Page NO-L

rumions trs Exminalion Quistiems

ESucbechmital culh, nalsanic
Cella ono
To PIC
Nen&t squatien

DUnder whaf Conditiugrd is Ea=o, As= o?

Quts
wlhim the
Ambulo

wih e
wih h
oll
Cell
galanic cell n
Pus-Dsict th
uoclien
uat
u+2A 2 A +

Am&ut CuI C2 | A" A

btutn
biluun Call petitial
Cl pottial
elotign
wWrit tha
pus 3 Cerlcmt CBSF- 2003J.
Jailibrium
E. 2-303RT
230sK eg. kK
leg .

Am El m

th Sigmlnamte Aalt bridae

ssltisn Just
Amb i Lt (swnul th
CBmplets Col init
hol- Culs Thu

Cin)
Tomalerint
t ther t .
mi hol-ll
3tiens em
 age No:-2

Quas 5) Caladate the lamdard

dlucusde potrtial NË"IN
The Col, NE (s) INECo-oIMDllatoim)lculs
lacbode imf F
O 0 59 V. ( Ciuen, F7cu t0-34V)C8SE- 200c
Amuu imn
Foly O-059 V
a/u t o34V

N 0-0lM
[ ] o-IM

O-051 a
[N]
Fl El
O.059 Eco
0-051 Co-o1 om:2
2
(O1

O051 F O 051 Jog

2

o:051 (-1)
O 051 E 2

00215 O0295 V o-03V

E o059- =

FR ECalhede F Anods
O-03 o-34- E Ameds

0:34 O 03 o 31 V.
EAnadla
CE
olouoima. t l at 2s'c
the Kell t 25°c
Caleulata the Cmf
uel=6
(16*M) II Cis'M) I GaCs)
AayCs IA
Gi, E
t0-46V d og 1o =n
CBSE- 2013J.
Ame : Fh No:3

Ag(s> IA (i6*M) II (i6'M) la(s

At wned A (s A lay) +e x2
At Cathode Cay+2e- Cu Cs)

OUwal! wactien
2 A + (ay) 2 A+ CuCs)
m: 2
Fad Eal
-

00 51 JnA
2

o-46-Oo5 Jeg C103)

2 CIo)
O.46 00511 log, 1o
2

E 0:608 V
us Caluset h eom wich

ollowsing Take& lot

uaclier
2+
Ni (o-l6o M) +2 ACs)
Ni Cs + 2 A (o 002 M)
CeSE- 2olo)
CCriun hat E l-05 v J.=

Ambut nwn ECo1-05v

m2
0511 dog LN*
CA
:05 0:02 511 leg Co:t6o)
Fll Co002)
1-05 o 0 295 eg 4xio"
E
05 -00
295 x 4-60 2
E
=0-91 V
E
 Po4a No-4
t ap t 25°c nuith the
Qus -3 A Woltaic l i b
olouwing halh ull
ono (o 1o M) I Cu
A (o-ool M) A Cell?
wlha wloulo the Ngtoge this

Grutn, Ed 46VJ CeSE- 2001, 20|2

Cinbm E 0 O46V
Ambuso
ool M
CA o

C o:lo M

uoctuen
2. A +
+2Ag
n 2

Full E
O:051
M
Laa
CA
0. 46 O.051 log
2 (13)
0.46 O 198 0 3 12.V

thu apilibtum Colant r the

uts-Caleulat
urtion
+ C Coay) Fe(oa) + Cd Cs
Fe Cs
Guib, Eaa/ca = 0:4oV,
E/E-0.4 VJ.
CBSE-2009

Amu
Ea sthoda E
Amods
- 0 4o
-
(-o .y4)
O o4VN
 Foge NO:5
E O: 051 leg k
M

O 051
f 2x 0:04
k mtileg 0-051
El oilo |o051
O-059

22.69.
K
K ntileg 1:356) =

Qus 19 Calonlatt th Stamdard ll potial -s

uodlien
Aaluari ull m which h ollowsna
Jaks pla
Cs ).
(aj ) ( 4 )
-->+3 Cd
2
2 CCS +3 Cd
ovd soilibruum
Censtant,k
Caltulat AzG
uoction 25°C.

-0-44V, E / - O4oV,
Cnium, C8SF-2oo 8 C)
1F: 96 500 C mol J
273t25: 28k
m 6 25C=
HA T
Amsys
E
FuEthadade
-04o-(-0 4 ) =O 34V

A -mFEal F-965oo
A - 6x 96500 x 0-34.

D -19686o J mal

AGi -

2. 303 RT g. K
 Po NO 6.
Jog K A 19686o
2-303RT 2.303X 8 314x 298

k 345014
keomtileg
k ( 34-5014)
K
K 3.173 x lo31.
Fomulate the loctrechmical cull uprusertia
Quus Ii)
h uoctien,
+3 Fe (ay) 22 (oay) + 3 Fe ls)
2 CCs
Cii Caluulatt E
Calwlath Fll at 25 L C3J= o:! M and
Cni)
-074V,
CFe =
o:0|MGintn, E /
Fe/ Fe -0: 44 VJ.
CBSE- 2008CJ.
Raprukrmtation he gien ull
Amsu Ci)
C(s a"(qy) I| Fe*"Coa) | Fe Cs)

Cii) E CathudeAade
- 0.44 (-0.+Y) =o.30V

o-051 Joa. Lc*J

Ciii El CFe3
30 0-051 Joa. Co.1
Ed 6 Co-o1)5
4
F 0 30 o.0098 Sog1o= 030 0-0018 x
V
E ull= o-26
 Pae NO:-7
Quts=19 Calenlats th Cm omd AGG for thu follouing
Call
MaCs) Mg" (o oo1 M)|| G"(o o0ol M)I Gu Cs)
(cRa) o:34V
(M/Mg)= -2:37V,
CBSE- 2015

Amsit At oned Ma Cs) M g a ) +2e

At Cotheds (o)+2e u Cs).

a l uolion

My(s) + (a/)>Mg (04,) + u Cs)

E 0:34- (-237) = +271V

CMa)
Fullall Cua) n:2
271 O:051 Jeg (ooo J
2
Co 000

o 0 215 eg lo
E 2.71

0'o 295 x|
Fall 2:1-

co 2.68 V

AG:-2x
-m F E

16500 X 2.68
( o F 16 500c
mo

AG52)lo k3 mol
 Page N0-8
Ques-13Calulat th AGand Cmf (E) that som
Com be
sbtaimo om the olowingll mdur the tandar
Conditien t 25°C
|l sn" (a) | (s)
ZnCs I zn" (oay) Sn

- 0 14 V
z/Zom -0:#6 V; Fst/sm
F 96 5o0 mal CBSE-2015C J.
2t
Anlse At Amade ZmCs) Zn +2e-
At Cathads Sn*" +2e 7 Sm

nal ruortiom
Zoy) t Sns).
Cs+ Sn (oq)
Zn

Ful ECamode EAmadu

-o -(-0 46
O 62 V. oF-965o
nFE =-2 X 96500 x
o6 2

AG -

AG -

11966o J mal
the owww.latiom or thaarit tll
19)wi
u-19
m whih

Cu Cs) + 2 A (oay) a2t (a ) + 2 Ag (S)

he satheda ond Jho mede
tak ou Idontih
uotisns it
Cii) wit Nomt A atien nd Lalulat tu emf
Aollousina Cl
HCG) | Pt (s) 1 bor )
Sn SCoo M) I1 HTCo o I 2M)
CS
riu Sn/Sn 0-L4VJ L CBSE-20 lIC
 gp NO-1
Amakt = Ci) At Amode u Cs CCoay +2e
At Catheds 2 A C 4 y ) +2e 2 2 AS

wall ochon
C Cs + 2 A > (a4y + 2 (s).

Cii) At mgde Sn Cs Sn (ay) +2e

+ 2e.

At Cathoda 2H (ay) + 2e Hg).

a l uoclion

SmCs)+ 2Ht Coay) SnCoay) +HC).

F Eull0:051
2
eg,Sn-Omm2
=2

EAAmada O-(-o14) =+o-1yv.

Codhode
E/-Fs"/s)
PteEa Valut im O, m
Jct

Eal o 14 0:059| log O.0

2
(o-02
O14-O:059) O O 809V.

Calulata the Cull em and A,F for the

us-15
Tundtion at 25°cC.
C Co-0M lcd Cs)
(o-1 M) |l Cd
Zn Cs) | Zm -O403v
-0t63% ca/
CCa Fz/zn
1 F 6500 C omal R=8-314 J lmol
C8SE- 200 cJ.
Pmduo (o1M) Il a(o -o|M) | Cd Cs)
ZmCs|Zn
E E
Cathode E -o 403 -(-0*763)
0 36 V

0 059 Zn
Eull Ecel m

0-36 - o-051 e r : L
2

36 0 029 5 log lo
.

0
0 36- 0-0295 XI = 0 33o5 V

nFEe00 2 x 9650oX 0-33.

a -

0,G -63 786-5 Jmal-

=

o AG -63.79 kj mad
 PaL NO:- I
TOPIC Conductamcek. Eluctrolge-
Leric Sdlutign Ordis Mabwiement

-1)Exprul h julation
a-1 blutn Corductuit
ad malar Comductinit olition held
CCBsE 2008, 20ll
Ambul Malar enduetiity, m lo0ok
M
whwu, M i u moloity osoltison
k- Lacilio Cerdutimte CComductiuity, )

the Cgmdutinity
s 2 Exsu th sulbtien
-amog

in th , the Call Condtont and

tion
Aolution in the ClcesE-2011)
sktont
the
Amb Comdvdivit
xA A k ond f= RA|
k R

k- (ønduliuit, R Rizistmce
Whi
Cll Cenatant

wlhat mior by imitim mola

ues 3
Cgrnductiuit? CBSE-20l0J.
Aolution t
Anb Th modar Conducdiuity
Cerdwlintiy-
iminite dillion ib talled imitimg melan
(m)
 Page No:- 2
w 4 Calculata thi dapu diseioten (x) s
ocidi its molat Cemductiuity (Am)
31.05 S Cm ml
Gnien (HT) = 341. 6Sont mol nd A(C Coo)=4o9
Stun nd
CBSE- 2017J.
Griw Aom
m 31-05 S Cm om
Ams
CH*) = 396 S Cm mo
A CCnCoo") = 40.9S om mal
CooH) = ACH*) +Cceco)
3416+ 4o 9
310 5 S m m

31-05
(Myu dikoidion)X Am
m 310 5

State Kohbrausch's lawt indshindant

ues 5
wighatism i g n . hy dsu the Conductinity
a Solulion d u a with dildion?
CBSE-
20ly
(pnductiuity
Amb -It gtats that imitg molar as thi &um
udtselt Kom

t
o th ion
indiuniduol Conbibtien
and

Catiom
t h aludtroly e
m CCC CooM) NnCoo + u

Comdunctiity o olion s ralatok with t

Th
wwbl ienb umit alumio the Selutisn
 Page No:-13

whtn the oliign dilukod, tu mumbe -digns pio

Cordudtiuity o Maic
mit uglum. ducrlale. H ,
Cgrdudaonts t h Solution decuass
l6M. mthaneic acid
cio
x
Condutimta 2 5
Qus 6) Callati its mola Corduetinity
i 5.25x lo Scm
and dugas disseialion
CHCo0=50:5
ord
iwn-
ACH*)= 349-SCmmol Som mal

CBSE- 2015J.
25x 1o M Ssutien is
Anb Molar Conductiuty
5
loxlooo
k xlo0o
M
525x
2-5 xlo-

Am 210S Cm mol

am CHCo oH) CHCo6) u)

50+3495
3915. 4oo Cwmmol

Am 210 o 525.
oo

o-olM Nac Solutien a

att
Qus 4= The Reistancs
25°C 200. The Cell
Censant
The Cerductiuite
in Unity . Caleulat the melar
ClL
Cendutuit - th 3kutio[C
C6SE-2014c
Ans Guinn Reajatance (R) =200
Malarity s Nac 8olution = 0 olM.
 PapNo 19

l = 1C
Comdlarl
Comdutint (k)=x Xx
5.0 x l0 am.

Malar Corductiuity CAm ). kxlooo

Molarity
(5 x I0S) x lo0o

5 00 S Cm mal.

Calanlati the dugru sdillecioien t i

Qua8 that
acid 298k, n
298
ACHCooH) I7Sm mo-
nCCH Coo) =u0-9 SCm mol
'm CHt) = 349. IS om mal. CCBSE-20llc)
I1.+ SCmmo
Amb Ginn m C CooM)=
m CCH3 Coo")
= 4o 9 SCm mol
349 IS Cmmo
m (H)
disseation (x) = m
Diy
AmnCooH)= A m n C o o ) + m O t ) .

CooH) = (o.9
349 1)
m
390 SCm mol

Am J -3.0X102
310
Am
 Examimalion Quaions

TOPLCcEbbalytis, Balttiis FaslsColls, nd Corroion.

Qu Wha Pumay coll? Grune t Eompla[cesE-2008
Am T Cll Mhich Preduats Cammot b thong
back it ruaclants talld Primony Cell
Rachargeable toll J Exaple Dy mtwy Co
Ngn-
2) 2) Wtite Th mam t h e Cell is qnpraly
which

hiauwwg Qidls. Wite th ruodienl takng

plare at th
anodla Ond Cathede thethe call
CceSE 2ol7].
Cell is uitable Cuun doni
Am Mukcwy
Jik huoking oid watths t
Cell Can be wsittem n
TF acbgda uoctions mittuy

At Amads
Zn CH)+
+20H
Zmo Cs) + H,0+ 2e

At Cothoda
+M0
Cs)+ +2e Hg () +20k
Hgo
Coll witin
utall tuote
Hgo (s) Zmo (s)+ HgC&
ZnCH)
ue 3 wih he mom the Co which
metally useol m an&l. wit e fsctioma Jaking
ploce ot t Omede -ond Cothode

CBSE- 20l7].
Ams: selomch Cul Commenly Mo m iansits
uoclions
Laclamthe Coll Com b
Th olactrode
wiltm

At Anole 2t
ZnCs) Zm+ 2e

At Cathods
Mm O +NHy +e Mno (oH) +NH
im uadtion a Cathoda gnnbints with
with
ww
NHa m
D 12t
the CBnplea Jike [zn CNHGy

Calcusat th Tim Je dloodit 1.27 -

Cathods when urtont
2A
thtegh Aolutigm nuSoy.C Mola mass
Cu = 635 -9mol). 96 50o Cmol')
CBSE- 2015J.
Gin m: 27 I - 2A
Amb -
mals CA 63.5 mo
Molat

Z
Eapinalort wuight
F
F 96500 C mal
 m Z xI x t
Eqpinalt
27
t wuigvt Mala
Z xI wwo
63-5 2
6500 x2
xrunn
e
2 4 x 2x 46506 1930S .

63.5 X 2

t1930 S 324 min

Juts 5) Frem th gutn Calls

Aad tooqt Cell Mbuy el, El Cell nd , a.
Anbnl the olousing
m hlarima qids ?
(i which ul Md

Cii) whish ll wab utd n Apolls a ProgtammeP

ll ud m automokils and imusiors ?

Cin) which
(iv) which ll do mot a Jong i ? [cese-20s)
Amb
Cii Fal l l
Ciw) LADd Atorng ll
Civ) Da l l

Suf e Npbnst 4aliono th stardatd d

Quas 6 hn bat th ueltoge
Cull uing this Jnation
cellduouaks lith L cBSE- 20 14CJ
doy
Duy wlLclmcht CuA J Cemli of o Zi
Ans
Contoim
Dy lhich ad Omod ond (otheds is a

Coske (aphit) red toumdd. by Powderud

Quts 1)A 2olutim Ni(N i slacbroyid babaun
Hotimum sluchodes uing Cunvut
5-0 A r
20 mim. wlhat nral mickel mill detpokitnd at
th Cathode? ( Ginn Atbmic mass N 5873 mol,
1F 965 0o Cmol). CCBSE- 2014).
Ams Cuotot (I)= 5.0 A
Lima (t) =20x6o 1200o S

Txt 5.0x [200 = 6o oo C .

m Z x t*I = Ciualernt wlight x t xI.

F
Mola mmal x t xI

Tanyar c) xF

58 7 1-82
x 6ooo =
2x16Soo
toraa
hu laod Staroge
Que 8) wuhat tya s a batiy
o*
battny? wite
the amode -and thet tatheds uilis
ond he Urall tuockio Suad
Cuaot is dam emit
0
batixy
CBSE 200, 2ooll, 2012