Calculation of vapour pressure from EOS

Input , ,
R-K Equation parameters , , , , = ()^(-1/2)
EOS parameters a, b, , q
Method Employed

1. Do trial and error for until (saturation condition)
2. Since depend on previous values, we take an initial guess for them
Value at T = 0.85
= 17.9 bar
Literature reported = 18.7 bar at T =
= 0.66 bar

Use Wilson Equation to plot T-x-y and P-x-y graphs

Here the working equation is 12.12 Given T, plot P-x-y
is fixed for given T
/P
Iterate over until + = 1
12.12 Given P, plot T-x-y
varies as T varies
At each T, is calculated
/P
Iterate over until + = 1