.

**

.. *

// :
//:

) (% .

) (%,
).(%,
) .(Hydrometallurgy

) ( ) ( ) (
/ ) /( ).(%,

.
) ,( ) ,/
( ) (%
).(%,
Abstract
This research include extraction of nickel metal from residual of fired heavy oil
in electric power station, the residual were pretreatment by grinding and sieving,
the nickel concentrated by particle size.
Magnetic separation was also performed in order to get rid of iron that was in
heavy oil residual in the form of magnetite, and the results show the ability of
separating 86% of iron.
* .
** .

Vanadium was recovered from the residual by alkaline leaching method using
sodium hydroxide solution and this step resulted in the leaching 98.63% of
vanadium, also increasing nickel concentration to 16.27%.
Subsequently extraction of nickel from the residual was studied using the
hydrometallurgy method. The leaching of nickel from the residues was carried
out using sulfuric acid and the result obtained show the possibility of obtaining
the highest leaching ratio at acid concentration 3 molarity, temperature 100oC,
time of leaching 90 minutes and solid /liquid ratio 5 gm/l.
In order to recover H2SO4 from the pregnant liquid, ion exchange process was
employed using strong anion exchanger and the concentration of nickel increases
in the liquid resulting from ion exchange process by evaporation.

.

.

.
) (L.B.Sukla)[4] (Das
1986

) (%

) ( )(
),
( )
.(%

)(V.Markovac

) [1] (H.C.Heller 1981

1982
] [2

) (%
) , /.(

) (P.B.Q ueneau
] [5


)( )(psig
)(N2,CO2,O2
) -/(

Fe (VO3)3 )(NiCO3

.
)(V.Kumar
] [6 1990

)[3](P.M.Afeny

) (S.Akita ][7
1995
.
)(%
)(,
) (
.

) (Na2S [Na2S]/[ Ni] = 1.22
) (%
).(NiS

) (T.Dodon
] [10 2001

)(
) / (

.

) (
.







)(%
) (Na12V24O64
) (% ) (NiO
) (% ) (Fe3O4
).(

) (Malcom)(Rachib
] [8 1997

) (%

.

.

) [9] (Daniel Kittely

.

53

H2SO

) : (

.
Ni

) : (

Ba

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) (

].[9

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.

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) (%,


) (% ) (%,

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) ,(
.

NiSO4
) :(
100

90

80

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4

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2 .5

1 .5

)(
) : ( .
) (%




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)-( )
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.

95
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105

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10

/
) : ( / .


:

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)(.

)
(.
/
) /(.

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) : (
|

Cr
56.1
ppm

Ca
14.4
ppm

Zn
8.70
ppm

Mn
41.1
ppm

Mg
10.0
ppm

.

) , /(.

Co
14.0
ppm

Fe
0.21
g/l

Ni
6.2
g/l

V
0.26
g/l

) ,(

) (
.

) ,(

).(%


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-
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). (%

-


) (% , -:
- )
( .
- ) .(
- ) (.
- ) /
(.
-
) (,
.

1- V. Markovac Principles of
electrodialysis
for
Nickel-plating
rinsewater Plating and surface
finishing, December 1981.
2- V. Marcovac Engineering aspects
of electrolysis for nickel plating
rinsewater Plating and surface
finishing, January 1982.
3- P.A. Afeny Extraction of Nickel
from Conakry Iron ore Indian Journal
of technology Vol. 20,October 1982.
4- L.B. Sukla Leaching behavior of
Sukinda lateritic Nickel ore with
sulphuric acid Institution of mining
and metallurgy 95,1986.
5- P.B. Queneau Processing of
petroleum coke for recovery of
Vanadium
and
Nickel
Hydrometallurgy, 22(1989) 3-24.

6- V. Kumar electrowinning of
nickel in the processing of Polymetallic
sea nodules Hydrometallurgy, 24
(1990).
7- S.Akita Recovery of Vanadium
and Nickel in fly ash from heavy oil
J.Chem.
Tach.
Biotechnol.
1995,62,345-350.
8- Malcom T. Hepworth Recovery
of Vanadium, Nickel, and carbonvia
flexicoking Journal of solid waste
technology and management Vol.
24,no. 2,May 1997.

9- Daniel Kittelty Stress relief for

Nickel Newsletter for the Aj parker
cooperative research center for
Hydrometallurgy, Issue 13, October
2001.
10- T.dobson Commissioning under a
microscope-the Cawse Nickel start-up
The Aus IMM proceedings Vol. 306
No. 1, 2001.

" -

/ "
/
.