INSTRUMENT CONTROL PARAMETERS:

Instr

ument #1
---------------------------------------------C:\MSDCHEM\1\METHODS\UNDERGRADYEASTPROJECT\SPME_and_StaticHeadspace.M
Control Information
------- ----------Sample Inlet
:
Injection Source :
Injection Location:
Mass Spectrometer :

GC
Manual
Rear
Enabled

=============================================================================
6890 GC METHOD
=============================================================================
OVEN
Initial temp: 35 'C (On)
Initial time: 2.00 min
Ramps:
# Rate Final temp Final time
1 10.00
250
0.00
2 0.0(Off)
Post temp: 50 'C
Post time: 0.00 min
Run time: 23.50 min

CRYO (N2)
Cryo: Off
Cryo fault: Off
Cryo timeout: 120.00 min (Off)
Quick cryo cool: Off
Ambient temp: 30 'C

FRONT INLET (SPLIT/SPLITLESS)

Mode: Split
Initial temp: 230 'C (On)
Pressure: 8.06 psi (On)
Split ratio: 6.69:1
Split flow: 9.6 mL/min
Total flow: 19.6 mL/min
Gas saver: On
Saver flow: 20.0 mL/min
Saver time: 2.00 min
Gas type: Hydrogen

BACK INLET (SPLIT/SPLITLESS)

Mode: Splitless
Initial temp: 250 'C (On)
Pressure: 17.53 psi (On)
Purge flow: 6.5 mL/min
Purge time: 1.00 min
Total flow: 14.5 mL/min
Gas saver: On
Saver flow: 15.0 mL/min
Saver time: 1.00 min
Gas type: Hydrogen

COLUMN 1
Capillary Column
Model Number: Restek Rtx-5

COLUMN 2
Capillary Column
Nominal length: 30.0 m
Nominal diameter: 250.00 um
Nominal film thickness: 0.50 um
Mode: constant pressure
Pressure: 8.06 psi
Nominal initial flow: 1.4 mL/min
Average velocity: 39 cm/sec
Inlet: Front Inlet
Outlet: Front Detector
Outlet pressure: ambient

Max temperature: 330 'C

Nominal length: 40.0 m
Nominal diameter: 180.00 um
Nominal film thickness: 0.40 um
Mode: constant flow
Initial flow: 1.0 mL/min
Nominal init pressure: 17.55 psi
Average velocity: 46 cm/sec
Inlet: Back Inlet

Maximum temp: 330 'C

Equilibration time: 0.50 min

Outlet: MSD
Outlet pressure: vacuum
FRONT DETECTOR (FID)
Temperature: 250 'C (Off)
Hydrogen flow: 40.0 mL/min (Off)
Air flow: 450.0 mL/min (Off)
Mode: Constant makeup flow
Makeup flow: 45.0 mL/min (Off)
Makeup Gas Type: Nitrogen
Flame: Off
Electrometer: Off
Lit offset: 2.0

BACK DETECTOR (TCD)

Temperature: 250 'C (Off)
Reference flow: 20.0 mL/min (Off)
Mode: Constant makeup flow
Makeup flow: 7.0 mL/min (Off)
Makeup Gas Type: Nitrogen
Filament: Off
Negative polarity: Off

SIGNAL 1
Data rate: 50 Hz
Type: test plot
Save Data: On
Zero: 0.0 (Off)
Range: 0
Fast Peaks: Off
Attenuation: 0

SIGNAL 2
Data rate: 20 Hz
Type: back detector
Save Data: Off
Zero: 0.0 (Off)
Range: 0
Fast Peaks: Off
Attenuation: 0

COLUMN COMP 1
Derive from front detector

COLUMN COMP 2
Derive from back detector

THERMAL AUX 1
Use: MSD Transfer Line Heater
Description:
Initial temp: 270 'C (On)
Initial time: 0.00 min
# Rate Final temp Final time
1 0.0(Off)
VALVES
Valve 7 Remote Start
TIME TABLE
Time

POST RUN
Post Time: 0.00 min

Specifier

Parameter & Setpoint

GC Injector
Front Injector:
No parameters specified
Back Injector:
Injector not configured, use these parameters if it becomes configured
Sample Washes
0
Sample Pumps
5
Injection Volume
0.50 microliters

Syringe Size
PostInj Solvent A Washes
PostInj Solvent B Washes
Viscosity Delay
Plunger Speed

5.0 microliters
3
0
1 seconds
Fast

Column 1 Inventory Number : AB008

Column 2 Inventory Number : AB001
MS ACQUISITION PARAMETERS
General Information
------- ----------Tune File
Acquistion Mode

: atune.u
: Scan

MS Information
-- ----------Solvent Delay

: 0.00 min

EM Absolute
Resulting EM Voltage

: True
: 1952.9

[Scan Parameters]
Low Mass
High Mass
Threshold
Sample #

:
:
:
:

40.0
200.0
0
1

A/D Samples

[MSZones]
MS Quad
MS Source
Timed Events
----- ------

: 150 C
: 230 C

maximum 200 C
maximum 250 C

[Timed MS Detector Entries]

Time (min)
0.01

State (MS on/off)

On
END OF MS ACQUISITION PARAMETERS
TUNE PARAMETERS for SN: US91922553
-----------------------------

EMISSION
ENERGY
REPELLER
IONFOCUS
ENTRANCE_LE
EMVOLTS
AMUGAIN

:
:
:
:
:
:
:

34.610
69.922
34.814
76.871
16.500
2623.529
2463.000

AMUOFFSET
FILAMENT
DCPOLARITY
ENTLENSOFFS
MASSGAIN
MASSOFFSET

:
:
:
:
:
:

122.000
2.000
1.000
16.063
262.000
-11.000
END OF TUNE PARAMETERS
------------------------------------

END OF INSTRUMENT CONTROL PARAMET

ERS
-----------------------------------