Estimation of HSP from Correlations

C5

Appendix

Table C5-4 Results of Calculation of Polar HSP via Equation C5-4

Solvent Name

Dipole
Moment D

Vm
cc/mol

Eq. C5-4

Appendix A1 Table
A1-5
MPa

% Difference

1,1-Diuoroethylene

1.38

5.03

6.8

26.00%

1,1-Diuoroethane

2.26

73.5

9.87

10.2

3.20%

1,1-Dichloropropane

2.08

100.2

7.77

7.8

0.40%

1,1-Dibromoethane

2.14

91.9

8.35

8.4

0.60%

1,1-Dichloroethylene

1.34

80.4

5.59

5.2

7.60%

1,1-Dichloroethane

2.06

84.3

8.39

7.8

7.60%

1,1,1-Trichloroethane

1.38

99.7

5.15

4.3

19.90%

2-Pentanol

1.8

109.5

6.43

6.4

0.50%

Acetonitrile

3.92

52.5

20.24

18

12.40%

Acetone

2.6

73.5

11.35

10.4

9.10%

Acetic Acid

1.54

57.2

7.61

4.90%

Allyl Alcohol

1.6

68.8

7.22

10.8

33.20%

Amyl Alcohol

1.65

108.3

5.93

4.5

31.80%

Butyl Chloride

104.5

7.32

5.5

33.10%

Carbon Tetrachloride

96.6

CFC-113

0.8

120.1

2.74

1.6

71.30%

Chloroform

1.02

80.2

4.24

3.1

36.80%

cis-1,2dichloroethylene

1.8

75.6

7.74

3.20%

Cyclohexane

0.26

108.1

0.93

0.2

364.00%

Cyclohexane

108

Cyclohexanol

1.7

104.1

6.23

4.1

52.00%

Cyclohexanone

2.98

103.8

10.93

8.4

30.20%

Cyclopentane

Diethyl Ether

1.33

Diethyl Ketone

105

94

103.9

4.9

2.9

68.90%

2.7

91.1

10.58

7.6

39.20%

Diethylene Glycol
Monomethyl Ether

1.91

135.7

6.13

9.2

33.40%

Dimethyl Ether

1.3

68.9

5.86

6.1

4.00%

Dimethyl Formamide

3.86

77

16.45

13.7

20.10%

Dimethyl Carbonate

0.91

84.7

3.7

3.9

5.20%

Dimethyl Sulfoxide

3.96

71

17.58

16.4

Di-n-Butyl Ether

1.2

169.8

3.44

4.2

7.20%
18.00%
(Continued)

609