Hasil Percobaan

Larutan pada bagian

anoda Zn/Zn2+ (M)
1,0
1,0
1,0
1,0

Larutan pada bagian

katoda Cn/Cn2+
1,0
0,1
0,01
0,001

A. Analisis Data
1.) Persamaan Reaksi
Anoda : Zn
Zn2+ + 2e2+
Katoda : Cu + 2e Cu
Zn + Cu2+ Zn2+ + Cu
2.) Perhitungan
Diketahui :
[Zn2+ ] = 1,0 M
[Cu2+ ] = 1,0 M
Zn

2+

Cu

2+

log

1,0 M
= log 1,0 M

= log 1
= 0
Diketahui :
[Zn2+ ] = 1,0 M
[Cu2+ ] = 0,1 M

Esel
(Volt)
0,93
0,90
0,87
0,82

Zn

2+

Cu

2+

log

1,0 M
= log 0,1 M

= log 10
= 1
Diketahui :
[Zn2+ ] = 1,0 M
[Cu2+ ] = 0,01 M
Zn

2+

Cu

2+

log

log

1,0 M
0,01 M

= log 100
= 2
Diketahui :
[Zn2+ ] = 1,0 M
[Cu2+ ] = 0,001 M
Zn

2+

Cu

2+

log

1,0 M
= log 0,001 M

= log 1000

= 3

3.) Membuat grafik hubungan antara Esel

No.

1.
2.
3.
4.

Esel
(Volt)

Zn

2+

Cu
terhadap

2+

log

Zn

2+

Cu

2+

log

0,93
0,90
0,87
0,82

grafik hubungan antara Esel

0
1
2
3
Zn

2+

Cu
terhadap

2+

log

0.94
f(x) = - 0.04x + 0.93
R = 0.98

0.92
0.9
0.88
0.86
Esel 0.84
0.82
0.8
0.78
0.76
0

0.5

1.5

2.5

Dari grafik diatas dapat ditentukan nilai slop dan intersep

Slop berdasarkan teori
R = 8,314
T = 250C = 293K
F = 96500
Slop =

RT
nF

x 2,303

8,314 .298
2.96500

x 2,303

= -0,03
Intersep berdasarkan teori : +1,10
Slope berdasarkan percobaan
Diketahui :
y1 = 0,93
y2 = 0,82
x1 = 3
x2 = 0
y 2 y 1
slope = x 2x 1

0,820,93
30

3.5

= -0,0367
Intersep berdasarkan percobaan : + 0,934
Persamaan Nernst
1.) Persamaan Nernst berdasarkan teori

Esel = E0sel -

Zn

2+

Cu

2+

RT
2,303 log
nF

= 1,10 0,013 x 2,303 x 0

= 1,10

Esel = E0sel -

Zn

2+

Cu

2+

RT
2,303 log
nF

= 1,10 0,013 x 2,303 x 1

= 1,07

Esel = E0sel -

Zn

2+

Cu

2+

RT
2,303 log
nF

= 1,10 0,013 x 2,303 x 2

= 1,04

Esel = E0sel -

Zn

2+

Cu

2+

RT
2,303 log
nF

= 1,10 0,013 x 2,303 x 3

= 1,01
2.) Persamaan Nernst berdasarkan percobaan
Zn

2+

Cu

Esel = E0sel 2+

RT
2,303 log
nF
= 0,934 0,013 x 2,303 x 0
= 0,934

Zn

2+

Cu

2+

Esel = E0sel -

RT
2,303 log
nF
= 0,934 0,013 x 2,303 x 1
= 0,904
Zn

2+

Cu

2+

Esel = E0sel -

RT
2,303 log
nF
= 0,934 0,013 x 2,303 x 2
= 0,874
Zn

2+

Cu

2+

Esel = E0sel -

RT
2,303 log
nF
= 0,934 0,013 x 2,303 x 3
= 0,844
Penentuan % Error
1) % Error E0sel = | E0sel teori - E0sel percobaan | x 100%
= (1,10 0,934) x 100%

= 16,6 %
2) % Error E0slope = | E0slope teori - E0slope percobaan | x 100%
= (-0,03 (-0,0367) x 100%
= 0,67 %
3) % Error Esel
% Error Esel = | E sel teori E sel percobaan | x 100%
= (1,10 0,934) x 100%
= 16,6%
% Error Esel = | E sel teori E sel percobaan | x 100%
= (1,07 0,934) x 100%
= 13,6 %
% Error Esel = | E sel teori E sel percobaan | x 100%
= (1,04 0,934) x 100%
= 10,6 %
% Error Esel = | E sel teori E sel percobaan | x 100%
= (1,01 0,934) x 100%
= 7,6 %