Professional Documents
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CSV Sept09
CSV Sept09
Regulars
September 2009
Year12 Issue139
Editorial
Science and Technology
Latest General Knowledge
Inspiring Young Talent
Selected in UP-CPMT-2009 (Rank 6)Ratish Kumar Mishra
Science Tips
799
801
805
809
811
Physics
Editor
MAHENDRA JAIN
814
822
828
834
Chemistry
Transition Elements : Elements of d-Block
842
849
856
861
Zoology
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articles by the authors.
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Botany
Vegetative Parts of Plant Body
885
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Biogeochemical Cycle
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Other Features
Assertion and Reason Type Questions
902
True or False
905
Do You Know ?
909
General Awareness
913
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To Our Readers
Dear Readers,
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COMPETITION
SCIENCE VISION
Hackers tap into personal computers all the timebut what would
happen if they focussed their
nefarious energy on neural devices
such as the deep brain simulators
currrently used to treat parkinson and
depression or electrode systems for
controlling prosthetic limbs ?
AWARDS/HONOURS
Gandhi Peace Award
The pro-democracy Myanmar
leader and Nobel Laureate Aung San
Suu Kyi was felicitated with Mahatma
Gandhi International Award for Peace
and Reconciliation on July 21, 2009
in Durban. The Award was bestowed
by the South African-based Mahatma
Gandhi Foundation. Burmese Prime
Minister in exile received the Award
on her behalf.
The Award is in recognition of
her strong commitment to non-violence, justice and peace.
BOOKS
Readings in Indian Agriculture
and IndustryEdited by K. L.
Krishna and Uma Kapila (A collection
of essays written by noted economists
providing insights into two vital
sectors of Indian Economy).
Global BollywoodEdited by
Anandam P. Kavoori and Aswin
Punathambekar (The book is a
collection of scholarly essays which
examine the manner in which Hindi
cinema has reframed relationship
among geography, cultural production
and cultural identities).
Accelerating Growth and Job
Creation in South AsiaEjaz Ghani
and Sadiq Ahmed (A study of South
Asian political economy beyond the
conventional discourse of market and
state).
Archaeology in IndiaGautam
Sengupta and Kaushik Gangopadhyay
(The book deals with the glimpses of
the methods and means adopted by
the pioners in archaeology to unravel
Indias past).
DAYS
August 1World Breast Feeding
Day
August 3International Friendship Day.
August 6Hiroshima Day.
August 8World Senior Citizens
Day.
August 9Quit India Day,
Nagasaki Day.
August 15Independence Day
of India.
August 18International Day of
the Worlds Indigenous People.
August 19Photography Day.
August 20Sadbhavna Diwas.
August 29National Sports Day.
Desert
National Park
(In
UNESCOs Heritage List )After
remaining merely on official records
for almost three decades, the Desert
National Park in Jodhpur division is
now on the Tentative list of UNESCOs
World Heritage. The unique habitat, a
3,162 sq. km, treeless, sandy, gravel
and rocky tract punctuated by desolate hills, houses many rare and
endangered species of flora and fauna
including the Great Indian Bustard.
SPORTS
Cricket
Champions
TrophyPrize
money hikedThe International
Cricket Council announced a new
format for the Champions Trophy
according to which only the top eight
one-day teams will battle it out for an
increased prize money of $ 4 million.
Tennis
Wimbledon 2009On July 5,
2009 in London, Switzerlands Roger
Federer, came up as the most
Archery
Deepika is World Champion
Deepika Kumari of India won the
individual gold medal in the cadet
recurve women section of the 11th
Youth World Archery Championship
in Ogden (Utah), United States on
July 21, 2009. Deepika, a trainee at
the Jamshedpurbased Tata Archery
Academy, is the current senior
National and sub-junior National
Champion.
This is second time India has won
a world title in archery. Palton Hansda
became the first Indian to be the
World Champion in 2006 in Mexico.
UPKARS
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CSV gives latest and
important points regarding premedical tests of various medical
institutes. I have found it extremely useful in my examination.
Ratish Kumar Mishra
RatishMy studies were mainly
based on text-books. I went through
all the books. Questions in PMT
examinations are mainly based on
concepts. So I mainly cleared my
concepts in every topic.
CSVHow much time did you
devote daily and regularly for Physics,
Chemistry, Zoology and Botany ?
RatishI used to study 8-10
hours daily. I devoted only two or
three subjects daily. For each subject
I gave 3-4 hours daily.
CSVOut of the above four
subjects, to which subject did you give
more weightage and why ?
RatishI mainly gave weightage
to Biology because I find it hard to
learn so many of facts. I also gave
importance to Physics.
CSVDid you make complete
study of all topics or of some selective
topics ?
RatishYes, I made complete
study of all the topics.
Personal Qualities
HobbiesW a t c h i n g
playing football
cricket,
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DELHI
Including
Previous Years
Solved Papers
Website : www.upkar.in
in
preparation
of
Physics49 marks
Chemistry47 marks
Zoology45 marks
Botany47 marks
Total188 marks
CSVWhat books/magazines/
newspapers did you read for G.K.
preparations ?
RatishCSV, Dainik Jagaran.
Physics
1. What is dimensions of conductance ?
1
[C] = [R] = [M 1 L 2 T3 A2]
2. When horizontal range of a projectile is n times the
maximum height, then
4
tan = n
3. What are field forces ?
These are the forces in which contact between two objects is not necessary. Example :
Gravitational force between two bodies and
electrostatic force between two charges.
4. When a particle moves with constant speed in a circle
its velocity and acceleration both have
Constant magnitude but continuously
changing directions
5. What is the principle of conservation of momentum ?
If no external force acts on a system of two or
more bodies, then the total momentum of the
system remains constant
6. Change in momentum of projectile at the highest point
of its trajectory is
mv sin
7. What is Daltons law of partial pressure ?
The pressure exerted by a mixture of several
gases equals the sum of the pressures
exerted by each gas occupying the same
volume as that of the mixture.
8. The maximum speed with which a car can turn round
a curve of radius r is given by
vmax = rg
where is the coefficient of friction
9. What is equation of stationary wave : when the wave
is reflected from a free boundary ?
x
t
2
2
y = 2a cos
. sin
T
[ ( )]
16. For what purpose are heavy water and cadmium rods
used in a nuclear reactor ?
Heavy water as moderator to slow down
neutrons. Cadmium rods as controller to
control the rate of fission
17. Impedance of L-C-R circuit is given by
Z=
R2 + (XL XC)2
Chemistry
21. A substance which has some of the structure of
solids and some of the freedom of motion associated
with liquids, is called
Liquid Crystal
22. What is the IUPAC name and symbol of an element
having atomic number 111 ?
Un-un-unium (Uuu)
23. When mercury (Hg) was cooled below 41 K its
resistance to an electric current becomes zero. It was
first observed by
Heike Onne (1911)
Metathesis reaction
34. What is the trade name of heavy medicinal liquid
paraffin, extensively used as a mulling agent in spectroscopy ?
Nujol
35. The intermolecular forces resulting from attractions
between induced dipoles are known as
London dispersion forces
36. What is the use of bromochlorodifluoromethane
(B.C.F.) ?
Used in fire extinguishers
37. A solid whose molecular arrangement lack, a regular,
long-range pattern is called
Amorphous solid
38. What is the name of sodium aluminium silicate containing sulphur having a beautiful blue colour ?
Lapis lazuli
39. The net positive charge experienced by an electron in
a many-electron atom, is called
Effective nuclear charge
40. What is the IUPAC name of chloral hydrate ?
2, 2, 2-trichloro ethanediol
Zoology
41. What is called small calcareous granules found in the
inner ear of certain mammals ?
Otolith
42. What is called the creation of mutation ?
Mutagenesis
43. What is called the opening of the occipital bone of
skull through which the spinal cord passes ?
Foramen magnum
44. How many membranes comprise the nuclear membrane ?
Two
45. Which anticoagulant is present in the saliva of leech ?
Hirudin
46. What accepts the final electrons in electron transport
system ?
Oxygen
47. Which type of mutation involves a change in nucleotide and ultimately a change in a specific codon ?
Point mutation
48. What was virtually absent in primitive atmosphere ?
Oxygen
49. What is called the peculiar stage in Plasmodium
merozoites which appear like sepals and petals of a
flower ?
Rosette stage
50. Which vector should be eradicated for the prevention
of African sleeping sickness ?
Tse-tse fly
51. To which kind of disorder, the systemic lupus
erythematosus is associated ?
Autoimmune disease
52. What is the unit of natural selection ?
Individual
53. What is called a catalytically active complex formed
by an apoenzyme and a coenzyme ?
Holoenzyme
54. What is called a movement response to air or water ?
Rheotaxis
55. What is called an artery in mammals that arises from
an arch of the aorta and divides to form the right
carotid and right subclavian arteries ?
Innominate artery
56. What is usually lost from bones during aging ?
Calcium and phosphate
57. What is called a movement response to air or water
current in Amoeba ?
Rheotaxis
58. What type of nutrition is found in Monocystis ?
Saprozoic
59. Which enzyme is involved in light production in certain
insects ?
Luciferase
60. In nearsightedness effect the image does not focus
on which part of eye ?
Retina
Botany
61. How many ATP molecules are formed per glucose
molecule by substrate level phosphorylation ?
4 ATP molecules
62. Which family is commonly called gourd family ?
Cucurbitaceae
63. What term is used for a change in the permeability of
a cells plasma membrane that allows sodium ions to
diffuse rapidly into the cells interior ?
Depolarization
64. What is called the process by which a cell secretes
macromolecules by fusing a transport vesicle to the
plasma membrane ?
Exocytosis
65. What does taxonomy deal with ?
Naming of organisms
66. The resolving power of an electron microscope is how
much greater than the resolving power of a light
microscope ?
One thousand times
67. What does phloem transport usually from the leaves
to roots ?
Organic nutrients
68. What type of energy was used by Miller-Urey experiment ?
Electric spark
69. What is the correct name of slow viruses ?
Prion
70. In which group all unicellular plants and animals with
true nuclei are included ?
Protista
71. To which family Atropa belladona belongs ?
Solanaceae
72. What type of Saccharomyces, a fungus is ?
Nonmycelial unicellular
73. What is the shape of microspore of Cycas ?
Tetrahedral
74. What type of fruit dispersal is generally found in
Papaveraceae ?
Censar mechanism of fruit dispersal
75. What is called a group of conjugated proteins in
which one of the FAD or FMN is bound as prosthetic
group ?
Flavin
76. What causes early blight of potato ?
A fungus, Alternaria solani
77. Which process is inhibited by the drug streptomycin ?
Prokaryotic translation
78. What type of ovule is reported to have been found in
Pea ?
Campylotropous
79. Which is the earliest era in the geologic record ?
Precambrian
80. How many codons are present in valine, an amino
acid ?
Single codon
New
Release
SALES/FINANCIAL
EXECUTIVES
TEST
By : Dr. Lal & Jain Code 1666
Hindi Edition
Reasoning
Numerical Ability
General Knowledge
UPKAR PRAKASHAN, AGRA-2
E-mail : publisher@upkar.in
Website : www.upkar.in
Exam. Date
6 Sept., 2009
Main Features :
Test of Reasoning Ability
Test of English Language
Test of Numerical Ability
Officework Aptitude
By : Dr. Lal & Jain
Code No. 307
HINDI EDITION
Website : www.upkar.in
1. Wave Motion
It is defined as a disturbance that travels through the
medium due to repeated periodic motion of its particles
about their mean position, each preceding particle
handing over the disturbance to next.
Points to Remember
(i)
v=n
(iii) The relation v = n holds good for any type of
wave motion-transverse or longitudinal
(iv) When a given wave passes from one medium to
the other, its frequency does not change.
v 1 1
=
v 2 2
(f) PhaseThe phase represents the state or condition of a vibrating particle. After a distance , the particles
are in same phase. Also a particle comes to the same
phase after completing one rotation or an angle of 2
radians. So path corresponds to 2 phase change.
2
Phase difference =
path difference
( )
t x
( )
( )
(d) y = a sin 2n
x
v
In x direction
t x
y = a sin 2
+
T
( )
y = a sin (t + kx)
x
y = a sin t +
v
y = a sin 2n
( )
t+
y = a sin k (vt + x )
2
y = a sin
(vt + x )
x
v
2
= 2n
T
k = 2/
where,
v = n=
k
NoteThe above equations represent only a simple
plane progressive wave without attenuation (amplitude
gradually decreasing with distance). But in the case of
propagation of actual wave through a medium, its
amplitude gradually diminishes due to resisting effect of
viscous medium. Due to loss of energy, the amplitude
decreases exponentially with distance and the equation of
the attenuated plane progressive wave is given by
N = Avogadro number
M
m =
= Mass of one molecule
N
y = ae x sin
2
x
(ii)
(iii)
v=
E
d
vt
=
v0
v =
v =
B
d
v =
P
d
vt v0
1+
t
273
1/2
1+
t
2 273
v t v 0 (1 + 000183t )
In air,
v 0 = 332 m/s
1100 ft/sec
Note :
(i)
vt = v0
or
273 + t
273
Tt
T0
v=
P
=
d
RT
=
M
k T
m
Note :
(i)
1 W
watt/m2
A t
I = 22 a2 n2. v
10 db
40 db
6070 db
785 db
80 db
115120 db
150155 db
9. Loudness
The intensity of sound refers to external or objective
measurement, whereas loudness refers to internal or subjective aspect. The loudness of a sound is the magnitude
of the auditory sensation produced by sound.
The loudness of sound increases with intensity of
sound given by the psychological law known as WeberFechner law which is as
I
L = K log 10
where K is a constant.
I0
Sensitivity of ear
L = K log I
(as I0 is constant)
K
dL
=
I
dI
dL
is known as sensitivity of ear which decreases
dI
with increase in the intensity of sound.
UnitThe unit of loudness is Phon.
10. Pitch
It is the characteristic, which differentiates the notes
of same loudness and quality. It is an audio sensation
which depends on frequency. Higher the frequency,
higher is the pitch and more shrill is the sound. Sound of
lower frequency, hence, of lower pitch corresponds to dull
or grave sound. The voice of children and women are
shrill due to high pitch, whereas voice of adult persons is
grave due to lower pitch.
(b) HarmonyWhen two or more notes which produce concord are sounded simultaneously, the pleasing
effect is called harmony.
(c) MelodyWhen two or more notes are sounded
one after the other, the combined note producing the
pleasing effect is called melody.
(d) Musical IntervalsThe ratio of the frequencies
between two notes, greater one taken as numerator and
smaller one taken as denominator is called as musical
interval. Its numerical value is always more than one. The
terms associated with musical interval are
n2
(i)
Unison :
= 1
n1
n2
= 2
(ii) Octave Tone :
n1
n2
9
=
(iii) Major Tone :
8
n1
n2
10
(iv) Minor Tone :
=
9
n1
n2
16
(v)
Semi Tone :
=
15
n1
Solution :
Example 7. What is the maximum angle of incidence for a sound wave, on air-water interface so that
sound may be heard inside water ?
(Sound speed in air = 350 m/s, Sound speed in
water = 1400 m/s)
Solution :
OBJECTIVE QUESTIONS
1. What happens when a sound
wave is reflected from the boundary of a denser medium ? The
compression of the incident wave
is returned as
(A) Crest
(B) Trough
(C) Compression
(A) 025 m
(B) 05 m
(D) Rarefaction
(C) 1 m
(D) 2 m
(B) 20 m
(C) 25 m
(D) 50 m
x = A sin (kx t )
The velocity of the wave is given
by
(A) kx
(B) k /
(C) t
(D) /k
(B) 1/2
(C) 1/16
(D) 16/17
(B) 30
(C) 45
(D) 60
( )
(c 2 v 2 )
(c 2 v 2 )
(C)
(D)
c
y 1 = 10 sin 3t +
4
y 2 = 5 (sin 3 t + 3 cos 3t )
Their amplitudes are in the ratio
(A) 2 : 1
(B) 1 : 2
(C) 1 : 1
(D) 4 : 1
17. A longitudinal wave is travelling
in a coiled spring with a velocity
of 2 m/s. The time period of the
oscillations is 05 sec. What is
the wavelength ?
(A) 2 m
(B) 1 m
(C) 05 m
(D) 025 m
18. The Laplaces correction in the
expression for the velocity of
sound given by Newton is
needed because sound wave
(A) Are longitudinal
(B) Propagate isothermally
(C) Propagate adiabatically
(D) Are of long wavelength
19. The velocity of sound in oxygen
at 30 is 330 m/s. Therefore, the
velocity of sound in helium at the
same temperature is
(A) 330 m/s
(a + b)
(D)
a2 + b2
Just Released
loge N0 = A
loge Nt = t + loge N0
p t
p = t,
Nt
dt
d Nt
= Nt ,
dt
where is a constant of proportionality called disintegration constant.
d Nt
= dt
Nt
loge Nt = t + A,
[ ( )]
t
n
where t = n t
The probability that nucleus will survive after a time t
is
limn
t
n
= et
t = n t
=
= e
Nt = N0 et
is called disintegration or decay or radioactive or
transformation constant. It is independent of the external condition and the age of the sample. It only depends
on the energy available for nuclear transformation and on
the characteristics of parent and daughter nuclei.
et 1/2 =
2
loge 2 2303 log 2
t 1/2 =
=
0693
=
N0
te t dt
= N0
=
et
( )
( )
t
A 4
Y
Z2
Y
Z +1
238
t Ndt
= N0
e t
e t
dt
Alpha Decay
The nuclear attractive force is a short-range force but
coulombian repulsive forces between nucleons are of
unlimited range. Nuclei with more than 210 nucleons are
so large that short-range nuclear force cannot counter
balance the mutual repulsion between the protons.
N0
t 1/2
t av =
0693
It is evident that t av > t 1/2.
The activity of a nucleus is defined as A =
dN
dt
ZX
where Q
decay.
Q
where, mx
my
m He
Z2YA4 + 2He 4 + Q
(mx my m He)c 2
Mass of parent nucleus X
Mass of daughter nucleus Y and
Mass of alpha particle
R v3
( )
A4
Q
A
Properties of -rays
1. These rays have been identified as helium nuclei.
2. The velocity of these particles ranges from
14 107 m/s to 205 10 7 m/s depending upon the radioactive substances emitting them. Energy of -particles
emitted from radioactive substances varies from 419 to
678 MeV.
3. They have least penetrating power among the
three rays emitted by radioactive samples because of
their massive mass. They can be stopped by aluminium
sheet of 002 mm thickness or by even paper sheet.
4. They have great ionising power and this is the
most important property of -particles. The distance
through which an -particle travels in a specified material
before stopping to ionise it is called its range or
ionisation path length, which depends on (a) Initial
energy of the -particle (b) Ionisation potential of the gas
and (c) the chances of collision between the -particles
and the gas particles, that is, on the nature and the
temperature and pressure of the gas.
Geiger showed through his experimental studies that
for monoenergetic -particle of velocity v , the range R in
standard air is proportional to cube of velocity.
R = av 3
where a is a constant.
1
mv 2
2
v =
2E
m
R = av 3
= a
( )
2E
m
3/2
Beta Decay
Beta decay is another process through which by
changing its composition nucleus becomes more stable.
Beta-decay has its puzzling aspect, the principles of
conservation of energy, linear momentum and angular
momentum are all apparently violated in beta decay. Both
positive and negative electrons are emitted spontaneously from radioactive nuclei. There is a third process of
electron capture, where the nucleus absorbs one of its
orbital electrons, also comes under -decay. These
particles ejected from a radioactive source possess a
range of velocities and hence, a range of energies varying
from 0 to a maximum value characterised by nuclide.
The direction of emitted particle and recoiling nuclei
are never exactly opposite to each other as required by
conservation of linear momentum. The fundamental
particles electron, proton and neutron are spin half
particles.
In -decay the mass number A of parent nuclei does
not change, only the atomic number Z changes by one
unit. In -decay Z changes to (Z + 1) and consequently N
ZX
Z+1YA + 1e 0, [n p + + e ]
Energy released
Gamma Decay
ZX
Z1YA + +1e 0 [ p + n + + ]
ZX
1e
Z1YA [p ++ e n ]
n p+ + e +
1H
2He
+ 1e 0 +
p+ n + e+ +
and
For example
6C
11
11
5B
+ 1e 0 +
The existence of neutrino particles was experimentally established by F. Reines and C. L. Cowan in 1956. It
could not be easily observed because it almost does not
interact with matter.
Properties of -rays
1. They are found to be stream of electrons.
2. Their velocities vary from 33% to 998% of velocity of
light. Their average energy is only 2 to 3 MeV due to
their negligibly small masses.
3. They can easily pass through a few millimeter thick
aluminium sheet.
4. Their ionisation power is quite small as compared to
that of -particle.
5. Their range in air is several metres.
6. They can produce fluorescence in material like Zinc
Sulphide and Barium platinocyanide.
For example
27
12 Mg
1015 MeV
0834 MeV
27
13 Al
Properties of -rays
1. -rays are electromagnetic waves and have velocity
equal to that of light.
2. They are highly penetrating and can penetrate
through several centimetre thick lead or iron block.
3. They have got small ionising power.
4. They can produce fluorescence in substance like
willimite.
5. They can affect photographic plate.
6. They are not deflected by electric and magnetic
fields.
7. They knockout electrons from the surface on which
they fall.
8. They heat the substance on which they fall.
9. They produce simultaneous electron-positron pair.
e + e+
10. Hard -rays are used for medical purposes.
OBJECTIVE QUESTIONS
1. A radioactive nucleus 92X235
decays to 9 1Y231 . Which of the
following particles are emitted ?
(A) One alpha and one neutron
(B) Two deuterons and one positron
(C) One alpha and one proton
(D) One proton and four neutrons
2. N atoms of a radioactive element
emit n alpha particles per second.
The half-life of the element is
N
n
(A)
sec
(B)
sec
N
n
0693N
0693 n
(C)
sec (D)
sec
n
N
3. The radioactivity of a sample is
R1 at a time T1 and R 2 at a time
T2. If the half-life of the specimen is T, the number of atoms
that have disintegrated in time
(T2 T 1) is proportional to
(A) (R1T1 R 2T2
(B) (R1 R 2)
(R1 R 2)
(C)
T
(D) (R1 R 2)T
4. The probability of a radioactive
atom to survive 5 times longer
than its half value period is
2
(A)
(B) 2 5
5
5
(D) 25
(C) 2
5. As a result of radioactive decay,
238 is converted into
234 .
92 U
91 Pa
The particles emitted during this
decay are
(A) A proton and a neutron
(B) A proton and two -particles
(B) 2430
(C) 3240
(D) 4860
radioactive
reaction is
238
206 . How many
U
Pb
92
82
- and -particles are emitted ?
200
90 X
80Y168
(A) 6 and 8
(B) 8 and 8
(C) 6 and 6
(D) 8 and 6
(B) 80 s1
(C) 625 s1
(D) 20 s1
(B) 65 hrs
(C) 55 hrs
(D) 45 hrs
(A) 10 , 6
(B) 4 protons, 8 neutrons
(C) 6 electrons, 8 protons
(D) 6 , 8
(D) Zero
3
17V
2
5V
(A) 1 A from Q to P
(B) 1 A from P to Q
(C) 2 A from P to Q
(D) 12 A from Q to P
(B) 1000 N
(C) 750 N
(D) 250 N
(B) 510C
(C) 473C
(D) 573C
(B) 10 m
(C) 21 m
(D) 40 m
(B) 4285C
(C) 40C
(D) 385C
5
4
3
2
1
0
(B) 675 cm
(C) 45 cm
(D) 15 cm
--------|
|
8 4
|
0
10 9
(C) 875 10 7 J
|
4
(B) Density
(D) Specific heat
(B) 4
(C) 3
(D) 2
1H
(B) Fusion
R2 = 100
R
R3 = 100
30.
(A) 5
(A) Fission
(D) 67 10 7 J
R1 = 100
For water
|
|
|
8 12 16
Temperature ( C)
(A) Volume
(C) Depth
R4 = 100
S
(A) 100
(B) 180
(C) 220
(D) 440
(B) 2000 Wh
(D) 800 Wh
(B) 230 2 V
(C) 220 2 V
(D) 200 2 V
C
3V(rms)
(A) 1
(C) 3
(B) 2
(D) 4
(D) Ip I g
10
10
10
10
A
10
10
10
(A) 1000 A
(B) 2000 A
(C) 2946 A
(D) 4200 A
()
(A) 12 A
(B) 105 A
(C) 100 A
(D) 1000 A
(A) 80
(B) 60
(A) 10
(B) 05
(C) 30
(D) 40
(C) 024
(D) 075
(B) 80 cm
(D) 60 cm
(C) 01 m, 05 m
(D) 04 m, 08 m
(B) 62 45
(C) 45
(D) 30
ms1
u2 gL
(D)
5R
(B) 2 2 ms1
(D)
ms1
2(u 2 g L)
(A)
(B)
(C)
(D)
806 mg , 4 R
608 mg , 2R
806 mg , 3R
680 mg , R
(A) 32 1019 C
(B) 64 1019 C
(C) 48 1019 C
(D) 16 1019 C
31. In the given bridge the value of X
for which the potential difference
between the points B and D will
be zero is
B
1
(A)
(B)
2
3
(C) Zero
(D)
2
(B) 2V
(D) 4V
(A) 1V
(C) 3V
3/2
3
2G
(D)
3/2
3
2G
3
G
(B)
(C)
2
2
( x t) = j sin
vt cos
x
represents
(A) Transverse
progressive
wave
(B) Longitudinal
progressive
wave
(C) Longitudinal stationary wave
(D) Transverse stationary wave
(A)
(A) 5
(C) 15
(B) 10
(D) 20
T
2
T2 T3
+
2
6
(B) + T
(D)
(B) 10 2 cm
(C) 20 cm
(D) 5 2 cm
(A) 5 k
(C) 23 k
(B) 02 k
10
(D)
k
23
( )
50. Two electrons leave a radioactive sample in opposite directions, each having a speed 08 c
with respect to the sample. Find
relative speed of one electron
with respect to other
(A) 89 c
(B) 0089 c
(C) 098 c
(D) 98 c
Introduction
Transition elements are the elements which occupy
their position between most electropositive s-block and
electronegative p-block elements in the long form of
periodic table.
The transition elements are called so because their
properties lie between those of s-block and p -block
elements and make a bridge, i.e., a transition or
change between s- and p-blocks.
The transition elements are also called d -block elements because the last or differentiating electron in
their atoms always enters in the d-orbitals of (n 1) or
penultimate (last but one) shell.
The transition element may thus be defined as an
element whose atom or ion in the ground state has
incomplete d-sub-shell, i.e., it contains 1 to 9 electrons.
The irregularities or exceptions in electronic configurations of some elements like Cr, Cu, Ag, Au, Mo etc. are
explained on the basis of the concept that half-filled or
completely filled orbits are relatively more stable than
other d-orbit configurations.
The explanation of irregularities found in configuration
of some other elements is rather difficult. This can,
however be achieved by other factors like :
(I)
Nuclear-electronic attraction
(II)
d -Block Elements
or
(Transition Elements)
21
22
Sc
Ti
3d 1 4s 2
3d 2 4s 2
39
II
4d 1 5s 2
57
IV
6d 1 7s 2
3d 5 4s 1
*
27
Mn
Fe
3d 5 4s 2
3d 6 4s 2
43
42
26
44
Mo
Tc
Ru
4d 4 5s 1
4d 5 5s 1
4d 5 3s 2
4d 7 5s 1
Ta
5d 2 6s 2
5d 3 6s 2
105
Rf
5d 4 6s 2
5d 5 6s 2
Bh
5d 6 6s 2
4d 8 5s 1
4d 10 5s 0
4d 10 5s 1
79
Pt *
5d 7 6s 2
Cd
4d 10 5s 2
80
Au*
5d 9 6s 1
110
3d 10 4s 2
48
Rh
109
Hs
47
78
Zn
3d 10 4s 1
Ag*
Ir
108
Cu
Pd*
77
Os
107
Sg
76
Re
106
Db
75
3d 8 4s 2
46
4d 2 5s 2
74
3d 7 4s 2
30
29
Ni
45
Zr
73
28
Co
Nb
104
Ac
3d 3 4s 2
Hf
5d 1 6s 2
89
25
Cr*
41
72
La
24
40
III
23
Hg
5d 10 6s 1
111
5d 10 6s 2
112
Mt
Important Characteristics
(1) Metallic Nature
All the transition elements are well characterised
metals having hcp , ccp or bcc lattices.
The metallic properties like high thermal and electrical
conductivity, lustre or brightness, malleability, ductility,
hardness etc. are ascribed to the metallic-bond
present in them.
Metallic bond is caused due to the presence of a
fewer number of electrons in the outermost energy
level and also by presence of unpaired electrons
present in d -sub-shell. It is commonly observed that
greater the number of unpaired electrons in d -sub-shell
stronger is the metallic bonding and the harder is the
metal e.g., Cr, Mo, W etc. Zn, Cd and Hg are soft as
they do not have unpaired electrons.
(2) Oxidation States
Transition elements show variable oxidation states
but +2 and +3 oxidation states are commonly observed
in d-block elements. This is because of very little
energy difference between (n 1) d and ns orbitals.
Hence, the electrons from both energy levels can be
used for bond formation.
The highest oxidation states of transition elements are
found in their oxides and fluorides because oxygen
and fluorine have high electronegativity. The highest
oxidation known is + 8 in OsO4.
In general, transition elements form ionic bonds in
lower oxidation states (+ 2 and + 3). But high oxidation
states give covalent bonds. For example in KMnO 4
and CrO42 where Mn and Cr are in + 7 and + 6 oxidation states, all bonds between metal atom and oxygen
are covalent.
The lower oxidation states (0 or +1) of transition elements are stabilised by ligands which can accept electrons from metal through pi () bonding. CO molecule
is one of such ligands. In nickel carbonyl [Ni (CO) 4],
the oxidation of Ni is zero.
The relative stability of different oxidation states of
transition metals can be determined with the help
of standard electrode potential data. For example E
values for the couples Cr 3+/Cr2+ = 041 and
Mn3+/Mn2+ = + 150 volts suggest that Cr2+ is unstable
and is oxidised to Cr3+ stable state whereas Mn3+ is
unstable and is reduced to stable Mn2+ state.
Similarly Fe2+ ion is unstable in aerated water and is
oxidised to Fe 3+ and Cu+ is unstable in water and is
oxidised to Cu2+.
It must be remembered that in gaseous state Cu+ ion
is more stable than Cu2+ ion due to stable, d 10 configuration of Cu + ion.
(3) Catalytic Properties
Many transition metals and their compounds are used
as catalyst in many chemical reactions.
On account of variable valency, they easily absorb or
emit a wide range of energy necessary for the reaction
under question.
In manufacture of H 2SO4
by contact process.
Co-Th alloy
In synthesis of petrol by
Fischer-Tropsch process.
Finely divided Ni
In hydrogenation of oils
into fats.
Spongy Pt
In manufacture of H 2SO4
by contact process and in
manufacture of HNO3 from
NH3 by Ostwald process.
Iron (Fe)
In the manufacture of NH 3
by Haber process
Fe 2O3
Cr2O3
Molybdenum (Mo)
(Pt/PtO)
Wilkinsons catalyst :
[Rh(Ph3P)3Cl]
Platinum (Pt)
In homogeneous hydrogenation.
Lindlars catalyst
:
Pd-CaCO3 partially
poisoned with lead
acetate.
Crams catalyst
Pd-BaSO4 partially
poisoned with quinoline is by far better.
CuCl2
:
ZnO + Cr2O3
In manufacture of Cl2 by
Deacons process.
In manufacture of CH3OH
from synthesis gas
(CO + H2)
region of visible light having wavelength range 4000 . Actually the transmitted light gives colour to
7500 A
the substance as transmitted light has colour complementry to that absorbed.
CuSO 4.5 H 2O absorbs radiation corresponding to red
light, the Cu 2+ ion transmits radiation corresponding to
blue colour and hence Cu 2+ compounds are blue.
Most of the transition metal compounds are coloured
both in solid state and in aqueous solution. This is due
to incompletely filled d-orbitals.
When a transition metal forms a compound the
degenerate d-orbitals (all five d-orbitals having same
energy) of metal ion splits in to two sets one (having
d xy, d yz and dzx called T2g orbitals) with lower energy
and other (having dx 2 y 2 and d z2 called eg orbitals)
with higher energy in octahedral field. This is called
crystal-field splitting.
The colour of transition metal ion arises from excitation
of electrons from d -orbitals of lower energy (T2 g) to
those of higher energy e g . The light radiations corresponding to such small amount of energy which are
required for this d -d transition are available in visible
light.
The transition metals ions which have fully filled dorbitals (d 10) are colourless. There is no vacant orbital
to permit any electronic transition.
The transition metal ions which have completely
vacant d-orbitals ( d 0) are also colourless.
The colours of some important metal ions are summarised as
Metal ion
(Hydrated)
Configuration
in valency
shell of ion
No. of
unpaired
electrons
Colour of
the ion
Sc3+
3d 0
Colourless
Ti 4+
3d 0
Colourless
Ti 3+
3d 1
Purple
V3+
3d 2
Green
V2+
3d 3
Violet
Cr3+
3d 3
Violet
Mn2+
3d 5
Light pink
Mn3+
3d 4
Violet
Fe2+
3d 6
Green
Fe3+
3d 5
Yellow
Co2+
3d 7
Pink
Ni 2+
3d 8
Green
Cu2+
3d 9
Blue
Cu+
3d 10
Colourless
Zn2+
3d 10
Colourless
Colour
Orange
Rose
Purple
Green
Blue Green
Blue
Colourless
Blue
Colourless
Key Points
In iron, cobalt and nickel, the magnetic moments
due to unpaired electron spins are aligned parallel
to the external magnetic field more efficiently
resulting in an exceptionally strong reinforcement of
paramagnetism. These substances are, therefore,
known as ferromagnetic.
Paramagnetic substances lose their magnetism in
absence of magnetic field. TiO, VO 2 and CuO are
paramagnetic substances.
Ferromagnetic substances show permanent magnetism even in the absence of magnetic field. Some
examples of ferromagnetic solids are : Iron, Cobalt,
Nickel and CrO2.
Ferromagnetism arises due to spontaneous alignment of magnetic moments of ions or atoms in the
same direction.
Ferromagnetism
Antiferromagnetism
Ferrimagnetism
Paramagnetism arises due to the presence of unpaired electrons in the (n 1) d-orbitals. Paramagnetic
substances are attracted by the external magnetic
field. As the number of unpaired electrons increases
from 1 to 5 in d -orbitals of metal ions the magnetic
moment and hence paramagnetism also increases.
BM =
n (n + 2)
BM (Bohr magnetons)
(n = No. of unpaired electrons)
eh
4mc
Wood metal
Bi (50%),
Pb (25%), Sn
(125%) and Cd (125%),
used in fuse plugs and automatic sprinklers. It melts
even in boiling water.
Yellow Brass
Sterling Silver
Dental amalgam :
Ag (70%), Sn (18%), Cu
(10%), Hg (20%) used in
dental filling.
German Silver
Monel Metal
Points to Remember
Some transition metals form three kinds of oxides namely
mixed oxides , non-stoichiometric oxides and spinels.
Mixed oxides : ZnFe 2O 4, CoMoO4 etc. (having different metals in different oxidation states
Fe3O4 (FeO.Fe2O3), Mn3O4 (2MnO.
MnO 2) having same metal with different oxidation states.
Non-Stoichio- : Fe091O, Fe095O, in which metalmetric oxides
oxygen ratio is not whole number.
Spinel
: ZnFe 2 O 4 is a normal spinel in which
trivalent ion occupy octahedral holes
and divalent cation, tetrahedral holes
Fe (Fe2 ) O4 is an inverse spinel in
which dispositive ions are present in
the octahedral voids and tripositive
ions are distributed equally between
tetrahedral and octahedral voids.
Fe, Co, Ni are called ferrous metals. Ru, Rh, Pd, Os, Ir and
Pt are known as platinum metals and Cu, Ag and Au are
known as coinage metals.
Both Au and Pt are inert and are called noble metals, but
they are soluble in aqua-regia due to the formation of H
AuCl4 and H2PtCl6 respectively.
A transition element with atomic number 43 was named as
Technetium (Tc). It was the first man made or synthetic
element. It is a radioactive metal.
Cobalt (Co) is a crucial element in vitamin B-12 where its role
is to act as a catalyst.
Iron (Fe) is a key element in the biological oxidation-reduction
processes using haemoglobin or myoglobin.
Mo and Fe together with sulphur, form a reactive part of
nitrogenase, a biological catalyst to convert atmospheric
nitrogen into ammonia.
4S (S + 1) BM
n (n + 2) BM
OBJECTIVE QUESTIONS
1. Transition metals
(A) Exhibit diamagnetism
(B) Undergo inert pair effect
(C) Do not form alloys
(D) Show
states
variable
oxidation
Co 2+
(B) Cu 2+
(D) Ni2+
(A) Ni
(B) Al
(A) Zinc
(B) Scandium
(C) Sn
(D) Po
(C) Copper
(D) Nickel
V3+
(B) Co 3+
(D) Cr3+
(C) ns electrons
(D) ns + (n 1) d electrons
20. The number of d -electrons in
Fe 2+ ion is not equal to
(A) p-electrons in neon
(B) s -electrons in Mg
(C) d-electrons in Fe atom
(D) p-electrons in Cl ion
21. Among the following outer configurations of transition elements,
which one can show the highest
oxidation state ?
(A) 3d 3 4 s 2
(B) 3d 5 4 s 1
(C) 3d 5 4 s 2
(D) 3d 6 4 s 2
22. Which of the following transition
elements does not form amalgam ?
(A) Silver
(B) Gold
(C) Iron
(D) Zinc
23. Which is the ferrous alloy ?
(A) Solder
(B) Type metal
(C) Invar
(D) Magnalium
24. Which transition metal is used as
promoter in the manufacture of
ammonia by Habers process ?
(A) Fe
(B) Os
(C) Ni
(D) Mo
25. A transition element has a configuration [Ar] 3d 4 in its + 3 oxidation state. The atomic number of
the element is
(A) 22
(B) 25
(C) 26
(D) 19
26. Which one of the following pairs
of ions contains same number of
unpaired electrons ?
(A) Mn2+ and Fe 3+
(B) Ni2+ and Mn 2+
(C) Ni2+ and Co 2+
(D) Ti3+ and Co 2+
27. Which ion has the same number
of unpaired electrons as that of
V3+ ion ?
(A) Fe 3+
(B) Ni2+
2+
(C) Mn
(D) Cr3+
28. Which
compound
is
both
coloured and paramagnetic ?
(A) K3 [Cu (CN)4]
(B) K2Cr2O7
(C) (NH4)2 (TiCl6)
(D) VOSO4
29. Which of the following elements
shows the highest oxidation
number ?
(A) Cr
(B) Mn
(C) Os
(D) Pt
(C) Fe 3+ and Co 3+
(A) Red
(B) Blue
(D) Sc 3+ and Cr 3+
(C) Green
(D) Violet
44. Which one of the following species has an atom with oxidation
state of + 6 ?
(A) MnO4
(B) CrO2Cl2
(C) [Cr (CN)6] 3
(D) VOCl2
(B) Ruby
(C) Emerald
(D) Sapphire
Introduction
In nitrobenzene, nitro group (NO2) is directly attached to benzene ring and hence it is called a nitroarene.
Nitrobenzene was first isolated by Mitscherlich in
1834 and it is of great industrial importance and is put
in the market as an artificial oil of bitter almonds under
the name of oil of mirabane.
The nitro group is isoelectronic with carboxylate anion
and is the resonance hybrid of two equivalent resonance structures
O
O
O
O
(ii)
NO2+
Slow
>
Benzene
HSO
fast
H
NO2
+ H2SO4
NO2
Nitrobenzene
Note : Slowest step involves the formation of benzene carbocation (Phenonium or benzenonium ion) intermediate and this is the ratedetermining step. This reaction takes place
at temperature below 60C.
When temperature of the reaction is 100C following
will be the main products :
NO2
NO2
HNO + H SO
90C
3
2
4
Nitrobenzene
NO2
m -dinitrobenzene
NO2
nitrites.
Fuming HNO
Oleum 100 C
Preparation
H
|
HOSO 2OH + HONO2 HONO2 + OSO2OH
Acid
Base
Acid
Base
H2O +
NO2+
(Nitronium ion)
NO2
Properties
Nitrobenzene is a lemon yellow oily liquid having smell
of bitter almonds.
Nitro compounds are highly polar. For example nitrobenzene has dipole moment of 40 D. Due to dipoledipole interaction nitrobenzene has high boiling point,
209C.
ReductionIt is one of the important properties of
nitrobenzene. The final product of reduction depends
upon nature of reducing agent as well as the pH of the
medium.
(a) Catalytic reductionAniline is formed.
Ni or Pt
(Nitronium ion)
Note
NO2
Sym-trinitrobenzene
(Poor yield)
C6H5NO2 + 2 Zn + 4 NH4Cl
C6H5NHOH + 2 ZnCl2 + H2O + 4 NH3
Phenyl hydroxylamine
Key Points
Ether
+ 2H
+ 2H
C6H5NHOH
O
C6H5N
H 2O
Nitrosobenzene
Na 3 A sO3 / NaOH
C6H5N
NC 6H5
or glucose / NaOH
Azoxybenzene
[ 6H]
+ 3 H2O
Zn/Na O H, CH O H
3
NC 6H5
C6H5N
C6H5NO2
[ 8H]
Azobenzene
Weakly acidic
medium
NO2
Aniline
Nitro
benzene
NHOH
NH2
Electrolytic
reduction
Rearrange
Strongly acidic
medium
Phenyl
hydroxylamine
OH
p-amino phenol
Azobenzene
Rearrangement
+ 4 H2O
Benzidine
Zn/NaO H
C6H5NH NH C6H5
[10 H]
Hydrazobenzene
+ 4 H2O
Key Points
Mononuclear intermediate products such as nitrosobenzene and phenyl hydroxylamine interact together to
produce bimolecular products such as azoxybenzene,
azobenzene and hydrazobenzene.
(i)
O
C6H5NO2 C6H5N
Nitrosobenzene
[2H]
O
C 6H 5N
+
C6H5NHOH
C6H5N
||
C6H5N
[2H]
H 2O
Azobenzene
[2H]
+ 6 NH3 + 2 H2O + 3S
NO2
C6H5N O
||
C6H5 N
Azoxybenzene
+ 3 (NH4)2 S
NH2
C6H5NHOH
Phenyl hydroxylamine
(ii)
NO2
NO2
[2H]
H 2O
C6H5NH
|
C6H5NH
Hydrazobenzene
NO2
NO2
HNO3 +
H2SO 4
H SO
2
4
Nitration
SO2OH Sulpho-
m -dinitrobenzene
Halogenation Cl2
NO2
2-nitro compound
(Nitrolic acid)
+ KOH
H2 O
RC
NOK
|
NO2
(Red colour)
CNO
|
NO2
Aciform
H2O
Cl
m -nitrochlorobenzene
1 Nitrocompound
CH + ONOH
|
NO2
R
NO2
nation
m -nitrosulphonic acid
Uses of Nitrobenzene
It is used as a scenting material for many cheap
soaps.
On account of its inertness it is used as a solvent for
Friedel-Crafts reaction. It dissolves anhydrous AlCl3,
used as catalyst in this reaction.
Nitrobenzene penetrates leather well and hence used
in making shoe polish.
It is used as a starting material for many explosives
like trinitrobenzene.
Nitrobenzene is used in manufacture of many important organic compounds like aniline, acetanilide, hydrazobenzene, benzidine a large number of azodyes and
sulpha drugs.
Points to Remember
In presence of nitro groups, the reactivity of halogen increases as :
Cl
Cl
Cl
Cl
<
NO 2
<
<
In case of acids
COOH
<
NO 2
NO 2
COOH
COOH
NO 2
<
NO 2
NO 2
NO 2
NO 2
COOH
COOH
<
NO 2
NO 2
In phenolic compounds
OH
OH
<
OH
OH
NO 2
NO 2
<
<
NO 2
Due to the presence of nitro group on o- or p-position, H of
alkyl group gets activated and condensation of p -nitrotoluene with benzaldehyde takes place to give p- nitrostilbine.
NO 2
OH
NO 2
<
<
NO 2
CH3 + O
CH
NO 2
OH
NO 2
<
NO 2
NO 2
C H ONa
2 5
NO 2
NO 2
CH
CH
p-nitrostilbine
+ H 2O
+ H2O2
NH 2
NO
NO2
C6H5
NO2
o- or p-dinitrobenzene
NO 2
NO 2
NH2
o-nitroaniline
NO 2
NO 2
HNO
Dry
Cu2O
NO 2
( CH3) 3C
NO 2
C (CH3)3
OCH3
NO 2
NO 2
Toluene musk
Musk ambrette
COCH3
CH3
CH3
NO 2
NO 2
NO 2
H
C (C H3)3
Musk ketone
o-dinitrobenzene
n-butyl nitrite
The aryl nitro compounds like C 6H5NO 2 contain no -hydrogen hence they resemble tertiary aliphatic nitro compounds in
being not acidic in nature. Nitrobenzene does not tautomerise
like tertiary nitroalkanes.
N = NC l
NaNO + HCl
COOH
NO 2
NO 2
K Cr O
2 2 7
NO 2
NO 2
NO 2
NO 2
Acinitroform (solid)
CO
NO 2
NO 2
NO 2
OBJECTIVE QUESTIONS
1. Nitrobenzene can be prepared
from benzene by using a mixture
of conc. HNO3 and conc. H2SO4.
In nitrating mixture HNO3 acts as
a/an
(A) Base
(B) Acid
(C) Reducing agent
(D) Catalyst
2. Which one is the false statement ?
NO2
(C) Trinitrophenol
(D) Nitrobenzene
+ KOH (solid)
NO2
OH
OH
is an example of
(A) Electrophilic
substitution
reaction
(B) Nucleophilic
substitution
reaction
(C) Free
radical substitution
reaction
(D) Electrophilic addition reaction
6. Which of the following compounds can tautomerise ?
(A) Nitrobenzene
(B) Phenylnitromethane
(C) m-dinitrobenzene
(D) Tertiary nitroalkane
7. In the nitration of benzene with
conc. HNO3 + conc. H2 SO4, the
active species involved is known
as
(A) Nitrite ion
(B) Nitrate ion
(C) Nitrosonium ion
(D) None of these
(D) Activating
12. When nitrobenzene is reduced
with zinc dust and aqueous
NH4Cl, the final product will be
(A)
(B)
(C)
(D)
Aniline
Benzene
Phenylhydroxylamine
Azoxybenzene
X
Sn + HCl
X is
(A) Cl group
(B) NH2 group
(C) NH3+ Cl
(D) SnCl2 group
Nitrobenzene
m-dinitrobenzene
p-dinitrobenzene
Sym-trinitrobenzene
(B) Trinitrotoluene
5. The reaction
(A)
(B)
(C)
(D)
Aniline
Phenyl hydroxylamine
Nitrosobenzene
Azobenzene
(C) Nitration
(D) None of these
23. Which of the following will be the
most reactive towards the nitration ?
(A) Benzene
(B) Nitrobenzene
(C) Toluene
(D) Chlorobenzene
24. The strongest acid among the
following aromatic compounds
is
(A) Orthonitrophenol
(B) Paranitrophenol
(C) Metanitrophenol
(D) Parachlorophenol
25. When benzene is treated with
conc. HNO3 at room temperature, what will happen ?
(A) Benzene will be oxidised to
CO2 and H 2O
(B) Dinitrobenzene will be obtained
(C) Solution will become dark
red
(D) None of the above is correct
26. In the reaction sequence
Zn distillation
(B) Chlorobenzene
(C) Nitrobenzene
(D) None of these
30. The nucleophilic substitution
reaction is the most easier reaction in
(A) Benzene
(B) Toluene
(C) Nitrobenzene
(D) Chlorobenzene
31. Nitrobenzene generally finds
application in preparation of
(A) Aniline
(B) Floor polishes
(C) Shoe polishes
(D) All of these
32. Which of the following compounds is the most steam volatile ?
(A) Paranitrophenol
(B) Orthonitrophenol
(C) Metanitrophenol
(D) Phenol
33. The major product of reaction
between m -dinitrobenzene and
(NH4)2S is
Phenol X
conc. HNO3 + H2SO 4
Zn
Y Z
NaOH
following is the
meta directing
(B) SO 3H
(D) NO2
(1)
(2)
is as
(A) 2 > 3 > 1
(C) 1 > 2 > 3
CH3
(I)
OH
,
NO2
(IV)
(A) II and IV
(C) I and II
NO2
NO2
HS
(B) IV and II
(D) III and IV
NH2
(D)
(II)
OH
NH2
(C)
(III)
NH2
(B)
OH
OH
NO2
NH2
NH2
(A)
(3)
HS
NH2
2
Nitrobenzene
CH 3COCl
HNO3
B C
+
H /H2O
HBF4
D
E
NaNO2
NaNO2
Cu
the product F is
(A) m-dinitrobenzene
(B) Para dinitrobenzene
(C) Ortho dinitrobenzene
(D) Both (B) and (C)
NO2
NO2
(B)
(C)
3
C6H6
OH
NO2
(A) 2
(C) 4
OH
(C) m-dinitrobenzene
m-nitroaniline
(D) p-dinitrobenzene
p-nitroaniline
and
and
NC6H5
(D) C6H5 N
45. In the reaction sequence,
Zn/HCl
C6H5NO2
NaNO2/HCl
H2O/H3PO 2
B
C
product C is
(A)
(B)
(C)
(D)
(D) NO2
(B) 3
(D) Zero
OH
ANSWERS
Just
Released
(B) m-dinitrobenzene
(C) p-dinitrobenzene
(D) None of these
Benzoic acid
Benzene
Phenol
Chlorobenzene
com-
ANSWERS
C6H5NO2
C H COCl
6 5
B + HCl
the product B is
(A)
(B)
(C)
(D)
Azobenzene
Hydrazobenzene
Benzanilide
Acetanilide
HINDI EDITION
Code No. 215
Rs. 110/-
(B) [Ar] 3 d 4 4 s 2
(A) Ag+
(C) [Ar] 3 d 6 4 s 0
(B) [Ag(NH3)2] +
(D) [Ar] 4 d 5 4 s 1
(C) [Ag(NH3)4] +
(D) [Ag(NH3)6] +
14
C
6
in upper atmosphere is
14
N
7
+ 11H 146C +
(B)
14
N
7
(C)
14
N
7
(D)
14
N
7
146C +
0
e
+1
+ 11H
0
e
+1
(B) Na +
(D) H+
Mg(s) + Cu2+(aq)
Cu (s) + Mg2+(aq)
(A) 23
(B) 7
(C) 30
(D) 14
(A) + 203 V
(B) 203 V
(C) + 271 V
(D) 271 V
is
(A) 1
(C) 5
(B) 10
(D) 033
CH3C
C CHCH2C
CH
|
|
|
Cl CH3 C2H5
is
(A) 6-chloro-4-ethyl-5-methylhept-5en-1-yne
(B) 6-chloro-4-ethyl-5-methylhept-1-yn-5-ene
(C) 2-chloro-4-ethyl-3-methylhept-2-en-6-yne
(D) 2-chloro-4-ethyl-3-methylhept-6-yn-2-ene
36. The average K. E. of an ideal gas
per molecule in SI unit at 25C
will be
(A) 617 10 21 J
(B) 617
10 21
(C) 617
10 20
(D) 716
10 20
37. Gammexane is
38. What quantity of ammonium sulphate is necessary for the production of ammonia gas sufficient to
neutralise a solution containing
292 g of HCl
[(NH4)2SO4 = 1320, HCl = 365,
NH3 = 17]
(A) 272 g
(B) 408 g
(C) 528 g
(D) 1056 g
(B) 16 x 2
(C) 96 x 5
(D) 108 x 5
(B) 1/2
(C) 2
(D) 4
(A) DDT
(B) 57 kJ
(C) Chloral
(D) Hexachloro ethane
(C) 57 104 J
(D) All of the above
45.
235
(B) 6
(C) 5
(D) 8
1. In a radioactive decay
(A) then and then emitted
(B) or and then emitted
(C) and and emitted
simultaneously
(D) and emitted simultaneously
2. 106 grams of a substance of
molecular weight 106 was dissolved in 100 ml. 10 ml of this
solution was pipetted out into a
1000 ml flask and made upto the
mark with distilled water. The
molarity of resulting solution is
(A) 10 M
(B) 102 M
(C) 103 M
(D) 104 M
3. Equation for a real gas is
a
P + 2 (V b) = RT
V
(B) 2 : 3
(D) 1 : 4
(B) 224
(C) 42
(D) 84
PV
for 1
T
mole of gas ?
(A) 42 107 cal/K
(B) 42 cal/K
(C) 831 cal/K
(D) 2 cal/K
10. Reaction of benzene with alkyl
halide in the presence of AlCl3 is
called
(A) Friedel-Crafts reaction
(B) Wurtz reaction
(C) Williamsons synthesis
(D) Bayers reaction
11. Experimental
verification
matter waves was done by
of
(A) de Broglie
(B) Rutherford
(C) Bohr
(D) Davisson and Germer
12. The effective atomic number of
Cr in [Cr(NH3)6]Cl3 is
(A) 35
(B) 36
(C) 27
(D) 33
H + 21 H 24 He + B + Energy
and
(C) 2ZnS + 3O2 2ZnO + 2SO2 31. How much volume of 04M NaOH
is required to neutralise comp(D) MgCO3 MgO + CO2
letely 200 ml 05 M H 2SO4
23. 01M CH 3COOH is 13% ionised.
solution ?
The dissociation constant of it
(A) 600 ml
(B) 300 ml
will be
(C) 500 ml
(D) 200 ml
(A) 169 105
32. Among the following compound
(B) 169 106
which have more than one type
(C) 169 104
of hybridisation for carbon
atom ?
(D) None of these
(i) CH3CH2CH2CH3
24. In Wurtz reaction the reagent
CHCH3
(ii) H3CCH
used is
CH
(iii) H2C CHC
(A) Na
CH
(B) Na/liq. NH3
(iv) HC
(B) 5 102
H 2O
(C) (D)
CH2OH
CH2OH
M = Molecule, R = Reagent
M and R are
(A) CH3CH2Cl and NaOH
(B) CH2ClCH2OH and aq.
NaHCO3
(C) CH3CH2OH and HCl
(D) CH2 CH2 and heat
O
41. Formic acid and acetic acid may
be distinguished by the reaction
with
(A) Sodium
(B) 2, 4-dinitrophenyl hydrazine
(C) Litmus paper
(D) Tollens reagent
42. Which of the following is redox
reaction ?
(A) H2SO4 with NaOH
(B) In atmosphere, O3 from O2
by lightning
(C) Nitrogen oxides from nitrogen and oxygen by lightning
(D) Evaporation of water
43. The number of coordinate bond
in a molecule of H2SO4
(A) 4
(B) 3
(C) 2
(D) 1
44. Which of the following 01 m
aqueous solutions will have the
lowest f.p. ?
(A) Al2(SO4)3 (B) C5H10O5
(C) KI
(D) C12H22O11
is
(A) CH3CH2NH2 (B) CH3CN
45. Carnallite is
(C) HCONH2
(D) CH3CONH2
(A) KCl
(B) Li Al(SiO3)2
37. Metal which does not react with
(C) MgCl26H2O
aqueous solution of copper
(D) KClMgCl26H2O
sulphate is
(A) Pb
(C) Zn
(B) Ag
(D) Fe
Lothar Mayer
Niels Bohr
Mendeleef
Moseley
(A) ZnSO 4
(C) NiSO4
(B) CuSO 4
(D) FeSO 4
Introduction
The adult human skeleton consists of 206 bones linked
in a specific order. Many of these bones are joined in
ways that permit movement.
The growth of skeletons begins during early development and continue until about age of 20 years.
Like all other organ systems of body, bones undergo
alterations during the entire life span, from infancy to
old age.
The various parts of the skeleton are so articulated
that they can absorb the tremendous shocks generated in locomotion.
Skeletal System
Human skeleton can be divided into two parts : the
Axial skeleton and the Appendicular skeleton.
Axial Skeleton
Axial skeleton occupies the longitudinal central axis of
the body and includesskull, vertebral column, sternum and ribs.
Facial Bones
The facial bones make up the front of the skull and lies
under the anterier part of the cranium. It is composed
of 14 bones. These include nasals (2), maxillae (2),
palatines (2), zygomatic or cheek bones (2), lacrymals
(2), inferior nasal conchae (2), vomer (1) and mandible
(1).
Cranial bones
Frontal
bone
Suture
Parietal
bone
Sphenoid
bone
Facial bones
Temporal
bone
Nasal
bone
Zygomatic
bone
Maxilla
Cranium
Opening to
ear canal
Mandible
Skull
Occipital
bone
Axial Skeleton
Vertebral column is also called backbone. It is curved, vertical rod the mid-dorsal line of the neck and
trunk.
Vertebral column consists of 26 vertebrae in adults (33
in infants), while in sacral region 5 vertebrae fuse
together to form a sacrum and in caudal region 4
vertebral fuse together to form a coccyx.
A single spinal bone is called vertebra. This series of
interacting bones extend from the skull to the pelvis.
Together these bones have three major functions :
1. Provide flexible support for the head and trunk.
2. Protect the delicate spinal cord.
3. Permit the passage of spinal nerves to and from
the spinal cord.
1. Cervical vertebraeThere are 7 cervical vertebrae and are present in neck region. The first
cervical vertebra is called atlas. It is almost ringlike and provides up an down or nodding movement to the skull on it.
The second cervical vertebra is termed axis and its
centrum bears an odontoid process. The cervical
vertebrae allow widest range of motion to head to
turn in many directions. These have apertures,
called foramina transversaria in their transverse
processes.
These foramina form a channel for the vertebral
artery to pass through the brain.
2. Thoracic vertebraeThese are 12 in number and
are present in the upper back region. They are
modified to provide articulation to the ribs at special
facets on the centrum.
3. Lumbar vertebraeThese are 5 in number and
are located in the abdominal region. They have
large neural spine and transverse processes.
4. Sacral vertebraeThese are 5 in number and are
placed in pelvis. They fuse in childhood to form a
single bone, sacrum in adults.
Process can be seen and felt as one of a
series of bumps along the middle of the back.
Ribs attach to
thoracic vertebra here.
Cervical vertebrae (7)
Canal contains and
protects spinal cord.
Curvature
A notable feature in the vertebral column of human
beings is the formation of four curves : cervical,
thoracic, lumbar and sacral.
The cervical and lumbar curves are directed forward;
thoracic and sacral curves backward. Because of
Spinal cord
Intervertebral
disk
Spinal nerve
Ruptured material
pressing against
spinal cord and
nerve
Vertebrae
Normal disk
Slipped disk
Fig. : A slipped disk pressing against the spinal cord and spinal nerve.
Ribs
The ribs are curved bars, which movably articulate with
the thoracic vertebrae at the back and unite with the
sternum in front, forming a protective cage for some
internal organs. The interior of this cage is called
thoracic cavity, and houses heart and lungs.
There are 12 pairs of ribs. The upper 7 pairs of ribs are
attached in front directly to the sternum. These are
called true ribs.
The next three pairs of ribs are joined to the sternum
above each other, and termed false ribs.
The lower two pairs of ribs are free in front (not joined
with sternum) and are called floating ribs.
Clavicle
Pectoral girdle
Head of humerus
Scapula
Humerus
Ulna
Radius
Carpals (8)
Metacarpals
Phalanges (14)
Appendicular Skeleton
Arm Bones
The uppermost bone of the arm is called humerus. Its
upper end fits into the socket on the scapula. This
attachment (joint) is stabilized by muscles and tendons
provides a wide range of movement.
The lower part of the humerus joins with two bones of
the lower arm, ulna and radius, forming elbow.
The lower end of the ulna and radius is attached to a
group of bones called carpal bones that form the
wrist.
The palm of the hand contains the metacarpal bones.
The fingers or phalanges consist of bones that join
with the metacarpal bones.
In the hand, there are 8 carpels in the wrist, 5 metacarpals in the palm and 14 phalanges in the fingers.
Vertebra
Coxal bone
Sacrum
Coccyx
Pubic
symphysis :
a disk of
cartilage joining
the coxal bones
Femur
Patella
Pelvic Girdle
The pelvic girdle consists of two large bones called the
Coxal bones, commonly known as the hipbone.
Linked together by cartilage in the front (the pubic
symphysis), the two hipbones also join with the vertebral column in back, forming a ring-like structure called
the pelvis.
The pelvis of adult males and females differ somewhat
in shape and size. The female pelvis is wider and
provides a large opening for the passage of the infants
head during birth.
Pelvic girdle is located in the lower part of the trunk. It
consists of 3 bones : upper ilium, lower ischium and
inner pubis, fused to formed a stout hipbone, the
innominate.
The hipbone has at the middle of its lateral surface a
deep cup-shaped hollow, the acetabulum, where the
head of femur articulates. Below the acetabulum, the
hipbone has a large oval gap, the obturator foramen.
Leg Bones
The upper leg bone is called femur or thighbone. Its
upper end is formed into a ball-shaped unit that fits into
a well-defined socket of a coxal bone.
This ball-and-socket arrangement results in a stable
load-bearing joint, that is capable of a great range of
movement.
At the knee, the lower end of the femur meets two
bones of the lower leg : the larger tibia and the smaller
fibula. The knee joint forms where the femur joins
directly with the tibia.
Infront of each knee-joint is a small triangular bone, the
patella or kneecap, which protects the knee-joint and
acts as a pulley for the upper thigh muscles.
Tibia
Fibula
Tarsals (8)
Metatarsals (5)
Phalanges (14)
Fig. : Anterior view of the pelvic girdle with left leg
and foot bones.
Joints
Where two or more bones join together, a joint or
articulation is formed. All body movements occur at
joints.
Many joints are held together and stabilized by bands
of fibrous connective, called ligaments. Often the
ween zygapophyses and of the vertebrae, between the carpals in the wrist, tarsals in the
ankle and between sternum and clavicles are of
this type.
5. Pivot jointThis joint allows only a rotary movement of one bone on the other which remains
stationary. The joint between the atlas and axis
vertebra in humans is of this type. It enables the
head to turn from side to side. The upper ends of
radius and ulna articulate with each other by a
pivot joint.
6. Saddle jointThis joint resembles the ball-andsocket joint but both ball and socket are poorly
developed. The joint between metacarpal of the
human thumb and the corresponding carpal is of
this type. It enables the thumb to move in many
directions.
Bone
Joint
capsule
Synovial
membrane
(produces
synovial
fluid, which
reduces
friction)
Joint
cavity
Cartilage
Bone
Fig. : Anatomic structures characteristic of
synovial joints.
Disorders
OsteoporosisThis disorder results from the loss of
calcium and phosphate from the bone matrix.
Throughout life, bone is continuously deposited and
removed by osteoblasts and osteoclasts respectively.
In osteoporosis, osteoblast activity is decreased and
the bone is deposited more slowly than it is removed
by osteoclasts.
Osteoporosis,
primarily
affects post-menopausal
women. After menopause, there is decline in womans
production of the female sex hormone-estrogen, one
function of which is the stimulation of osteoblast activity. As a result, the skeleton is weakened and bone
fractures can occur even with normal activity.
OsteoarthritisThis is an inflammation of the large
weight-bearing joints. It is believed that osteoarthritis
results from the gradual wearing of the surface cartilage of a joint. As the cartilage is worn, the underlying
OBJECTIVE QUESTIONS
(C) Pectoral girdle
(D) Vertebral column
(B) Ilium
(C) Sternum
(D) Acetabulum
9. Human
vertebral
column
shows
(A) Cervical curvature
(B) Thoracic curvature
(C) Lumbar and sacral curvature
(D) All the above
3. Acetabulum forms
(A) Shoulder joint
(B) Hip joint
(C) Elbow joint
(D) None of the above
4. Number of floating ribs in human
body is
(A) 3 pairs
(B) 1 pair
(C) 2 pairs
(D) 4 pairs
Just Released
(B) 21
(C) 24
(D) 30
ANSWERS
UPKARS
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Chhattisgarh
Pre-Medical Test
Upkars Chhattisgarh PMT
Combined GuideAT A Glance Rs. 455/Highlights
Main Features
Paper
Mathematics
Science (Physics,
Chemistry, Biology)
General English
E-mail : publisher@upkar.in
Website : www.upkar.in
165/175/-
Zoology
Botany
115/115/-
Introduction
Cause
Symptoms
Effects on Foetus
Treatment
Complications
Acquired Immune
Deficiency Syndrome (AIDS)
Exposure to AIDS
virus and other
infections
Drugs to treat or
delay symptoms;
no cure
Dementia
death
Chlamydia
Chlamydia
bacteria
Premature birth,
blindness,
pneumonia
Antibiotics
Genital herpes
Herpes simplex
virus type I or II
Brain damage,
stillbirth
Antiviral drug
(acyclovir)
Increased risk of
cervical cancer
Genital warts
Human
papilloma virus
Warts on genitals
None known
Increased risk of
cervical cancer
Gonorrhea
Neisseria
gonorrheae
bacteria
Blindness, stillbirth
Antibiotics
Syphilis
Treponema
pallidum
bacteria
Miscarriage,
prematurity, birth
defects, stillbirth
Antibiotics
Death
Hepatitis B
Hepatitis B virus
Cirrhosis,
cancer
Chlamydiosis
and
liver
Gonorrhea
Syphilis
Genital Warts
AIDS
Genital Herpes
The envelope
is derived from
plasma membrane of human
host cell.
Reverse transcriptase
Protein that attaches
virus to cell.
Microbial Agent
Symptoms
P. carinii pneumonia
Toxoplasmosis
Cryptosporidiosis
Cryptococcosis
Candidiasis
Histoplasmosis
Cytomegalovirus disease
Cytomegalovirus (virus)
Herpes simplex
Tuberculosis
Hepatitis B
OBJECTIVE QUESTIONS
1. Chlamydiosis is caused by
(A) Bacteria
(B) Virus
(C) Fungus
(D) Protozoa
Homo erectus
Homo habilis
Australopithecus afarensis
Australopithecus robusta
(C) Exonuclease
(D) Polymerase
32. To make a karyotype, chromosomes are photographed during
(A) Fertilization (B) Meiosis
(C) Mitosis
(D) Interphase
33. In which of the following
mammals do the ducts of the
excretory system and genital
tract have a common opening ?
(A) Porcupine (B) Pangolin
(C) Hedgehog (D) Echidna
34. An interaction between nonallelic
gene in which an allele at one
locus prevents expression of an
allele at another locus, but not
vice versa, is called
(A) Collaboration
(B) Complementation
(C) Epistasis
(D) Modification
35. Cerebral malaria is caused by
(A) Plasmodium falciparum
(B) Plasmodium malariae
(C) Plasmodium ovale
(D) Plasmodium vivax
36. A fruitfly is heterozygous for sexlinked genes, when mated with
normal female fruitfly, the males
specific chromosomes will enter
egg cell in the proportion
(A) 1 : 1
(B) 2 : 1
(C) 3 : 1
(D) 7 : 1
Balantidium coli
Escherichia coli
Plasmodium vivax
None of these
Alanine
Glutamic acid
Histidine
Glutanine
(C) Endoneurium
(D) None of these
26. An exergonic reaction is
(A) A spontaneous reaction in
which energy is given off
(B) An uphill reaction requiring
input of energy
(C) An oxidation reaction
(D) An anaerobic reaction
27. Method of coelom formation
within pouches of mesoderm is
called
(A) Pseudocoely
(A) Demes
(B) Cline
(B) Schizocoely
(C) Clisere
(C) Enterocoely
(D) None of these
28. The internal mechanism by
which a biological rhythm is
maintained in the absence of
appropriate environmental stimuli
is termed as
(A) Circardian rhythm
(B) Sleep movement
(C) Biological clock
(D) None of these
29. A metastatic cancerous tumour is
termed sarcoma if the disorder is
in
(A) Immune system
(B) Epithelial cells
(C) Fibroblasts
(D) Circulatory system
30. The arrangement of numerous
setae in a ring in each segment
of Pheretima is known as
(A) Lumbricine
(B) Oligochaetine
(C) Otochaetine
(D) Perichaetine
31. The most striking example of
point mutation is found in the
disease, called
(A) Thalassemia
(B) Downs syndrome
(C) Sickle-cell anaemia
(D) Night-blindness
32. Poisonous fangs of cobra, krait
and coral snakes are
(A) Solenoglyphous
(B) Proteroglyphous
(C) Opisthoglypous
(D) None of these
(B) Huxley
(D) Aristotle
Introduction
The leaves, stems and roots of a plant all consist of
the same meristematic, dermal, ground and vascular
tissues. Yet plants show a wide variety of formsfrom a
prickly cactus to a lush vine to the majestic sunflower
(Helianthus annuus). Natural selection sculpted different
arrangements of plant tissues for better adaptations to
particular environment. A stem is the central axis of
shoot, leaves are extremely diverse photosynthetic
organs and roots anchor plants and absorb, transport and
store nutrients.
Leaf
blade
petiole
Internode
Nodes
In addition to performing photosynthesis, leaves provide support, protection and nutrient procurement and storage with the following specializations
(i) Storage leavesThese are fleshy and store food,
e.g., onion (Allium cepa).
(ii) SpinesSpines of plant such as cacti are leaves
modified to protect the plant from predators.
(iii) BractsBracts are floral leaves that protect
developing flowers. They may be colourful in certain
plants. e.g., Poinsettia .
(iv) TendrilsThese are modified leaves that wrap
around nearby objects to support climbing plants.
(v) Insect trapping leavesInsect-trapping leaves
are found in about 200 species of carnivorous plants and
are adapted for attracting, capturing and digesting prey.
Some leaves have sticky flypaper surfaces, whereas
others form water-filled chambers that insects drawn in.
The trigger hairs of a venus flytrap respond to a visiting
insects movement by stimulating the two leaves to snap
together. The insect is then trapped as the leaves secrete
digestive enzymes that destroy it.
Leaves
Leaves are the primary photosynthetic organs of
most of the plants. These are the most diverse plant
organs and may be classified on the basis of blade structure, attachment pattern, organization around nodes and
venation. American elm may have several million leaves,
minor veins, where water and solutes move into and out
of veins. Xylem is present on the upper side of a vein and
phloem on the lower side.
Petiole
Cuticle
Upper
epidermis
Cross-section
Palisade
mesophyII
Xylem
Vascular
bundle
(vein)
Spongy
mesophyII
Phloem
Lower
epidermis
Air
space
Chloroplasts
Stomata
Fig. : A leaf in cross section. The mesophyll areas contain different kinds of parenchyma cells.
Stem
The central axis of a shoot system is the stem. The
stem of flowering plants produces leaves and if upright as
most are, supports, leaves in such a way that each one is
exposed to as much sunlight as possible. A node occurs
where leaves are attached to the stem and an internode
is the region between the nodes. The presence of nodes
and internodes is used to identify a stem even if it
happens to be an underground one. Food and water is
carried through the stems of plants.
Stem elongation normally occurs in the internodal
regions. However, some plants have stems called
rosettes that do not elongate. Rosettes have short internodes and overlapping leaves. For example, a banana
tree is a rosette as its trunk is made up of large and tightly
packed leaves.
epidermis of stem may also possess protective trichomes. Trichomes have been put into a number of
groups on the basis of their morphological characters.
Hairs constitute a very common type of trichome. The
wall of trichome is commonly of cellulose (a polymer of B
glucose) covered by cuticle.
The ground tissue that fills the area between epidermis and vascular tissue in a stem is called the cortex.
Some cortical cells are photosynthetic and store starch. In
plants that have concentric cylinders of xylem and
phloem, the ground storage tissue in the centre of the
stem is called pith. The pith stores the products of photosynthesis.
The vascular tissue system differentiates from the
procambial strands and is organised into vascular
bundles that branch into leaves at the nodes. Phloem
(the food-conducting vascular element) occurs towards
the outside of the bundle, whereas xylem (water-conducting vascular element) is found towards the inside of vascular bundle.
Vascular bundles are arranged differently in different
types of plants. Familiar flowering plants are divided into
two classesmonocotyledons and dicotyledons of
which the former possesses one cotyledon and the latter
two cotyledons. Monocots such as corn have vascular
bundles scattered throughout their ground tissue, whereas
dicots such as sunflowers have a single ring of vascular
bundles. In contrast to flowering plants, pines have an
outer cylinder of phloem surrounding an inner cylinder of
Root
Roots have various adaptations and associations to
enhance their ability to anchor a plant, absorb water and
minerals, and store the products of photosynthesis.
Fig. : (i) Development of the Tap root System in dicots. (A) Germinating dicot seed with growing radicle. (B) Tap root
system developed out of a radicle. Fig. (ii) : Development of the Adventitious Fibrous Root System in monocots.
(A) Rice seedling showing radicle roots, seminal roots, adventitious fibrous roots and mesocotyl. (B) Rice plant
with extensive fibrous root system.
Endodermis
Pericycle
Phloem
Xylem
Cortex
Epidermis
Root hair
Zone of
maturation
Vascular
cylinder
Zone of
elongation
Zone of
cell division
Root cap
Fig. : Dicot root tip : The root tip is divided into four zones, best seen in a longitudinal section such as this. The vascular
cylinder of a dicot root contains the vascular tissue. Xylem is typically star shaped and phloem lies between the
points of the star.
OBJECTIVE QUESTIONS
1. Between the bark and the wood
in a woody stem, there is a layer
of meristem called
(A) Apical meristem
(B) Cork cambium
(C) The zone of cell division
(D) Vascular cambium
2. The Casparian strip is found
(A) Within the secondary wall of
parenchyma cells
(B) Between all epidermal cells
(C) On four sides of endodermal
cells
(D) Between xylem and phloem
cells
3. A leaf usually consists of
(A) Blade
(B) Petiole
(C) Both (A) and (B)
(D) None of the above
4. Mesophyll containing irregular
cells bounded by air spaces is
termed
(A) Spongy mesophyll
(B) Palisade mesophyll
(C) Both (A) and (B)
(D) Petiole
5. Root hairs are found in the zone
of
(A) Elongation
(B) Maturation
(C) Cell division
(D) All of the above
6. A flowering plant has three
vegetative organs. Which of the
following
vegetation
organs
anchors a plant, absorbs water
and store the products of photosynthesis ?
(A) Leaves
(B) Roots
(C) Stems
(D) None of the above
(C) Arbovirus
(D) None of the above
7. HIV has a protein coat and a
genetic material which is
(A) Single stranded DNA
(B) Single stranded RNA
(C) Double stranded DNA
(D) Double stranded RNA
8. AIDS was first reported in
(A) Russia
(B) Germany
(C) USA
(D) China
9. For which of the following
disease, there is preventive
vaccine ?
(A) AIDS
(B) Hepatitis B
(C) Syphilis
(D) Gonorrhea
10. Disease vaginitis is caused by
(A) Candida albicans
(B) Trichomonas vaginalis
(C) Phthirus pubis
(D) Chlamydia
ANSWERS
ANSWERS
Introduction
Fats or lipids are best described as a diverse groups of
organic compounds found in plants, animals and microorganisms.
Fats and certain other compounds, more or less
densely closely related, are often called lipids.
Lipids made by cells are important not only because
they serve as an energy source but also because they
form the structural components.
Fats are produced in all actively metabolising plant
cells and serve a number of indispensable roles in
plants, particularly as reserve food substances.
Fats, such as olive oil, contain a mixture of fatty substances called triglycerides.
The proportion of the lipids in food-stuffs varies from
02% in white potatoes to 70% in some nut kernels.
Characteristically, they are greasy to touch and insoluble in water but soluble in ether, alcohol, acetone
and other organic solvents.
(a) Phospholipids :
Phospholipids are lipids containing a phosphate group.
The commonest type is formed when one of the
OH groups of glycerol combines with phosphoric
acid instead of a fatty acid. The other two groups
combine with fatty acids as in the formation of a
triglyceride.
Lecithin, the best known among phospholipids in plant
cells, is an essential structural material for living cell
membrane, where it maintains continuity between the
water and lipid phases inside and outside the cell. The
function of certain enzymes depend upon their attachment to lipids such as lecithin.
(b) Galactolipids :
Galactolipids are major lipid constituent of green leaf
tissue of plants.
Monogalactosyl diglyceride and diglactosyl diglyceride
are commonly occurring galactolipids in chloroplasts.
Fatty Acids
(a) Fats :
Fats are esters of fatty acids with glycerol, i.e., fatty
acids are esterified with glycerol to form triglycerides.
These are true fats and are indispensable as reserve
food material and as a source of energy in living cells.
(b) Waxes :
Waxes are esters of higher aliphatic acids with long
chain of alcohol other than glycerols.
These are important components of cuticle of epidermal cell walls.
Waxes have been isolated from the outer layer of
bacteria, leaves, roots, stems, fruits and flowers of
plants.
Waxes are solid at 20 C; crystalline; melt above 40 C
2. Compound Lipids :
Compound lipids are esters of fatty acids containing
groups in addition to alcohol and fatty acid radicals. It
may be of the following types
Number of C-atoms
Behenic acid
22
Arachidic acid
20
Stearic acid
18
Palmitic acid
16
Myristic acid
14
Lauric acid
12
No. of C-atoms
Palmitic acid
16
Oleic acid
18
Linoleic acid
18
-Linoleic acid
18
Erucic acid
22
2. -oxidation :
-oxidation is the principal method of fatty acid
degradation in plants.
This process occurs in mitochondria (and also in
glyoxysomes) and involves successive removal of
2C in the form of acetyl CoA molecule from the
carboxyl end of fatty acid.
Because -carbon (i.e., carbon atom number 3) of
the fatty acid is oxidised, it is called -oxidation
which involves the following sequential reactions
(i) The first reaction involves the activation of fatty
acid in presence of an enzyme thiokinase and
ATP. CoASH is consumed and CoA-derivative
of fatty acid is produced.
Thiokinase
Adenylate kinase
2ADP
Should be Known
Each turn of -oxidation generates 5 ATPs.
However, in the first turn there is a consumption of
2ATPs in the reaction of step (i) and hence, in this
turn there isa net gain of only 3 ATPs.
Each turn of -oxidation generates one FADH2
[reaction number (ii)].
A huge amount of energy is generated in the form of
ATP by mitochondrial oxidation of fatty acids
through -oxidation and TCA cycle (Tricarboxylic
acid cycle). For example, one molecule of palmitic
acid (16C-atoms) on complete oxidation produces
129 ATP molecules.
Malonyl-CoA + Acetyl-CoA
2NAPH 2
OBJECTIVE QUESTIONS
1. In which of the following organic
or inorganic compounds, lipids
are soluble ?
(A) Alcohol
(B) Water
(C) Ether
(D) In alcohol and ether
2. Which of the following is/are
saturated fatty acid(s) ?
(A) Palmitic acid
(B) Myristic acid
Introduction
The chemicals found in living organisms are derived
originally from the abiotic components of ecosystems,
such as soil, water and air, to which they eventually return
by way of decomposition of the waste products or dead
bodies of organisms. Bacteria and fungi bring about
decomposition, obtaining energy from the waste products
and dead organisms in the process. Thus a constant
cycling of the chemical materials needed by living organisms occurs within an ecosystem. Since both living and
non-living parts of ecosystem are involved in these chemical cycles they are called biogeochemical cycles.
Carbon Cycle
The main carbon store is the estimated 75 million
billion tonnes in the earths rocks. A further 5000 billion
tonnes are found in fossil fuel reservoirs : coal, gas, oil
and peat and about 150 billion tonnes are held in the
uppermost ocean bed sediments. They represent the
main carbon reservoirs, however, these carbon sources
are not normally available to living organisms.
The main carbon source for living organisms is CO 2
present in the atmosphere or dissolved in surface waters.
In photosynthesis green plants, algae and blue-green
bacteria convert CO 2 to simple carbohydrates, the building blocks for all other organic molecules. This conversion
of CO 2 in photosynthesis and the counterbalancing
7
16
(Evapotranspiration)
23 Precipitation
over land
Evaporation
ice
from
land,
Evaporation
lakes and
from ocean Transpiration
rivers
84
77
Precipitation
into ocean
Ocean
7
Ground water
Total water
Oceans 97%
Fresh water 3%
Bedrock
Fresh water
Ice sheets and glaciers 75%
Ground water 25%
Lakes 0.3%
Soil moisture 0.06%
Atmosphere 0.035%
Rivers 0.03%
to nearest whole %
Atmosphere
750
.66
11.
5.5
90
90
92
Surface ocean
1020
10
0
50
40
Marine biota
3
Phosphorus Cycle
The weathering of rocks on land makes phosphate
ions available to plants which take it up from the soil.
Some of this phosphate (PO 4= and HPO4= ) run off into
aquatic ecosystems where algae take phosphate up from
the water before it becomes trapped in sediments. Phosphate in sediments become available only when a geological upheaval exposes sedimentary rocks to weathering
once more. Phosphorus does not enter the atmosphere,
therefore, the phosphorus cycle is called a sedimentary
cycle.
0.
5
n
io
ct 1.4
du 6
o
pr
e
y
ar on
us
ir m rati
nd
i
p
a
l
et sp
g
in
l n re
ng
ba nd
a
lo a
h
G
C
Vegetation 610
soils and detritus 1580
2190
on climate. The balance is also affected by human activities, notably by changing land-use as in deforestation or
reforestation, using of fossil fuels and in cement manufacturing.
91
.6
DOC
< 700
Intermediate and
deep ocean
38100
0.2
Surface sediment
150
Nitrogen Cycle
Nitrogen makes about 78% of the atmosphere by
volume, yet nitrogen deficiency commonly limits plant
growth. Plants cannot incorporate nitrogen into organic
compounds and, therefore, depend upon various types of
bacteria to make nitrogen available to them.
Fig. : Nitrogen cycle. 78% by volume of the atmosphere is nitrogen. This is the main nitrogen reservoir.
Worth-Remembering
Biogeochemical cycles show the more or less circular
paths of chemical elements passing back and forth between organisms and environment.
The rate at which vital elements become available to biological components of the ecosystem is more important in
determining primary and secondary productivity than
flow of solar energy.
If an essential element or compound is in short supply in
terms of potential growth, the substance may be said to be
a limiting factor.
The productivity of an entire ecosystem is sometimes limited by one material available in least amount in terms of
need. Thus water limits the desert ecosystem and nitrogen or phosphorus often limits ocean ecosystems.
From the standpoint of the biosphere as a whole, biogeochemical cycles fall into two groupsthe gaseous type
cycles, as illustrated by nitrogen cycle; and the sedimentary type cycle involving movement of the more earthbound
elements.
OBJECTIVE QUESTIONS
1. Which of the following contributes to the carbon cycle ?
(A) Photosynthesis
(B) Fossil fuel combustion
(C) Respiration
(D) All of the above
2. Since the pathway by which
chemicals circulate through ecosystems involve both living and
nonliving areas, they are known
as
(A) Biogeochemical cycle
(B) Nutrient cycle
(C) Ecosystem
(D) Autecology
3. For each element or chemical,
the biogeochemical cycling process involves
(A) A reservoir
(B) An exchange pool
(C) Biotic community
(D) All of the above
4. How do plants contribute to the
carbon cycle ?
(A) When they photosynthesize,
they consume CO 2 from the
atmosphere
(B) When they respire, they
release CO2 into the atmosphere
(C) Both (A) and (B) are correct
(D) They do not contribute to the
carbon cycle
5. During water cycle, water falls on
land enters the
(A) Ground water
(B) Surface water
(C) Aquifers
(D) All of the above
6. Which of the following processes
maintain(s) the stable water
balance on the earth ?
(A) Evaporation
(B) Precipitation
(C) Surface run off
(D) All of the above
7. Nitrification is the production of
(A) Nitrates
(B) Nitrites
(C) Nitrogen
(D) Ammonium
8. In the phosphorus cycle, weathering makes phosphate available
to
(A) Consumers directly
(B) Producers
(C) Reservoirs
(D) None of the above
9. The main nitrogen reservoir in
the biosphere is the
(A) Organisms (B) Atmosphere
(C) Rocks
(D) Ocean
10. Phosphorus cycles in the form
of
(A) PO43
(B) HPO 3
(C) P2 (a gas) (D) All of these
ANSWERS
ANSWERS
10. Who among the following introduced the term pure line for the
first time ?
(A) Swamminathan
(B) Johannsen
(C) Borlaug
(D) Blakeslee
Initiation of translation
Chain elongation
Chain termination
All of the above
Nodes only
Internodes only
Leaf primordia
All of the above
(C) Sclerenchyma
(D) Parenchyma
46. In coconut, the dispersal is due to
fibrous
(A) Epicarp
(B) Mesocarp
(C) Curved hooks
(D) Endocarp
47. When a fungus is able to pass its
complete life cycle on one host it
is called
(A) Autoecious
(B) Heterosporous
(C) Heterothallism
(D) Heteroecious
48. The leucoplasts are
(A) Green plastids
(B) Red plastids
(C) Colourless plastids
(D) Any type of colours (pigments)
49. During which stage of lytic cycle,
viral DNA and capsids are
assembled to produce several
hundred viral particles ?
(A) Biosynthesis (B) Maturation
(C) Penetration (D) Attachment
50. The sulphur-containing amino
acids are
(A) Methionine and tyrosine
(B) Cysteine and glycine
(C) Glycine and tyrosine
(D) Methionine and cysteine
Pitcher plant
Sundew
Bladerwort
Venus fly-trap
(a)
(b)
(c)
(d)
(A)
(B)
(C)
(A) Ecosystem
(D)
(B) Eutrophication
(B) Second
(C) Third
(D) Fourth
(C) Mutation
(D) Descent from a common
ancestor
10. Bacteria do not possess
(A) Mitochondria
(B) Plasma membrane
(C) Cell wall
(D) All of the above
11. Carnauba wax is found in
(A)
(B)
(C)
(D)
Prunus amygladus
Brassica napus
Both (A) and (B)
None of the above
12. Small dry one-seeded fruit developing from superior monocarpellary ovary with the pericarp
fused with seed coat is called
(A) Caryopsis (B) Nut
(C) Cypsela
(D) Achene
13. Floridian starch is the reserve
food material of
(A) Claviceps
(B) Cyanobacteria
(C) Volvox
(D) None of the above
PHYSICS
1. Assertion (A) : The ratio Cp /Cv
for a diatomic gas is more than
that for a monoatomic gas.
Reason (R) : The molecules of a
monoatomic gas have more
degrees of freedom than those of
a diatomic gas.
(A)
(B)
(C)
(D)
(E)
2. Assertion (A) : When
Q.
Reason (R) : The relation will
(C)
(D)
Reason (R) : Voltmeter is connected in series with the resistance across which voltage drop
is to be measured.
(A)
(B)
(E)
(C)
(D)
(D)
(E)
(B)
(C)
(D)
(E)
(A)
(B)
(C)
(D)
Reason (R) : =
(A)
(B)
1
= tan ip
sin C
(C)
(D)
(E)
(B)
(C)
(D)
(E)
n = 1
(E)
(E)
( )
(A)
(C)
| P + Q | = | P Q |,
(A)
(A)
(B)
(C)
T2
T1
(D)
(E)
CHEMISTRY
11. Assertion (A) : The energy of an
electron is mainly determined by
the value of its principal quantum
number.
Reason (R) : The principal quantum number, n is a measure of
the most probable distance of
finding the electron around the
nucleus.
(A)
(B)
(C)
(D)
(E)
12. Assertion (A) :
[ CH2CH
(C6H5
] n is an important copolymer and it is also known as
condensation polymer.
Reason (R) : If a mixture of more
than one monomeric species is
allowed to polymerise, a copolymer is formed.
(A)
(B)
(C)
(D)
(E)
13. Assertion (A) : Fluorine atom has
capacity to oxidise other elements
to their highest oxidation state.
Reason (R) : Fluoride ion has a
small size and on account of the
same, it is rather difficult to oxidise
fluoride ion to fluorine atom.
(A)
(B)
(C)
(D)
(E)
14. Assertion (A) : There is only one
atom per unit cell in a primitive
cubic unit cell of a crystal lattice.
Reason (R) : In a simple cubic
structure of a lattice, there are
eight corner atoms which are
shared between eight units.
(A)
(B)
(C)
(D)
(E)
15. Assertion (A) : Phenoxide ion is
a stronger base as compared to
ethoxide ion.
Reason (R) : Phenol is a stronger
acid in comparison of ethanol.
(A)
(B)
(C)
(D)
(E)
16. Assertion (A) : At a freezing
point of a solvent, the solid and
liquid are in equilibrium and it is
possible only if they have same
vapour pressure.
Reason (R) : A solution will
freeze when its vapour pressure
equals the vapour pressure of
pure solid solvent and for this it is
necessary to lower the temperature of the solution.
(A)
(B)
(C)
(D)
(E)
(B)
(C)
(D)
(E)
ZOOLOGY
21. Assertion (A) : The nature of the
skeleton is an important characteristic in sponge taxonomy.
Reason (R) : Sponges are supported by a skeleton that may
consist of microscopic needle-like
spikes called spicules, which take
on a variety of shapes.
(A)
(B)
(C)
(D)
(E)
22. Assertion (A) : Cartilage (protein
matrix) and bone (calcium matrix)
are rigid connective tissue.
Reason (R) : Blood is connective
tissue in which plasma is the
matrix.
(A)
(B)
(C)
(D)
(E)
(B)
(C)
(D)
(E)
BOTANY
31. Assertion (A) : There are two
principal translocatory systems in
the vascular bundles of plants.
Reason (R) : The xylem vessels
are lignified, thick-walled dead
cells, whereas the tube cells are
thin-walled and living cells.
(A)
(B)
(C)
(D)
(E)
32. Assertion (A) : Intercellular
spaces usually are found among
meristematic cells.
Reason (R) : In meristematic
cells, the cells may be rounded
or polygonal in shape.
(A)
(B)
(C)
(D)
(E)
Reason (R) : The cells of endodermis are non-living and characterised by the presence of
casparian strips.
(A)
(B)
(C)
(D)
(E)
(B)
(C)
(D)
(E)
(A)
(B)
(C)
(D)
(E)
(B)
(C)
(D)
(E)
Physics
1. When a silicon semiconductor is doped with a boron
atom, it behaves as P-type semiconductor.
T/F
2. The difference between the length of a certain brass
rod and that of a steel rod is claimed to be constant at
all temperatures.
T/F
3. By applying magnetic field -rays can be deviated.
T/F
) ( )
Va
T/F
15. Green glass when heated to high temperature emits
red light.
Chemistry
T/F
T1
T/F
T2
Ia
27.
28.
29.
30.
Zoology
31. The hippocampus of human brain consolidates shortterm memories into long-term memories.
T/F
32. The parathyroid glands release parathyroid hormone
which decreases calcium levels in blood.
T/F
33. Encephalins and endorphins are natural painkillers.
T/F
34. Genetic drift is random change in the gene pool of
small populations resulting from death, migration, or
isolation.
T/F
35. Genes coding for proteins are regulatory genes, and
genes controlling regulatory genes are structural
genes.
T/F
36. Individuals affected by Klinefelter's syndrome are
males only.
T/F
37. Polygenic inheritance occurs when several separate
genes control a single phenotypic trait.
T/F
38. Human karyotype can be best prepared at metaphase
stage of cell division.
T/F
39. The phenotype includes traits which can be observed, measured, or analyzed. The genotype includes
the genes for the traits of the phenotype.
T/F
40. Prosmian is a group of primates that includes apes
and humans.
T/F
41. Connective tissues bind organs together, support and
insulate the body, and store energy.
T/F
42. A conserved DNA sequence of 180 base pairs
encodes a protein domain in many proteins.
T/F
Botany
46. In the year 1928-29 the Dutch plant physiologist Went
finally proved the existence of a chemical transmitter.
T/F
47. Lock and Key hypothesis can be misleading when
applied to the question of enzymatic catalysis.
T/F
48. A mycorrhiza is a mutualistic association between
green algae and fungi.
T/F
49. Eolian landforms are topographic features generated
by the wind.
T/F
50. The fruit of cereals is mostly referred to as caryopsis.
T/F
51. The family of Leguminosae is divided into three subfamilies on the basis of calyx and gynoecium
arrangements.
T/F
52. The point of contact where crossing over occurs is
called a chiasma.
T/F
53. Ca and Mg are microelements because they are
required only in extreme small quantities by plants.
T/F
54. A cover providing protection to root cap is called
tunica.
T/F
55. Chemiosmotic theory does not provide the intellectual
framework for understanding many biological energy
transductions.
T/F
56. In eukaryotes nucleus stores genetic information.
T/F
57. Germplasm protection at a very low temperature is
known as cryopreservation.
T/F
58. A normal human karyotype shows 22 pairs of
autosomes and one pair of sex chromosomes.
T/F
59. The plasma membrane is followed by the colloidal
fluid of called endoplasm.
T/F
60. The lytic cycle is not divided into any stages.
T/F
Physics
2
1
dF
=
= . E2
d S 20 2 0
1
= (C 1)
fC
=
and
(C 1)
R
1
= (D 1)
fD
1
1
(1)
1
1
( D 1)
(2)
R
Now as the lenses are in contact
1
1
1
=
+
F
fC
fD
(C D)
=
R
=
i.e.,
F =
R
(C D)
C1
C2
(A)
Y
I'
The
stoichiometric compounds, where the number of different types of atoms or ions are present exactly in the ratio indicated by
their chemical formula are called
Daltonide compounds. The nonstoichiometric compounds where the
chemical composition of a compound
is variable or not constant, are known
as Bertholide compound.
Q. What is isoelectronic principle ?
Isoelectronic species are
those which have same number of
electrons. Such species have similar
structure. This may be extended
to species with the same number
of valence electrons. Thus BF4,
CH4, NH4+ are all tetrahedral, CO32,
NO3 and SO3 are all planar triangular and CO2, N 3 and NO2+ are
all linear.
Q. Why a catalyst is generally
needed when an organic compound is reduced with hydrogen ?
The lack of reactivity of hydrogen is related to the strength of HH
bond. An essential step in H2 reacting
with another compound is breaking of
HH bond to produce atoms of
hydrogen. This requires 4359 kJ
mol 1, and there is high activation
energy to such reactions. Hence most
of reactions of hydrogen involve
heterogeneous catalysis where catalyst first react with H2 and either
breaks or weakens the HH bond
and thus lowers the activation energy.
Q. What is inorganic benzene ?
Borazine, B3N3H6 is called
inorganic benzene because its
structure shows some formal similarities with benzene, with delocalized
electrons and aromatic nature. The
physical properties are also almost
similar. Borazine is comparatively
more reactive than benzene and
addition reactions occur quite readily
B3N3H6 + 3 HCl B3N3H9Cl3
H
|
B
I'
C1
C2
(B)
Chemistry
Q. What is the difference between Daltonide and Bertholide
compounds ?
H N
|
H B
N H
H N
|
|
BH
H B
H
|
N H
||
BH
N
N
|
|
H
H
1444444424444443
Borazine
RT
V
Dividing we get
PN2
n(N2)
=
=
Pmixture
n(N2) + n(SO2) (N2)
((N2) = mole fraction of N 2)
or
HO
HO
OH
|
C H
|
CH2NHCH 3
Zoology
Q. How bone grows ?
Botany
Q. What do you mean by protogyny ?
Protogyny is a condition in
hermaphrodite or dioecious animals
and plants in which the female reproductive structures mature before the
male structures. It is of rare occurrence. Botanically, protogyny occurs
in some plant species in which the
female part stigma develops, withers
and dies before male part anthers
mature.
Q. What do you mean by primary vascular system of plant ?
O
C2
C3
VA + VB + VC
C1 + C 2 + C 3
(B)
VA C1 + VBC2 + VDC3
C1 + C 2 + C 3
(C)
VA VB + VBVD + VDVA
C1 + C 2 + C 3
(D)
VA VB VD
C1C2 + C2C3 + C3C1
5. A wave is represented by
y = 04 cos
(B) 14 sec
(D) 10 sec
4. Assertion (A) : If
A + B + C = 0,
then A B = B C = C A
Reason (R) : The vector sum of
three vectors can never be zero.
Choose the correct answer from
the following
(A) Both (A) and (R) are correct
and (R) is the correct explanation of (A)
(B) Both (A) and (R) are correct
but (R) is the correct explanation of (A)
( )
8t
x
2
(C)
C1
(A)
sec 1
4
(D)
sec 1
8
(D) 16 times
(D) H2S2O3Mg
(B) Enzymes
(C) Ribosome
(D) Lysosome
(A) Enantiomers
(A) Vertebrae
(B) Potentiomers
(C) Chargers
(D) Decomers
(B) Gerontopia
3.
4.
5.
6.
7.
8.
Q. No. A
1.
11.
2.
12.
3.
13.
4.
14.
5.
15.
6.
16.
7.
17.
8.
18.
9.
19.
10.
20.
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General Principles of Taxonomy
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Photosynthesis : Part-I
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Blood Clotting Mechanism
Organ Systems of Vascular Plants
Plant Breeding Vernalization
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Many Typical Model Papers and other
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PRIZE WINNERS
First Prize
Krishan Kumar Rajbhar
B-57, N.C.L. Khadia,
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U.P.231 222
Second Prize
Vishal Tiwari
III-B-231
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(B) Ambush
(C) Attack
(D) Invade
(E) Raid
(iv) If an odd number is followed by a prime odd number, the first number is to be
divided by the second
number.
(v) If an odd number is followed
by an even number, the
second one is to be subtracted from the first one.
21. 32
13
5
15
12
15
Which of the following will be the
answer if the resultants of the
two rows are added ?
(A) 45
(B) 54
(C) 36
(D) 18
(E) None of these
22. 67
12
11
20
x
14
If x is the resultant of the first
row, what will be resultant of the
second row ?
(A) 16
(B) 5
(C) 11
(D) 6
(E) None of these
23. 12
36
31
x
11
15
If x is the resultant of the first
row, what will be the resultant of
the second row ?
(A) 5
(B) 10
(C) 45
(D) 75
(E) None of these
24. 27
18
3
21
x
9
If x is the resultant of the first row,
what will be the resultant of the
second row ?
(A) 63
(B) 36
(C) 3
(D) 16
(E) None of these
25. 35
12
7
16
2
x
P + Q means P is sister of
Q.
P Q means P is brother
of Q.
(iv) P Q means P is mother
of Q.
(iii)