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Core Laboratories: Reservoir Fluid Study For Occidental de Colombia Caricare-5 Well, Form.: M2
Core Laboratories: Reservoir Fluid Study For Occidental de Colombia Caricare-5 Well, Form.: M2
for
OCCIDENTAL DE COLOMBIA
Caricare-5 Well, Form.: M2
RFL 0603116
The analyses, opinions or interpretations in this report are based on observations and material supplied
by the client to whom, and for whose exclusive and confidential use, this report is made. The
interpretations or opinions expressed represent the best judgement of Core Laboratories Venezuela,
S.A. (all errors and omissions excepted); but Core Laboratories Venezuela, S.A. and its officers and
employees assume no responsibility and make no warranty or representations as to the productivity,
proper operation or profitability of any oil, gas or any other mineral well formation in connection with
which such report is used or relied upon.
Core Laboratories
Cra 39 Nro. 168-52, Bogot, Colombia
Tel: +57 (1) 6740400 Fax: +57 (1) 6730060 Web: http://www.corelab.com
Core Laboratories
Cra. 39 Nro. 168-52
Bogot, Colombia
Tel: 57 1 6740400
Web: http://www.corelab.com
Occidental de Colombia.
Bogota, Colombia.
Attention : Eng. Aldo Caliz
Subject:
Well:
Formation:
Interval:
File:
Dear Sirs.:
Two bottomhole samples and two wellhead samples from the subject well were collected on
July 9th and July 10th of 2006 by Core Laboratories representatives and delivered to our
fluid laboratory in Bogot for use in the performance of a Reservoir Fluid Study. The
samples were transported to the laboratory whereupon sample validation and analysis
commenced.
Preliminary results were reported during the execution of the study and the final report is
presented in the following pages.
It has been a pleasure to perform this study for Occidental de Colombia. Should any
questions arise or if we may be of further service in any way, please do not hesitate to
contact us.
Sincerely,
CORE LABORATORIES VENEZUELA, S.A.
David McEvoy
Manager
Reservoir Fluids Laboratory
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Table of Contents
Section A - Summary of PVT Methods and Data
Page
A.1-A.3
A.4
B.1
B.2
C.1-C.2
D.1-D.2
D.3
D.4-D.5
D.6-D.7
D.8-D.9
E.1
E.2
E.3
E.4-E.5
E.6-E.7
F.1
F.2
G.1
G.2
G.3
G.4
Section H - Appendix
Data used in gas compositional calculations...................................................................
H.1
H.2
___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Sample Validation
The bubble point pressure at ambient temperature and free water content of each bottomhole
sample were determined as initial quality checks. From this quality control, the measured bubble
point pressures of the samples showed good agreement with one another and very little free water
was measured. The PVT study proceeded using the bottomhole samples while the wellhead
samples were retained as backups.
Heat Treatment
The selected bottomhole fluid sample was heated to 200F prior to subsampling for laboratory tests
to avoid potential wax deposition problems.
Pressurized Fluid Composition
Approximately 30 cc of pressurized fluid was flashed to atmospheric pressure at 120 F and
separated into gas and oil phase. The evolved gas and residual liquid were analyzed separately,
using gas-liquid chromatography and recombined on a weight basis to produce a C36+ weight
percent composition.
Gas Compositions
Gas composition were measured using a "one shot" Varian 3800 gas analyzer using GPA 2286
method. The gas chromatograph utilizes 3 columns to clearly identify all of the eluted components
from N2, CO2 and C1 through C11+.
The chromatograph is calibrated weekly using air and synthetic hydrocarbon gas with a known
composition. The resultant calibration data is checked statistically against previous calibrations
prior to performing analyses on unknown samples.
Liquid Composition
Residual/stocktank liquid composition were measured using a Varian 3400 chromatograph. The
gas chromatograph utilizes a cold on column, "sandwich injection" technique to ensure that a
representative sample is injected and swept onto the column. The sample is run twice; first the
original fluid and then fluid spiked with n-tetradecane. This allows the laboratory to take into
account any heavy end (C36+) losses that may have occurred during the chromatographic run, and
make an accurate correction prior to reporting the liquid composition. The data obtained from the
gas chromatograph is in weight %. Calculations to mole% and the plus fractions properties are
described later.
The chromatograph for liquid samples is checked daily, using a gravimetric n-paraffin mix
containing a range of pure components from C8 through C36 and a synthetic gas-oil mix (D2887)
with known composition. The resultant calibration data is checked statistically against previous
calibrations prior to performing analyses on unknown samples.
___________________________________________________________________________________________
A.1
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
___________________________________________________________________________________________
A.2
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
___________________________________________________________________________________________
A.3
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
289 psig
301 psig
332 psig
412 psig
7.42
x 10 -6 psi-1
0.7756 g cm-3
Total Solution
Gas-oil ratio
(scf/bbl)
Stocktank Oil
Density at 60 F
(g cm-3)
Test 1
412
200
60
0
200
200
412
200
30
0
200
200
1.139
97
0.8504
Test 2
1.140
98
0.8534
___________________________________________________________________________________________
A.4
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Choke....................................................................... *
Status of well............................................................ Shut-In
Bottomhole pressure................................................ 3115 psia
Bottomhole temperature.......................................... 210 F
Wellhead pressure................................................... 415 psia
Wellhead temperature............................................. 95.8 F
Separator pressure ................................................. *
Separator temperature ............................................ *
Pressure base.......................................................... 14.7 psia
Temperature base ................................................... 60 F
Separator gas rate...................................................
Separator oil rate .....................................................
Water flowrate..........................................................
Gas gravity (Air = 1).................................................
Supercompressibility factor......................................
H2S..........................................................................
BS&W......................................................................
API Oil Gravity .........................................................
*
*
*
*
*
*
*
*
Comments:
* Data not provided to Core Laboratories
___________________________________________________________________________________________
B.1
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Sampling :Pressure
Temp.
(psia)
(F)
Laboratory
Bubble point :Pressure
Temp.
(psig)
(F)
Sample
Number
Cylinder
Number
1.1
815666
3115
210
299
1.2
818424
3115
210
300
Free water
drained
(cc)
Sample
Volume
(cm3)
BSW
(%)
75
Trace
560
0.0
75
Trace
540
0.0
Free water
drained
(cc)
Sample
Volume
(cm3)
BSW
(%)
Wellhead Samples
Sampling :Pressure
Temp.
(psia)
(F)
Laboratory
Bubble point :Pressure
Temp.
(psig)
(F)
Sample
Number
Cylinder
Number
2.1
896612C
415
95.8
NM
--
NM
500
NM
2.2
966951D
415
95.8
NM
--
NM
500
NM
Notes:
NM = Not Measured
Bottomhole Sample 1.2 was selected for compositonal analysis and PVT study.
___________________________________________________________________________________________
B.2
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Compositional Analysis of Bottomhole Sample to C36 plus
Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
Hexanes
Methyl-Cyclopentane
Benzene
Cyclohexane
C7
Heptanes
Methyl-Cyclohexane
Toluene
C8
Octanes
EthylBenzene
M/P-Xylene
O-Xylene
C9
Nonanes
TrimethylBenzene
C10
Decanes
C11
Undecanes
C12
Dodecanes
C13
Tridecanes
C14
Tetradecanes
C15
Pentadecanes
C16
Hexadecanes
C17
Heptadecanes
C18
Octadecanes
C19
Nonadecanes
C20
Eicosanes
C21
Heneicosanes
C22
Docosanes
C23
Tricosanes
C24
Tetracosanes
C25
Pentacosanes
C26
Hexacosanes
C27
Heptacosanes
C28
Octacosanes
C29
Nonacosanes
C30
Triacontanes
C31
Hentriacontanes
C32
Dotriacontanes
C33
Tritriacontanes
C34
Tetratriacontanes
C35
Pentatriacontanes
C36+ Hexatriacontanes +
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
C5
iC5
nC5
C6
Mole %
0.00
0.00
0.19
0.08
13.50
2.97
1.91
0.54
1.10
0.00
0.81
0.91
2.50
0.78
0.09
0.39
3.60
1.67
0.47
5.25
0.41
0.52
0.21
4.87
0.44
5.27
5.03
4.40
4.58
4.12
3.55
2.95
2.68
2.70
2.32
1.91
1.75
1.55
1.38
1.25
1.17
0.98
0.92
0.86
0.78
0.69
0.62
0.49
0.45
0.39
0.35
3.65
_____
Weight %
0.00
0.00
0.05
0.01
1.22
0.50
0.47
0.18
0.36
0.00
0.33
0.37
1.22
0.37
0.04
0.18
2.04
0.92
0.24
3.38
0.24
0.31
0.13
3.52
0.30
4.23
4.17
3.99
4.52
4.42
4.13
3.69
3.59
3.83
3.44
2.96
2.87
2.66
2.48
2.34
2.28
1.99
1.94
1.88
1.76
1.62
1.52
1.23
1.17
1.04
0.97
12.90
_____
___________________________________________________________________________________________
Totals :
100.00
100.00
C.1
Core Laboratories
Note: 0.00 means less than 0.005.
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Compositional Analysis of Bottomhole Sample to C36 plus
Mole %
Mole Weight (g mol-1)
Density at 60F (g cm-3)
75.49
224
0.8397
C11 plus
Mole %
Mole Weight (g mol-1)
Density at 60F (g cm-3)
51.52
273
0.8655
C20 plus
Mole %
Mole Weight (g mol-1)
Density at 60F (g cm-3)
19.19
402
0.9011
C36 plus
Mole %
Molecular Weight (g mol-1)
Density at 60F (g cm-3)
3.65
624
0.9372
177
0.8073
___________________________________________________________________________________________
C.3
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
412 psig
7.42 x 10 -6 psi-1
0.7756 g cm-3
Final Pressure
(psig)
Mean
Compressibility
(psi-1) (1)
5000
3735
6.92
x 10 -6
3735
3000
6.99
x 10 -6
3000
2000
7.13
x 10 -6
2000
500
7.75
x 10 -6
500
412
8.88
x 10 -6
___________________________________________________________________________________________
D.1
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Relative
Volume (1)
Density
(g cm-3)
Instantaneous
Compressibility
(psi-1 x 10-6) (2)
5000
4000
3735
3000
2000
1000
900
800
700
600
500
412
411
410
409
406
405
404
400
376
362
321
257
196
157
121
92
0.9671
0.9738
0.9754
0.9807
0.9877
0.9951
0.9959
0.9967
0.9975
0.9984
0.9992
1.0000
1.0010
1.0019
1.0029
1.0058
1.0068
1.0078
1.0119
1.0386
1.0562
1.1191
1.2681
1.5212
1.8034
2.2441
2.8663
0.8020
0.7965
0.7952
0.7909
0.7853
0.7795
0.7788
0.7782
0.7776
0.7769
0.7763
0.7756
6.87
6.92
6.94
7.03
7.27
7.91
8.03
8.17
8.34
8.55
8.81
Reservoir pressure
Saturation pressure
Y-Function (3)
2.361
2.275
2.128
1.967
1.848
1.723
1.606
(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
'(3) Y-function = (Psat - P ) / ((Pabs)(V/Vsat - 1)).
___________________________________________________________________________________________
D.2
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
1.000
0.995
0.990
0.985
0.980
0.975
0.970
0.965
0
500
1000
1500
2000
2500
3000
3500
4000
4500
5000
Pressure (psig)
Y Function vs Pressure
2.400
2.300
2.200
Y-Function
2.100
2.000
1.900
1.800
1.700
1.600
1.500
0
50
100
150
200
250
300
350
Pressure (psig)
___________________________________________________________________________________________
D.3
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
332 psig
5.71 x 10 -6 psi-1
Final Pressure
(psig)
Mean
Compressibility
(psi-1) (1)
5000
3735
5.10
x 10 -6
3735
3000
5.24
x 10 -6
3000
2000
5.46
x 10 -6
2000
500
6.00
x 10 -6
500
332
6.64
x 10 -6
___________________________________________________________________________________________
D.4
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Relative
Volume (1)
Instantaneous
Compressibility
(psi-1 x 10-6) (2)
5000
4000
3735
3000
2000
1000
900
800
700
600
500
400
332
329
0.9744
0.9794
0.9806
0.9845
0.9899
0.9957
0.9963
0.9970
0.9976
0.9982
0.9989
0.9995
1.0000
5.05
5.14
5.18
5.32
5.62
6.12
6.19
6.27
6.35
6.45
6.55
6.66
Reservoir pressure
Saturation pressure
327
325
324
323
1.0000
0.9950
0.9900
0.9850
0.9800
0.9750
0
1000
2000
3000
4000
5000
Pressure, psig
(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
___________________________________________________________________________________________
D.5
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
301 psig
4.58 x 10 -6 psi-1
Final Pressure
(psig)
Mean
Compressibility
(psi-1) (1)
5000
3735
4.20
x 10 -6
3735
3000
4.31
x 10 -6
3000
2000
4.44
x 10 -6
2000
500
4.84
x 10 -6
500
301
4.34
x 10 -6
___________________________________________________________________________________________
D.6
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Relative
Volume (1)
Instantaneous
Compressibility
(psi-1 x 10-6) (2)
5000
4000
3735
3000
2000
1000
900
800
700
600
500
400
301
300
0.9792
0.9833
0.9843
0.9875
0.9919
0.9966
0.9971
0.9976
0.9981
0.9986
0.9991
0.9997
1.0000
4.15
4.24
4.26
4.35
4.54
4.92
4.98
5.06
5.15
5.26
5.40
5.59
Reservoir pressure
Saturation pressure
298
296
294
292
1.0000
0.9950
0.9900
0.9850
0.9800
0
1000
2000
3000
4000
5000
Pressure, psig
(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
___________________________________________________________________________________________
D.7
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
289 psig
4.79 x 10 -6 lpc-1
Final Pressure
(psig)
Mean
Compressibility
(psi-1) (1)
5000
3735
3.93
x 10 -6
3735
3000
4.12
x 10 -6
3000
2000
4.35
x 10 -6
2000
500
4.99
x 10 -6
500
289
7.90
x 10 -6
___________________________________________________________________________________________
D.8
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Relative
Volume (1)
Instantaneous
Compressibility
(psi-1 x 10-6) (2)
5000
4000
3735
3000
2000
1000
900
800
700
600
500
400
300
289
0.9787
0.9826
0.9835
0.9866
0.9909
0.9956
0.9961
0.9967
0.9972
0.9978
0.9983
0.9989
0.9995
1.0000
3.84
3.99
4.04
4.20
4.52
5.12
5.22
5.33
5.46
5.62
5.80
6.04
6.40
Reservoir pressure
Saturation pressure
285
283
281
280
279
1.0000
0.9950
0.9900
0.9850
0.9800
0
1000
2000
3000
4000
5000
Pressure, psig
(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
___________________________________________________________________________________________
D.9
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Pressure
(psig)
Solution
Gas-Oil
Ratio
Rs(1)
Relative
Oil
Volume
Bod(2)
Relative
Total
Volume
Btd(3)
412
300
150
0
113
92
63
0
1.130
1.123
1.107
1.072
1.130
1.341
2.109
At 60F =
Density
(g cm-3)
Deviation
Factor
(Z)
0.7756
0.7775
0.7845
0.7955
0.975
0.988
Gas
Formation
Volume
Factor (4)
Incremental
Gas
Gravity
(Air = 1.000)
Saturation Pressure
0.05779
0.689
0.11192
0.765
1.193
1.000
0.8524
API
34.3
g cm-3 at 60F
(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of residual oil at 60F.
(2) Volume of oil at indicated pressure and temperature per volume of residual oil at 60F.
(3) Volume of oil plus liberated gas at indicated pressure and temperature per volume of residual oil at 60F.
(4) Volume of gas at indicated pressure and temperature per volume at 14.70 psia and 60F.
___________________________________________________________________________________________
E.1
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
100
80
60
40
20
0
0
40
80
120
160
200
240
280
320
360
400
440
320
360
400
440
Pressure, psig
1.140
1.120
1.100
1.080
1.060
0
40
80
120
160
200
240
280
Pressure, psig
___________________________________________________________________________________________
E.2
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
1
300
2
150
3
0
Component (Mole%)
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11+
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Heptanes
Octanes
Nonanes
Decanes
Undecanes plus
Totals :
0.00
0.00
0.00
0.00
0.00
0.00
1.15
1.53
1.51
0.46
0.28
0.13
82.95 76.07 47.84
10.64 12.78 17.31
2.81
5.30 12.81
0.50
0.79
3.11
0.38
1.20
5.06
0.11
0.30
3.06
0.19
0.39
2.52
0.28
0.57
3.06
0.25
0.36
2.02
0.08
0.21
0.89
0.14
0.18
0.67
0.06
0.04
0.00
0.00
0.00
0.00
_____ _____ _____
100.00 100.00 100.00
0.689
0.765
1.193
___________________________________________________________________________________________
E.3
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11
C12
C13
C14
C15
C16
C17
C18
C19
C20
C21
C22
C23
C24
C25
C26
C27
C28
C29
C30
C31
C32
C33
C34
C35
C36+
Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Heptanes
Octanes
Nonanes
Decanes
Undecanes
Dodecanes
Tridecanes
Tetradecanes
Pentadecanes
Hexadecanes
Heptadecanes
Octadecanes
Nonadecanes
Eicosanes
Heneicosanes
Docosanes
Tricosanes
Tetracosanes
Pentacosanes
Hexacosanes
Heptacosanes
Octacosanes
Nonacosanes
Triacontanes
Hentriacontanes
Dotriacontanes
Tritriacontanes
Tetratriacontanes
Pentatriacontanes
Hexatriacontanes plus
Totals :
Mole %
0.00
0.00
0.00
0.00
0.14
0.22
0.35
0.26
0.75
0.66
0.85
2.86
5.84
9.00
7.25
7.01
6.16
5.40
5.63
5.07
4.41
3.69
3.39
3.39
2.93
2.42
2.21
1.96
1.75
1.59
1.49
1.25
1.17
1.08
0.98
0.88
0.79
0.62
0.57
0.49
0.45
5.04
_____
100.00
Weight %
0.00
0.00
0.00
0.00
0.01
0.03
0.07
0.07
0.20
0.22
0.28
1.13
2.57
4.50
4.12
4.51
4.15
3.99
4.52
4.42
4.17
3.76
3.69
3.90
3.54
3.05
2.95
2.74
2.55
2.41
2.35
2.05
2.00
1.93
1.81
1.67
1.56
1.27
1.20
1.07
1.00
14.54
_____
100.00
___________________________________________________________________________________________
E.4
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Mole%
Molecular Weight (g mol-1)
Density at 60F (g cm-3)
93.91
227
0.8421
C11+
Mole%
Molecular Weight (g mol-1)
Density at 60F (g cm-3)
64.81
277
0.8671
C20+
Mole%
Molecular Weight (g mol-1)
Density at 60F (g cm-3)
24.74
407
0.9022
C36+
Mole %
Molecular Weight (g mol-1)
Density at 60F (g cm-3)
5.04
629
0.9375
218
0.8524
34.3
___________________________________________________________________________________________
E.5
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Pressure
(psig)
Oil
Density
(g cm-3)
5000
4000
3735
3000
2000
1000
900
800
700
600
500
412
300
150
0.8019
0.7963
0.7947
0.7910
0.7851
0.7792
0.7787
0.7782
0.7775
0.7767
0.7759
0.7756
0.7775
0.7845
Reservoir pressure
Saturation pressure
Solution
Gas/Oil
(scf / bbl)
Rs(1)
Formation
Volume
Factor
Bo(1)
Gas Formation
Volume
Factor
Bg(2)
97
76
46
1.102
1.109
1.112
1.117
1.125
1.134
1.134
1.135
1.136
1.137
1.139
1.139
1.132
1.116
0.05779
0.11192
Notes:
(1) Differential data corrected to surface separator conditions of :Stage 1
Stage 2
___________________________________________________________________________________________
E.6
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Pressure
(psig)
Oil
Density
(g cm-3)
5000
4000
3735
3000
2000
1000
900
800
700
600
500
412
300
150
0.8019
0.7963
0.7947
0.7910
0.7851
0.7792
0.7787
0.7782
0.7775
0.7767
0.7759
0.7756
0.7775
0.7845
Reservoir pressure
Saturation pressure
Solution
Gas/Oil
(scf / bbl)
Rs(1)
Formation
Volume
Factor
Bo(1)
Gas Formation
Volume
Factor
Bg(2)
98
77
47
1.103
1.110
1.113
1.118
1.126
1.135
1.135
1.136
1.137
1.138
1.140
1.140
1.133
1.117
0.05779
0.11192
Notes:
(1) Differential data corrected to surface separator conditions of :Stage 1
Stage 2
___________________________________________________________________________________________
E.7
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Oil
Viscosity
(cP)
5000
4000
3735
3000
2000
1000
600
412
300
150
0
1.748
1.615
1.584
1.484
1.357
1.236
1.190
1.170
1.259
1.364
1.751
Reservoir pressure
Saturation pressure
Calculated
Gas Viscosity
(cP) (1)
Oil/Gas
Viscosity
Ratio
0.0134
94
0.0129
105.9
(1) Calculated using the method of Lee, Gonzales and Eakin, JPT, Aug 1966.
___________________________________________________________________________________________
F.1
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
1.800
1.700
1.600
1.500
1.400
1.300
1.200
1.100
1.000
0
40
80
120
160
200
240
280
320
360
400
440
Pressurre, psig
1.800
1.600
1.400
1.200
1.000
0
1000
2000
3000
4000
5000
Pressurre, psig
___________________________________________________________________________________________
F.2
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Pressure
(psig)
Temperature
(F)
Gas-Oil
Ratio
Oil
Density
(g cm-3)
(1)
Gas-Oil
Ratio
Rsfb
(2)
Formation
Volume
Factor
Bofb (3)
1.139
Saturation Pressure
412
200
97
0.7756
60
0
200
200
76
14
82
15
0.7908
0.7933
1.082
1.072
1.025 *
1.515
0.8504
API
34.7
g cm-3 at 60F
Note :
*
(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 412 psig and 200F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.
___________________________________________________________________________________________
G.1
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11+
Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Heptanes
Octanes
Nonanes
Decanes
Undecanes plus
Totals :
18-Sep-2006
Caricare-5 - 60psi Sep Test - First Stage Gas
818424
60.0 psig @ 200.0F
Mole %
0.00
0.00
2.35
0.67
65.46
13.29
7.54
1.96
2.53
1.29
0.92
1.59
1.23
0.75
0.29
0.11
0.02
______
100.00
Weight %
0.00
0.00
3.79
0.69
38.54
14.66
12.20
4.18
5.39
3.41
2.44
5.03
4.52
3.14
1.36
0.54
0.11
______
100.00
Mole Weight
(g mol-1)
109.9
120.1
136.0
147.0
Density
(g cm-3 @ 60F )
0.7038
0.7188
0.7798
0.7890
Heptanes plus
Octanes plus
Decanes plus
Undecanes plus
Calculated Whole Gas Properties
Real Relative Density
Whole Sample Mole Weight
Real Gas Density
Ideal Gross Calorific Value
Ideal Net Calorific Value
Pseudo Critical Press.
Pseudo Critical Temp.
Gas Compressibility Factor, Z
Gas Viscosity
GPM (C2+)
GPM (C3+)
0.9474
27.26
1.1609
1544.9
1409.4
656.5
453.0
0.9934
0.012
9.662
6.123
___________________________________________________________________________________________
G.2
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Pressure
(psig)
Temperature
(F)
Gas-Oil
Ratio
Oil
Density
(g cm-3)
(1)
Gas-Oil
Ratio
Rsfb
(2)
Formation
Volume
Factor
Bofb (3)
1.140
Saturation Pressure
412
200
98
0.7756
30
0
200
200
84
7
91
7
0.7945
0.7965
1.078
1.071
1.222 *
1.725
0.8534
API
34.1
g cm-3 at 60F
Note :
*
(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 412 psig and 200F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.
___________________________________________________________________________________________
G.3
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11+
Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Heptanes
Octanes
Nonanes
Decanes
Undecanes plus
Totals :
18-Sep-2006
Caricare-5 - 30psi Sep Test - First Stage Gas
818424
30.0 psig @ 200.0F
Mole %
0.00
0.00
2.31
0.64
59.15
13.82
8.83
2.49
3.37
1.84
1.39
2.33
1.84
1.21
0.49
0.24
0.05
______
100.00
Weight %
0.00
0.00
3.31
0.58
30.89
13.52
12.67
4.71
6.37
4.32
3.26
6.53
6.00
4.50
2.05
1.05
0.24
______
100.00
Mole Weight
(g mol-1)
111.0
120.9
136.2
147.0
Density
(g cm-3 @ 60F )
0.7063
0.7214
0.7800
0.7890
Heptanes plus
Octanes plus
Decanes plus
Undecanes plus
Calculated Whole Gas Properties
Real Relative Density
Whole Sample Mole Weight
Real Gas Density
Ideal Gross Calorific Value
Ideal Net Calorific Value
Pseudo Critical Press.
Pseudo Critical Temp.
Gas Compressibility Factor, Z
Gas Viscosity
GPM (C2+)
GPM (C3+)
1.0704
30.73
1.3121
1732.8
1584.7
646.4
482.7
0.9912
0.011
11.964
8.284
___________________________________________________________________________________________
G.4
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Section H - Appendix
___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Hydrogen
Oxygen/(Argon)
Nitrogen (Corrected)
Methane
Carbon Dioxide
Ethane
Hydrogen Sulphide
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
22DMC4
23DMC4/CYC5
2MC5
3MC5
Hexanes (nC6)
22DMC5
M-C-Pentane
24DMC5
223TMC4
Benzene
Mole Weight
Density
Component
(g mol-1) (g cm-3 at 60F)
*
**
**
**
**
**
**
**
**
**
*
**
**
*
*
*
*
*
*
*
*
*
*
2.016
31.999
28.013
16.043
44.010
30.070
34.080
44.097
58.123
58.123
72.15
72.150
72.150
86.18
78.16
86.18
86.18
86.18
100.20
84.16
100.20
100.20
78.11
N/A
1.1410
0.8086
0.2997
0.8172
0.3558
0.8006
0.5065
0.5623
0.5834
0.5968
0.6238
0.6305
0.6529
0.7129
0.6572
0.6682
0.6631
0.6814
0.7533
0.6757
0.6947
0.8820
33DMC5
Cyclohexane
2MC6/23DMC5
11DMCYC5/3MC6
t13DMCYC5
c13DMCYC5/3EC5
t12DMCYC5
Heptanes (nC7)
22DMC6
MCYC6
ECYC5
223TMC5/24&25DMC6
ctc124TMCYC5
ctc123TMCYC5
Toluene
Octanes (nC8)
E-Benzene
M/P-Xylene
O-Xylene
Nonanes (nC9)
Decanes
Undecanes
Dodecanes
Mole Weight
Density
(g mol-1) (g cm-3 at 60F)
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
***
***
***
100.20
84.16
100.20
99.20
98.19
99.20
98.19
100.20
114.23
98.19
98.19
114.23
112.21
112.21
92.14
114.23
106.17
106.17
106.17
128.26
134
147
161
0.6954
0.7827
0.6917
0.7253
0.7528
0.7262
0.7554
0.6875
0.6994
0.7740
0.7704
0.7060
0.7511
0.7574
0.8734
0.7063
0.8735
0.8671
0.8840
0.7212
0.778
0.789
0.800
Note :
The gas mole % compositions were calculated from the measured weight % compositions using
the most detailed analysis results, involving as many of the above components as were identified.
The reported component mole % compositions were then sub-grouped into the generic carbon
number components.
___________________________________________________________________________________________
H.1
Core Laboratories
Bogot, Colombia
OCCIDENTAL DE COLOMBIA
Caricare-5
Well, Form.: M2
RFL 0603116
___________________________________________________________________________________________
Hydrogen
Hyd. sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Me-cyclo-pentane
Benzene
Cyclo-hexane
Heptanes
Me-cyclo-hexane
Toluene
Octanes
Ethyl-benzene
Meta/Para-xylene
Ortho-xylene
Nonanes
1-2-4-T-M-benzene
Decanes
Mole Weight
Density
Component
(g mol-1) (g cm-3 at 60F)
*
**
**
**
**
**
**
**
**
**
**
**
*
*
*
**
*
*
**
*
*
*
**
*
**
2.016
34.080
44.010
28.013
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
84.16
78.11
84.16
100.204
98.19
92.14
114.231
106.17
106.17
106.17
128.258
120.19
142.285
N/A
0.8006
0.8172
0.8086
0.2997
0.3558
0.5065
0.5623
0.5834
0.6238
0.6305
0.6634
0.7533
0.8820
0.7827
0.6874
0.7740
0.8734
0.7061
0.8735
0.8671
0.8840
0.7212
0.8797
0.7334
Undecanes
Dodecanes
Tridecanes
Tetradecanes
Pentadecanes
Hexadecanes
Heptadecanes
Octadecanes
Nonadecanes
Eicosanes
Heneicosanes
Docosanes
Tricosanes
Tetracosanes
Pentacosanes
Hexacosanes
Heptacosanes
Octacosanes
Nonacosanes
Triacontanes
Hentriacontanes
Dotriacontanes
Tritriacontanes
Tetratriacontanes
Pentatriacontanes
Mole Weight
Density
(g mol-1) (g cm-3 at 60F)
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
147
161
175
190
206
222
237
251
263
275
291
305
318
331
345
359
374
388
402
416
430
444
458
472
486
0.789
0.800
0.811
0.822
0.832
0.839
0.847
0.852
0.857
0.862
0.867
0.872
0.877
0.881
0.885
0.889
0.893
0.896
0.899
0.902
0.906
0.909
0.912
0.914
0.917
Note :
The residue mole weight and density values ( eg heptanes plus, undecanes plus, eicosanes plus)
are calculated so that the calculated average mole weights and densities correspond with the
measured values. This can lead to anomalous residue mole weights and densities where the Katz
and Firoozabadi values may not be suitable for the isomer groups detected.
___________________________________________________________________________________________
H.2
Core Laboratories
Bogot, Colombia