SECARY SC

LIST OF MPORTANT REAGENTs

S. No REAGERIT_
PuRPoSSE ISA
REACToNKHAPATNAN
TNAM-3

R-H+Co
1.Sodaime DeCaybo xylatjon R
NaoHCao) -CO)
atc-kot
- - -

2. lc.koH ) DehydrohalogenaTion CH2-CH-CH,-Ct3

lc. Nabt(o (-Hx) CH-CHEH=etg-o

Et oK or Etona eliminaion)
C H =CH-CH,-CH

Naot XCo)4aloform
er
tec Nactt
Naox Hotmann C-R
aAcid
---

bromanj de
dearadlon Ketone)
R o4+HC,

ualofovm
XNat, tho
RCNt2

R-NH
(Hoffmann brorni
gradakiom)

4.DilNaoH Aldo
ConteAahon5
Ct

OH
-

C Tauto merisn
( ldol)

-CH
6ut- 2-enad)

5 Conc Naot CannizkaO

Teacion
 REACT1ON
Sorto REAGENT PURfoSE
Na(N
TYans educi on C CEC-CH
+H) CH-H=H-CH3
alkynts
H Cao3|Ccis-reducty)|(cH eu
CLindlavs Ciolle d hyd ogei) trans)
Aa.Nao+
A NaoH A s a Soua bonde R-C --

eaut w R - o Na
Oranic adis o
give Aats
o A4:NaoH.
ONa

2)ASa nucleobhile R-x tOH

in Con&ti R- R-oH+

alcohols.

9. Pd-C/ (oy Cis-reducT+on (+t) CH2-CE 3rdlar

catayst
pd-Basoy of alkunes
Quinoline
Lindlay Catulys)||

kn diu ) Dehalogenatum H-

)
eliniato)

GH
Remova a oxugen
tn phendlS +n

Zn-Ha/tc Conyerting atekaes

ov)kemas t alans R
Hc
(c emmensenYeb etim)
R R
Akane
 ANY
PAA
ONDARY SCHS
t..ne.
REACTiON
REAGENT PURPOS E -

12Raney Ni, ISAKHAP

CH3C=¢-Ct t t
ATNAM-3

t alkenes or
alkunes Con To et or
N Ov N

Convert unsádlual d
Compoynds ing CHCH-4+-t
S a r a e CorpoUnds

NiOT
+C2CE CCt*Hot
CH-CH=CH-C

13Ni-Al Reduction er halo-

qYene t ben2tne
allot

D Friedel Czaft'ss
. All alklation 4atuon CH

CHgeoc

ct-CH-CH-CH4,-CHs
2 Tsorn-e Yi Sallon
(Csnvertt tinea attazes
tbranchtd alkan:)
CH-H-t-H-CH3 t

CH3-CH-H-H-CH3

AOMata
CA/ (Cony o
erk liner dlkan C9 A
Me-9 Ent ben2ene (a) aley
hene yclohaxane
benen)
 REAGENT| PURPoE REACTiON

CrP-h3
600C

n-heplaye watn
CudoheyaNe-

o
Toluêe

6ConC. HSoy Dekydation LHg-Ctt-O4 CH=CH

eliniatfor) 413kthoy
V
Hs-0-Cts
2) Suphonaion Sogt
(o
um oze-03
=c-ot
Dil.Hoy Esterificdien thSoy
CH2ott
4ydrolsis(+ Hh)
(adaition) or

oMerurdluon
aksn
(DemertuYaten
HCECH+HoH
Aune-
H-CH=H-oH+
CH2-C=0,
Bakdeh
C H c ECn +HaH
Akne
CHa--CHa
(Ketone
&Grianerd's As a udegakile
eagent (Rmin Converting R-CHo4
CasleonlCompound
aambls *R-acd+RR
 PANYS ARYSARY SC
N REAGENT PURPor E REACTIONN

HBr+ PATNAM-:

aulka H6Gt6 Ma(o4)Br

3 Conutti K-M-xt R-cEN
tiler to kebnes R-C=R R-¢R

CKetone)
Nalpry eher Converti Siniar *R{ +Na t R
or
dissimnj lar halo- (wyrt) R-R+2dak
alkanes t alkanes R-R-+2Nat {
usyta uuta-Fta| Ciourda-Ftpyet
R +2dax
Ftereadions)
-+2Nat xo
Fitig) dyalker
nNax

Na
y Convets estexsto R Et-
.NaEtot
alcsha

)Nileamjue Na
R=tEN=Ht+7
EtoH
Mtndius readion
R-ChNH-
Ben 2enes to -denes NaN )
21 Na N
Bircheduction)

Condensadim o NHN
22. N
CAybms kpdrotiorn
CH
 S-No
REAGENT PURPoSE REACTION
- kot Converiing a deies
--- -
-20 NhNH
o keone to alkanes
Cwolf-Kishne
euetion)

CAlkane)
B
4Br or Cl Reas- with alkanes t
CH-CH
q h t ov heat)
ve mfure mond CHCtkr
27
and poly halo alkanes

Succe ssiye. Yeplace- CHCHh gt

me ohydvoqens
CFreeradia) uletulien) CH CHHBr+
fminer
- -
ClH2-CH-Clt
A
25. B r Cl Kaatt il alkeres
Ccly nve Vicinal dihalvdes
-

losngr artuadditio
alkynes eat o
PJorm teka halo alkanes
RCL-R
- -

Reacts um l3-butadiene
wndergo addztion
aAmaqor pkduc at Oc

and -ddition a mafor (major) a-oc

dditor 6r

adrticy

26- BrJor)cn Akenes react wit tho HoBY

Souction of halogen in w
HO hlohjdyia
OH NaoH

(epoxiae
sNo REAGENT PURPoCE REACTOoN
ANY SE CONDA
SCH S

wity phnots
VISA4 ATNAM

hes2 4,6 fot38

Trikalogenderiktie

Reactwrith benzene
to fov kaloarene
Alc, ev Fed3
Underyo ng edrophilic HO
Substhtion Yeaction
chor Byin V2 Teachan
(Convert Carkoi R ot H
Red P acids t -hdo aleX*

BY TCaybon

Oseletve bromnatien
NBS(N-Bvomo
Suinamida) at allylic and bepaylie [o] NE
Pocitin

bentyli CHBY
cason

oxidse. (-alcbh R-CH-ot N

t aldehyde and -altal RCHO
*R-CH-oH

R
R

R-

30. KMnOa
conver.t alkones
3
3 C4= 4 + 2kMOy +YH,O
Vinal glyels +2ko#
(Cold altaline) aro n 3 + 2MnO,
Baager's 1eageit
ad&tior
SAlD REAGENT PURPosE REACT 0ON
31 RMnOy Con V alkene
Chot alkaline)
3 Kmnoy
ts atil kelone

CH-C-c+
((Ketone)
CH3 Ot
adi)

2) 0xidise -alrhol *CH-CH-alkokol)

and
K Mnoy
acid hoh
CH2-C -o4
-alholt kelone
CHg1ai
R-ct-0t
ho
(alinol)

RKebne)
3) Convert akyl
KMnoy
ben2eneto aTmatic (o
acd
c
KMnOy
COOH

4) -amimes onvett
CH3-CH- Nttbj
t aldehydes, kelone
Or) n alkanes
C-CHNH
dependiug On thL
CHyo
calk ooup Ljna CH-=o
2or 3° respecti-
vel
(adakyda
5 Conver ketonu t C--CH
Cayboxylic adds is
aidic wedium. CHhcooH+CHhCH,cooH.
 UARY

SCH
ANYSEC

SAO REAGENNT PURPOSE REACTION

Ihert wi akanes
RCHkMnby VISAKHA
but feauk wit5 H4PATNAM-

aIkanes having *
bond S and Oidses Chot

to alcaAd
32 HX D ConvertS alkeneS T CH-CH=CH+

halo alkants +HY

CH3-CH-CH2

Br ()

CH-Ch-H,B

) Conuerts alkynes o -CEC

eninal haliler

slad Hx.

Gemina
dihalide

3) Convet etieis t
Haloalkanes ahd
A
alcsh ds.

Convet n+riles t R-CEN

sndjd
3SnHel
aldehudes
Cstephen vedution)

H NHcL

Convert niYobenzenei lo2 FeHc

34: Fe/tcl
aniline NH2
O
S-No
REGENT
Red P HL PURPoSE
Convert iodo akare REACTION
R-T R-+
alkare ContHE
2) Con Vert nikosobentene
to pheny Re
hydvezyl Me Con -HT
NHOH
---

3) Convert alcohols,
-OH+HL TSOC
aldekdes , kétones,
acials to alkanes
----
R-4 +HhFt
R-C=o +HE
(So Red"P
R-CH+

KCooH +6H+T Kd
+5oc
R-CH+ 2 t o t2Ti
36MoIt Convertakl halideL R-toH
A toacolko
3 D nvert alklkalige 2R +A
eher shake

R-o-RtAgx
eher
CL
3 Cu A t 3o0t Cone *-CHot
(-alcohsl to aldehyde RCHO
Cu
9-lcohol t ketone *RCt-R . 5 KK
-alcohd ta alkere R-CR

R--ot Cy
513K
R-ç=Cth

RR=CH
Cu
Convert mllan 2.Chy+ 23
2 CHhoH
mehaned
S-bREAGENT PURPoSE REACToN
3) Convert Aryl iodida Cu

tbiqr S73k

ull mann TeatTon)

39. Pcls CHCHo +Pcls

) Conutrf alcohol ts
(Readian chloroalkane CHgCHcl+Pocl
So s Same 9 Conv4rt Cavkokyli R-oH+ Pcls
as pels) acd t aud chorida
-
Pocdg
3) Convert amida. ta
pcl
NGtvile R
R-CEN

4) Adeyles and- Keones o+fls.

T t m i hal halude

podz
5)Cone Ting kéboimes =N-o4

To Amia nitiles R

CBeckmann acTon

-Po

R-C

R-CEN

40 M 9 In preserce dyeh
ConVerts hale alkanas
Garards veagent
MGBr
) Convest ketse ot
pinnaco R - - RCpinnacole)
 REAGENTT PURPOSE REACToN
ul Bh THE Alkenes Veact ViS
AKHAI N A M - 3

CH-CH=CH2 t Blt
rVe ialk boranes
CH3-CH-CH

CHCHth)B

CHCH=4 B/THF
2 H3 THE CDlin4 Teactron

takes plate afte (CH CtH,CH),3

ladtt akyl borane it Canve 4ogNoot
Into Coupled alkane
Ctyd vokxtton Coupling)
CHÉtaHs
n-heiane)
CH-CH=CH
3BtH2THE Conuevsion o alk
wth CH Coot boranes into alkanes
prsbrlysis ofaci (CH CHh)B
CHCoot
CHCHCH

4BizTHF Alklboraues inta

tRminalalohol Cta-CH=CH2
Naot (ti-Markovnikovs B THE

produt
CHtyCh,CH28

CHCh,Chot
+BCot)
Pcc(Collins Convers alatah t * PCC
ys Yeagent) Cor)
Carm Gmpunde ot PCCR--R
PDC (o)MnO, ev)|
CrOg Cov) tCro
CJones
S-No REAGENT PURPOCEE REACToN

46 Ft,0 9 Conveyt benene Fe h

Fentons pheno -f

Taaer)
) Convert -.
R-CH-ot Fe
hD - -

alcohol t aldekyde R-CO

and ketanet
Fel
R

C03
)Convet g -alcohol R-LH-oH CHLoOH
47Cro3|Acefc
aldek and R-+o
KeanesS
R-C4-oH
ACettc
acid

R-1-
alketnes ta CH=
2) Con ve
HCcot
Cavkoxic auis lyt -

S p i t i T K dsuble

bond
Convfrt ben &ne Ta
)
Y&.ConC-+No3
niben2ene
HhSoy
---

2 Conhert 9lutase to CHo ConC-N

Saccharic acid
CHo
onl tevmina -CHo CooH
CHt
orterinel-ot
Youas Ta-Coot) oott
3) Convevt ketong CH-GCH
Cavboxyicauss
CH,CooH +CH CH, CoOH
4idied
o -alhr acids
4-9 Crov) -al o t ketne *RCHoH RwOF
R-ch-d R- R
 REAGENT PURPo SE Ot..
S.Nd REACTIo N
2)-cHo- -CooH RCHo>RC
RCNSaktAPATN ATNAM-

3 CH-c-4CHC

ketsne) CH2-00# +
(Splitting- keane CH CODH
akes place s side
havin kueve Carbons
Popoff rule

SoH8F, Converh nA
aA atonium kaida-

ints Flusro énzene

* ***