Cu hi nh trong Group

Cu 1: (23/1/2016) Hn hp X gm Cl2 v H2. Cho 6.72 lt hn hp X ra ngoi nh

sng thu c hn hp Y trong V HCl = 2/3 V hn hp Y v th tch ca Cl 2
trong hn hp Y bng 50% th tch Cl 2 trong hn hp X. Tnh % th tch tng kh
trong hn hp X
Gii

H 2 Cl 2
2HCl
ban u:
a 6,72-a
phn ng:
x
x 2x
sau phn ng: a- x 6,72-a- x 2x

V HCl trong Y chim 2/3 hn hp Y, ta c:

%Cl2 trong Y bng Cl2 trong X, ta c :

Vy %H2 = 33.33% ; %Cl2 = 66.67%

2x
2
x 2.24(l)
6.72 3

6.72 a x 1
a 2.24 l
6.72 a
2

Cu 27: Ha tan 17,32 gam hn hp X gm Mg, Fe 3O4 v Fe(NO3)2 cn va ng

dung dch hn hp gm 1,04 mol HCl v 0,08 mol HNO 3, un nh thu c dung
dch Y v 2,24 lt hn hp kh Z (ktc) c t khi hi i vi H 2 l 10,8 gm hai kh
khng mu trong c mt kh ha nu ngoi khng kh. Cho dung dch Y tc
dng vi mt lng dung dch AgNO 3 va thu c m gam kt ta v dung
dch T. Cho dung dch T tc dng vi mt lng d dung dch NaOH, lc kt ta
nung n n khi lng khng i thu c 20,8 gam cht rn. Cc phn ng
xy ra hon ton. Gi tr ca m l
A. 150,32.
153,56.

B. 151,40.

C. 152,48.

D.

Gii.
Bc 1.
17,32 gam X gm: (Mg : a mol, Fe 3O4 : b mol, Fe(NO3)2 : x mol) to 0,07 mol NO,
0,03 mol H2. Dung dch Y cha MgCl2, FeCl2, FeCl3, NH4Cl. 20,8 gam cht rn gm
MgO (a mol) v Fe2O3 (1,5b + 0,5x mol).
Bc 2.
Da vo bo ton O th s mol H2O to thnh bng 4b + 6x + 0,17.
Da vo bo ton H th s mol NH4Cl to thnh bng 0,18 - 2b - 3x.
Bc 3.
24a + 232b + 180x = 17,32
2x + 0,08 = 0,07 + 0,18 - 2b - 3x

(theo bo ton N)

40a + 80(3b + x) = 20,8

Tnh c a = 0,4; b = 0,01; x = 0,03.
Da vo bo ton nguyn t Cl tnh c dung dch Y c 0,4 mol MgCl 2, 0,01 mol
FeCl2 , 0,05 mol FeCl3 ; 0,07 mol NH4Cl nn suy ra kt ta gm AgCl 1,04 mol v
Ag 0,01 mol.
Vy m gam kt ta bng 150,32 gam.