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ALT n /2n
N

v
N

Corditigm issactisried hen Tis hugh 4,


at high Jemperature dabsical readfment Is_
Ua
2Tmk
h 2h2 (N

We a roducethe mtan fhexmal waMelenerth

2mkT)|2
As long as i Sis much amao
than paice
Spacina stahshics tl be classical
The meaO. eneroyin
vibyationa_condttion
eNt
Page.
The Spe cidic beat a t
diatamic go IS coNstant Nolune for

Cu (vib)= E
At hiqh emp fKL
pho

b oealeating aiaasa powex terms

Itefw

Ntw

Nw N
2

by Degeotinq fom._

N kT),

(tw N N|
The uibxathional enenqyleNe }s fOYSNSter
Ndiatomic moleulg
nt w
he patitiaD unotim

Loz phw-nC-e

LE
2 ehLT

he mean eneyg IS
K E 3NEw

Specidie heat is.


-
E
T
3Nhwe fhu
Cy 3Nk (DE

calleol ag Einstein Chaaass


demperaure

At lo temp

C y 3N

4 Translaiono Motioo
of paaHhim functn,
We howe e
V 2Tm kT
h
for iatomic
misyeplaced tm
teule

(mitme)kT)
V C211
b
4 ln(2n) +3 Lnlm,t2
Jn Jn (
3 pT
N tne)

NLT

C E 3Nk
T
2. Potadtimal otim

2 kT

Oucet ac unlike
2 Ducle CUre Le sane)

n2 Ln 2 ALm l a-L

N
n (lc ox BE. stadih

-1

D fDstadistics

E n Ce '

We can wDie

SLo-e

Substitute
As V is ve ara e we can
Summaehon by inteqxati m.

Noafstates be P PtelfP ac

N dp 4m_pdp

P 2 mE
Now
2

beplacing
P by 2mf

d P V2m
Noot stales ET V 2 mE 2
2E

V C2m) JE
uT)
Meon Dumbex oparhic\cs gen b

PEs

E
BCE-

BCE
V (2m 3lT2
LT3

32 3/2
20) E
BCE-u
P_ .
P

AnC1e-PCE V 32 t/2

em)

4T
:

2 e dA
3 T
from

ato take
2 lhe angular momeDtum_ o f an
distrete valuRS 4 75compo0nt. Mi appllsa alto
d a k e i g c r e t e Jalua
indinotian of
magncHic ield B n taka al vaus betueeo

S,-T+L
aqne:tuc momentis

he partitim tuDction i l be_


B

Suppose Bis emN laqe a maqnehc


mo entsusd bealined in directism s
this field Magnctic homeDt willbe
n p
for Wak_deld
As_put. 7 PqJ

+ m t*mt
21
b nealrct1ng hiqhey ordur tems
23t 1+22
3CT+1D 3+1)
Ema

2T+1t*2JT+)2J+)
Siace b_S Vryow

. < 1
maybe Deglectes

-ng2 (JLJH))-

TA@AOetic moment e r uDit Nolume

m ng JU) B

Suseeptibl pe uDit volume

h B CTCT+I)
J

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