YDROCORBON (o1)

(yenehun ilhManl)
Rene n)
(tkutkitio 7R-R
(Wuntz Roaoion) RX +Na

R-XPh-xN Ph
A
Radction) Ph-x +Na
(Filig
PhPh
Renetion) (Mamklamd Ran otioen
(Wmann
Ph-X
Cu Ph-Ph Ph-X n Ph-Ph
R-X 2n R-R
EHL RadialCaxbamien both a intexmned ate
Um 8X
ROs imuo)ve C-X Bond AkU
Ca
Teduco
R0-R 8 RI RB? RCR

*dymamalkue al alkones axo obtaumo d

CHy Cam nuwe be obtauma d. 6idib

duspxopolionaion)
eactiem

Hoignad favmatien

R-X 8 R-Mg-x

MgR M R-MgX d
2e
#(Kolbe'sElecbolaib)

AnDds- R-C-0 R C-o R+CO2 TT

NaOH + Ho T
Cuhods-OH R-R
F
* CO
* pH

Tn casa
RCOOR
&

ma
l
Radical Tntevmadiato Fomad

H2 olhasts at omode

dcum

o yaxmie
be
um 00ases

majon R
aid (Hcoo),Ha
anmd

(NaOH

us
11)
cathode vospeotwely

gas willvaloase atomo de

terthay .
amdl cathod: borth
 02 HYDROCARBON(02)
t#
(Photahalogemaben
Uabe
ilpAR Odical untewm dinto obtaumad

R-H Xa/h y R-xHX

tomplh o dia ubslitulioo oaacti00

:ds
TniliatenX-X
R-H+X
hN2xO
XKimelio dsotbpia
Kumelio sobp'

raumation
aotu ohsued
Hc-0C-T)
fee" Hadical s Ros
RO +H-X
R+X-X R-x 4X fatan Oadto slabilidy
o ()

Clwronntien) lodumatien) ChWayinatien) (BHomumatien

Highy enotheemie XSboest RaveuibleOnstabl los abe u
CHy+2 hi 4F|CH+T2 *Ma Reochwe *LssRadnolite
black CHg+
HI*Los3Aeleclive &Mao aluebive

2
Rates Rados
eidias unto T2 by Reachivty Reactio4
o:A-(HLO3,HNOs) (1:
3-8:4-5) 80: 1600)
12 3 3

+HRenction oithNBS:-)

NBS N-8Homo Aucciimide N-&y alylie Bemaylie oy oi

fe Hadical utexma diate obtaumad
*Eompla
Kinaic
ouRacical Aubstitilion
Tsobpic oplaat
Rondtin
us
o baaxueel (C-HC-D>C-T)
NBS
%Pura
(Jubatihdos"nly
int so
allie3 8emzylie positien) A
NBS HB BH2 is addad as
impwily .
To odain maximum
stabiuty (Heawramgernort Canbocation
CC
HOaramges.
3C-2e bond un Uolved um cas o88,migrataxy apltuda us
3 MCTS unvolued odowea
* Occwts
1,2-4hift H7 AH7R
Duung uastiamgemont,conguwtaon Ring Expanaien 8- 4-S()6-1(x
chomges.
nawey S-6(
*Caxbocatien must get 4tabilitu BicyclnFS
un enh lap uaHoNamgemamt
 HYRoCAR BON (03)

(ECeobophllin
dddilionReaohion

A
N
x
unmaroel
have

X Camt y
Y
*closaical
y
can'haue

unshaod
Non-caujcal
Caxbocotion
cc)
CC Carbo caten
(NCC)
P2
Raagent e Nu Path
H-C4/H-8M/H-I
0- Co 1
H/H20
di
eH Hso @
H2SOy H HOH
ROH/HO HO ROH
RCOOH H HO RcooH
X2/CCy X 2
BH2/H20 aH HOBy & Ha O Br 2
Br2/H20 un Brime
boln He 0,B9 ca 2
NoR NO 2
TN3 2

Addiien H CH2 CH2 y

CHa - CH

CH2 ECH
1)CH2 CH3CH2 Canbocauen yamod /abtauned as Pntbumocua

GHO * Keaoiamgemtont may be pai

Fovmabn of cC R:0S.
X Both yn b Anti addition paisible
2) X8 Y may- may not be vicnal.
CHa-CH2 CHg-CH2 XRale HI>H&n)HCa K
o Raachion

Rata E addilion nuelhophilueity of

alkona

Caxbo cationstabillhy

4tabilihyof alkema
 HYOROCAR BONO)

CHaCHXXONdu
) CHa CHa CHa CHa
Cc

du ala
XNon-cdasaical Caubocahon (Ncc) nteuma
Gxd
XNo- J avoramy em.om.t

X8oth X 8X mus} bo uucinad

2) CHa-H2
CHa-CH2 XInvoloesamti addibon
R0:R FaCla A1,2

tà
TptsAkant

(-munms
dnti
()ym
P Procduct

(-)
cnt
(4tis ( (+)
(4)

X
#(4Um Poc)* Uatd to elaet ums wm compo wnd
aturatien,
XReddiuh Bxown colowt o! &2 becomes colowloss

+X2
&oon
Coloun O (Colousles)
O
#RCPand TP RcP)
contalled
XKumatically *Theemo dy namicall Conty ollod
Rat (fdst) (PModue atable).
Atability
fauourS at dow dmp fauowts at hoh domp
* aloays ,2produet s amumed Ttcam he L,2 0 14
08 RCP

* Jost am caxbo ontien 8 attack A

x Thom cation wi0 Aho Rabo bo chook
atabilhpHo duct TCP wl be pModuet
#yduation Alkumas) H/H20 Reatnamgemem
dit-HaSoy O
O CC
OM DM *No eOJUHagemamt
NCC
XMaknolKou
HBo HO No Juawramgemam
NCC
&Antimaxkomikou
 HYoRoCARBON (05)
ydbtatien ofAlkyn
OH
CH-CCH d Hg SOy CHa--CHaCH -CCH2

JA (maould
Poor

highayumstablo
(Tum@)

CH3-C CH,
dus do (+Ue) On alken

#Kuchvou Randen
OH

CHg-CCH 17.HgSoy
dio Hasoy yold as vy g0oa
Tmum@)
(majo)
OH

CH-C CH
H20 CH3-= CHa

o alecHophilie addition oaction

Enamelo
*NCC THRA
umteume diato InuolvesTaudorousm
Mimed Covubony a obt amed

#Czymo1nation Domoycun atisn (DMDM)

(
)Hg-(0Ac)2/H20
Makoni kous additien
R-CHCH2 R-CH-CH3
i)
Na BHy/Na0H withod tOUamg emomt
OH * Both yn amd anti add"
1RCH CHa 2R-CH-CH2-HaoRc
H20
OM us amti add"
A
4o fc OAc KCH2
R-CHCH2
(XNccL
HaO
DM
S0
umuolves

un amd amti
both
0o Hadue a

GHa *Mtal (Ha)sobtaumed

OAc (No-ment
Roaetange
OH
OH

R-CHcH, oC NaBHy
NaOH
R-H-CH3

(*Hg (ofic)2/h0 OM
*NaBHy NaOH DM
 06) HYDROCARBON (06)

FEdo B0 atien bidatiom HBO)

(
Rx)R-CH=CH )82H6-THF R-CH-CH20H
i)H202/ Na OH

R-CH-CHo
B2
TC
THF
H6
H

R-CH2CH2-BH2
R R-CH2-CH2 -B-CH-CHa
CH2
-
R

BH3
CH 2
BB
R-CH
BF 8e8F
HBH2
h4MCTS
CH2

A
*qn add"

|2)(R-CHa-CHz-B9
0R-CHa-CHz OH
OH

HhoHa0 R-CHa -CH27H

R-CooH R-CHa -CHa-H

X2
NH2
R-cH2 -CHa-X

R-Cta-CHh -NHa

7eidation) H202-H20
Hoo
RO
RaBH-0-0Ra-B86H 6-OR BOR)3 B-OH
Rovo RO
6
3ROH H
A R
OH
B03
3 RO
B03

XRx
Commex.ciad mažhod

de oxm phanal

o-0-H
CuuTemLR HyduopeH0zidd)

o-DH
H
o-OH2 Ph
pn

(o) H20 oPh

(Phamul AJhi)
HO Ph (o
 HYDRO cARBON (o7)

Bieh Roduction

Case I R-CEc-R Na/dig NHs

OH
R
CR
H
H

R-CECSR R---R
H
2)
c-C
RCC~R EtoH
RcC
H R
RccR
h
COso T- Na ig,
NHs
EDH

e
EtOH

Na /0i9NHa s a blu olou solutien

Both bo odieal amd cavbamien

ROH us used 0b pHoton sourC

*Tewmim al alkyne wul not gwe adkana( T do
acid Bass Rxn ond
am
ae eaibl and
vteD

In cosa oalbsuluds banz eme m@u 09aumaxm compound)

stable alkane us mo pHoduut.

Caialhie Hudrogematen

HO daion ta tA 4 us am
enample o additien

Ha/Mi on Pd o P HOnctien amd vodox onotipn2

H An ezanph e n add
addilien
B8 Raduetion
Enanplo wace phumomamon
BF BeBA amd 4 MCTS
HH unvolues

Lindday Catalyst *Pd/Baso a CaCog kmown

us addod
asundlo
as

A) Atum CatalyatQumaluns

d2) Add Hadido ene

PQLben

* Tn cae of conyugatod
duu
dibna

to 6MCTS
L,4-
takes placo
addihon
 yoROcARRoN-(o0)
F(Rasemmumd
Renetien
R--Ce H2 R-CHO
Pd fwdhuot o dalt@n H20
0H
BaSOy
pau oxicdizehoga
R-CHO Ha2 RCOO
RHt (Ha0 /Ha02)

*Ozonolyis Zn.,s
Og3
R-CH CH-RT R-CH0 +R-CHO (duotwe
)znH20 020lysis
902ygan trapp0
i) Og R-Co0H +R'C0OH 0zidabwe
i)Hao H202
o2onobyai

Og
H3C-CHO CHO-CH2 -CHO HCHO
2n/H20

03
Ho0 lHa. 3C00H + COOH-CH2 -CooH + OH-C-OH
202
H2 C03

loko nolb lo H20tCO2

+xiclahien Akoma
(S.0-A) 2CH3CoOH
KMn04(Oci
HO dabwe Ozonoyu)
*HC-CHFCH-CH3
7:
RMn04
CH3
213K(0°c -CH -CH- CHs50yes
Sun
Rragsnt
OH oH Acld
CH3-CHCH-CH3 K Ma M Aad)
*Gauch àtabl *yycoluaton
OH,OH)*M Mnt6 (Base)
*BHouon
H-Bondun
PPtS(Ma Mn (Ntubal)

CH3

H
H
O OH
-OH +Mn02
Mn eslo
indevmedido

o CH3 Ayn
qyco
Add

ubatien
 HYDROCAR BON(O9)

CH3
Lochemuby-
-0H
CH3
KMnOy
L7- KMn04
CH3
Colcd
OsOy H0HOH
H
CH3

R-COf0H R-CoyH OiAoACH H

CH3
A20 HOHHO -on
Agues nacondt HO-H HOH
Lo) CH3
OTHaen CH3
bond
Sn add"
*panoy
m-CPBA 4buad

*Bruyy's Ro0gent alsoozidusoaldahyclos KMn0y

R-CHO R-CCoH
0c
lhsodha

LHO OHC CHO

+ HCHO Roduuctuwe
OHC

nint cooH +HCoOH

+HOO uelhtCo+HOOC Ozidntiwe h

CO2

#PHoet kekulae8-

3x+ 24 + dimelhyl
Z

CHO
+CHO CHO
CHO
O Gyoxol)
CHO
O CHO
(mathu
yoxal gyoxal) Dimathy

faimehy
HOxal
 HYDROCARBON(10).

7T Complor
Colbr charye

(Elacbuophilie

Rxn

Mechamusm

J M
a H
*o Comploz
*Cavbocahon

,
Ke fndexmoclicb
[O) *whe dand
Comp lor
(1weAible) Reuveraiblo)

Eve
PE tabd TTodinalion)
utnh
Biomolecula (Alklaion)
Hale =KA-H][er) coCboylahen)
(soa,
gadeous produet
Sulphonaien)

D
P&

PoR Compx

A
#(Reacbuit PoR
Robinhood
EDO

o] Rat
(+R,+1)(+H
(aclijvang)
3
(Daachoatung)
(Net-7)
2)
lo] Rada (CR Robinhood eWG
(-R,-)
(D2actuai)
 HycbvocaNben(1)

tntahisn)
& DO &DO EDO
ED4
PoM)
2
Mo
Robim hood Rcbinhoed Aobinhood
Robinhood
o,P>M
PoM
Robunhood shoos Induehve
ect(-7) a achi
Resonanca
ct (+R) or auentahen
actoxs Forauentatisn

ei\k
1) B AtablitO-Comploe, dacido the maja pioduct

2) bame
3) AL
-Comp en ,Hhem
yactars sama Hhon
Aluia hindotwm
e uich it
D T (P,9,9 elaebonie ecto alk
2) sizeo} x
X 8 0i(9,5)
3)texicefAlky
aO A
OA
TO Monol 9)

P:9,s()
o-N
HNO3 Ha SOy

OH2
Nog(hHao
HYDROCARBON

O
2
2iso
HSOy

No
. (12)

eordboomdo
exnmplksAS)
HNOS HS0y
(o) NLLbyatLOn

Conc Haso
o Audphonati @n

R-xFACl3 Ak ahen o
Nehen cam b)HNO3/ H230y
Nitsaien Aenolin W2Os CHcooNO2
No2
oYtoM 02 Cone HNOg S)NO28 Fy NOgwOy

3)dilHN03 6)HNO Pallowedby

Rxn:[O
HNOG
Mochaniurm- ) mix
aorls HNO3 tHSoy H n0g Ha0 tNO2+ HSo
NO 2

Hso No, 20
2) B Cone HNO3
3)Py di HDO3
2H NOg H o-NO2 +Nog NOg

+No2
NO 2
( NO2
A A
4)8oyBfy OA oX
ND,CIOy Noy.co

NO2 Bfy

Na0s CH3cO0 NO28

S) By NO2

Nfo
ND3
0 C00
CH3 O1
6)B HN02 & HNO3 No NO2+HCA HtNal Ho-ND NO
NO N0 HN03
(o-A-)
 HYDRocARBONJ (13

ubatienAnilin)
NH2
NH2 NH2 NH N02
HNO3/H2 S0y
NO2
NO2
(27)
(47 7
Roasen DO de aum alion (S7)
Mcy@
Mayo

Ac20/Pgicin(trong
Aciclia
M A Maclu

8Ac0/Ppicio utd
Fo lBrthyYeld

a
WHAc NH
NH2 NHAC
Ac20 HNO3 H3o *qpod yeld
PPyidune HoSo4 O
a HaSo04 NO2
N02

R-NH2 RNH-ACHNO RNHACLHa0T & NH 0 o

Pgvdin H2SDy NO2

R-OH Ac,0y
Pyicine R-CoNH2
hl Acg0
Pyidine

FF{ Nubralien Phamol

OH
OH Pioxie Acuol
Cone HN0 NO2
3 Bad Yeld/Pao7 Jield

OH

Conc
ND

Ha SOyNO
rNO

O
OH

SagH
SOgH
N02

Cenc

HNO3
ON O
OH

NQ2
NO2*PucrLe Aad
Good iedd
 HYDROCEARBON(4)2
F(Cbulphonatien
Readien KX-may Cond H,S0

SagH

Ranction:[0)

Mechanism SOgH
Conc:H2 S0y

HaS201

H2SOy
t HaSoy

1 HO--OH+H2S0y H20-OH SO3

A
)
#(Halogunaben
o Renchen)
SogH

Xmay
OH

Ha9/
1)X(un
afW
Os

bs Colso Achvatad vung kp

OMe
2)XalLtoisAod (Fe,feXg,Zna,
AK3)
Rxn8-[O 3) Tdeehalogen 1-8)amd (TN3)
(1-8,
Xa] PPS (Ha0,CHa C0OH)

Mach.6
1)xfx
a
FeXs8 Fe xtx
x I2 eyeribl
So HNO O H
LO

X-X Fe Xa

O2 /ho OtAT

(encos)

[o Ceacosb) A
 HYD ROCARBON (IS)
Halogen atien on Phanol

NPS

9
OH
Rta1(CSy
H Anio
CC
CH03

QH
XDuy ts Haum atitn
BH2/H20 B
PPS
B (1ohitoppt)
Ph-o9

+ (Haloganalien o Anline
0H

BH2/ CS2 By
NH2
CCly
BH
OH
B2/Ha0 B

A)MAAA
o
X OH

SogH
B HB/H20, Au.
HUeHsyble.
B

F(THudal Cuat Ronctons

(ALrylatisn
Xmayba-)R-x lLeis
Auid (Fe,
fex3,8F3,
ARX3)
2) R-0H HO
3)ADkume /H
) R-OH 1 Alkama/LA (BF3)

Mechamism-

R-x-AX3
2)R-oHH R-OH2 R+H20
 HYORoCARBON (16
3 R-CH CH2 H
R-
Cawbo calien us obtaunsd as untewmocliaty

XReaeramgement may b pasajble

XHghty detiuatd uimgs coesn'tshow this Hdaoien

R-x
AL X3

don't gwe ths HaAion.

XHighty doactivatod wngp
ND2 HO NR3
glhues)

Daachuabd ungb cam bo ued ab Joluent.

Polyalkglatienocws duingUaoien. diaduantage..

ALK3

2)(AcRatien)
K-may bs3-1) R-x/-
A (AY3)
( O
Reac-[O) O 2)R-C-oH/H2Soy
R-
3 (Rt),0/Ald
Ha POy

Machamusm 1)Suecine Anhydida/Alclg

R-Ca
. R-c=8 R-o
R-u-AKs
O

R--0--R R R-C-o

o-H
H R-C~oH
R-C-oH OLACR3
oAL CO3
DH

u)
ACl
Vey (
impov tant Maund()) Aclu (2011-2022)
 IYDROCARBONI7)
u Catien us oblaunod as imtewmadiate

RiarHamgemand not
possyblo .
Hh achuatod
H
ung doesnt how hu utdachon.

OR--x
Sneess amourt of L nouyenr
*Aylalen sbexod ouey alkylatiem.
favmyl atien
not pbl
H COCR ALCl3,cotHU +AR3
* Gatomam Koch ReaciLPn
CHO

CoHCO
a
ANcl3
O CuCR

R-0H/ RT7H2 RcocalAAC,R-ococPlR-NHcOCH3

Acz0jPyeiciny

do neutnali tha HC

If
*Ppurcling

In
, RH
addod

than

aceipadien
wa0
wn, mass
ze

inouasos
)
is avmylalien.R4H3 than
b42 gm (-C-CH3
"Acadabion

Raachen lmoun as (SchotenBaum amn Raactien)

#F (HUnsb04 Test lA M
Ph- SOgC a9-KOH
RNH2 Pyridsre
NH-S R-
AlKal
(Hünabexg )
Raagert) Aulphonami da)

Ro-NH Ph-S02 Ce
R:N-
PsidinnRzN-o2koH
Alkal
X
Ph-So20
R3-N Pygdimo
 HYDROCARBO

t Poc) h
N19)
li
*acd to pate and dotiyuih 233 amun
A

Ph$o
(3
Amine) fithey (1Amino)
add

olidot P88 9 NadH

A Youid e
De cam also ue dyl ch!axide a 2amum

Cits
2
00.
Fomt eot Reactions
O D

OH OH NH
Zn
+Zno K2Ct201
dut,
A
(8em20quunêna)

# (Diptiatien)
Rxn-KNH2
Na N02
HCA
R-OH G 0 on

Machanum 1 Na NO2 + HC
( Ho N0 HNO2
oda
(Nitto
us Aid)
NO
2) R-NH2 R-NH- N=O R-N=N-OH
3) R-NFN-OH + HU RHM=N R-NEN
R-NNf0h2
H20
4)R4NEN
4
R-OH + N2
OH
(Maya)
R-CL (R2NA
RaNA faN-N 0
Gydlo aillydog)
RNO2R-
H20R-0H
+R-0-N0 NO2
XCanbocabon umteuma
* Reavv1angemont may bo pasaiblo
diate

edmay Avomatio Aminas fann Atable Boc

Can buaerl de dalinguish1,293 at 0-s"c
minos.
 Hdvo
caubon/19

Unimoleeulay AMomatio Nuedophilio ubstilulion

NH2
Na NO2
EN
HC,0C
CO
o+Na
&tabloat 0-s°c
* Colouwrless
*Wate doluble

os
Ph-F H8Fy Ce HCO
Ph
H20 ay
Ph-0H CuB/H8
Bei led Ha0 PhB O
Ph-NO2
HBFy
Na NO2 /u CuCN /RCA Ph-CN

Cu/HCA
oluble Ph-o
HsPOg +0 W

Colbuloss
atoy

*BDC Cu/HB Ph-By

CHg CH20 H

CtgCHO RIPh-Ti
HBFy PhN2

R-NO2
H2/ Po
EthoH
R-NH2 R-NO02 HCA R-NH2
H2 F2 R-NH-0H HeRNH2
R-NO R-N-
*3mo H2 H2

AA R-NH foH2
H

d -
R-c H
H
Sn-2e HO Sn -2
R-CH =CHSn
XH
R-CH-NH2
-CH-NH2 4
R-CH2-NH2 Lud =6

CHg CH20 A 6mol HC ,3molS

R-CH2-NH2
Sn ued
R-NO2 /R-CEN HC R-NHaR-CH2-NH2
 HYPROCAR BON(20)

FSom otheRenolens8

V20s
2s0

O vz09
Soo'C
(Maluie Anhyubido
ol
CHO

CHOgCla
HIOCNOHC)

U 2
2H20 ,o *&tand Raantion

CHS

N
CH(o GrCH3) GHO
CHO3 Oolio
Ac20 2H0 0 NH2
NO2
3 Sn HC
NO2 R
H HCA
NH2
6 HC&
NO2 NH3 HS NH2Aadecotu
L-aN7 Redn
(MHA)S Wo
(Coupln Reactien)

QH OH
ph ca
*C-NCouplung
Otamge
Sight Bae Colod Py
*Antibiotic
NFN-Ph
Sumnay
NH2
NH-NN-Ph
Ph u co9
o N-N Couplun ht Bas Phonol
aightBass
(Paxa)
NH2
NH2 6lightAide )Anilinp
Phn coG C-N Counlung (Pana)
Vedlo D
) NN-Ph
Nothung Momhon
N
Aniun
N-N-Ph
0H PhN OH
C-N Couplung-
O daut[OTo XRod-ColowtDy

H PhNa OH

n*C-N Coupling AU
Atight Base [olo
A N -Ph
 HYDROCARBON (21)

Chemuty

k)Ractivity
f
O
Naphtalene)

6R S

Carbylamim Reaction) ISoyanido Testt

* Foullbmoll
Rxn + 3H20
R-NH2 CHU3/KOH R-NC t3KC Only by L-NH2
O
Machamum- )R-NHa)+ -TH
- ca-0H
R-NH-G

a R-=C-
R-NH2
0D6 U
-H20

(
DR-NH ol Auno72l M lil il
c) R-Nfce R-N=C
QLchlayo axbene u Obtaumsd as un teumodiaty
Move e densihy on Nmwo leasily
Vattack idm oi
*endy shown b Pümay Amunp.(1°)
*L mol CHC 3 3 molés of KOH dtequuiy ed

P(RLumoH emamn Reactiom

OH OH

CHO
i)CHCR3/Na0H
i)HO 4O (Minan)
(Majo) CHO

oNa
CHO3/NgOH Intewmadialo
o LD/ ROS
CHd2
Aubstitalod
Bemzal Chloide

ONa oNa
2) CHCR2 C20
C LonieChalatien
OJ
 HYOROCARBON/22)
Di-chlavocwbene us obtaumad as intexmadyato. JUNSAA4
*ctho s maj@y pHoduot duw to ionic chelato
Anothor intewmediato s substitusd Bunaal Chwaxids
* allpasilionsax blockad then attaok yrom Pona

# (KolbeReaotisn)
OH
OH
CO0H add
*Salicylie
NaOH
+Co2
H

O
O
a
Basie mduum s gwen umow as of bemzen
nueleophilicily
bacauss CO2

wenk alacbi
ophil
tho dubstiiutbd s ma@ pHooluct bicusa uo nie chalahen.
We com also ust (CCA)unstead oCO2
(Ouidation with Hot RMnOy)
ut ww e od
has amyH O RHOs enthom Conu

Bemzylic Canben
Ban2ofc acid.
C00H \OA
CH3
RMnOy,kDH /A
fo CH3 Hot KMnDy
CooH

CODH
CH2CH3 1
2) oCH3 oCH3
 HYDRO CAR BON (23)

(Pexozid keta Khayash eet

H&y

Roactien
HAH
(Phcoa)

Machanum 3-Ph--ofo-2- h 2Ph-0 Ph +Co2

T

2 Ph +H8

(3) B ()moa tabldua de stablihy o

Popepation)K
(n Hadical.

9 8B H-B ,B &y

paR Radical untewma oliatn obtainod

Enample o
Anamaxkovnikou
u s
Radieal adelitionseaotion

addibien unvolued.

HU HI doest show pyozide ect.

*f Radical Intevmu diata omud /bbtaimed.
X
enanplo of
Kimatie otopue
u eotHadical ubsbihibion
w obaewed (C-H)C-D)-T)

N8S 3
substitubs only allylie Benzylic
pasition Av 3Ph-c<
* Puwra NBS us Jmat bo HB Bx2 s added as
impuuty

B
NBS
a-S(T-S)
t2) b= 9(Steuo)
h)
(c 8(cc)
Bbt h B (9
d 5(Frachon)

B
(13)

POmahon
ytydbocakbon)

0)HydbvolyuoCobidas
*AR Ca+ H20 4A(oH)2+3Hi2 (CHu)

*Mg2Cg Ha0 + 2 2 Mg (oH)2 +CaHy (CHg-CECH)

+ Ca H2 (ethyna)
* Ca C2 +H20 ca (OH)2

Be2 C + H20 2 Be(0H)2 +CHy

6) Aomatiuation

)8 Red Hot fe Tubt

HCECH (o), (Bem2ea)
CH3

CHt-C ECH HoC -CH3 (Maibylama)

*CHa-CEC-CHa Hezomstl Bem2enu)
(1,1,3,4,5,6-
)Bu Ae,A a
Palc
Pd/C
Pd/c-

|O+ 2H2 w l
2H2
N H2

*O 2H2

i)By Al0s/C0a/Mo Og3

(o CH3
LCHs
CH CH o

CH3
) CH3

CH3

C)Tsomeahon
Alcls
H,
8-
(mao
HC o CH3

may@
(maqa)

(fenchons tydhoCarbons)

a)Combution
CxHy+)o2 xCOg +H 0
b) B KMnOy, D (only toith 3-H)
KMnO4 OH(Teiox Budanol)
C)Nbraion
NO2
NO2 + CH3 NO2 + &tNO 2
HNO3
A
d)AudphonizuDnR
SOgH (

Ha$04 + SegH

e) Thcomp.latoCombustion

CHy +02 Cs)+2H20()

RoactiDn wth TeuminaALkyne
1) HCECH 20
OH
2) HCECH u2U2
NHyDH

3) HCECH Cu22
Nh4C

Contby@Wacd xidation
Cu CH304 (Mthanol)
1) CHy+02
(s23 K)
0H CH2=0
2) CHy +02 MOg03
MO203 CHL
CH2~0H (Aldehyde)

0H
MoCHsc092, cH-OH CHaCoOH(thamoic acid)
3)CH-CH3+O2 OH
CH3

steam
hReaction toth

CHy +Ha0 Co +3H2

) Pprolysis(Oxaeking)

13
CyH3
6Hi2 + H2
+C2H6
CH4 C3H +CaHyt CHy

2)Ci26 CyH6C7H16 +CsHio +othas