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ater fs adcle t to ehny n

ng Coy , SOy

+
Aeealdeuy de

6-CEC =1 + H0H hgsoyHC


Eye
OH

Ch3 CCH
RDSenmumd Recduchn
a Benzyl Chlorfcle nclegC)hydrog enom
prenCe 9 Pd-BaSO y benzaldehyde/
aLetophenone
CHO
2

Benzyl chlbd clt


Pol-Ba4
3)Ehay nitotle trcatol oim Sntlh t nu

ollael by hydoolyais
a0 CHstHO
+ SmCl, tU CM,- CH-C1=NH H0
C-CN
n thloaids
Rea cf6n
oun innu realdelud
Stephen's

E H u prop0noate toecdcol wt bIg AL H


coldt tton o a t e r

CHrCce)-C-O5 1)0fb-
al-H >
C _po0 panocu ii)
i) M30
MaO
C-Ch -H
PTopana
5) TOulen ts treated wit Chrom ych/oHol
Pn CS2 Jollooecl by hydoolui's
Ch ium pler
cH OC 0H
+CaO Cl, CS2
Toulen

Bemzaldlohyou

trect of th romsc outcL f


6) Toulet ayelrolyis
at etfc ouh hydole otlowco ly

73-283k

Co +(Cnc0),0
acec
Om ydri cle
ul

ChO
A0
Gemzaldlyoe

Toulent Ps threeted w1H C m Sunlg


4ollneabhyeouysi

CHU2
+Cl,/he
313K
bulen Oemzalcelyl
emzy
tuio iicl
treatecd of dn tO ano, 7U Tn resen ce
BenzeMe
or Cucl
anh PIU

CO,Mu.
Anhyh Plth/u
bemz aldeluyde
enzeu

utterman -KoCh rcacthsn)


YeacH@n

Lofhn olietuyl Cadnuum


Acey Chlotde

-cl +C2n Cd
-Ca FdCl2
2C tena

wPh phen
phemyt
m?ttl trect cel uo
OPrtopane
bwmrcu Jollaweel bhyeholsls
ageafu

MgBaC-Ch ,N Mg6
C-C1-EN
+ CgMs

CH C -C=o

+N C6 S
HU emt
trceut ed
uOTtn
to
Renz eMe
ben7oyt cnloot de
11 9-h
fn
Attt6
presen ce
Ett
AnhA1Cl2

Pnhe Pl
benzenu

ben3ey bemzophenone

Chiefeole
2 Ac etGu r o ted Lolh MCN

O PhCN cn
CCH3
celone CN
Acetene

yanonycbin

oHu Socium biiulphate


3Acetal oluyde treated

C C-O Na SO 2
C ONg

Acecldthydle S01

C 3C-OH

SO No
c h o nol Cn
y Acekalelehyole trecteel
Ores enee

CaO OC2Ms ipn ORCais


CnCH0 a s C -C L R- CN
19calduyes
on
nenia ceta OC
Acetal
16 Cetone treoteel i*h
ehylene ycoD
Cha O-C
chh PlM
ChoH
cefem
C
tretec w Pin
1celeme CdOX ant'ne
6
ch C - 0 4+ Hz N-0' CN-Oh
C
cekeme Aydaouy
CAmt Ordne

1 1-truldelycde trect cel wih


hydrozin

c O + N-N2 CA3CAla N- N12


hydaf 2tme
Pcetldtelyelk
Aceulodhyu
hy dhuzene

e c e lceinyde eto coeo o1n phany ydraztme


8

"3co H NH-

C - NH.

19 hCetaddehy o e t e teated ott metnantanmiNe

Ch HNCH

+Ho
w uon Se miaTba zdo
treeted
20 Ac efuldely de

NH

e mCabazihe

CEN-NH

C
zna
Ca
S e n n i C a b a z o e

Sennu

A c e f a l e h y ) e

ectcd wf
1 Acetul dehyde
hydrazfne

CA H-N

C = N - N t

2 Dine
AeetLede

eeute@

C3 CH NH

mine
23 tcetono uteel o dh 27m -*1G and Conc. n
oH

C
C4-CCH
ConHU
Ch44A
PopAe
ACRttn)

Llemeh Sen TedULH


tueatec wlhn udraz in llsw e
hoa tna wh KOM m
b
ylen gy col

(T) HnN-NH2
CA ) V
(loH, ete Pp

5 Acekuld ely de Leeut ed wim tollesis reao en

Olt

C4 CUD
Tolles test

uaco ehlng eent.


26AcePeuldeluy cle
cHcO0 + CuO t O
0+ 2Cu+ 5 Oh
Ca-Cxn RuO-lavon ppt

eLeted w i n Na01
27 c etld elny de
Na OT
C h
CH +HEANa
odoto,
f Na l H,o

yele renipatr
Peetldhuyde eeted ottn olNa0n.

dp-rlae
CH TCH,-C0

OH A CH-CH=H-CH
CH-CAO
CHCH
H
aldol

R9 eurzalclely cle treate tottn


pxesence olil Nao aucerophenon n

HeCH dlnao

CH C4

-cH=CH-O

+
20BemzQldebuycle
ueted ltn COmC Nad n

CHO
CDNe

Ben7alelahyde Bemz Soolfum


alo benzocte

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