RoUP 16 OEN FAMILY

O O yen
S-Sulehar

O,S, Se, T Se Sdlenivm

Metallo ds
Me
TeTelluriv
Don
metals P o -Polbnium

CHALCOGEASS
(ore fmin)
-

a.
CAttmc vadiw

IE DTG
uterionic Yepulaioa
EE
S>se > Te> ro >O

,s, Se, Te, Pg

sold
gas
ns2

S
min
DT
O.S
eeet
T6 stakestalili ty
d e b iner par
a t a natina fosr

has hiaher but

and,
Slphwr or
efecively
Oxye
Sulph ur camnc

GYGEN
YGEN
PPEPARATION
decom postian
Therma

A0

He O
P * O2

lead)

Yed
O
P2

Brin Pess
6
BaO+ O2
aiv
O2

chbrae

MnO- loast

FMn ac

x KMn4
Cr
yelbw
otage

me thod
n d s rial
air
2 Fvocti omal i s t i lla hion
sater
Ecto y s

RCRTIEs
So e
aaAndance

aualie Py r o l l a l
cluble Solvenbs vore
oraa C

lu y
han s
2ene emy eme ore
en

e
meli C2 es
 OZoNE Co
allotrope 2
doar duelamaanetic
t u r fen t n e
solulde in
s te
ehadpy ferma tHen
Enely deompse
into O
elec
PrEPAration: 3 disehaIE

HF O3 CitHe)
F

ozo nsed oy en O 2

d
oxI i s i

oxidation

S so
Sulde Sulphate
oCN
cy a naHe
ayande

N H HNo
Fe2 Fe3t

C C
I 2 (ary ton di tiens
eHmaRon
wC mbishure ispresent)

NO s ne L Can

NO NO 2
Le t i t a t
hs+ hyo

-the decompsiton ozone s Tapd n acic modi

sharad alkaliw l o s ae sabe

O snen t S paesel o conc lali, it

orr Ozonide in (o pafa maave ie)

alkali metals PYM o2onides
oranaC cooured solid
H Ho * HaO+ Taing
weccu
loss
meniscus

merr ury

H sa+e

sissinfectant tor
i s u&ed
Steriising
er

HYDPIDES
HTe
H2S se re 1 DTG
natu
H reducin
pon e th D r G DT 6)
ydridel AH
Exohermic
4 . S -
hydride (aH o
Endothermic
H,Te S e
e
dewsi ty
chavne s t r e nq h
4SSH Se<u,
le
. b a s i c s t r e v g t h T : H o <

acd how i4
con in he Same waY
DTG OT Hitrogen fam ly)
ond aae OT or

B.P HS Se < Te A cendina

HS smell i
ro Hen e '

Pepaaton H
anyS salt

Feso, HST
FeS 4
2 . i P P s

ootaina ey iet
s
stjor
F
Pure a l e m en t s a t
(omlatione
 en+
mild
du
S exposel
shen o soluhion s HS
t OridisecA
sbuly
s tH
4 S O , taiv)
with lugh lame
ourve
2

sed
dentying e t a l ions
ions area

PAg, 2B3" s "

S4

precipitede

Precipi tade

S 24 3
HS 2 H +
eem
me ve wd
lesss meve back move S
n

Z1
NiS Bleck MnS- Pink
Cu S Cas- ye llow
-Black CoS
PoS

-all me alkali sulhideS ave ant luoride s u c Hu re

ides Ma,CaS, Ba hNe NaC truatu re

sulphur also ormS her hydrides Cop)

hey al dis pYOpor tionate
C K I D E S

S02 pOXIDES

PeParAtion

rcost
S ores.

Clourless

d s.
d i oX i d l e
Se e > Se Te are

dio xi de DT
re dcinq Fer +y
due t nert air ePect
Lsiee

hiaer 0S stabiky DTG

combination2)
Prepare ay direet
d i o x i d e s

ater

l dioxide are seluble in

So2 Se2 e z
acidie am photeric

Se2in solid staie eXIst aS an i i n e ehai

Te S An
cic solid Te o),
35 3
S GS
-

F.ES
O vo\veA iv
end wth O)
hybnd isation (

be Liwe jied at S s C and

liquidis use a SolveMt r ont chaemica)
AnS.
SOPYe
Conc.

A
Con

react th eí to form piieSu phie

 ime e t e
CoS
Hca c CacOa
w y w t eFpt

me oter
Cono
m1lFy wite Ppt
Hso
acidies
acidi fied
C203 (orange
Mn
CPAPe C

(reen)
So M
Color aene
e cherge
co2 (or) kMno/H
Canno be oxi e d )
aid ewis base
lewis
CAn
e r

So *

CL.)
Me
s-CN-Me
Mea
CLA
Ct4 + 6 )
So2 ca act as Yedcivna qent

Fe Fe
CTes for so2

(TaS
starcm
io d a t
tarch
lue-black
C m o i S t )

+Ho HP+H4
this plachina
acthen, t
So as bleching
empo Kay
cion

+HGa scen H)
So2
H cderless maHer
ooue

mot er

PC 2 POA, +so,
preparatioy
HPO

CeS F 3 +S0
Fe s°4 F 3t So2+ SO
NOTEE

so2 2 N SO
3

3disind
a n h y dd iid
dee
and exist in
sud,
e mP
SO3 Cycic +rimer

rms

So
SO3
on me

this is kept
n t e r

races either x or

ver t ivm t o
COn
ECan

trime
-ycic

chain
T [ s 3 unib
helical
ininite

mest
staLeorm inked into
choss
cMai ns
made a
shees

noture
has exidisi
S C
> POC
PA + SD

selube inHsA Coleum)

more
 SseO EO
on dss su tion i wwte selinic c d (H*eo)

HSeO (selinic id)

Se0+,
TeO3 HTeO C Telluric aaid)

H .o

other Gxdes ike:

Sulphur orme

S0,S,Sec

AALIDES
Ex 2
lides frem F I
Staloi t y

HALIDES F SULPHUR
luor ides Salphu

SF S y

s ,s

6pen kcok) S
F

these ae t e
Va lidess
SF4
as CSe Fy - l q , TeF -solid)
g A s

Poe rf l Florinotin neni

RcOH SFL eCF3 So Hz0

Sp

tydolysis
HF
SF4 H,

Odour \es
on lamnabe
nert Colourles
enemically
naolube Cin scter)

aeneradrs ¢
msuati for vol
tyonormes

eS
e x a tuergdes
SF%, Sef, TeF.) a
all

a sulphur
Su'phur
halidesS
other
S,2
+ S u l p h u r Mncone c h b r i d e
S
Cmol t e n )

yelbs uguid
oxic plden

t
Fe Slphur dehlenide

(excess)

che ry red Liguid

EFH 2
Sa2 + C C2
C2
C
mutad ces

auid c slid
sc2 hal wsike
 wono h a l l d e s - SF Sa
Suphu os ,

diha lides
itoms only SF2,d2
etra ha lhds
it orms
heahalides

my e
M o s a l i d e s Call)

Aonalaaludes e dis Proor hoate

Se Se Sell4

OxO HALIDES oF SULPHOR

SOX2 Ahiony I halide X- F, , Br

halide F,A
So Sal pury l X -

SOF SO2- -codourles vcdlortile liau'se

ia
caaar ed vedohe ludà
SOBr, -

oranqe

Pep
PO
3OC0+ Po
OR
S0
So3+ S a , > sO1

-CR
acs viqotously wthw
nyorolysis

dehy draing aqent for MaCH AlA.cH,O

Fea 6H
sin on simple e ting e do no dehy dohe
M Go Ma Co4) CA
ALCR GH, Al3
Fett 6 1o
te,O3
co2

(soF
is a sat)
vdattlee
cdour less liqud
S lsurlegs
voa He )

Pre
Fea o1
SO2 a civa+ed charcoa

PO Conc H,9
CF SULPHUR
ALLO TREoPES
SWLPHOR
SLPHUR X
.RHOMBIC
m os4
sabe allotope
thermody nam 1Coal\y
colou red
yell in S2
evapovatiea a . ot Sulphur
pre
conavns ina

arrnaemen

Salid -

rhom halra
m o l e C u l a r

Ceacr sp here

oluole in benzene ethers

H
i n s e l u b e

akhe S2

SLPHUR
NOCLINIC|e
2. Mo lphunr
melino erhom bic
prep nt worocinics
raeprMS
rhowmi c
-a

ure
Trove ition emperat
-Contoins 3ving
- emoPy AS or

deneity PS < denaiy

esolve Ezeme cher a lceho,CS
3 SLPHIUR
-a- mothes paar
Paarl

-CantiMS S rinas
Pae yoo naadls
Pale

SuLPHUR
stSulphur
- colloical orw

Clloidal

Con tains Singa

SULPH UR
5. PLAsTIC SULPHUR,

6. E SLPHUR LENGLE SuLPHU

Tn4s in
chair w
- Conta ins

ON SuLPHOR
THER MAL EFFECT
rhomeic
is h eateit melts intu a

nevM
mobilc ltqwd. on
Con inuin the
Pae yellow
mealing, he Ctame dar ker and

viscolS At about 200 C + h e

ncrnsig m uch mone
and
liquid beomes dar rou

rther eaia,
the viscosity
viscouaS

deerases

renke into edicels

2EACON The S ns
rod ica ls end to poly merise nich
These
and ence he Viscocity

s
 4 4 C
all
all me ineai Py wmenie chainss
no mallerr chainS shic

l e o d s
visco Y
ets nto aaecE.
ston neatin
On ery
Cwhich is porea moqetic
mdecule

s t a t e
aS S2
i ke 2

SULPHUe
Oxy ACIDS OF
Ac ID SER IEs .S
SULPHU POUS

Sul phu rows

acid o-4
H53 S2
2
thiosulphuroMS ecid HS

H2°a
+333
aid
dithiOnous
-oH
or
hypo SAlphurous a i d

S,+3

SulphurouS
4Ss Py so
acid or) acid
d i sul phuvouAS i n ree sBade

exist
do ndt their Salts
A
nouon ony
sER IES . s

SUL PHURIC
acid HAo
sulphuY iC
H 4
-2,t6
h i o sulphuric
acid

-oH +,+6
ic
ros ulphur
Py
acid
 TH1ONIC AciD SERES
-OH
dithionic aad

-OH
poly thionic
e- S,0
acid

olated upto n= 12

SERIES
rEPOxy ACI D

HSO Peroxo mono sulphurC

acid
HO-S-O-oH

Caro s acid)

Peroxo disulphuric he- -0- -CA

acid CMorshall acid)

SULPHURIC AaD
Repaaiion
CoNTACT PRocess
Brning Sulphur/Slphide ore
Sepi
+ aenerake SO S +o2 So2

Convering so P CVOs-Catalys4)
Siep 2
AHLo)
So > so
to forw
Step3 absorphio S°3 in Hs
So H2 So HS
aeum sth ater
dilutiom
Step4
S HS
2 LEADD CHAM BER PeocESS
is
contac ercess lout cataly st
Same

NO

Preper +ies
iqui d
coleur less

Kcte r
luior d heat
dissdved

dil H,sou NO NO
Cnidrid ey
+hiusulphate

s o r HSO coor HCo

salt
sal
coT
HCN

Br
H Cnc. Hso,
o Cchlsvatc)
NO Cnitrate

C
HCooH H

2S4
+Co+Co

cooH
iCHUNG oF METALS
e Yemoval Boeic metal Oxide wetal Carovee
mctal ydroxide Yom e
thee fe e
meta)
dil. H So4

Mo H
2SOu
M CO2 form
H,So.
tclule
M
Colube
Ho)
,SO4 Pa Ho - Po
POG chloro sulpmenic
Cexa aad

S pry\ hlone.

RERCTIONS of SOLPHURC AD
Metas els H te elec Ho
do no chemical series
i eraie
iute te
tso But
hey
cxi dised PYe seee cenc.
HsoL
Cu
Ccone)

Zinc

*Cenc.S0 Znso +H,O

 HALIDES 6F

Mono Di Tetra Hexa

E l e m eM t s
Conly E )
oF 2
O

sF2, S0a,
S S,2 SF2

SefS, seF

Tea2 Te Fu,TeO4, Te
Te e Br2
TeBru(er