Name: SaKshi Agrauoal Date 12/02/2021

Registrahon no:208ce 2932

Experiment- 3

ConstrvcHon and oorking Of a n Zn- Cu electrochermical

Cell

Observaion and Calwla ion

Table I: ¬MF meagured for various ConcentraHorn Of
M/M Systemn

EM/Mt
electrodellecouye ceu (V)EM/m EMIM Averoge2
etecMolye Conc N) ceutcajomel CFromei] E 'm*

0.01N
-0-629-0 385 -0.3213
Znl Zn2 O.05N 0.592-0.34? -O. 9021 -10.816
0 1N -0.607 -0 363
0 3244
0 01N +0O13 O.25 + O 3202
Cu/Cu2 O.05N 0 2 60 -O.309
+O 016 0 3053

+O.019 O 2633 O 302

Solution Termperature (T) 'C,

Potenios Of Sce = 0.24+00007 (25°c)

eM/M Emjm* -0-0595og [XCJ -0

ohere, E iS Standard elecmode poleniat of me
is acHvity of metas 1ons in soluHon
eleCrod e, aM*
(a' lO); Yc is acHvihy Coefficient andCis concennata
Of elecrolye solution

Table 2 Individuos activihy CoefticientS uf Cu"ond znin

aler at 25 c
Meta ion Cyuern
Cu2/zn 2) 0.001 o 002 O.005 001 002 0-05 01 0-2

ACHvit CoePHaCnecc 0-905 0.10 0 8O9 0.7y90-675 0-50 0gs 0 <405

Name: Sakshi Agrawa Dare:12/02/202
2932
Regishraion no: 208CE

Table : ErMF Of Daniel cell Observed foro three diferent oNC.

Ofzn and CUsolutions.
Metals ConcentraHon Metel ConenraHön EME Observed

(N) N) CEceu V)
O.O1N 0.0LN . gg4
Zn/Zn2t+ O 02 Cu/cu2t O. 02 N I-022
O 05N O. 05NN I 033

Average I 023

Result:_
SCE
a) Standard elecode poeniat OP Copper CE)
=
+0.300 vs.

SCE
b) Standard elecmde pOtenHal of zinc (E")
=
-O.316 vs.

daniel ceLU L.023 = V

C) EMF Of he Constmeed