You are on page 1of 12

YOUVA

Dste

Streng aidshae high


chanees PKa
thay 1
Ra a
PRa

Pka =-log Ba
OH
NO2
a) CH

Value ot Pka 7.2


lo.2l1S. 4
oH

7.1 ol2
NO
OH

PRa : e>>C>>a>
Decrealing

ot C-o rond in
J)3) Reatns inuing cleaage
aleohoi
)Reaction with Hydnogen Halida
R-OH + HX ’R-xtH,o

LUCAS Telt
Beogent- Conc. HCd t ahy Znchz

Whon
occwnd inmediat
aleohaly tiunridiy
When added o 2',tndidita oteund afon Slo mil
kaat. tunbidiy
P.T.O
Page No.:
YOUVA
Date

Lces Reaget
Chz CH2 OM
2n Clz

CH3

CHa

Mechanidm: CH
Lucad
CHg
1
CH-C -CH3
CH-c-CH Reagut

-Hao

CH3
1 CH3
CHg-c-CH <CH -c -CH3
(39
Nee: 3° aleohots ertemy Note i z° Carloeetion
eatie onddot eny Atabde, henee 3°
aleohali immediately
addina ony canc. HCl will. becone trlid uhen
alds facihtate the neeted with

2) Keacthon ith

3 RoH t PBn’3RE tHzPo

3) Dekydnation of adeohols:
Remondot watenmolecule

CH3 CH2 OH. Hg Po )


Thehelatiueeade-. -CH CH
Step Mechanisni
:FonationSte of the CH-c OH
-
3°>2°> 9 ct3 1

Ofnation H
Hso
Bale H--H tolouing
H CH-CH2-H
20% (o)Pou H3
H
Detonminang -0 8S%
H3Pou
of -Ht H3Pou,Hzo + emoveo

alheney &lowedt
tenandhenee nden CHa
H dehydnation of CH
sten
Canbotation Fast -c=CH, CH3
fotonated
aleotali -CH
CR.D.s) =
CH
oLoniun
(Ethyl
ion)
elimination (protonateol
aleohot) Hao t
ot Date: Page
No.!
alRonc
ton
T
the W
TFS S
ot nlaetion YOUVA
pneton the
mild
a
R.ss, gom
CAdekide) (Cayoy
is 1-Atooidaton
do P.c.cis
he Canbocation chomate
Chetans) unthe
NOT condition
CH
H-CH3 -
CH, (-CH ehlargCHa-cH
CHa oxidide
3-4
fiAt wigenous
H cH-
CH2 az ’ agentdi
oidiking
Strena
CH Oidatien
i Oxidakons PyidniursCH cannot
HaSoMy
of
otdehydation
)cH--CHa0h
(uuo) HLSou
Conc.
cone- Atadilihy CHH Kotonesw
H-C-
C+H
CHa OH CHa
-CH3 4)0xidationi
H
-CH,-C -c.c.
P. 2°adeshod
Ou/Ht
KMn CH, CH
oH o)
CH3-
CH H H
CHa
H Rate CH CH
oiiling
nald.
YOUYA
noesction to
Culs73K
oceund.
-ctH6
neactian
CH CH,o)
CHanCH= and with
ChOlace
anl
RcHO
ptned 73W2 622NCH-C=CH,
R-c-R' dehydnation
itneaets
BcHO
aeetond.
in
CaO OH KMnOu/H
C
C.
P. -qet
CHCH,
673K ad
adeohot,
CH-CHrCHz 1
RCH2oH
73k2
CHg C-cbond
-c-cHg aJRanes
R-CH-R'
2-2
ReHaoH agant CH CHa CH,H
CHa 3°
ge
*hn
Cnon-polar
s.
ubed)Aowent
JbondingH- aNitation
Reaetiond
Phenol of
)Halngenaion. Aaplnated Theintamoeodan
whinhmadeela DEJetophilie
CHCAs o
() 48
2R
idomen p to
-nitophenall
H-bendiag
whide y actvaing
grop
henee Ahomatit
BJ 24, Steam
etmoeeuled.
adloiation
6 toamwoatila NO
tunitohenol to ot N°2

dilttation. sullttuton
Jondino H-
itormoelar CMino)
intenmaacilas
oeding
Pierie ( due Date: Pagefio

acid) ta
YOUVA

intna
he
YOUVA
S
S
TF MECHANI acid.
2chydoybenyoie
W
No.:
Page
MT
Date: acid)
(saliyie
dudti
Zn
+-3HBni CooH
(4,b-tibernaphenal)
oH
t. tZnO
with
ofhenol
Aeactio (Bengoqinone)
Uwhite Ht
ii)
Oxidaienoshenoi
Hao
t3Bn, CT|ON
REA
KOLBE'S
NaoH
H
dolnont
(olan
OH
ii)
YOUVA
MT
T
W FS P.T.
Page
No.!
Bate:
oH
JON
OH
CooH
BE'SREACT
OH
. thg.
n
H-Jornding
Oj
Nat
RoL a
hiakan
oF
MECHANISM:
oH
Na
ANISM
oH,
Na
MECH
octet
isdeeade
thid
S YOUVA
S
F
WT incamjlete
is toic
T Page
No.
M Date:
NaaH
2 to higA
atiaoolaclanH
athe
oH
cHho ue
yuotenic
Dcc
Intennediate
NaoH
cl-C-H+ then
+NaoH goto
RomnAnha
Cl
+CH MECHANISM
aont
t
the
pratanatad
YOUVA CHa CHz-rcH
CHz
ß-CHa
(Eruetohe)
Page
No.
oH, meleeule
to -CH,
Date:
-
CHa-CHz oHi2cH3
HSo4
CeHgoc,
Hs
(Gdacode) aleohodd
CHCH
+2co aleaha'
anothen
SN)
Ctolous&
Mechanilmi
HT cHa-cH¡
CMethanol) (Ethano)
HOH the: ’
E -H+
Uwertale of 3 Deotona
tion
2C2 -Q -Ö:.t
Zymade’
Bydehydration
2n-0/Crz03
R
-673
S73
yeadt
ot
Prspanation CH3-CH2
ofAttark
aleohadi
H
OH
CH
CHa CH2
CHg
Ethens
Co+2Hg
)
+NaI +NaT elninatin
z°,
eompetes
+CHyoH Hs) Renes
najon
CHa cH
11 CC
CH CH,o-
3H,
2CHz--CzHe
thsne)
(rathany
cHe H-¢-I’cH
CHy
2CH-o-Che 11
CH,-C-I
+
CHaoat and
Austihfion
-+CH
AcH,--eNat
(e) CH2
CH
CH2
ha Cha
CaHt
Na+
CH0Tat CA) aduet
A+B
cHo
pnedenee
of
H-bontng
YOUVA
T
MTW
F
B.P.
otadeoha
dipoe
moment 396R
No.:
Page
Date:
Oe
+
Na
B Uorddin
ethen 307.6R
+
NaT
Q-CHg Andoe
difenenee
dange
the
Phenetala
Phydical
Propentied: deta
to
hare adeehols
in
CHzCH2),
CH3
+
cH-Bn -Ihe
C-o 3o9.1R
R-o-R
ether
ethens
Nat
"The
B.P.

You might also like