elaso R

ALLOHOLS
ydsony duivative atkam

- OH

Laatiow ba4ed on m0. ofOH goupi

Diyduic die Poluyyduic
MOyadu
CHa-CH-CHa CH2-0H
CoRDH CHa-CHa
(CH OH
OH oH Oy 0

CHCH-CHg Sluouds choin, positiOa,

CH3 LAtDwal 4 CptiLal
ouLism

No dLou
IUPAC
CowMon namL
CaubinoH, OH
CH2
0H wMettcaevno
CHi A,C, OM AtytainoL
 PALpaatio
ORydaoly o allyl haliu od00 akal MAGLKt ,0

RX t KDH 0a) RoH KX

PX + Agon por tA1X

Rxgmd seld ot oluolat

3KX major pmdut duL to lininatim
Hydiatiow e alko
R-CHCH+H2 SOy R- -CH3 R-CH-CHa
OH
AiL) oso3
alucbol
Maimly k pepaatio s43 aluousls A Ovly
OLpia aluaol-GHrH be prepauud
MK adddtige sLaUMgmt poil
CH-CH- CH CH H20 CH CHCH-CH3
OnFuttet ydid2et
HCH Hz0

CHa-CHCH=CH 7
Ha0
CH-C- CH-CH
OD
 y d ra (die H, s )
OMDM (MR) alassnate
altoluat tlyd robova^(AnAR)

CH-4-CH = CH
CH-CHCH-H3

H-CHa -M2 CHz-CHCH-CHD

DEO
OD

014mLLLLLLALo DEDuLnALUADtiou
R-CH CH, L--CH NOBHy
Olf
R-CH-Cs
HT

ACL to AR, n0 uauansgimusposible.

Ruduohoutiow -czid atio mturd
GH-4 CH tB, Hg 3(1,-u-it-B
OH

HsBO+ CH-tH-CH2O
AMMR podutt no ÁLauagemocupeaibl.
OHydutygu o uteaR-CoOR stes 1oalohel
dcid
+ H
MzDDRÍOH
OK R-C-6H KoH
OR (DH

CH3-CTU2H t Ha0 CH-C-0 +CaHs

oltolw
CH-CotM Ho CH -ONNa CHroH
 Hdsolysis ag ethu R-0-R H,o OH

R-oR HOH Lai Ha PoH oH

CHa- HS t HOH CHsOH CHTO R
R

CaHs- aM+HLD 20 HrOH R2

O 0nksneA al HNO
RNH+
HOND) ROH t N21 t H20

C2HsNHa t HON CaHsOH +Nt+H2D

MAuyl amune de NOT ield miu alualol

CMaNH2t 2H0NO CH3-0-N- t2H20 tN21

KRtsNH t MNO Cns0-M3 t sHaD N2

RNH
ik or witing prduu
ONO0

8RAuctiow oCaulouyl copouud includin caceauli

Lacids A ut¢Al
Addng agT ZnlHuNa in CH O
LiA4 NaBHy
C t HNiPE Rtz DH
akdalayd 'alohol
K
0t H N PE Rc-DH
utona R aluoluo

O t 4 R-HOH H20

R-ctoR+ 4 -0H+ R'oM

R- + 0 RCHL0H H

tR RCHDH+kUDDH
K

dutio LiALH|NaB y Canmot udue Olepinie

aleine)
CH H =-C=0 CH-CHCH CHOH
a
CHa-l =CH-r0H S C H CH ata OH

Ts bond utaintd audoat ot alkysu ú

uductd
AtdLydu 0d auiu, Hu, gtu tuinal
Md WAt C give (altohol
Kutouau U t i s a l qive 28 alunhel
 Huundtional dutprduet Ruagent

CH2OH LiRHuNabfu, Ea Ha
-CHD
nldebeqds THE,NilHa, Wa lCaHrt

CH-O
-CH DH LiAH BaHs[THF
-CHaDH iAAuNaBH4, 5a
LOC THF

(RCo), o R CH2 OH Liatt BHa|TE

HaNI

-CH-CH Ha/Ni, BH6lTH

-CH OH LiAlHy, B Ha|THE
-COOR

OAAAiiou 2Mgk to aldzbud 4Katonu

CMy
Ma=
oonaldulyda OH
CHs-C=6 +CuRSMI H- H30
Cans
ALLtal dilyda CH
tCA-COH alolol
 CH CH Hsot
Eute
CH-C-O
CH Saluakal
rwaldilyd Mgx alooluo
duydu P2'aluohol
(oftat tad fmaldskyde)
keto 3 alLohol
altoluo
CH-CHE+RMax sRHcHDMgx RLHtHL OH

cyelie etae
10FuwAtotiow O tabouduatu
RMInL cataustd by
atMat ibttt
Ci HaOL+ H20 E CHn Og t CA

2CHcOH t 20
>ital Proputie.d
(DC-C colouul gids
(2oric o buLAing taste CHsOH toio
(3)ugtor has att
(A)C-a Mustibt un H,0
Tley Have intes moleculag H-
bondig
miscibtuty un Ha0 wC
wadtbiu brdmaluinat D-H

pt 1Ct
Bancling 1 pt
6)Boiliug pont ighur taa alk
Clhenaical Propetiua

finwwo FOR bond

Hsion ok Hbond
22a (auicdic natu) 32'z
Reatiou iwotrinq iuiow o -0H bond
ORartiow sAte idl alolhott M alLozide ah,1
2LOH t2Na 2PONa t Ha 1
Sedum Qlkeuid Wrt AOU}
SunttasaU
> CaHsDNa tHz
GHOH Na

3 H-CH-0N tht CH AtH2

CHs
olunuaU ucppmliL
 Mutak udidk A MiOL wwidu sL ADO
alunhol +MHM 0 a aide

LOH NaH RoNa + Hz T

C2HsDA+NaNHa HgONA t NH

AADol no ALadtiou wa DHIEOH

ROH R MaX Ht Mao
ROR TNa cECH RoNa t H-C2C
abH +CH
EsteaiHcotiou
neuibl actioV m pRML LQcHS0ud
HL
RLOOH Pou R-(OR+ H20
altohol H2Oy est wtt

w dHeL ga is Specicsteutratios
CHs, DH CaHroH HLSOY

lLoeu CH, OH >>>3

or addi HtOOA RH2ooHRCHCOOH RatoDH

MpthauM
O ROH R--Ok H0
 Atulatiouw w acid chulouid arid oulydida
R-OH R-Ca But R-oR +HCL
altohol2
C2HsOH+CHs-CC 7SCHs-0CeHr
CHs tt H 0Car
R'COOK RCoOH
RDH T(RCo), b t

013- Pyaidane
t Cz HsOH CHs-C-0 CaHr t CH3 CoDH
CH-
T Raautiow iwrolui wiou o ROH bowd
ORLacto sit HX
Nuclsopile Svlestitufiou

HI> HBy > HU >HE

> KX t Ha0 3
ROH HX
or CH-CH-CH-H3tra CH-C-CH-H3
CHs OH

HC Znda LUtas Laqnt Gr00ueg Mottuod

alohol SN no ALaLLALgEALTA)
23alohou 9N (aLAgkATu pomblu)
alohols uat wo catlyst (1 A1otkAD
 CHs)-o HCD (CH), -u t H0
ADLAOA I 4Ld giveututtioto aa
aHsOH + aH1dothion GH 12)+ H0

Ractow Phopls.ou.ow halidt

SN
3RDH Px3 3RX +Ha P03
RoH + PX RY PoX 3t HX
CHs Of t Pac CH CL+ PO cd t H
PET QMd PI, au_prtpaitd in sittl inid aL
Mixhu)
IRatuow s sou thiose chlbndu
SN
SN w pyzidine
ROH+Sod dSRu + So1 t Hl t
Raction ammmia
ROH+NHs R-NH -NH-& K-NR
alc)Ha0

fvoAwain las a P r pAasttakNH i t xLLE

CHs CRS H CH3

CH OH CHs-HN- O
CH
H-
CH-CHNH
 Muceiasco Ruactio
ODiledacquatios (actio 9gCAot Cu)
RtHaOH 30p
fakcalel Aldilsde
&-C-o
KLtowt
alcole
C--0oH CH- H0
CHts dgdraten CHs
Luckel olk

Oridatio alcolol > T>2'>3

Kar0,/H KAAn Du H tOR DH dil HN0s

+ 4 t S0u
KaS0u t (s0u), 4HaD
Kara 0
3(0
Lalolual

puitiatien)caukezulleaea.
aldtlyde
alcohel
CH-C 0 CH=0 0 + H20
CHa-oy CHC0T1 H +

Luton
 s altouol
CH3 dekdaa CHS
CHa--OH CHs-C 2 t o Eetp
4) CH alka(a (3 Ha0

O dni
CHs-C=0t t HaD
CAL a i d 620)
ridinio cularoch romate (Pet)0EN H
aluonol alduyd
ca,imela nuixhuL o CGD3 t HatPyndin
OCHcN HO
alt aldihyde4 o 4feting
a alt kuton

w usonudu add Talt aldukyde

HCr 04) al kuom

C) CrOs t HSOu 'al aud

(JonLu uaalst 'alt alduhydu agcting

emmit au 2'al KLoni =C<
04 atu.tons)

(MnOa sulutively Oriduu allyic amd

bnzytit A2' alabbu to aie
aldukudu katoul
Rea cticm talogunl
Lalcohol tdhspdk
aloh kutode (coy-CHo)
CHyCH-OH cs-=0 c--so
clulo
Talokoloxiédationaldnlgk ,3,2-Taichiotkenea

NCH-OH-pRU
ML ML
alsalal ketowe Trdlvoautose
@Raction leackisg_poudesl Caocla)
PhLpanatio culao HC)
GHsOH+ CaOCl +H0

Ca OC H0 alon), d

aHCL

CH-pO+32 cus-C0 3HC

H chlora

OH+ Cus-C
aH
tCClyCz0
 Mettup ds tb dirtinguia blw ' 4 glpho
O LuCa Raqent Tet:(Znth t HR)
ROH + HCe RU H, 0
(Cont.)
Laqunt
RLactivityorde 3>z No twtbidiy
J n immudiate Twrbidity uooM tmp
tuwrbidityy aftea bminu (only on htahin)
2 DicwaMatu bxidatiou Tut i 2fom 3
noonidah
alcolhol
R CH OH RCH D- RLO0H
C
07ange r

2aloko
R
Ruon
aluohol

No OKÍd. alLon
TUMans
OT0AQ
Victor Myp Tust
T'al ouol
R-CH-OH RCH,1 R-CH-N HORND

Blod Rid Sutt R--NO

N-OH,acidic H
Niboue 2ud
aluobol
Rcn-oH CH-1 K~CH-NO2
R
R HonND
nD MaLtiow NaOH
R--NO2
N=0 (BuL gloua)

aloluol
R-C-O k-c-1 R--ND, 0
RLactiow
CTotowles
B
Col0ul
@atalutic Dekyduoqualiou
KCH2
altolho
0H duhgdtisgaatiot

KCH-OH R-c-O
Rkohal
eor
R-C-OH HKent duhy dsatio
kalcohal

LConvertion eimact
CHa-H-H-OH -CHO H CH-o
0 -pmpyl alohol uopmpyl alcehel

>thamel
) to pn aluothel 3 butyl alzolhol
(4) Ett aluhs utuul alueluel

(5 Sec buty aluelsl u t aluslusk

(6)1et butyl aluolhol uopropyl alshol
 hLpatation o dodok (o 1)
CH04tItNaOH
NaOH 1 NaDI +Na1 tH20

H-CH,-0H Nao1 CHs tdNao

Cl-CHO
CHs-Co t3Na0T SRdiraI-
Lodal)

NaD T,C-C-0A CHT t Na0-C=o

yellowppt
CH3
X CHsOH, R-CH-OH altohogiv CH3
alkali
Or 4 3 al co luau au
t0dfonm-
CH=O R H aL todekdrm tVe
o H
AUL othe aldihydLU LetenL a ioAohonm -Ve
acetoatdeluyde

adotnom + CHsoH CH-CHtD R-G0

howmal AMal)
CH3
R-Ct-OH