Aoids

TUPAC

Chlg CHO
Melhanal
etHg-C-H - Ethana al CHycH,GH 5fuopanal

3-&Hogaudaual
Ctig--CH CHO = 3,8dume fryl
loetanal
CH, =H-CHO CHe
Ph-- c4-CHO
-CHD
SPhany' pep 2-eral
cycloperiareeavbal dahy d.
-CHO
), yolo huan caxbaldthyde
CHO

-)
CHO

pnityo langal dahyd

 - bunyaldihyd 2muthyt enclo hexansnu
kutons 5-kehyt kux-3-n-2-on
Cacetoe )
frokanon ta
Bectanoe 12:)
fentan- 2- one

OHlg- cH- CHD

CHg

4-mettasypntan-2-on
Phenyl ethansn.
Cabatophenoru)
Phco h - kungo phunont 3- Hyduosy but anal
(w) 4-Oropartanal Che- C
0- CH, -CH,- CHD
yelapntanant ()

2ethyl oy clo hu sane

4- Flueo aotophenana.
-coch;
CH, -cH -CH) ),213 puoparu tricauboldehyd
CHOCHO co,hsy
pontan -2-one

qadka mottuye pante

epaatuön < Aldehyds and Katon

CHE CH
17. Hg S04

cr'g
CHla- Ctt, -CE0H t,o CHz-tt3
(a)
Cth- CE0-CH

eHa- C CH - CH, (6)

Cth cH =t -eH,- CH,

CHzCHO t CH, CH, cHO
=CHrCt
CHg CoCH3 t CHz CHO

HCHO (e

CK
 -Ctlg
Co-H,) GeHD

CHg CHO

9)

Couo, ls) olloued by byduolgis

)
(b) Tolutne ui o0tdisnd loy oulg aud
to
avo acotie arkydui'd
Hgo
cH(0 cocHs)h

-CHO
 R-c=NH
A=

R-CEN

cotalt which à deaetivaid (R-cN

R- co-'+H-Hfa- basa
R-cHO tAct
Hce
CHy CHO H

kactiolly oteduud *RCODH 80

A=
ROH0
RCHC

*R-C=N 3HOH
Rre-ox
So2,
Rre-OH
 K-CH0 NH3
Qlluyl oqanid
kotone
on uith

R-cEN 2g0
CR-N) R-c-oH
R

K-co-R'

*RCo0H 30d2, APd- Basoy

A=

B RCHO

HO
Pd-Basly
Gatixan Koch Ran ; 04/o8/2 3
(o-01HCL

Gatt eran aldehydt dynthten i

HCN 1 HCR ,CHo

taluminio iygdbida/alH (Gbu'),

aldthyds
RCN DlGAL-H
>RCHo
RCOoR' RCHO
RCOOH
Cl, =eH- Cth-C0 oe, H5 CH,=CH -CH,
-Chh - CHo
Cadmium

(dialkut

(o1 Reox _anhy alCls

Ackylaton)
+CHg C00oy
 knggphoners

Ghanieal

(u) HeC-0=C -H Cti-- CtH Hetone

uclcghi
tnat c
NO,

to wat plana
ihiy readily joun n-bond itb wstie tnslsns
(nolase rramj Ketor
ÜnoNaAD , thucky dolubility o aldohydo darurgcs
Bin
OR

nlsnaty purgnt mdl caebor

than that
 Sntext

Chuvnleal Porkuiu
dh aldchydt ucl as keont eh
canbongt Cand caxbayl
Hee caukonuyl eaboo s Cenle
)
Kelone i ltas reaclie than aldohyoe
bccauak t
that ch ony ona Subttuunt o aldehyd

tan

eHg-e=0 <
CHa

t Keton

Bngaldlydi
OR
is ows iaclie Han pukanal, why ?
pcjanal , why ?
bungaldthyde chas
diecots the naolecbhilicty caubonyl cabon and hi

,
 Mecharium
1) ohowo)

) enp

)A
ddtioo R
1

H
hiyly pulo)

R-C. 9)
P

u)
Jhoo .
 cnueao

) ethaal to 9 hydo yhancic aeca (iactue acid)

Ctia-~-tooH

Cchival)
phunyl2-hydueny cttonauc acid
) engaldehyde to (Máundalie aid)
c-c00H
1

ciHg
to 9-hydsueny-2-phenyl
aeid
projna
C-cN
)
CH3 CH

CN H0
H-c-CN

0.
Ch-tct CH-c-cN CH3-e-cCN

Sow

CtB 1)
 (iat ohonce oh s0)
tto CHo
CHO

NO

(-7)
.e daljitint

CHO

2) detal Rxn 4 Kotal Rxn

R-C oy He 1

|uhun Cabonyl nuactid with C

ohani aninl)
nild, aud uactiuity
 1/

CHC- Ce, Hg

CHa Cti

CH
CHg lo Chlg CHz0H

Ct

(kotal)
ktal)
 ConuooL CHO
CHO

H0
1
CHO

A=

NaBy

o-CH

cocH3 coCHg
cHO HCNCInoa)
CHO

(ktal ui not ckorcble iin trans)

KCN
) CHa-CH=Ci2Feid
íOTHCH CHycoOH S002 A Anhy,il, ethan

A9 CH-Chg-CH, e

bo) CHa- CH,- Ch, ChN

B=

CIntamoeulo
fudd ba)
 CHa
A
allkass

Riclu otion R-tHO

a) R-CHO NaBHa /1:BH, let, /Ni) / (H, 1PE)
U'alcche)

alccho)

Hel to allane

C-Cbt
yR-cH3

A) Oois
ReHO
R- Cth
 dlolehy dr & lectene iact
(uith
hiatrig th alliali Co,H 0Na /'Nae/Ko) to gie
allant

(NH NH) N, M, R CH= NA)

R-CHo R-cH3
R-CH3
A

vo H/y
- k

R- C0-R

-Hg.

Ongdalin by etongot exiduing gont

ReHO KHpOy -KoH/Mg0
 to
aduce

R CHO

KCHO Ao
ROH Cu,

CHo

iognt
dcu not ordues tollrti iogut

foopa

9lu504
RHO+ 30
 -(po

KHO 9,0o (T) -

lrqpanal
CiHo 2 ut"o CHO

alo can
 )
yoosil Aníns NI,o)
(

/NH, NH)’ n,N

) y dnosuu NH NH) H,N NH"s R
o)
Nt, , NNHCON:
sudt (it, NCe NH
D n-Ca vka
K-CHO

1,N NH
NO
(d)
-NO,

) IAnL RNH,
4) Atnonia -NH (2)

uitt

-C0t NOH
 kelo mu
6) hycdiasn
hydvngone
R-C =NN H
R-C=0 1, N- N

R-c-R'

(a)
K-C.0 H, NNH c0
C0 NH}Ro=NNH CO Nb2

R-C= NNHC NHa

R

R-C= NNH
|2) KC=0 t
H

1,N NH
-N
R R
 68
kelimine.
41dinine &
E)
as
ldumin s lenoen
A

85
FNOH
-CHO
tæ)
-NNH
)

) Hetir

()

atone
jot
N
 68

(4) CH3

-CHO
jalauig

Ny Hy/koH

Dthan al ond

fhan Veton btcouer

to
yeot ineC005) wshich duosas the atocl rscisph
yde and éoerdy due to Hi
utwo hindyan .
 Hgo 9-znal
) 3-Phtnuyl
uep
loHCH0 -

-CHCHO CH NaDH olil. -CHO

pent-r-en-
one 2- 4-Hekhuy
CH3
H-e0-CHa

one -)- 4-Hydsozy

pnt 4-othye
CHg
CHy-C0-Ctl bauyata balew),I - CH-
CH C0 2
dehydBuotonal [
CHH-CHO Ctor al) en 2-
bute t

btlnal) 9atlg-ChHo
NaoH di
eCthydvrationpuuct atòneondtns aldol N
giepuodint Fhia .kotol ond aldou
tng atom Ho-haur mose dao ketone &
 9 CH2-(tl

-CHO
Ctlg-(0--CH2
acbena!

CH HO HOHO

Ple:
OH 2CHaCHt,
OH

ialde
CHgt Hlg-CH10 CHl- CH, CHO

Aldol =

Ct CH -CH0
CH3

2CH, - CH-CH0

CH-Ctl,- CHO -