TConCept of Avhenivs '4vhenius

k Ae -ERT
l a G (onst9nt
A Pre -espon ential ol
reqvey
faty (Unit of k= dnit
Fa2 Ativati'on eneiy
A)
A-Ea_ arhenivs paameter Acc
toAhenius sth A 4 Ea are
inep endenl
O Teretule.
'-EanT ation o bivate
Bott2maun factuv molecues
Kat Constout inreaseS exonontially wh le w

Accading to AyheniUs CAthe molecules lnhe

ra ting Species do hot have the Sdme kinctic enery
Spe
Sineit is dijiaslt t pvedist e behaViour efa
moecule with pyecisisn bolt2 mlun 4AXWell USe
StuisticS topraelit the_behaVjur of large Aumbex
ele olecules Accordiag to Bien 2 dislibinbn of kinch
tney
en May be described bplottirg the acho
the fracho
o lecule wih a given k e s k.e
Nature o (Urve T
M
fPachrbu

Ayecy
kE
On inlyea sing bthe ewp, he Cuvve byoadeMS Out
1 i ckay em raph that_on
MeaSiu b l o c , the aYea shuwug
frartyow factfon of activated moleta
gets almost dovh le leadu
to doule the YaT
An
 Dfferent fotnns oAveni

c Ae
Ink nA Ea/aT

303 RT.

lak)= ta
RT2
dT
1f at T t y a = l ya Congb isk
Tewpt2 rab

log Pa
30312

The ral Costants 6f q Txn_a

7ok qYe 0 . 0 Sec 0-07 secYelp
Calcela Ualue aL E a t A_at Sook
Solp AE K O.02
TFo 6.0H

s03 R T
d-07 Ea
2
303 x 8 2145
Ca 132.30 8T.

log ke lojA
a3s3 PRT.
AE T5ok, log(o02) = l2A - 19230-3
loq O2
A Antib O-2) = .
 voUv^

The Tau *n triples when p changy

rom 2 50 c Cal ach vation RygY
fer he Teato
I, 2 293k
T2
T2 5 323 k 3E
03
Fa L
9 -
B03 xS 314 323

foy a Yeachun lacd e 3:2x10Ye i-

Valve a t 316k
S k - A eEal RT
k=A Ghitant
e k a t 3ok= k at 3sok 3:2x0
toy a ga(eovs Yx cto is
tollowing deo IS give
A- /T.
2= lo Too/T
find twyp at hich
-2ATo7T oe/T.
=

24T/ T

Take t je

J
T loU 3 4 2 kel-
 youvh

The rara ConstnnE,Ea pre -exptnenba

3xI 7
Fauto O a Cheuice n Ye
Kec
04.4 ate Ysee
f i m Ualue

kA EafpT
as T kA 6xI7 ec..

for a Tt_oideY Teaction A P, the

tempeature () dependene of rali Conttaut
W ' found to fo llow &o equabon
-2ooo (G+6 PapYe tpsneha
fattoy (A) ach vaho) enegy
loke 6 20

logka legA
On ComMpazisoly
logk 6 -2oo
ke_hnkleg 233RT
k: o
q-2oG0 X2303 xK

75 of a_1eY Yeath on occOy in

30min- a t 27 c 37.5 Ohe Sae
yeachan OCcOY in 30minQ E 57CHad
&etivation CyeyY YAU
So
AE 27 E75y is 30mih
S k 2-38
30
25 x0.6
 ate

At 57c ts7-s Y i s 30 ha1

Se
k2 23e3 ( 0 2 x.0 9.
30 2-S

2303 xO 9 0

30 x 2-503 xO 6

NO 0Se le k2
232KI 7

loq1.5:
303 S 314L 3a0

. We can
fepíeSe nt the decompos tion ef Nas g
ab a hise te
te p
np. by he follouwig twe chewaical ea)
NOG g) 4N02)t VO2,) Achvati
4tivati
Eney Et
Ea-

I. N05 q) No2 19 thO29 Hchvatien enerqy a

hen
a) E Ea b)PaEa )Ea k ta d) Ea 2Ea
A tivation Enegyis in dependeut_f
Ctojchj met Ea Ea

A Catallyst_decyeases the achvation energ(Ea,)

fom loo kI/husle t o go kha AE what trip.
the rai
the Of Txn_in_obsente of Catalust at_ 506k
wiI he equa yao af Tn_inPYelete of_Catalyst