1.

A basketball is inflated in a garage at 25 oC to a gauge pressure

of 8.0 psi. Gauge pressure is the pressure above atmospheric
pressure, which is 14.7 psi. The ball is used on the driveway at a
temperature of -7 oC and feels flat. What is the actual pressure of
the air in the ball? What is the gauge pressure?

2. A 38.0 L gas tank at 35 oC has nitrogen at a pressure of 4.65

atm. The content of the tank are transferred without loss to an
evacuated 55.0 L tank in a cold room where the temperature is 4
o
C. What is the pressure in the tank?

3. A flask has 1.35 mol of hydrogen gas at 25 oC and a pressure of

1.05 atm. Nitrogen gas is added to the flask at the same
temperature until the pressure rises to 1.64 atm. How many
moles of nitrogen gas are added?

4. A piece of dry ice (CO2(s)) has a mass of 22.5 g at 25 oC. It is

dropped into an evacuated 2.5 L flask. What is the pressure in
the flask?

5. Calculate the density ( in gram per liter) of ammonia at 75 oF

and 1.25 bar

6. Cyclopropane mixed in proper proportion with oxygen can be

used as an anesthetic. At 755 mm Hg and 25 oC, it has a density
of 1.71 g/L. What is the molar mass of cyclopropane

7. A sample of a smoke stack emission was collected into a 1.25

L tank at 752 mm Hg and analyzed. The analysis showed 92 %
CO2, 3.6 % NO and 1.2 % SO2, and 4.1 % H2O by mass. What is
the partial pressure exerted by each gas?

8. A sample of gas collected over water at 42 oC occupies a

volume of 1 liter. The wet gas has a pressure of 0.986 atm. The
gas is dried and the dry gas occupies 1.04 L with pressure of 1.00
atm at 90 oC . Using the information, calculate the vapor pressure
of water at 42 oC.

9. An unknown gas effuses through an opening at a rate one-fifth

as fast as that of helium gas.
a) Is the gas heavier or lighter than helium?
b) What is the molar mass of the gas?