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Parity inversion
Symmetry under parity inversion is
known as mirror symmetry
x x
P : y a y
z z
Parity Operator
Let us define the parity operator via:
x = x
Parity operator is Hermitian:
x x = x x = ( x + x)
x x = x x = ( x + x)
=
Parity operator is its own inverse
x = x = x
2 = 1
Thus it must be Unitary as well
=
= 1
= 1
x = ( x
)=
= x
x= x
What is the action of the parity operator on a
generic quantum state?
Let:
=
x = x
x = x
( x) = ( x)
( x) = ( x)
x = x
( x) = ( x)
Must be true for any physical
transformation!
Proof:
Let:
It follows that:
2
=2
2 =1
= 1
= +1
x+ = x +
= 1
x = x
x + = x +
x = x
p = dx x x p
p = p
Commutator of X with
First we can compute X :
x X = x X
= x x
= x x
= x X
X = X
2
X = X
X = X
X X = 2 X
So and X do not commute
This is the
important result
for calculations
Commutator of X with
Next we can compute [x2,]:
x X 2 = x X 2
= x2 x
= x2 x
= x X2
2
X = X
2
X = X
2
X = X
X 2 X 2 = 0
So and X2 do commute!
This is the
important result
for calculations
P2
,
=0
2M
[,V (X )]= 0
2
even
Let
Then
P2
H=
+ Veven ( X )
2M
[, H ]= 0
P2
H=
2M
Energy eigenstates are doublydegenerate:
h 2k 2
H k =
2M
h 2k 2
H k =
2M
E ,1 := k
k=
E ,2 := k
2 ME
h
k =
2 ME
h
1
( E ,1 + E ,2
E ,+ :=
2
1
( E ,1 E ,2
E , :=
2
E , + ( x) =
1
cos
2 ME
h
E , + ( x) =
i
sin
2 ME
h
P2 1
H=
+ M 2 X 2
2M 2
Therefore [H,]=0, so simultaneous
eigenstates of Energy and Parity must
exist
The energy levels are not-degenerate, so
there is no freedom to mix and match
states
Thus the only possibility is that each
energy level must have definite parity
The Hermite Polynomials have definite
parity: Hn(-x)=(-1)n Hn(x)
So ground-state (n=0) is even
Thus we have:
n = ( 1) n
(n=2) is even
Etc.