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Non-electrolyte

Polar

Check next diagram

Electrolytes?

Electrolyte

Electrolyte NTRL
or Pitzer

Real

Polarity?

All Nonpolar

Peng-Robinson.
Redlich-Kwong-Soave,
Lee-Kesler-Ploker

Chao-Seader,
Grayson-Streed or
Braun K-10

Real or
pseudocomponents?

Pseudo & Real

Pressure?

Vacuum

Braun K-10 or Ideal

Yes
Yes

P<10 bar

Interaction
parameters
available?

NTRL, UNIQUAC, and their variances

Liquid/Liquid?
No

Wilson, NTRL, UNIQUAC, and their variances


Yes

No

Liquid/Liquid?
No

Yes

Polar Nonelectrolytes

P> 10 bar

UNIFAC LLE

UNIFAC and its extensions

Schwartentruber-Renon,
PR or RKS with WS,
PR or RKS with MHV2

Interaction
parameters
available?

No

PSRK,
PR or RKS with MHV2

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