0los23 CAAPIER 3

ELECTBROHEMS TRY Exam

’GALWAIC CEL
galvanic ceu anode isVely chafqed ohete
oxdation tahes Hace and ohodeis tYe aged she
educion takes plae

lCELL FAUATIONS
Z2e
(ss of oxidn ande)

Cu
(gain of e redco ttede)

ouelall eqn
24
2+

CEL REPRESENTATON

Anode AnocksCathadic sol"

Cattode

sabndal
2+

IM I M

Em ok ceL Ecell =Eroode - Fanote

(R-sugEy
Hstaodad emt

’ SRP (Standa•d Reducion Atenhal 1

xmpla
cell eqatios
Laodei

lcell reptesentahioa

tat
cell eauations
lacode Zn 20 +2e
athode: 2H7 + 28

cel seplesertahon
202t 2H
Latm

20/20
2t

|cell seefesentetion eyation

amde Ca Cu +2e

cel repíesentaho a
..2t
IM

Emy
NERNSI EQUATON

Nefos c is ued tal calutahng the

athes than M concentieion. t is quen as
Q-OEAI eg Anode Sola]
atode saln]
ne ak e invalved in
wbele
ale the
n is the
m o espechie iots
heseachoa
emf o the cel and weite
calalate the thecel sehsenta
2

cel seplaentaion:

Ilotu

:3.16- 0-06 log 9-05

3 3.16 03log 5xo

r 3.(6- 9-03 (log5t 4logi)

:216- o:03 (o-6A90+ 4)
 LPAGE NO:3S
DATE :S/6 1 23

the em n the cel

Awite the Nefnst eg ad cafutate

So+ 2H Sn2+ B

Q-(-0:4)

E Ee 00591 log [so*

2
logCo.02)2
[o.cs]

4-2
2t92
Q-0sogs2tugin)=2lng2}

MaxiMumamaunt o aak daoe hy a qiven galvaic cel is

AG=
free
T Ecels is koo standord Gibhs Snel4
bG -nFE

hen the cell ceac thon is at Eeeta

O059t
 ConduchvihyAmat ny given alhanis:
Molat

19ncetohan
k isio Sm then
k

on dah
DILUTION
VARIATON OE k ANDA AITH
an the 00 DnS þeunit
cooducivity depends Yolume
Heoce it decíeasei o0 dluion A is a bulk ouo
iocteases o0diluhoo

Diluhon

wealk

lxerise 3-|

Ciod a andk

o- 024I M

340 -5
 (PACE NO:31
DATE : 10 /G 123

lcatutate the moloa. ionic opd uclance d Jon al- infnte

land EO Sem²mo

R58
222= 858- 460 204
318
2

FARADAY'S LA oF ELECTROLUSS
an aectolyte
It As

is also eaal to
he ducion o LMo of ionic SuhstaXe to depcsite le

Lmole Lnaole nole

chefe fe faladay's eonstant 96R481

çeduetion ok o0e mole.

of =LMole
tprmed ater etuctia.

a2caluuate the aMaunt electicity íequifed to dersit,Mile

om Mno
em cuso (hoettea)

SF oloumbs.
2e 2t

Olounbs
 3(atuate He Hne takene ezeinySIS

IOA 2[

eulA avan cal s ostuceaLnlhg ha ceu.

DI(o.054)

Eceu EelL 0.069)

Jog

o:24+ -65) - o0C

6 (5 xi6}3

(Sxi6y

QGcauate the Teducthon potehat oLn and

sbich

-o: 16 - 003 log

 PAGE NO:39
DATE :Jo / 6/ 23

o H elecrcode in ootaclk
caLculate he elechode potenha
luoith a
- 0-069 logq
E 2ut + 2 e H

-0" 69(LO)
-O-59i V

heen LOOStraned
A 4alvamc cell has

-O-44 V

2 (o-coy
- O03 log o

O32V

& Giveo a alvaic

p(s)
(0-1n)

Cind

pHe 3.
ol623
4lcalutate emb the olzoing
(oIM) (6olM)

eleHolyhc cels ale onnec ted series

usay, Z0So sahma. A steady cutent
Caluote
ondhe mass u and Z0 deositd. tehme toke

1295-6 C

+ 20
for u, 1295-6 : (46SOo) 2 x 2
635
2x6504o, 635
Pos 2n 245G

2966 (46500)2 X 2
65-3

||PRODLCT DE ELECIROLYSIS
 PAGE NO: H
DATE : 13/6 1 23

verpoteatal
evouion g qa needs exHapotental called
Broduct
s the híeyeiedak the aode is (a qas

200

H aod Na.
lhe cathede, the ions plaet ate
2H + 2é H
’ Na )2

the feactinn oith geatec E is pregeiced so, Haqas

evolved.
He0ce the oVera0 Cegchoo is :

cathode píefered feachion is

M the agode
2$0 20o

At the cathode

A the anode
Sioce +6 ( Max. bxid" state)ik cannot

ndeigo ulthee So PH qeks oxidised to o

pt electode
 gaR is eNolued to oxia
due

Kin 45(man. Oxd" state)

2,9

Ak cathode,

the one soith qreater

Aqis (educed to Ag
cothode
At aode

Red? oith geatef sRPS Heeed So he

boduct is: píeeired
Pt elechiede
At anode,

SiOCe plmahon o O 0eeds uelpotethal, oxidn

egered.
E - 29
At cotbode,
Red oth greater sRP is píerered So,
lu is he producle.

At
 PAGE NO:42
DATE :G/6 /23

AH cathode
Redn

roduel.
+ 2¬

Mercu
cataode:

Lead storaqe Patery oith hO,

packed aith qrid ak ead coated
Aoocte Lead anode
as catode.

Electroluyhc soln iS 38L H,SO4

Euelcels
eficiencey dnd alo causes less
used due. to ts high
Tney
pallukion- They
llkoavet into electrical energ

QH0, Buel ceu

paraug cabon elechode
Bubbles oy H ad g are passed Hacugh ato
H0ally duided s sed
Aetfalte conc solution o NaoH
liocseose the feacion.

Athich o the olloroin relahon ís incoret2

G= ke Here, G= con dutance

G =cel constanl
 dereasesoit6
2A Nola colducivity
Repih hve R ihenc ahþtoaches 2eo, Amiis caled
Queshou Aad Rale tue kbut. R doR hat explain A.

3alo the igllriag fairsþrelick aith

geter co0duetion ok electiciky
or

b u ote at 23C

a01 M a cHaMuan diluton Om

increose
Locteases o0.
metauC
disassociohan incceae
Conductan e deereae arth ncceOse in
au oie at 27 tere
Given
e 16-3 Sem'moi 16 3

258 6
258-G Semmo1|

Ma is more reacthve than fe and preueNts oxidisa ton _al fe.

the canme electolyte. alalate Am o o.5 M soln io Snmo!

GxR
GRk 00

Fof 5 M
K G
280
 (PAGE NO 45
DATE Mi6 /13

o25
Ame

onaueDw th
lWhena cent c 05 A is pOas edthrough
divalent ion tol 25 níoutes of the metal gek
atoic mas d the soetal
depoaited at the cathode fiod the

OF depasits 1 Mole (mem a the metas 15

3860
2X469oo- 0-369
016 x2% x 6o
Lt

containers? ive0 s034

8 Cao cusOL soln be stored io Ni

E o34to.25>
S spodaneoug sOCe, Ni is Mofe seachve thaa
Tme eachon
it canA be stored,
Cu as Eret S +ve

q-|Giue the ade and cothode Keacho o dy cel

rencion Alelost en a caletote he enf s

9ite the net
at 248FaHAg
B 01 (M

Eahode 2+
28r-Ht

603M
 Aoode

Cathede
Br,+2é 286

o-03 loq (3x103

9-03 (2og 2)

electochemical ceU bebaveg Qg an

IAn qalvanu cell
ELEat elheg
E the reacion is
NOTE when Ee <Frathde
aod behaveg asa galvanic cetl

2E Ahat hophena ohen EselLJu

Reacho0 qets reyefsedand Cu qoes into soln ad 20 9e%

deposted

3.Roto is the ph of bioe onafects Hhe electalysis

As losoer te ph, gster the produd a electolugs
[Dectease in oncentrohon, incceoses pH ad Eceu i0c(es
Dore
Diluio0’ ionic movement E cell incceose