is ideal, so a shunt resistance and a series resistance component are added
to the model. The resulting equivalent circuit of a solar cell is shown
From the equivalent circuit it is evident that the current produced by the solar cell is equal to that
produced by the current source, minus that which flows through the diode, minus that which
flows through the shunt resistor:
I = IL ID ISH
........................
where
11
Equation 2.1
The current flowing through these elements governed by the voltage across them:
Vj = V + IRS
...........................
Equation 2.2
where
RS = series resistance ()
By the Shockley diode equation, the current diverted through the diode is:
.............................
where
q = elementary charge
k = Boltzmann's constant
T = absolute temperature
volts.
By Ohm's law, the current diverted through the shunt resistor is:
12
Equation 2.3
...............................
Equation 2.4
where
Substituting these into the first equation produces the characteristic equation of a solar cell,
which relates solar cell parameters to the output current and voltage:
................
Equation 2.5
An alternative derivation produces an equation similar in appearance, but with V on the left-hand
side. The two alternatives are identities; that is, they yield precisely the same results.
In principle, given a particular operating voltage V the equation may be solved to determine the
operating current I at that voltage. However, because the equation involves I on both sides in a
transcendental function the equation has no general analytical solution. However, even without a
solution it is physically instructive. Furthermore, it is easily solved using numerical methods. (A
general analytical solution to the equation is possible using Lambert's W function, but since
Lambert's W generally itself must be solved numerically this is a technicality.)
Since the parameters I0, n, RS, and RSH cannot be measured directly, the most common application
of the characteristic equation is nonlinear regression to extract the values of these parameters on
the basis of their combined effect on solar cell behaviour.
2.1.2a
The values of I0, RS, and RSH are dependent upon the physical size of the solar cell. In comparing
otherwise identical cells, a cell with twice the surface area of another will, in principle, have
double the I0 because it has twice the junction area across which current can leak. It will also
have half the RS and RSH because it has twice the cross-sectional area through which current can
13
flow. For this reason, the characteristic equation is frequently written in terms of current density,
or current produced per unit cell area:
.................
Equation 2.6
Where
This formulation has several advantages. One is that since cell characteristics are referenced to a
common cross-sectional area they may be compared for cells of different physical dimensions.
While this is of limited benefit in a manufacturing setting, where all cells tend to be the same
size, it is useful in research and in comparing cells between manufacturers. Another advantage is
that the density equation naturally scales the parameter values to similar orders of magnitude,
which can make numerical extraction of them simpler and more accurate even with naive
solution methods.
A practical limitation of this formulation is that as cell sizes shrink, certain parasitic effects grow
in importance and can affect the extracted parameter values. For example, recombination and
contamination of the junction tend to be greatest at the perimeter of the cell, so very small cells
may exhibit higher values of J0 or lower values of rSH than larger cells that are otherwise
identical. In such cases, comparisons between cells must be made cautiously and with these
effects in mind.
14
2.1.2b
Cell temperature
Temperature affects the characteristic equation in two ways: directly, via T in the exponential
term, and indirectly via its effect on I0. (Strictly speaking, temperature affects all of the terms, but
these two far more significantly than the others.) While increasing T reduces the magnitude of
the exponent in the characteristic equation, the value of I0 increases in proportion to expT. The
net effect is to reduce VOC linearly with increasing temperature. The magnitude of this reduction
is inversely proportional to VOC; that is, cells with higher values of VOC suffer smaller reductions
in voltage with increasing temperature. For most crystalline silicon solar cells the reduction is
about 0.50%/C, though the rate for the highest-efficiency crystalline silicon cells is around
0.35%/C. By way of comparison, the rate for amorphous silicon solar cells is 0.20-0.30%/C,
depending on how the cell is made.
The amount of photogenerated current IL increases slightly with increasing temperature because
of an increase in the number of thermally generated carriers in the cell. This effect is slight,
however: about 0.065%/C for crystalline silicon cells and 0.09% for amorphous silicon cells.
The overall effect of temperature on cell efficiency can be computed using these factors in
combination with the characteristic equation. However, since the change in voltage is much
stronger than the change in current, the overall effect on efficiency tends to be similar to that on
voltage. Most crystalline silicon solar cells decline in efficiency by 0.50%/C and most
amorphous cells decline by 0.15-0.25%/C. The figure below shows I-V curves that might
typically be seen for a crystalline silicon solar cell at various temperatures.
2.1.3
Series resistance
15
Fig 2.4: Effect of series resistance on the current-voltage characteristics of a solar cell
As series resistance increases, the voltage drop between the junction voltage and the terminal
voltage becomes greater for the same flow of current. The result is that the current-controlled
portion of the I-V curve begins to sag toward the origin, producing a significant decrease in the
terminal voltage V and a slight reduction in ISC. Very high values of RS will also produce a
significant reduction in ISC; in these regimes, series resistance dominates and the behaviour of the
solar cell resembles that of a resistor. These effects are shown for crystalline silicon solar cells in
the I-V curves displayed in the figure below.
2.1.4
Shunt resistance
Fig 2.5: Effect of shunt resistance on the current-voltage characteristics of a solar cell
As shunt resistance decreases, the flow of current diverted through the shunt resistor increases
for a given level of junction voltage. The result is that the voltage-controlled portion of the I-V
curve begins to sag toward the origin, producing a significant decrease in the terminal current I
and a slight reduction in VOC. Very low values of RSH will produce a significant reduction in VOC.
Much as in the case of a high series resistance, a badly shunted solar cell will take on operating
16
characteristics similar to those of a resistor. These effects are shown for crystalline silicon solar
cells
in
2.1.5
the
I-V
curves
displayed
in
the
figure
to
the
right.
Fig 2.6: Effect of reverse saturation current on the current-voltage characteristics of a solar cell
If one assumes infinite shunt resistance, the characteristic equation can be solved for VOC:
.........................
Equation 2.7
Thus, an increase in I0 produces a reduction in VOC proportional to the inverse of the logarithm of
the increase. This explains mathematically the reason for the reduction in VOC that accompanies
increases in temperature described above. The effect of reverse saturation current on the I-V
curve of a crystalline silicon solar cell are shown in the figure to the right. Physically, reverse
saturation current is a measure of the "leakage" of carriers across the p-n junction in reverse bias.
This leakage is a result of carrier recombination in the neutral regions on either side of the
junction.
17
2.1.6
Ideality factor
Fig 2.7: Effect of ideality factor on the current-voltage characteristics of a solar cell
The ideality factor (also called the emissivity factor) is a fitting parameter that describes how
closely the diode's behaviour matches that predicted by theory, which assumes the p-n junction
of the diode is an infinite plane and no recombination occurs within the space-charge region. A
perfect match to theory is indicated when n = 1. When recombination in the space-charge region
dominate other recombination, however, n = 2. The effect of changing ideality factor
independently of all other parameters is shown for a crystalline silicon solar cell in the I-V
curves displayed in the figure to the right.
Most solar cells, which are quite large compared to conventional diodes, well approximate an
infinite plane and will usually exhibit near-ideal behaviour under Standard Test Condition (
). Under certain operating conditions, however, device operation may be dominated by
recombination in the space-charge region. This is characterized by a significant increase in I0 as
well as an increase in ideality factor to
while the former acts to increase it. The net effect, therefore, is a combination of the increase in
voltage shown for increasing n in the figure to the right and the decrease in voltage shown for
increasing I0 in the figure above. Typically, I0 is the more significant factor and the result is a
reduction in voltage.
2.2
BATTERY CHARGERS
18
A battery charger is a device used to put energy into a secondary cell or (rechargeable) battery
by forcing an electric current through it. The charge current depends upon the technology and
capacity of the battery being charged. For example, the current that should be applied to recharge
a 12 V car battery will be very different from the current for a mobile phone battery.
2.2.1
input
requirements
and
their
output.
Generally,
Simple Chargers
A simple charger works by connecting a constant DC power source to the battery being charged.
The simple charger does not alter its output based on time or the charge on the battery. This
simplicity means that a simple charger is inexpensive, but there is a trade-off in quality.
Typically, a simple charger takes longer to charge a battery to prevent severe over-charging. Even
so, a battery left in a simple charger for too long will be weakened or destroyed due to overcharging. These chargers can supply either a constant voltage or a constant current to the battery.
2.2.1b
Trickle Chargers
A trickle charger is a kind of simple charger that charges the battery slowly, at the self-discharge
rate. A trickle charger is the slowest kind of battery charger. A battery can be left in a trickle
charger indefinitely. Leaving a battery in a trickle charger keeps the battery "topped up" but
never over-charges.
2.2.1c
Timer-based Chargers
The output of a timer charger is terminated after a pre-determined time. Timer chargers were the
most common type for high-capacity Ni-Cd cells in the late 1990s for example (low-capacity
consumer Ni-Cd cells were typically charged with a simple charger).
19
Often a timer charger and set of batteries could be bought as a bundle and the charger time was
set to suit those batteries. If batteries of lower capacity were charged then they would be
overcharged, and if batteries of higher capacity were charged they would be only partly charged.
With the trend for battery technology to increase capacity year on year, an old timer charger
would only partly charge the newer batteries.
Timer based chargers also had the drawback that charging batteries that were not fully
discharged, even if those batteries were of the correct capacity for the particular timed charger,
would result in over-charging.
2.2.1d
Intelligent Chargers
Output current depends upon the battery's state. An intelligent charger may monitor the battery's
voltage, temperature and/or time under charge to determine the optimum charge current at that
instant. Charging is terminated when a combination of the voltage, temperature and/or time
indicates that the battery is fully charged.
For Ni-Cd and NiMH batteries, the voltage across the battery increases slowly during the
charging process, until the battery is fully charged. After that, the voltage decreases, which
indicates to an intelligent charger that the battery is fully charged. Such chargers are often
labelled as a V, or "delta-V," charger, indicating that they monitor the voltage change.
The problem is, the magnitude of "delta-V" can become very small or even non-existent if (very)
high capacity rechargeable batteries are recharged. This can cause even an intelligent battery
charger to not sense that the batteries are actually already fully charged, and continue charging.
Overcharging of the batteries will result in some cases. However, many so called intelligent
chargers employ a combination of cut off systems, which should prevent overcharging in the vast
majority of cases.
A typical intelligent charger fast-charges a battery up to about 85% of its maximum capacity in
less than an hour, then switches to trickle charging, which takes several hours to top off the
battery to its full capacity.
20
2.2.1e
Fast Chargers
Fast chargers make use of control circuitry in the batteries being charged to rapidly charge the
batteries without damaging the cells' elements. Most such chargers have a cooling fan to help
keep the temperature of the cells under control. Most are also capable of acting as a standard
overnight charger if used with standard NiMH cells that do not have the special control circuitry.
Some fast chargers, such as those made by Energizer, can fast-charge any NiMH battery even if
it does not have the control circuit.
2.2.1f
Pulse Chargers
Some chargers use pulse technology in which a pulse is fed to the battery. This DC pulse has a
strictly controlled rise time, pulse width, pulse repetition rate (frequency) and amplitude. This
technology is said to work with any size, voltage, capacity or chemistry of batteries, including
automotive and valve-regulated batteries. With pulse charging, high instantaneous voltages can
be applied without overheating the battery. In a Lead-acid battery, this breaks-down stubborn
lead-sulphate crystals, thus greatly extending the battery service life.
Some chargers use pulses to check the current battery state when the charger is first connected,
then use constant current charging during fast charging, then use pulse charging as a kind of
trickle charging to maintain the charge.
Some chargers use "negative pulse charging", also called "reflex charging" or "burp charging".
Such chargers use both positive and brief negative current pulses. Such chargers don't work any
better than pulse chargers that only use positive pulses.
2.2.1g
Inductive Chargers
Inductive battery chargers use electromagnetic induction to charge batteries. A charging station
sends electromagnetic energy through inductive coupling to an electrical device, which stores the
energy in the batteries. This is achieved without the need for metal contacts between the charger
and the battery. It is commonly used in electric toothbrushes and other devices used in
bathrooms. Because there are no open electrical contacts, there is no risk of electrocution.
21
2.2.1h
USB-based
Since the Universal Serial Bus specification provides for a five-volt power supply, it's possible to
use a USB cable as a power source for recharging batteries. Products based on this approach
include chargers for cellular phones and portable digital audio players.
2.2.1i
Solar chargers
Solar chargers employs solar energy in charging devices and are generally portable.
2.3
CIRCUIT COMPONENTS
The following components were employed in the design of the solar mobile phone charger and
since they come in various sizes and ratings, it is worthwhile to briefly discuss them.
2.3.0
varying amounts of current of voltage to be applied at specific portions of the circuit and to
various components. Resistors, as their name implies, are used in such instances to ensure
resistance to the flow of current to various portions of the circuit. Generally, these are
materials with specific values of resistance in the range between that of a conductor and an
insulator. Their values of resistance are expressed in ohms and their heat withstanding rating
is expressed in watts. Resistors are classified as either being fixed or variable. Fixed resistors
have a constant value while variable resistors also known as potentiometers or pots have
values that can be varied depending on requirements. Generally, resistors used in circuits are
linear while non-linear resistors are used for special applications. The resistance of any
material is given by:
R = L/A
Where R = Resistance in ohms
Resistors are connected either in series or parallel. For resistors connected in series, the
current that flows in each resistor is the same, and total resistance of the series connection is
22
equal to the sum of the individual resistors. If for example, n resistors of equal resistance are
connected in series, the total equivalent resistance will be given as:
RT = nR.
If n = 3 i.e. 3 resistors of same resistance connected in series,
RT = R 1 + R 2 + R 3
For resistors connected in parallel, voltage across each resistor is the same, but current across
each differs. Therefore the total resistance RT of say 3 resistors in parallel is given by:
1/RT = 1/R1 + 1/R2 + 1/R3
Fixed Resistors are generally manufactured in four basic types which are carbon
composition, metal film, carbon film and wire wound. The carbon composition type is most
commonly used in electronic circuits. Generally, resistors are colour coded and this means
that to ascertain the value of a resistor, the colour codes must be understood. There are
typically four colours on a resistor. The first two colours denote the first and second digits of
the resistance value; the third colour indicates the multiplier while the fourth colour indicates
the tolerance value for the resistor. The table below gives the standard for colour coding
resistors.
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COLOUR
DIGIT
MULTIPLIER
TOLERANCE
Black
Brown
10
1%
Red
102
Orange
103
Yellow
104
Green
105
Blue
106
Violet
107
Gray
White
Gold
0.1
5%
Silver
10%
No Colour
20%
CAPACITORS: These are passive circuit components which are made of two
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parallel plate capacitor is directly proportional to the relative dielectric constant of the
insulator and to the area of the plates. Furthermore, the capacitance is greater if the
separation between plates is small and vice versa. These are expressed by the following
equation:
C = KoA/d
Where C = Capacitance in farads, F
It is seen from the equation that capacitance may be increased by increasing the area of the
plates or the dielectric constant and by decreasing the separation between plates.
Although, capacitors are available in various types, shapes and sizes, they can be
generally grouped into four broad categories which are fixed, variable, chip and voltage
variable. Types of capacitors available are silver mica, electrolytic, ceramic and trimmer
capacitors. Electrolytic capacitors are generally employed in circuits where a large value of
capacitance in a small volume is required and these capacitors can be either polarised or non
polarised while silver mica capacitors generally have small capacitance and greater
mechanical stability capacitance remaining constant at different temperatures with different
voltages and does not easily wear with age of capacitor. They generally have uniform
characteristics and will not break down at high voltages or high resistances. Trimmer
capacitors are a type of variable capacitors operated by a screw driver instead of a knob.
Their capacitance can be altered by pressing the plates tightly together which in turn alters
the distance between the plates.
2.3.2
when current passes through an integral wire core, which may be an air core armature and
made of soft iron or some other ferromagnetic materials. If an applied e.m.f (electromotive
force) applied to the coil changes, a back e.m.f is induced which opposes the change (Lenzs
law). The coil acts strongly against rapid changes in e.m.f and the strength of this effect is
called the inductance of the coil, measured in Henry.
25
The voltage, V applied across an ideal inductor equals the value of the inductance L (in
Henry) multiplied by the rate of change of current with respect to time (ampere/time). For an
indicator, the greater the voltage applied across the coil, the faster the current increases,
Hence:
V=L
di
/dt
L = inductance of coil
It should be noted that inductance increases with permeability of core, increase in number of
turns and with increase in area of core while increase in length for the same number of turns
decreases inductance since magnetic field will be less concentrated. Also it is worthy to note
that inductors are made of wires and the coil has dc resistance which is equal to the resistance
of the wire used in the winding of the core. The amount of resistance however, is less with
heavier wires and fewer turns.
2.3.3
DIODES: These are probably the simplest semiconductor devices. Most diodes
are made from a host crystal of silicon (Si) with appropriate impurity elements introduced to
modify, in a controlled manner, the electrical characteristics of the device. They are formed
when a p-type semiconductor is joined to an n-type semiconductor and doped. The resulting
component is a diode which allows flow of current in only one direction. To achieve this, the
diode must be forward biased with a voltage higher than the threshold voltage which is 0.6V
for silicon and 0.25V for germanium. The threshold voltage decreases at the rate of 2mV per
degree rise in temperature. Another type of diode is a schottky (unipolar) diode,
manufactured by placing a metal layer directly across the semiconductor. Diodes are mainly
used in rectification, which is the process of converting ac into dc. Power diodes are a type of
diodes which are able to carry current of several amperes. Types of diode include: power
diodes, zener diodes, Schottky diodes, Light emitting diodes, photo diodes etc.
2.3.4
TRANSISTORS: They are three terminal devices (emitter, base and collector)
used as amplifiers and as switches. Generally, there are two types which are NPN and PNP
transistors. A transistor is an active circuit component in that it is capable of modifying or
amplifying the input signal. They are delicate and heat sensitive. Typically, a transistor is like
two diodes with either their p-type or n-type materials joined together at the ends. Transistors
26
come in different types and specifications, of which some are BJTs (Bipolar Junction
Transistors), Unipolar transistors, FETs (Field Effect Transistors), JFETs (Junction FETs),
MOSFET (Metal Oxide Semiconductor Field Effect Transistor) etc.
The criteria for a properly biased transistor is that the base-emitter junction is forward biased
while the base-collector junction is reverse biased. There are manufacturers data books
readily available that contain all the necessary information about any particular type of
transistor, including possible substitutes if a particular transistor is not readily available.
Since transistors are heat sensitive, excessive heat should not be applied when soldering and
all terminals should be correctly identified before installing them. Although all transistors
have terminals that are easily recognised in circuit diagrams, distinguishing these terminals
on the actual devices is not always quite easy
2.3.5
FUSES: The fuse is a simple and reliable safety device. It is second to none in its
ease of application and its ability to protect people and equipment. The fuse is a currentsensitive device. It has a conductor with a reduced cross section (element) normally
surrounded by an arc-quenching and heat-conducting material (filler). The entire unit is
enclosed in a body fitted with end contacts.
Most fuses have three electrical ratings: ampere rating, voltage rating, and interrupting
rating. The ampere rating indicates the current the fuse can carry without melting or
exceeding specific temperature rise limits. The voltage rating, ac or dc, usually indicates the
maximum system voltage that can be applied to the fuse. The interrupting rating (I.R.)
defines the Maximum short-circuit current that a fuse can safely interrupt. If a fault current
higher than the interrupting rating causes the fuse to operate, the high internal pressure may
cause the fuse to rupture.
CHAPTER THREE
3.0 DESIGN AND CIRCUIT ANALYSIS
27
The design and construction requirements for this solar mobile phone charger are given
below. The circuit diagram is divided into two major parts. Using the battery as our point of
division, every component towards the left hand side (the solar cell, capacitors C1, C2, C3,
resistors R1-R6, Diode D1, Inductor L1 and transistors Q1 and Q2) are for trickle charging the
battery pack while the remaining components to the right of the battery including the battery
itself actually supply the voltage and current requirements that charge the mobile phone. The
addition of a battery to the circuit ensures that with or without sunlight, the circuit can charge the
mobile phone round the clock. The reason for the addition of a battery pack is to ensure as might
practically occur, that days of very little or no sunshine do not incapacitate the charger. On days
when there is sufficient sunlight as required by the solar cell, the battery pack is kept charging
and whether or not there is sufficient sunlight on other days, as long as the battery is present and
has been charged to a level, any connected mobile phone can be charged, without totally
depending on the intensity of sunlight available at that instance. In the actual construction of the
circuit, the following optional components were added for the sake of flexibility: 2 switches
SW1 and SW2, added to each upper diagonal extreme of the circuit and a 2A fuse between
switch SW2 and the output jack J1. This means that there is a switch SW1 immediately after the
photocell PC1 (the positive terminal of the cell) to stop the cell from supplying current
indefinitely to the battery at all times, thereby avoiding overcharging of battery. Another switch
SW2 is placed between resistor R6 and the output jack J1 to avoid indefinite supply of current as
long as a phone is connected to the output terminal. A 2A fuse is further added between switch
SW2 and the output jack J1 to disconnect the load from the circuit in case of excess current
exceeding 2A. Additionally, a light emitting diode may be installed close to the positive terminal
of the output to light up when SW2 is in the ON position.
28
The circuit shown above uses a small 3 volt solar cell to charge a 6 volt NiCad/NiMH battery
pack which, in turn, may be used to charge many models of cell phones and other portable
devices. The circuit "scavenges" energy from the solar cell by keeping it loaded near 1.5 volts
(maximum energy transfer value) and trickle charges the internal battery pack with current
pulses. The simple circuit isn't the most efficient possible but it manages a respectable 70% at
100 mA from the cell and 30% when the cell is providing only 25 mA which is actually pretty
good without going to a lot more trouble or using more exotic components.
3.1
MODE OF OPERATION:
When the voltage on the emitter of Q1 rises a little over 1.5 volts, both transistors turn on
quickly, snapping on due to the positive feedback through R5 and C2. The current increases in
L1 through Q2 until the voltage across the cell drops somewhat below 1.5 volts. The circuit then
switches off quickly and the voltage on the collector of Q2 jumps up, turning on D1, allowing
the inductor current to flow into the battery. Once the inductor has discharged into the battery,
the process starts over. The circuit can charge higher voltage batteries without any circuit
changes since the voltage will jump up quite high on the collector when the transistors turn off.
The circuit should not be operated without a battery attached. For a little more efficiency,
29
increase R5 in proportion to the voltage increase on the battery. (For example, double R5 for
charging a 12 volt battery.) A NiCad instead of a NiMH battery is preferable because they are
particularly forgiving of overcharging, simply converting the excess current into heat.
C2
C3
R1
R2
R3
R4
R5
R6
L1
D1
Q1 2N4403, or similar
Q2 2N4401, or similar
J1
output jack
B1
The photocell can be salvaged from an inexpensive solar sidewalk illuminator, gotten from other
solar products or bought in the market and it should have an open-circuit voltage of about 3 volts
and supplies about 100 mA in bright sunlight. The circuit can handle more current but cells that
supply more than 250 mA should be avoided. The inductor has a low resistance winding but a
30
surprising number of cores will work fairly well. The value of inductance isn't critical, perhaps
between 40 and 300 H and during proper operation there will be a pulse waveform on the
collector of Q2 with several 10s of microseconds period. This prototype operates at about 40 S
as shown and the inductance measures about 50 H.
For experimenting with cores or other circuit values, the NiCad/NiMH battery can be replaced
with a zener diode of the same voltage and replace the solar cell with a 3 volt power supply with
a series resistor, about 22 ohms to simulate moderate sun. Measure the current in the zener diode
and compare that power (zener diode current times zener diode voltage) to the power coming
from the power supply (3 volts times power supply current) to see how the circuit is doing. When
the power in the zener diode is over half the power from the supply, the inductor is good enough.
It is mandatory that a fuse be added near one of the terminals of the battery to shield the load
from excessive current supply should something go wrong. Battery packs can supply dangerous
current levels, so the lead from the fuse to the battery terminal must be kept as short as practical.
It is also better to prevent damage to the load by adding a fuse which can be easily replaced
anytime should anything go wrong, than eliminate the use of a fuse and subject the load to
possible damage.
In addition to the fuse a 10 ohm PTC was added in series with the output to limit the available
power but also to allow the unit to charge some special models of Nokia phone that in practice
do not like a very low impedance battery as a charging source. (The phone simply displays
"battery not charging".) The PTC is actually soldered directly to the copper board and one end of
the fuse connects directly to the top side (if a switch is used, then the 10 ohm PTC connects
directly to the switch and the switch in turn connects to the fuse).
The circuit works great! It can simply be left on the dashboard of a car to charge until needed.
Several Nokia phones can be charged with this circuit without a problem. It is actually more
convenient than a cigarette lighter adapter because it can travel with the phone and it doesn't
need sunlight to charge the phone.
It was noticed that the circuit charges phones suspiciously fast and it was thought that it might
not be a bad idea if the output resistance is increased. Fast charging cell phone batteries shorten
31
their life, if I understand correctly. The tradeoff is between fast charging the cell phone battery
and possibly shortening its overall life span or charging it more slowly (which increases the time
it takes to fully charge the cell phone especially when the phone battery is highly discharged) and
increasing the lifespan. Most phones have sophisticated internal charging circuits but it is
suspected that the manufacturers sacrifice battery life for fast charging. With the construction of
this charger, phones will not need to be significantly discharged due to lack of electricity supply
anymore.
CHAPTER FOUR
32
33
the solar cell and the positive terminal of capacitor C1 to avoid the solar cell from charging the
battery pack indefinitely and SW2 was installed between resistor R6 and the positive terminal of
the output jack, to make it possible to disconnect the phone from charging even when physically
plugged in. A light emitting diode was further added to indicate when SW2 is in the open or
close state. Installing capacitor C2 and R5 which formed out positive feedback path was not so
easy, but after so much thoughtful efforts, success was achieved. The type of battery used was a
6V NiMH (Nickel Metal Hydride) battery. In place of this, a NiCad (Nickel Cadmium) battery
could be used and this might even be a better option, following the information gathered online,
that NiCad batteries are particularly forgiving of overcharging, by simply converting the excess
charge into heat. If the negative electrode is overcharged, hydrogen gas is produced, If the
positive electrode is overcharged, oxygen gas is produced. The last thing to be installed was the
solar cell.
4.1
like casing of slightly flexible material. By cutting it into the required sizes to serve as an
enclosure for the circuit board, the different sizes were glued together and taped at the sides to
form a firm transparent casing. The inductor L1 used for the circuit was sealed and cylindrical in
shape. This initially served as a setback in the design of the casing but the top part of the casing
was later cut open to allow only the upper part of the inductor shoot out a little above the case.
To allow easy access to switches SW1 and SW2, the sides of the casing, restricting access to
these switches were cut open. The whole assembly was made compact and rigid, bearing in mind
that making the assembly too heavy would be a turn off when considering its mobility.
4.2
34
After installing every component, it was time to test the assembly. A Nokia phone was
connected to the output jack and nothing happened. The switches were confirmed to be closed
and the output voltage of the solar cell was measured and found to be within required range. It
was later discovered that the NiMH battery had naturally discharged over time and the measured
voltage was just 1.2V which was far too low to charge a mobile phone. The assembly was later
left in the sun for a very long period of time to ensure that the battery stored enough charge to
charge the mobile phone. A 6V speaker was tested and it was found to produce signs of current
flow, but when the Nokia phone was plugged, it simply displayed battery not charging. It was
later discovered that some models of Nokia phones generally in practice do not like a very low
impedance battery as a charging source and the 10 ohm PTC was added in series with the output
not only to limit the available power but also to allow the unit to charge those special models of
Nokia phone that dont like a very low impedance charging source. (The phone simply displays
"battery not charging
After the tests, it was realized that what determined if the unit would charge a phone or not was
not the amount of sunlight or power output of the solar cell, but rather, the output power of the
attached NiMH battery. So if the battery becomes too low, the phone will not charge.
CHAPTER FIVE
35
36
In conclusion, it has been a worthwhile experience and the effort and time invested into
this design and construction has really paid off. It has revealed that solar energy is in abundance
and can be harnessed for use in a lot of ways, even to the point of charging mobile devices which
removes total dependence on frequently unavailable and highly erratic electric power supply
from utility grids. It has also showed that mobile charging is possible and by mobile charging,
what is meant is charging while on the move.
RECOMMENDATIONS
I want to recommend that solar mobile phone chargers should be designed and
constructed indigenously by both students (for educational purposes) and corporate bodies (for
commercial purposes)
Also, I want to recommend that more research effort should focus on harnessing the
abundant energy from the sun into various useful means.
I want to recommend that practical hands on electronic circuit design and construction be
introduced early enough in schools to stir up early interest.
REFERENCES
37
01 April 2000.
HowStuffWorks.com.
14.http://www.instructables.com/id/Build_your_own_solar_powered_mobile_phone/
15.Solar Web, Inc./SunWize Energy Systems, The Power to make your design a reality,
1991.
39