B GIO DC V O TO

CHNH THC

( thi c 05 trang)

THI TUYN SINH I HC, CAO NG NM 2008

Mn thi: HO HC, khi B
Thi gian lm bi: 90 pht.
M thi 195

H, tn th sinh:.......................................................................
S bo danh:............................................................................

Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:

H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39;
Ca = 40; Fe = 56; Cu = 64; Zn = 65; As = 75; Br = 80; Rb = 85,5; Ag = 108; Ba = 137.
PHN CHUNG CHO TT C TH SINH (44 cu, t cu 1 n cu 44):
Cu 1: Cho bit cc phn ng xy ra sau:
2FeBr2 + Br2 2FeBr3
2NaBr + Cl2 2NaCl + Br2
Pht biu ng l:
A. Tnh kh ca Cl mnh hn ca Br .
B. Tnh oxi ha ca Br2 mnh hn ca Cl2.
2+
3+
C. Tnh kh ca Br mnh hn ca Fe .
D. Tnh oxi ha ca Cl2 mnh hn ca Fe .
Cu 2: Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l:
A. P, N, F, O.
B. N, P, F, O.
C. P, N, O, F.
D. N, P, O, F.
Cu 3: Nguyn tc luyn thp t gang l:
A. Dng O2 oxi ho cc tp cht Si, P, S, Mn, trong gang thu c thp.
B. Dng cht kh CO kh oxit st thnh st nhit cao.
C. Dng CaO hoc CaCO3 kh tp cht Si, P, S, Mn, trong gang thu c thp.
D. Tng thm hm lng cacbon trong gang thu c thp.
Cu 4: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d),
sau khi cc phn ng kt thc thu c sn phm l:
A. H2N-CH2-COOH, H2N-CH2-CH2-COOH.
+
+
B. H3N -CH2-COOHCl , H3N -CH2-CH2-COOHCl .
+
+
C. H3N -CH2-COOHCl , H3N -CH(CH3)-COOHCl .
D. H2N-CH2-COOH, H2N-CH(CH3)-COOH.
Cu 5: Cho s chuyn ho sau:
+o Br (1:1mol), Fe,
t

+ HCl (d)
+ NaOH (d), to ,
p

Toluen

Z.

X
2
Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm
A. m-metylphenol v o-metylphenol.
B. benzyl bromua v o-bromtoluen.
C. o-bromtoluen v p-bromtoluen.
D. o-metylphenol v p-metylphenol.
2+
2+
2Cu 6: Mt mu nc cng cha cc ion: Ca , Mg , HCO3 , Cl , SO4 . Cht c dng lm
mm mu nc cng trn l
A. Na2CO3.
B. HCl.
C. H2SO4.
D. NaHCO3.
Cu 7: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng
o
ng vi H2SO4 c 140 C. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v
1,8 gam nc. Cng thc phn t ca hai ru trn l
A. CH3OH v C2H5OH.
B. C2H5OH v C3H7OH.
C. C3H5OH v C4H7OH.
D. C3H7OH v C4H9OH.
Cu 8: Cho cc cht: ru (ancol) etylic, glixerin (glixerol), glucoz, imetyl ete v axit fomic. S
cht tc dng c vi Cu(OH)2 l
A. 1.
B. 3.
C. 4.
D. 2.

Trang 1/5 - M thi 195

Cu 9: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm
X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3)
trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l
A. 76,6%.
B. 80,0%.
C. 65,5%.
D. 70,4%.
Cu 10: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol)
etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l
0,8 g/ml)
A. 5,4 kg.
B. 5,0 kg.
C. 6,0 kg.
D. 4,5 kg.
Cu 11: Nung mt hn hp rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh (d).
Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l
Fe2O3 v hn hp kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia
a v b l (bit sau cc phn ng, lu hunh mc oxi ho +4, th tch cc cht rn l khng ng k)
A. a = 0,5b.
B. a = b.
C. a = 4b.
D. a = 2b.
Cu 12: Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi
cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam
FeCl3. Gi tr ca m l
A. 9,75.
B. 8,75.
C. 7,80.
D. 6,50.
+
2+
2+
3+
2+
2Cu 13: Cho dy cc cht v ion: Cl2, F2, SO2, Na , Ca , Fe , Al , Mn , S , Cl . S cht v ion
trong dy u c tnh oxi ho v tnh kh l
A. 3.
B. 4.
C. 6.
D. 5.
Cu 14: Phn ng nhit phn khng ng l
o
o
A. 2KNO3
2KNO2 + O2.
B. NH4NO2
N2 + 2H2O.

t
t
o
o
NaOH + CO2.
C. NH4Cl
NH3 + HCl.
D. NaHCO3
t
t

Cu 15: Cho dy cc cht: KAl(SO4)2.12H2O, C2H5OH, C12H22O11 (saccaroz), CH3COOH,

Ca(OH)2, CH3COONH4. S cht in li l
A. 3.
B. 4.
C. 5.
D. 2.
Cu 16: Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton
thu c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi
dung dch X l
A. 8,88 gam.
B. 13,92 gam.
C. 6,52 gam.
D. 13,32 gam.
Cu 17: Thnh phn chnh ca qung photphorit l
A. Ca3(PO4)2.
B. NH4H2PO4.
C. Ca(H2PO4)2.
D. CaHPO4.
Cu 18: un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong iu kin nhit
thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y l
A. C3H8O.
B. C2H6O.
C. CH4O.
D. C4H8O.
Cu 19: Cho cc phn ng:
Ca(OH)2 + Cl2 CaOCl2 + H2O
2H2S + SO2 3S + 2H2O
o

t
2NO2 + 2NaOH NaNO3 + NaNO2 + H2O
4KClO3
KCl + 3KClO4

O3 O2 + O
S phn ng oxi ho kh l
A. 5.
B. 2.
C. 3.
D. 4.
Cu 20: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml
dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht
rn. Cng thc cu to thu gn ca X l
A. HCOOH3NCH=CH2.
B. H2NCH2CH2COOH.
C. CH2=CHCOONH4.
D. H2NCH2COOCH3.

Cu 21: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau
khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon
ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch
kh u o ktc)
A. CH4 v C2H4.
B. CH4 v C3H4.
C. CH4 v C3H6.
D. C2H6 v C3H6.
Cu 22: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t
ca X l
A. C6H8O6.
B. C3H4O3.
C. C12H16O12.
D. C9H12O9.
Cu 23: Cho cn bng ho hc: N2 (k) + 3H2 (k) U 2NH3 (k); phn ng thun l phn ng to nhit.
Cn bng ho hc khng b chuyn dch khi
A. thay i p sut ca h.
B. thay i nng N2.
C. thay i nhit .
D. thm cht xc tc Fe.
Cu 24: Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc dng ht vi
dung dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l
A. Na.
B. K.
C. Rb.
D. Li.
Cu 25: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi
xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %)
A. 55 lt.
B. 81 lt.
C. 49 lt.
D. 70 lt.
Cu 26: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh
ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau
khi kt thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 11,5.
B. 10,5.
C. 12,3.
D. 15,6.
Cu 27: Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va
vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc
cu to thu gn ca X l
A. CH3OOC(CH2)2COOC2H5.
B. CH3COO(CH2)2COOC2H5.
C. CH3COO(CH2)2OOCC2H5.
D. CH3OOCCH2COOC3H7.
Cu 28: Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng
a
+
(mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l (bit trong mi dung dch [H ][OH ] =
-14
10 )
A. 0,15.
B. 0,30.
C. 0,03.
D. 0,12.
Cu 29: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm
KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng
thc phn t ca X l
A. C2H5COOH.
B. CH3COOH.
C. HCOOH.
D. C3H7COOH.
Cu 30: Cht phn ng vi dung dch FeCl3 cho kt ta l
A. CH3NH2.
B. CH3COOCH3.
C. CH3OH.
D. CH3COOH.
Cu 31: Cho cc phn ng sau:
to
H2S + O2 (d)
Kh X + H2O

o
NH3 + O2 850 Kh Y + H2O
C

Pt

NH4HCO3 + HCl long Kh Z + NH4Cl + H2O

Cc kh X, Y, Z thu c ln lt l:
A. SO3, NO, NH3.
B. SO2, N2, NH3.
C. SO2, NO, CO2.
D. SO3, N2, CO2.
Cu 32: Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr sinh ra 8,96 lt kh
CO2 ( ktc). Thnh phn phn trm v khi lng ca CaCO3.MgCO3 trong loi qung nu trn l
A. 40%.
B. 50%.
C. 84%.
D. 92%.
Cu 33: Cho cc phn ng:
to
HBr + C2H5OH
C2H4 + Br2

2 4

C H + HBr

CH

Br

askt (1:1 mol)

S phn ng to ra C2H5Br l
A. 4.
B. 3.

C. 2.

D. 1.

Cu 34: Tin hnh hai th nghim sau:

- Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M;
- Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M.
Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng
nhau. Gi tr ca V1 so vi V2 l
A. V1 = V2.
B. V1 = 10V2.
C. V1 = 5V2.
D. V1 = 2V2.
Cu 35: Polime c cu trc mng khng gian (mng li) l
A. PE.
B. amilopectin.
C. PVC.
D. nha bakelit.
Cu 36: Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3. Trong oxit m R
c ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R l
A. S.
B. As.
C. N.
D. P.
Cu 37: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia
phenol vi
A. dung dch NaOH. B. Na kim loi.
C. nc Br2.
D. H2 (Ni, nung nng).
Cu 38: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba
trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit ,
p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l
A. 3.
B. 4.
C. 2.
D. 5.
Cu 39: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch
sau phn ng thu c khi lng x phng l
A. 17,80 gam.
B. 18,24 gam.
C. 16,68 gam.
D. 18,38 gam.
Cu 40: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S
cht trong dy tham gia c phn ng trng gng l
A. 3.
B. 6.
C. 5.
D. 4.
Cu 41: Cho 0,1 mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c c cc cht:
A. K3PO4, K2HPO4.
B. K2HPO4, KH2PO4. C. K3PO4, KOH.
D. H3PO4, KH2PO4.
Cu 42: Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2
phn
ng. Tn gi ca este l
A. metyl fomiat.
B. etyl axetat.
C. n-propyl axetat.
D. metyl axetat.
Cu 43: Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c
cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l
A. 85.
B. 68.
C. 45.
D. 46.
Cu 44: Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong
dung dch
A. NaOH (d).
B. HCl (d).
C. AgNO3 (d).
D. NH3(d).
PHN RING
Th sinh ch c lm 1 trong 2 phn: phn I hoc phn II
Phn I. Theo chng trnh KHNG phn ban (6 cu, t cu 45 n cu 50):
Cu 45: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH
(phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l
A. 6.
B. 8.
C. 7.
D. 5.
Cu 46: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp
gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO)
A. 1,0 lt.
B. 0,6 lt.
C. 0,8 lt.
D. 1,2 lt.
Cu 47: Cho cc phn ng:
(1) O3 + dung dch KI
o

t
(3) MnO2 + HCl c

Cc phn ng to ra n cht l:
A. (1), (2), (3).
B. (1), (3), (4).

(2) F2 + H2O

(4) Cl2 + dung dch H2S

C. (2), (3), (4).

D. (1), (2), (4).

Cu 48: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2

lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l
A. C2H6.
B. C2H4.
C. CH4.
D. C3H8.
Cu 49: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi
lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng
A. ankan.
B. ankaien.
C. anken.
D. ankin.
Cu 50: Tin hnh bn th nghim sau:
- Th nghim 1: Nhng thanh Fe vo dung dch FeCl3;
- Th nghim 2: Nhng thanh Fe vo dung dch CuSO4;
- Th nghim 3: Nhng thanh Cu vo dung dch FeCl3;
- Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl.
S trng hp xut hin n mn in ho l
A. 1.
B. 2.
C. 4.
D. 3.
Phn II. Theo chng trnh phn ban (6 cu, t cu 51 n cu 56):
+ Cu 51: Mui C6H5N2 Cl (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng
o
+ vi NaNO2 trong dung dch HCl nhit thp (0-5 C). iu ch c 14,05 gam C6H5N2 Cl
(vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l
A. 0,1 mol v 0,4 mol. B. 0,1 mol v 0,2 mol. C. 0,1 mol v 0,1 mol. D. 0,1 mol v 0,3 mol.
Cu 52: Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2
l
A. 1.
B. 3.
C. 2.
D. 4.
Cu 53: Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt c dng rc
ln thu ngn ri gom li l
A. vi sng.
B. ct.
C. mui n.
D. lu hunh.
Cu 54: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z
u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm
chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l:
A. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO.
B. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH.
C. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH. D. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO.
o
o
o
Cu 55: Cho sut in ng chun E ca cc pin in ho: E (Cu-X) = 0,46V; E (Y-Cu) = 1,1V;
o
E (Z-Cu) = 0,47V (X, Y, Z l ba kim loi). Dy cc kim loi xp theo chiu tng dn tnh kh t tri
sang phi l
A. Z, Y, Cu, X.
B. X, Cu, Z, Y.
C. Y, Z, Cu, X.
D. X, Cu, Y, Z.
Cu 56: Cho mt lng bt Zn vo dung dch X gm FeCl2 v CuCl2. Khi lng cht rn sau khi
cc phn ng xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn phn dung dch
sau phn ng thu c 13,6 gam mui khan. Tng khi lng cc mui trong X l
A. 13,1 gam.
B. 17,0 gam.
C. 19,5 gam.
D. 14,1 gam.
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