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Plating On Plastics PDF
Plating On Plastics PDF
Plating on Plastics
John J. Kuzmik
The plating of non-conductors has been achieved for many years. Articles
plated were mainly decorative, and adhesion of the plate t o the substrate was
minimal. In the early 1960s' due to technological advances in chemical
processing techniques, plating on plastics began on a commercial level.
Industries that utilize plated plastics include the automotive, plumbing, appliance
and electronics.
One of the early plastics to be plated on a large scale was polypropylene,
which gave adhesion values of over 20 pounds per linear inch. Even though
adhesion was excellent, other problems occurred that ultimately led to the
demise of plating polypropylene. These problems included (1) failure t o pass
thermal cycling due to its high coefficient of linear thermal expansion (i.e., the
amount i n inches per inch the part shrinks in the mold-68 t o 9 5 x lO-'in./in./" c
for polypropylene); (2) brittleness after plating due to notch sensitivity (a
phenomenon whereby a crack in the plate will propagate through a normally
flexible plastic, causing it t o break easily); and (3) "sink" marks caused by the
plastic shrinking i n the mold, especially over bosses and ribs and showing up as
dimples or "sinks" after molding.
Some of the reasons various industries are interested in plating plastics
include (1):
Lowercost
No secondary operations (i.e., no deflashing or buffing)
Design freedom (i.e., the ability to mold large and complex parts)
Weight reduction
Weight reduction became a very real benefit to the automotive industry when
the gasoline crunch occurred in the early 1970s.
Many plastics are plated today, including:
0
ABS
Polypropylene
Polysulfone
Polyethersulfone
Polyetherimide
Teflon
377
370
ELECTROLESS PLATING
Polyarylether
Polycarbonate
Polyphenylene oxide (modified)
Polyacetal
Urea formaldehyde
Diallyl phthalate
Mineral-reinforced nylon (MRN)
Phenolic
Some typical applications of plated plastics are shown in Figs. 14.1 and 14.2.
Several of the above-mentioned resins have little or no adhesion and/or
unacceptable appearance. Of the resins listed, ABS, acrylonitrile-butadienestyrene, has found the widest acceptance in the plating industry. ABS is a
terpolymer thermoplastic that has an acrylonitrile-styrene matrix with butadiene
rubber uniformly distributed in it. This quality makes it unique for plating, as the
butadiene can be selectively etched out of the matrix (Fig. 14.3), leaving
microscopic holes that are used as bonding sites by the electroless plate. Other
factors influencing the choice are:
Lowcost
Low coefficient of thermal expansion
Ease of molding
Good metal adhesion to the substrate
Good appearance after plate
Because ABS is the most widely plated plastic, it will be the material mainly
referred to in this chapter. Scanning electron micrographs of ABS surfaces are
shown in Fig. 14.4.
Quality plating on plastics involves the following three basic steps:
Molding-converting plastic pellets into the desired part.
Preplate-processing the molded part through an electroless bath in order
to render it conductive.
Electroplating-building additional metal thickness using current.
Because of the importance of molding, which must be done properly to insure
a part with the high quality necessary for plating, it will be advantageous to
mention some general guidelines that should be followed. Molding consists of
transforming the plastic pellets into the shape (part) to be plated. A mold of the
part must be built and in doing so, certain design features must be taken into
account for the finished part. These include (2):
Gates (fill areas) should be put in a non-appearance area.
Integral parts should be used to avoid welded joints.
Ribs and bosses should be designed to eliminate sink marks.
Texturing can be used to break up large flat surfaces and hide any defects,
such as scratches.
0
379
Draft angles should be at least one degree (1") for easy removal of the part
from the mold.
Parting lines (where the mold opens) should be put in a non-significant area
if possible.
Close tolerance fits must include the final plate in the initial part design.
Wall thickness should be sufficient to insure rigidity.
Plate uniformity, which results from current density distribution, must be
considered in the initial design. Use no 90" angles, no V grooves, keep letters
close to the wrface, make angles as large as possible, and crown large flat
surfaces (Figs. 14.5 and 14.6).
380
ELECTROLESS PLATING
Plating on Plastics
381
i
Fig. 14.5-Design considerationsfor plating thlckness unlformity: (left) 90 angles and V-grooves
result in poor current distribution; (right) suggested design.
Fig. 14.6-Sharp corners(a) result in poor plating uniformity;(b) rounded corners, both Internal and
external,Improvecoverage. Expansive surfaces (c) should be crowned fora convex surtace as In (d).
Proper mold femperafure-If the mold is too cold, skinning can occur,
that is, the first material to hit the mold hardens instantly and the hot material
under it flows, causing a surface skin that may cause delamination.
Proper fill speed-A fast fill speed can overpack a mold, thus making it
harder toetch, resulting in adhesion loss. Best resultsareobtained using a slow
fill speed.
These are some of the more obvious parameters t o be considered when
molding a part to be plated. The mold design and molding parameters are
extremely important to insure good parts that are free of stress and other
imperfections. Most plastics can be evaluated for stress. In polycarbonate and
other clear plastics, stress can be detected using polarized light. ABS is
immersed in glacial acetic acid for one minute, rinsed and dried. Any peeling
indicates delamination, white areas depict stressed areas, which usually etch
differently than the rest of the part, causing adhesion and thermal cycle
problems. Cracks or actual breakage of parts indicate severe stress and should
not be plated at all.
382
ELECTROLESS PLATING
The type of mold release used can have a profound effect on the molded part.
For example, silicon-type mold releases (materials sprayed on the molded
Surfaceto help in the removal of the molded part) should not be used, as they are
extremely difficult to remove and usually lead to adhesion failures (blisters) or
misplate because they hindered the processing solutions from performing their
functions properly. Molders who mold plastic parts for plating generally do not
use a mold release. If it is essential to use one, a stearate or soap type may be
used sparingly.
The addition of fillers (4) to the resin can create problems when plating of the
parts is involved. In some cases fillers are added to the resins to increase
strength (i.e., glass fibers), to impart color (i.e., carbon black or titanium
dioxide), or for fire retardancy (organic phosphates, antimony oxide). In any
case, problems can arise. Glass, for example, usually gives a rough surface to
the finished part. Titanium dioxide can build up in the processing tanks and
cause a rough surface after plating. Some of the fire retardants and other fillers
can leave a non-adherent fiim on the surface that results in no adhesion after
plating. If the film can be removed prior to catalyst, good results are usually
obtained.
Other fillers such as calcium carbonate are added to facilitate etching. These
fillers are preferentially etched out of the surface to create bonding sites
required for adequate adhesion. If these particles are large, a poor surface
results. Generally, a happy medium is reached where adhesion is adequate and
the surface is acceptable. Mineral-reinforced nylon is one such material.
When parts are molded, they are ready to be plated, as there is no secondary
operation required. Parts are racked and run through the processing solutions,
which include cleaners and/or predips, etching, neutralization, preactivation,
activation, acceleration, and finally electroless plating (see Fig. 14.7). These
steps are known as the preplate cycle (5).
CLEANERS
Cleaners are used for removing light soils such as fingerprints, dirt, and other
debris from the parts. They are usually mild alkaline cleaners. In some cases, a
highly wetted chromic acid solution may be used to insure complete wetting of a
part in knurled or lettered areas prior to etching. This will minimize pinpoint
skips in these areas. Cleaning prior to etching is optional and generally not used
if parts are reasonably clean.
Troubleshooting these materials usually only involves chemical analysis to
insure they are up to concentration.
PREDIPS
Predips, which are generally solvents, such as dimethylformamide for
polysulfone, are used prior to etchants for two types of plastic problems. The
Plating on Plasfics
Fig. 14.7-Process
383
first use is to help improve the surface of a normally plated but poorly molded,
highly stressed part. This is done on ABS and its alloys by slightly swelling the
surface, allowing the etchant to more uniformly attack the surface. By using a
predip, non-uniform etch conditions are reduced on a stressed part, giving
better overall adhesion. As stated earlier, proper molding can eliminate stress as
well as the need for a predip in the above case.
The second use of predips is to attack or swell the surface of normally hard to
etch plastics. These materials include polypropylene, polycarbonate, polysulfone, and others. This swelling action of the predip enables the chemical
etchant to readily attack the surface of the normally resistant resin. Generally, a
different solvent is needed for each resin in order to be successful.
Troubleshooting the predips involves analysis to insure proper balance.
ETCHANTS
Etchants are usually strong oxidizing solutions that eat away the plastic Surface
to varying degrees, accomplishing two purposes. First, the surface area is
greatly increased, making the part turn from a hydrophobic (water-hating) to a
hydrophilic (water-loving) material. Second, the microscopic holes left in the
surface of the plastic by the etchant provide the bonding sites for the deposited
metal. These sites are needed for adhesion between the plastic and the metal.
When ABS is exposed to an etchant, the butadiene is selectively removed, thus
leaving small holes or bonding sites. Commonly used etchants for ABS are:
Chromium trioxide-375 to 450 g/L
Sulfuric acid-335 to 360 g/L
This is the so-called chrome-sulfuric version, or,
384
ELECTROLESS PLATING
Cr+
reduction
- 3e- - Crth
oxidation
at the anode.
Using this method and a flash evaporator for the rinses results in a tight closed
loop system. One problem with this system is that all impurities in the etch such
as dissolved metals and titanium dioxide filler are returned to it. This causes a
build-up of impurities that eventually results in problems such as stardusting, a
fine roughness usually occurring on the shelf of a part.
The etchant is the most critical step in obtaining an acceptable finished part.
An underetched part can result in poor adhesion and possible skip plate.
Overetching a part can degrade the surface causing poor adhesion and
cosmetics.
Some problems that may be encountered are shown in Table 14.1.
Plating on Plastics
385
Table 14.1
Troubleshooting Etchants for Electroless Nickel
Problem
Cause
Solution
Underetching
Increase time
Poor adhesion
High Cr3
Check chemistry
Overetching
Decrease time
Decrease temperature
Check chemistry
Stardusting or roughness on
part
TiO, build-up
Poor molding
Mold release on part
Lower temperature
Check rack tension and
adjust or change rack
Increase temperature
electroless nickel
Poorsurface-low adhesion with
black layer on plastic and
metal
NEUTRALIZERS
After etching, the parts are thoroughly rinsed in water and then put into a
neutralizer. These are materials such as sodium bisulfite or any of the
proprietary products available that are designed to eliminate excess etchant
from the parts and racks, usually by chemical reduction. Hexavalent chromium
( C P ) is harmful in the ensuing steps. Even with excellent rinsing, etchant may
be trapped in blind holes. If this is not rinsed out or reduced to trivalent
chromium (Cri3), skip plate can occur as a result of bleedout of etchant in
subsequent steps.
Neutralizers are generally cheap to make up and are usually dumped and
remade on a regular basis. They are usually run at 70 to 110 F for 1 to 3 minutes
with air agitation. Troubleshooting is relatively simple, as seen in Table 14.2.
386
ELECTROLESS PLATING
Table 14.2
Troubleshooting Neutralizers for Electroless Nickel
Problem
Cause
Solution
Check chemistry
Check bath color-if
orangish, dump
Increase air and/or
temperature
Check rack tips
Bleed-out of hexavalent
chromium
As above
PREACTIVATORS
After neutralization and rinsing, a preactivator may be employed for certain
resins, such as polypropylene or polyphenylene oxide. These proprietary
materials are designed primarily to enhance activator absorption. Generally
they do not reduce hexavalent chromium. Preactivators help make otherwise
unplateable resins plateable by conditioning the resin surface by forming a film
or changing the surface charge. One must be careful in selecting a preactivator,
as excessive conditioning can lead to resist overplate and rack plating. Typical
parameters for these baths are 70 to 120" F for 1 to 3 minutes.
if the partsarefullycovered out of the electroless plating bath, the preactivator
is doing its job. Troubleshooting guidelines for preactivators are given in Table
14.3.
ACTIVATORS
Activators or catalysts, as they are sometimes called, are materials that in most
cases contain some precious metal such as palladium, platinum or gold.
The early version of activation was a two-step procedure. Step 1 was a
stannous chloride/hydrochloric acid solution in which the stannous ion (Sn")
was adsorbed onto the surface. The part was then rinsed well. Step 2 was a
palladium chloride/hydrochloric acid solution which, when the part with the
stannous ion was immersed in it, caused the Pdt22 ion to be reduced to Pd"
according to the following reaction:
Sn"
+ Pd''
- Sn"
+ Pd"
PI
Plating on Plastics
387
Table 14.3
Troubleshooting Preactivators for Electroless Nickel
Problem
Cause
Solution
Bleed-out of Cr'6
Preactivator out of spec
The Pd sites formed the catalytic surface needed to deposit the chemical
nickel. Present day catalysts are essentially the earlier two step version
combined. In other words, the palladium chloride, stannous chloride and
hydrochloric acid are in one solution. What we get is a palladium-tin hydrosol,
which is a solution of complex ions and colloidal particles whose activity and
stability depend on the chloride and stannous ion concentrations (6,7).
A typical working activator bath today would consist of the following:
Stannous chloride-6 g/L
Palladium (metal)-20 to 100 ppm
Chloride ion-2.5 to 3.5 N
The chloride ion may be maintained with hydrochloric acid or sodium chloride.
When processing a part, the first noticeable change will be evident after the
activator. The part acquires a tan to brownish color. This coloration, unless the
part is black, can easily be seen and is an indication the activator isworking. The
absence of a coloring on the part usually indicates a problem that can result in
skip plate and possibly low adhesion.
The primary purpose of activators is to provide catalytic sites on the plastic
surface. The usual operating conditions for the activator bath are 80 to 95" F for 2
to 5 minutes. Because this is the most expensive bath in the system, care is taken
to analyze regularly. Even when the bath is not being used, analysis for tin is
required, as tin is continually oxidized to the stannic ion (Sn")). When almost all
the stannous is oxidized, the bath "falls out".
Troubleshooting tips for the bath are given in Table 14.4.
388
ELECTROLESS PLATINQ
~~
~~
Table 14.4
Troubleshooting Activators for Electroless Nickel
Problem
Cause
Solution
Roughness on parts
High temperature
High concentration
Lower temperature
Check chemistry
Low temperature
Low concentration
Raise temperature
Check chemistry
Stress in Dart
High temperature
Lower temperature
Check chemistry
Low temperature
Raise temperature
Check chemistry
Agitate parts
ACCELERATORS
After rinsing following theactivator, metallic palladium is present on the surface
of the part surrounded by hydrolyzed stannous hydroxide. Theexcess stannous
hydroxide must be removed from the part before the palladium can act as a
catalyst.
The role of an accelerator is just that. It is to remove the excess tin from the
part while leaving the palladium sites intact for the deposition of the electroless
bath. Tin will inhibit the action of the electroless bath, resulting in skip plate.
This step is important, as too short a time in bath, as well as too long a time, can
cause skip plate. These baths are usually organics or mineral acids.
The biggest problem with accelerators is the effect of metallic contamination.
Most proprietary baths contain a built-in reducer to eliminate any hexavalent
chromium. Chromium may be dragged through the line in blind holes or bad
Plating on Plastics
389
rack tips. These contaminants, such as hexavalent chromium, iron, and other
metals, can cause the accelerator to become over-aggressive. This causes the
accelerator to remove not only the stannous tin, but also palladium. When this
occurs, skip plate can be the result. Some materials are designed to minimize the
effect of these contaminants.
Accelerators are usually run at 110 to 140" F for 2 to 5 minutes. Some
problems that may occur are as shown in Table 14.5.
Table 14.5
Troubleshooting Accelerators for Electroless Nickel
Problem
Cause
Solution
Over-acceleration
High temperature
Check chemistry
Lower temperature
Lower time
Under-acceleration
Low temperature
Check chemistry
Raise temperature
Increase time
Agitate parts in solution
High temperature
Check chemistry
ELECTROLESS PLATING
After rinsing, the parts are put into the final step in the preplate cycle. This is the
electroless bath, which deposits a thin, adherent metallic film, usually copper or
nickel, on the plastic surface by chemical reduction. This is accomplished by
using a semi-stable solution containing a metal salt, a reducer, a complexor for
the metal, a stabilizer and a buffer system. When idle, the baths are stable, but
ELECTROLESS PLATING
390
CU"
[41
Plating on Plastics
391
Table 14.6
Troubleshooting Electroless Nickel Plating Baths
Problem
Cause
Solution
Skip plate
Low reducer
Low temperature
Contamination
Check chemistry
Raise temperature
Check for contamination
Roughness
Particulates in bath
Filter bath
Install spray rinse after bath
Agitate work
Burn-off in strike
Increase time
Increase temperature
Check bath rate
Check chemistry
Check racks
Bath sluggish
High temperature
High reducer
Palladium contamination
Low complexor
Tank plate-out
Low stabilizer
Lower temperature
Check chemistry
pH out of range
High stabilizer
Low reducer
Low temperature
Contamination
Check chemistry
Raise temperature
Check for contamination
solution. Normally 0.0003 to 0.0008 in. of semi-bright nickel are plated, followed
by an electrolytic bright nickel plating solution, which will deposit about 0.0002
to 0.0004 in. of metal. The deposit from the latter bath is generally very specular.
For the best corrosion resistance, a layer of about 0.0001 in. of microporous
nickel can be electrolytically deposited on the bright nickel, followed by an
electrolytic chromium deposit from either a hexavalent or trivalent bath. This
layer,onlyabout5to 10millionthsofan inch thick, isthefinalstepinproducinga
finished part. Be aware that if the surface of the substrate is pitted, scratched,
dented, or marred in any way, electroplating will enhance these blemishes. Care
must be taken when handling and racking plastic parts to avoid damaging them
(1). Parts are usually plated to meet various service conditions, which are:
SC7-Mild. Includes indoor exposure to normally dry, warm atmosphere
and subject to minimal wear and abrasion.
SCP-Moderate. Indoor exposure where moisture condensation occurs.
Examples are kitchen and bathroom fixtures.
ELECTROLESS PLATING
392
Table 14.7
Troubleshooting Electroless Copper Platlng Baths
Problem
Bath slow-dark
deposits
Bath overactive-dark,
deposits
grainy
Roughness on parts-precipitate
forms when additions are
made
Cause
Solution
Low copper
Low caustic
Low formaldehyde
High stabilizer
Low tern perature
Too much air
High caustic
High formaldehyde
Low stabilizer
High temperature
High loading factor
Tank plate-out
Low complexor
Increase temperature
Decrease air
Check chemistry, plating rate
Add stabilizer
Lower temperature
Decrease work in bath
Clean and strip tank
Increase air
Check chemistry
393
Plalmg on Plasfics
Table 14.8
Minimum Plating Thickness Requirements
Under Various Service Conditions
Total
Service
Copper
nickel
Chromium
SCl
sc2
0 6 mils
0 fi mils
0 6 mils
0 6 mils
-03 mils
10 pin
10 pin
10 Uin
sc3
sc4
0 6 mils
0 9 mils
1 2 mils
10 p i n
Thermal Cycling
Because various plastics have various coefficients of thermal expansion, some
do not readily pass this test, even though adhesion is good. To counteract this,
more copper may be plated on the part to act as a cushion.
I n thermal cycling, the part is first put into an air-circulating oven for 1 hr at
180" F. The part is then removed and held at room temperature for 15 min. The
part is then placed into a cold chamber at -20' F for 1 hr. This is repeated a
minimum of three times. Loss of adhesion, blisters, or cracking indicate a failure.
Part design and molding can also affect thermal cycling. This test was designed
for ABS and does not necessarily apply to other substrates.
C.A.S.S.
The C.A.S.S. ( l o ) , or Copper Accelerated Acetic Acid Salt Spray Test, checks
the corrosion resistance of the final plate. This test is generally performed in a
cabinet, according to ASTM 6-368. Requirements are as follows:
SC1-None
SC2-1 8-hr cycle
SC3--2 16-hr cycles
SC4-3 16-hr cycles
Failure is indicated by white or green corrosion.
The above are the most widely used tests. Others include:
N.S.S. (10)-5 percent neutral salt spray, which is also used in another
corrosion test-ASTM 6-1 17.
Plate thickness-Checking plate thicknesses by either a destructive or
non-destructive method.
Outdoor exposure-Setting industrial samples in environments they will be
normally exposed to.
394
ELECTROLESS PLATING
C.S.A. 8-125, LRP-15 (11)-A Canadian test for plumbing goods that
includes 450 cycles of dipping the parts in alternating hot (175' F) and ambient
(70' F) water baths for 40 seconds. One cycle is 40 seconds in the hot water, and
40 seconds in the ambient water.
New technologies in plating on plastics are leaning toward plating engineering
resins for printed circuits. Resins with high strength and heat distortion are also
being looked at to replace metals i n functional as well as decorative roles.
0
0
0
Airplanes
Computers
Electric motors
Ignition systems
Power lines
Radio and television transmitters
Videogames
Lightning
Pfafrng on Plastics
Fig. 14.8-Sources
395
copper and/or nickel. The process used would be similar to that presently used
to plate on plastics. Steps would include:
1.
2.
3.
4.
5.
396
ELECTHOLESS PLATING
6. Rinse
7. Preactivate (if necessary)
8. Rinse
9. Activate
10. Rinse
11. Accelerate
12. Rinse
13. Electroless copper
14. Rinse
15. Activate
16. Rinse
17. Electroless nickel
18. Rinse
19. Dry
The electroless copper (Step 13) generally would be deposited to a thickness
of 40to60millionthsof an inch.Thecopperisaveryeffectiveshieldby itself, but
because of its corrosive nature, an electroless nickel (Step 17) topcoat of about
10 to 20 millionths of an inch is applied to retard the corrosion. Nickel can be
used by itself, but itsshielding effectiveness is much lower than that of copper or
copper/nickel. It is also an excellent base i f the article is to be painted.
Electroless shielding is applied i n general to both sides of a plastic enclosure,
which assures the best protection against the transmission of electromagnetic
radiation (Fig. 14.11). Still, techniques have been developed to apply the
electroless coatings only to the inside of the enclosure, to allow the use of
color-molded finishes.
Shielding effectiveness is the ability of the method used to absorb or reflect
the unwanted "noise" signal, typically over a frequency range of 14 K H z to 1
Plating on Plasfics
397
Table 14.9
EM1 Shielding Effectiveness
Attenuation
Shielding
effectiveness
0 to 10 dB
10 to 30 dB
30 to 60 dB
60 to 90 dB
90 to 120 dB and above
Very little
Minimal
Average
Above average
Maximurntostate-of-the-art
ELECTROLESS PLATING
398
Table 14.10
Coating Techniques for EM1 Shielding
Of Plastic Housing
Method
Advantages
Disadvantages
Good conductivity
Hard, dense coat
Effective over a wide
frequency range
Good conductivity
Conventional equipment
Resists flaking
Conductive oxide
Easy to apply
Expensive
Conventional equipment
Conductive painfs
Silver
Nickel
Resists flaking
Economical
Easy to apply
Copper
Conventional equipment
Resists flaking
Economical
Easy to apply
Vacuum metallizing
Good adhesion
Good for all plastics
Not limited to simple
designs
Familiar technology
Cathode sputtering
Good conductivity
Good adhesion
Expensive equipment
Microscopic cracking
May distort housing
High power needed
Foil application
Conductive plastics
No secondary operation
Material expensive
Poor attenuation
Surface usually poor
Silver reduction
Good conductivity
Low initial cost
Tendency to oxidize
Difficult to mask
Multiple-step process
Uniform thickness
Good for all size and shape
parts
Good conductivity
Resists chipping
Can be electroplated for
metallic appearance
Can be painted
Plating on Plastrcs
399
REFERENCES
1. J.L. Adcock, Electroplating Plastics, American Electroplaters and Surface
Finishers Society.
2. Design and Converting Techniques for Plating Cycolac Brand ABS, EP3510, Marbon Division, Borg-Warner Corporation, Technical Bulletin, (May
1967).
3. Glossary of Terms, Thomas H. Ferrigno, ed.; Fillers and Additives
Committee, Society of Plastic Industry.
4. Plating on Plastics 11, Technical paper-Society of Plastics Engineers,
Connecticut Section.
5. A. Rantell and A. Holzman, Mechanism of Activation of Polymer Surfaces by
Mixed Stannous Chloride/Palladium Chloride Catalysts, Division of Metal
Sciences, Polytechnic of the South Bank, London SElOAA (February 12,
1973).
6. C.H. deMinjer and P.F.J. v.d. Boom, The Nucleation with SnCI?-PdCI
Solutions of Glass Before Electroless Plating, Phillips Research Laboratories,
Einhaven, Netherlands.
7. R.G. Wedel, Plating, 62(3), 235 (Mar. 1975).
8. R.G. Wedel, ibid., 62(1), 40 (Jan. 1975).
9. Metal Finishing Guidebook-Directory Issue, Metals and Plastics Publications, Inc., One University Plaza, Hackensack, NJ 07601.
10. ASTM 8-117, 15-22; ASTM 8-368, 164-169, Part 9, American Society for
Testing and Materials, Philadelphia, PA.
11. CSA Standard 8-125, LRP-15, Canadian Standards Association, Ontario,
Canada.
12. E.B. Saubestre, Plating, 52(10), 982 (Oct. 1965).
13. E.B. Saubestre, Modern Electroplating, p. 636 (1974).
14. W.P. Innes, Plating, 58(10), 1002 (Oct. 1971).
15. H.Narcus, ibid., 55(8), 816 (Aug. 1968).
16. Plating of Plastics with Metals, Chemical Technology Review, Noyes Data
Corporation, Vol. 27 (1974).
17. Plating on Plastics, Extended Abstracts (1965-1971), The International
Nickel Company, Inc.
18. James L. Adcock, Products Finishing, p. 51 (May 1982).
19. Gerald Krulik, lndustrial Finishing, p. 16 (May 1983).
20. Gerald Krulik, Products Finishing, p. 49 (Oct. 1983).