For water at 30oC and 1atm, = 3.04x10-4 K-1, = 4.

52x10-5 atm-1
= 4.46x10-10 m2/N, Cp,m = 75.3 J/mol-K, = 18.1 cm3/mol
Find Cv,m ,

V T

, JT

T 2
Cv,m C p ,m
74.2 J / mol K
T
U T
P 2.04 x103 atm

V T T

JT

T 1 0.0221K / atm

C
p ,m

For a liquid with the typical values, = 10-3 K-1, = 10-4 atm-1
Cp,m = 150 J/mol-K, = 50 cm3/mol, calculate at 25oC and 1atm
h

h

P T

s
,C
v,m
P T

NC p ,m = 150J/mol-K
T P
h
T = 3.5 J/atm-mol
P T
U

= 304 J/cm3
V T

C p ,m
s

= 0.50 J/mol-K2

T
T P
s
= -0.005 J/mol-K-atm
P T
Cv,m= 135 J/mol-K

Calculate S when 2.00 mol of water goes from 27oC and 20 atm
to 37oC and 40 atm. Neglect pressure and temperature
variations of Cp,m and and

dS

NC p ,m
T

dT NdP

310
4
275.3 ln
2 3.04 x10 18.30.00110 8.314 0.08206
300
4.93 J / K

Suppose that 1.00 mol of water initially at 27oC and 1 atm

undergoes a process whose final state is 100oC and 50 atm. Find
H and S.
H = 5.58 kJ
S = 16.4 J/K