ALIKENE

Aikene Addi hon Reachom

Date
Foge

Alkene off Substituthon whch S t o Girp p cu3

CH3 CH CH2 CH3-C -CH2H

HX
CA
@H
aakoni k ov Rule

Mecha mgm
Nue
C CH CH2 CHg-C1-CHg - H C CH3CH- CH2
RDS 2 'catte fe
H
CMore Stabe

rade Stable c
YeaTYUT Tent obsor/ed

C CH=C12 C13 (H=CH2 CkIC CH

RDS faß C
Cath on
Aes Stable
InEArditcn Reache Alkees Electreph1le ratace
fo m more sable cabocahEn slo ep.

Tnot feoibe becaue Canbocochn no mere

iabe
ninp
TSL

P F Fa

PnoduCt
Reatrnt

Ran
 th ? a t i n 1"catin
t

DH6 HCI-tF

Mark onik ov's Rute

M
HUDX
CH2 lioo-(1C
OH

Slable Ati lar koni kov

xh on
Rule

rshen Mechm ni Solve Masmigoy, Art notonio

-1t
l a Fontovs nd iJT MchamSm Se

Ch2
EL CH3 CH2

Ch
H Me
il Cl-

Me
Sh

ED
CSC CH CH3
CH CH

Ex2
 Dete
Poge EO
S2

F N 1Shif+

shrft

highly Stoble

0-3
Drodutt Nme

Solh
H

CH3- C2 O
Highly 9table
+ Cochom

Acel Funchimal oroup2

OR

OR CT
"Ftetd
O F+
oR
grDup

- CH CH
Ct . clil Ha $O4

CAl C =H 2

N CH= CH2
 byth t M, M

are pr esem+

SolM-L
-CH= CH -CH3 FH/HoO
i l H s0 -Ch Ct1y

Benzyie
corion
nlhem cagbocatcn nimedlale

1 to med4hen cattack
Chiacl procluuchs
o neophble gíve
both Ctyusa htn.
Ph- CH-E t
OH d+2)
mixture

Sol-2 ph-Chh-CM tHa

(t H-Chft
Ben2u
Cahan
Ph-CH.-C2 -CH2
Ph-CH Ph| (M-CH
eem7y
Cd Racemic eA scittaCE
nihure
sp2TP

O2N CH Ctl2
HC ON-CH C
produc
-M
O, N- CH2
-cM

so4 Bomel
- H Shi
- hft

H-o1
Ilbir Podcduc
 Dafe
age

Arrawnge for Rae o Rsn WIIth dil Ha$O4/HX

-2

O)
NO CA CA3 OH

Ph

Sol7-

3Catim 2°cat1tn

1
MO2 OH

M
+T tM
HC

Sol

L +M
H
-M
Homalys N Aable
Ycite
nenerelly Data
se c t

emzyliè Cahèn

HohiftF

Ph
M +M tM L
2

D
KHARA SCH RULE Peaoride Effcct)

Similo Anth -Mourk0nk ov's Rule

2H
CH3-CH= CH HBT CH3 UH- U2
ROOR (Peronde)
H

Br
Radt tol Adol
anh M rle
Peroxide e f
E Ad4 hon Khaenech Rulk
To Addititan
ruc addition
Mastonit ovis
 M
Anh M
Not App)cohle
( Dale
O
MechanI$30)
R-O- P R
Homolyss Pctcuca

2 redtastf moe
PDO C C1 CH2 stabP) He-sCH
CAge I B C3 CH (1 CH Ch1
1
B HB
CaSe 13 CHC
This exs on not for rned)
roditoul Cless stable

rae Stable

Jut lite nutleo

CHAN rx
h3rim Br pteuceg
evey hme.
Homolyss sgn
** Note rct peroyide at hiah Hempeahure o Gunliglyht are
Tesponuble for free. reiltal mechonm

Peroxèies are Called Tadia (nihctoas

R-O-0-R
g-O
KO-H= CH 013
H

-CH CH-CH3 Ph-CH CH CH3

B
M rue o t Cupplicable
 Meskornutan
Aluays 9o thnugh
Data
Pag

HBlez0

L 3cdutod
Anh M nve

Anti Mrue

CH=CH2 H/e20 Ph-cM-CH2- B

Anh MruL
Syreme

So3 Mehanism3
H-
-o-o-R
MOstormitovs Rue MMsT NeHiky
wrieln
choome Bewstr
nole copy
HBR0 Kherosch Pule.
Dete
Page

1Khoiasch e-ffectssonly Obseveel Whem H- C polyhaludes

CHC3 CCl ekc:) e pYexomt dn peIPmte
pepAde

2 H-F, H-c amd H-I does not Shows raouced reachóm

Khorasch effect Whethe7 peroxide pregont c
Mot They aloays ghow eleCtroph1lieaddrh reaction.
dummy
oyemt
CH=CH2 P-00ph-R -cHa-
_Ph -CH-CH2
Syreme 2aducal P1m EndotheomiRxm (d +
M re
racemk mixuac
Rocical achon H:F_HC H-T e
emdotheAmi ae
hemce Ceuible

dwmmy reaget which prezemt TCachen but not tunchcas

MARKONIKOVS RULE BY MM SIR)

In the odd hn o HX to am alkene hydrogem adds
to the Casbon the double bond having the grealer
Tmbe o

bydogpmg
Mankonikov's oftem paraphased cshe rèh gel iche

CHaCHcH H CHcH-CH2 CH3 CH CH2

propene 2-chleropop me hlopo pOme
(no foimcd)
This egioselech nty as moted by Vlad mi Mantonikov
C8 39 1904) who mode he
folloorg aenennlisaton, now)
AS Makonikovs rule I n the ddihn HX(whene X:itlg
to n glkeme_hyd1ogem adds to he doubl bonded Casbon
thod has he graT number d bydrcgons bonded to lt
halegen adols to the other cambon
 Data
Pag

NCERT Dehnhon

Mankonikov , a Rugsiàn chem3t malea gemeralisathar

in 1869 SFucyin uch reachès in deBai
These gemeali~ah0) Jed Moat onik ov's to frame a
rule Called Mor 0nikov's rue

The rule States hat negahive part o4 the

acdd emowm addimg mole culle) ets a ficached to
that Casbon atom wlhth posscg3e lessen numh er
hydaem atoms

Alkeme dil H2sO Adai hotn

HBr/R2 O2 Podital Add"